This safety data sheet provides information on Aviation Turbine Fuel A1. It lists the product name and description, identifies the supplier, and provides the supplier's contact information. The document describes the product as hazardous, flammable, and toxic. It may cause skin and eye irritation, drowsiness/dizziness, and is suspected of causing cancer. In the event of a spill, the document outlines protective measures, notification procedures, and advice for emergency responders.
This safety data sheet provides information on Aviation Turbine Fuel A1. It lists the product name and description, identifies the supplier, and provides the supplier's contact information. The document describes the product as hazardous, flammable, and toxic. It may cause skin and eye irritation, drowsiness/dizziness, and is suspected of causing cancer. In the event of a spill, the document outlines protective measures, notification procedures, and advice for emergency responders.
This safety data sheet provides information on Aviation Turbine Fuel A1. It lists the product name and description, identifies the supplier, and provides the supplier's contact information. The document describes the product as hazardous, flammable, and toxic. It may cause skin and eye irritation, drowsiness/dizziness, and is suspected of causing cancer. In the event of a spill, the document outlines protective measures, notification procedures, and advice for emergency responders.
This safety data sheet provides information on Aviation Turbine Fuel A1. It lists the product name and description, identifies the supplier, and provides the supplier's contact information. The document describes the product as hazardous, flammable, and toxic. It may cause skin and eye irritation, drowsiness/dizziness, and is suspected of causing cancer. In the event of a spill, the document outlines protective measures, notification procedures, and advice for emergency responders.
H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. H351: Suspected of causing cancer. H411: Toxic to aquatic life with long lasting effects.
Precautionary Statements:
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. -- No smoking. P233: Keep container tightly closed. P240: Ground / bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, and lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P261: Avoid breathing mist / vapours. P264: Wash skin thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves. P281: Use personal protective equipment as required. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P362: Take off contaminated clothing and wash before re-use. P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) for extinction. P391: Collect spillage. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents and container in accordance with local regulations.
Contains: KEROSENE
Other hazard information:
PHYSICAL / CHEMICAL HAZARDS Material can accumulate static charges which may cause an ignition. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited.
HEALTH HAZARDS High-pressure injection under skin may cause serious damage. May be irritating to the eyes, nose, throat, and lungs.
ENVIRONMENTAL HAZARDS No additional hazards.
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NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
This material is defined as a complex substance.
Hazardous Substance(s) or Complex Substance(s) required for disclosure Name CAS# Concentratio n* GHS Hazard Codes KEROSENE 8008-20-6 > 95 % H226, H304, H336, H351, H315, H401, H411
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
SECTION 4 FIRST AID MEASURES
INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIAN
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If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Unusual Fire Hazards: FLAMMABLE. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8.
NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen
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deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces.
Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE
HANDLING Avoid all personal contact. Do not siphon by mouth. Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices etc) in or around any fuelling operation or storage area unless the devices are certified intrinsically safe by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive,
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static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
STORAGE The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive)
Substance Name Form Limit/Standard Note Source ETHYL BENZENE TWA 20 ppm ACGIH KEROSENE Stable Aerosol. TWA 5 mg/m3 ExxonMobil KEROSENE Vapour. TWA 200 mg/m3 ExxonMobil KEROSENE [as total hydrocarbon vapor]
Non-Aeroso l TWA 200 mg/m3 Skin ACGIH NAPHTHALENE STEL 15 ppm Skin ACGIH NAPHTHALENE TWA 10 ppm Skin ACGIH
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation. Organic
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For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves. Nitrile,Viton
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical / oil resistant clothing if contact with material is likely.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.
ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION Physical State: Liquid Colour: Colourless Odour: Petroleum/Solvent Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.75 - 0.85 Flammability (Solid, Gas): N/A Flash Point [Method]: 38C (100F) - 45C (113F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 5.0 Autoignition Temperature: 250C (482F) Boiling Point / Range: 150C (302F) - 300C (572F)
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Decomposition Temperature: N/D Vapour Density (Air = 1): 4.5 at 101 kPa Vapour Pressure: 0.064 kPa (0.48 mm Hg) at 20 C Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: <1 cSt (1 mm2/sec) at 40C | <8 cSt (8 mm2/sec) at -20C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION Freezing Point: <-40C (-40F) Melting Point: N/A Pour Point: < 0C (32F)
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
MATERIALS TO AVOID: Halogens, Strong Acids, Alkalies, Strong oxidisers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Route of Exposure Conclusion / Remarks Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs.
Ingestion Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit): Data available. Irritating to the skin. Based on test data for structurally similar materials.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
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OTHER HEALTH EFFECTS FROM SHORT AND LONG TERM EXPOSURE Anticipated health effects from sub-chronic, chronic, respiratory or skin sensitization, mutagenicity, reproductive toxicity, carcinogenicity, target organ toxicity (single exposure or repeated exposure), aspiration toxicity and other effects based on human experience and/or experimental data.
For the product itself: Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Jet fuel: Some jet fuels have potential in mice to suppress indicators of immune system functionality. The relevance of these effects to humans is uncertain.
Contains: Kerosene: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in animal tests. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain. ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain.
IARC Classification: The following ingredients are cited on the lists below:
Chemical Name CAS Number List Citations ETHYL BENZENE 100-41-4 3 NAPHTHALENE 91-20-3 3
Majority of components -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. Majority of components -- Low potential to migrate through soil.
PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be inherently biodegradable Atmospheric Oxidation: Majority of components -- Expected to degrade rapidly in air
BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
ECOLOGICAL DATA
Ecotoxicity Test Duration Organism Type Test Results Aquatic - Acute Toxicity 48 hour(s) Daphnia magna EL50 1 - 100 mg/l: data for similar materials Aquatic - Chronic Toxicity 72 hour(s) Pseudokirchneriella subcapitata NOELR 1 - 10 mg/l: data for similar materials Aquatic - Acute Toxicity 72 hour(s) Pseudokirchneriella subcapitata EL50 1 - 100 mg/l: data for similar materials Aquatic - Acute Toxicity 96 hour(s) Oncorhynchus mykiss LL50 1 - 100 mg/l: data for similar materials Aquatic - Chronic Toxicity 21 day(s) Daphnia magna NOELR 0.48 mg/l: data for similar materials
Persistence, Degradability and Bioaccumulation Potential Media Test Type Duration Test Results Water Ready Biodegradability 28 day(s) Percent Degraded < 60 : similar material
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
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Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
LAND Proper Shipping Name: FUEL, AVIATION, TURBINE ENGINE Hazard Class: 3 Hazchem Code: 3Y UN Number: 1863 Packing Group: III Label(s) / Mark(s): 3, EHS
SEA (IMDG) Proper Shipping Name: FUEL, AVIATION, TURBINE ENGINE Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1863 Packing Group: III Marine Pollutant: Yes Label(s): 3 Transport Document Name: UN1863, FUEL, AVIATION, TURBINE ENGINE, 3, PG III, (38C c.c.), MARINE POLLUTANT
AIR (IATA) Proper Shipping Name: FUEL, AVIATION, TURBINE ENGINE Hazard Class & Division: 3 UN Number: 1863 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1863, FUEL, AVIATION, TURBINE ENGINE, 3, PG III
SECTION 15 REGULATORY INFORMATION
This material is considered hazardous according to the classification criteria of the Hazard Classification and Communication System for Hazardous Materials BE 2555.
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS
Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, KECI, PICCS, TSCA
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N/D = Not determined, N/A = Not applicable KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only): H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2 H226: Flammable liquid and vapour; Flammable Liquid, Cat 3 H302: Harmful if swallowed; Acute Tox Oral, Cat 4 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2 H332: Harmful if inhaled; Acute Tox Inh, Cat 4 H336: May cause drowsiness or dizziness; Target Organ Single, Narcotic H351: Suspected of causing cancer; GHS Carcinogenicity, Cat 2 H400: Very toxic to aquatic life; Acute Env Tox, Cat 1 H401: Toxic to aquatic life; Acute Env Tox, Cat 2 H410: Very toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 1 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Updates made in accordance with implementation of GHS requirements.
-------------------------------------------------------------------------------------------------------------------------------------------------- --- The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly or indirectly hold any interest.