Safety Data Sheet

Crown Paraffin Oil

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifier

Product name: Crown Paraffin Oil
SDS number: CR.PARFN
Synonym(s): Fuel oil blend
1.2 Relevant identified uses of the substance or mixture and uses advised against
General use: Torch fuel
Uses advised against: Not for indoor use
1.3 Details of the supplier and of the safety data sheet
Manufacturer/Distributor
Packaging Service Co., Inc.
1904 Mykawa Road
Pearland, TX 77581-3210 USA
1-281-485-1458
1.4 Emergency telephone number
CHEMTREC: 1-800-424-9300 (USA)
CANUTEC: 1-613-996-6666 (Canada)

SECTION 2 - HAZARDS IDENTIFICATION

2.1 Classification of substance or mixture
Product definition: Mixture
Classification in accordance with 29 CFR 1910 (OSHA HCS) and Regulation EC No. 1272/2008
Aspiration Hazard - Category 1 [H304]
2.2 Label elements
Hazard symbol(s):

GHS08
Signal word: Danger
Hazard statement(s): H304 - May be fatal if swallowed and enters the airways
Precautionary statements:
[Response] P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P331 - Do not induce vomiting.
[Storage] P405 - Store locked up.
[Disposal] P501 - Dispose of contents and containers in accordance with local and national regulations.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
May cause drying and cracking of the skin. May cause drowsiness or dizziness.

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Not applicable
3.2 Mixtures
% by Weight Ingredient CAS Number EC Number Annex Number GHS Classification
100 C14-16 Normal Paraffins 90622-46-1 292-448-0 ------------ H304
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identify and exact percentage
(concentration) of composition may have been withheld. Specific chemical identity and exact percentage composition will be provided to health
professionals, employees, or designated representatives in accordance with the applicable provisions of paragraph (i).
There are no additional ingredients present in this product which, within the current knowledge of the supplier and in the concentrations applicable,
are classified as hazardous to health or the environment and hence require reporting in this section.

SECTION 4 - FIRST AID MEASURES

4.1 Description of first aid measures
Inhalation: If product fume or vapor causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. If unconscious, maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. If symptoms persist, seek medical attention.
Eyes: Immediately flush eyes with large amounts of water or saline solution for at least 15 minutes, occasionally lifting the upper and lower lids.
Remove contact lenses, if present and easy to do, after first 2 minutes and continue rinsing. If irritation persists seek medical attention, preferably

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 from an ophthalmologist.
Skin: Flush skin with large amounts of water while removing contaminated clothing. Wash the affected area with soap and water followed by
thorough rinsing. Wash contaminated clothing and shoes before reuse. If irritation persists, seek medical attention.
Ingestion: Rinse mouth with water if the victim is conscious. Remove dentures, if present. DO NOT induce vomiting unless directed to do so by
medical personnel. Vomiting may occur spontaneously. To prevent aspiration of material into the lungs, lay the victim on one side with the head
lower than the waist. Never give anything by mouth to an unconscious or convulsing person. Do not leave the victim unattended. Seek immediate
medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Potential health symptoms and effects
Eyes: May cause eye irritation with redness, discomfort and tearing.
Skin: Prolonged and repeated contact with unprotected skin may cause skin irritation with localized redness, itching and discomfort.
Inhalation: Vapor from this product may cause irritation of the nose, throat and lungs. May be harmful if inhaled. Exposure to high concentration
of vapor may result in central nervous system depression with headache and stupor.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting abdominal pain and diarrhea. May cause headache, dizziness and central
nervous system depression. Aspiration of material during swallowing or vomiting can result in lung inflammation or other lung injury.
Chronic: Pre-existing disorders of the skin and respiratory system may be aggravated by exposure to this product. Prolonged and repeated skin
exposure may result in drying or defatting of skin and dermatitis.
4.3 Indication of any immediate medical attention and special treatment needed
Advice to doctor and hospital personnel
Treat symptomatically and supportively

SECTION 5 - FIRE FIGHTING MEASURES

5.1 Extinguishable media
Suitable methods of extinction: Use extinguishing media such as water spray or fog, carbon dioxide, foam and dry chemical.
Unsuitable methods of extinction: Water jets or streams may spread the fire.
5.2 Special hazards arising from the substance or mixture
Combustible liquid at high temperatures. Closed containers may explode due to the buildup of pressure when exposed to extreme heat. During
emergency conditionsoverexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent or may
be delayed. Obtain medical attention.
Explosion hazards: Not expected to be an explosion hazard.
5.3 Advice for firefighters
Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent
pressure buildup and possible autoignition or explosion when exposed to extreme heat. If possible, firefighters should control runoff water to
prevent environmental contamination.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Evacuate non-essential personnel. Wear appropriate protective clothing and equipment designated in Section 8.2. Ventilate the area. Remove
all sources of ignition. No smoking. Clean up spills immediately. Spill creates a slip hazard.
6.2 Environmental precautions
Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways.
6.3 Methods and materials for containment and cleaning up
DO NOT flush the spill down the drain. Approach spill from upwind direction. Cover drains and contain spill. Cover spill with a large quantity
of inert absorbent. Do not use combustible material such as sawdust. Collect material using non-sparking tools and place into an approved
container for proper disposal. Observe possible material restrictions (Sections 7.2 and 10.5). Do not allow material or runoff from rinsing
contaminated areas to enter floor drains or storm drains and ditches that lead to waterways. Dispose of via a licensed waste disposal contractor.
If spilled on water remove with appropriate methods (e.g. skimming, booms or absorbents).
This product is classified as an oil under Section 311 of the Clean Water Act (CWA) and under the Oil Pollution Act (OPA). In the USA discharges
or spills of material on waters of the United States, their adjoining shorelines or into conduits leading to surface waters must be reported to the
National Response Center at 800-424-8802.
6.4 Reference to other sections
For indications about waste treatment, see Section 13.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for safe handling
Wear all appropriate personal protective equipment specified in Section 8.2. Do not get in eyes or on skin or clothing. Do not inhale fume or vapor.
No smoking. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash
contaminated clothing and shoes thoroughly before reuse.
Advice on protection against fire and explosion
Avoid exposure to high temperatures, hot surfaces and sources of ignition.
7.2 Conditions for safe storage, including any incompatibilities
Store in dry, cool, well-ventilated areas away incompatible materials (see Section 10.5), food and drink. Transfer only to approved containers
having correct labeling. Keep containers tightly closed when not in use. Protect containers against physical damage. Containers that have been
opened must be carefully resealed and kept upright to prevent spillage. Containers are hazardous when empty as they contain product residues.

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 Use appropriate containment to avoid environmental contamination. Ventilate closed areas. Do not take internally. Keep out of reach of children.
7.3 Specific end uses
Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective
equipment. Use adequate ventilation. Local exhaust is preferable. Refer to Section 7.1.
Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be
selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance
of the protective equipment should be enquired at the representative supplier.
Hygiene measures: Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminated
clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking, smoking or using the lavatory.
Eye/face protection: Wear safety glasses with unperforated side shields or protective splash goggles during use.
Hand Protection: Wear chlorinated polyethylene (CPE) gloves or those recommended by glove supplier for protection against materials in Section 3.
Gloves should be impermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period.
Skin protection: Wear protective clothing. Wear protective boots if the situation requires.
Respiratory protection: Always use an approved respirator when vapor/aerosols exceed exposure limit values. Where risk assessment shows
air-purifying respirators are appropriate use a half mask respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator
cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA
respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.
Environmental exposure controls: Do not empty into drains.
PPE must not be considered a long-term solution to exposure control. PPE usage must be accompanied by employer programs to properly select,
maintain, clean fit and use. Consult a competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure
adequate protection.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance Clear, colorless, oily liquid
Odor Hydrocarbon
Odor Threshold No data available
Molecular Weight No data available
Chemical Formula No data available
pH No data available
Freezing/Melting Point, Range 4 °C (39 °F)
Boiling Point Range 248 - 284 °C (478 - 544 °F)
Evaporation Rate No data available
Flammability (solid, gas) Not applicable
Flash Point Range 118 °C (244 °F) PMCC
Autoignition Temperature 204 °C (400 °F)
Decomposition Temperature No data available
Lower Explosive Limit (LEL) 0.5% (v)
Upper Explosive Limit (UEL) 4.7% (v)
Vapor Pressure <0.1 mm Hg @ 20 °C
Vapor Density 7.1 (Air = 1)
Specific Gravity 0.768 @ 16 °C
Density 0.768 g/ml (6.41 lb/gal)
Viscosity 2.3 - 5.5 cSt @ 40 °C
Solubility in Water Negligible
Partition Coefficient: n-octanol/water log Pow = 3 - 6 [estimated]
Oxidizing Properties Not applicable
Explosive Properties Not applicable
Volatiles by Weight @ 21 ºC 100
9.2 Other data
Flammability Classification IIIB

SECTION 10 - STABILITY AND REACTIVITY

10.1 Reactivity
This product is stable under normal handling and use.

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 10.2 Chemical stability
This material is stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4 Conditions to avoid
High temperatures, hot surfaces, sources of ignition and contact with incompatible materials.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Thermal decomposition products include oxides of carbon, hydrocarbons and hydrocarbon fragments.

SECTION 11 - TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute oral toxicity
LD50 rat: >2,000 mg/kg
Acute inhalation toxicity
LC50 rat: >5.8 mg/l, 4 h
Acute dermal toxicity
LD50 rabbit: >2,000 mg/kg
Skin irritation
May cause skin irritation.
Eye irritation
May cause eye irritation.
Sensitization
No data available
Genotoxicity in vitro
No data available
Mutagenicity
No data available
Specific organ toxicity - single exposure
May cause drowsiness or dizziness. May cause irritation of the respiratory system.
Specific organ toxicity - repeated exposure
May cause damage to the central nervous system.
Aspiration hazard
May be fatal if swallowed and enters the airways
11.2 Further information
No component of this product present at levels greater than or equal to the 0.1% threshold (de minimis) is identified as a probable, possible,
potential or confirmed carcinogen by IARC, ACGIH, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of this
product, nor is there any available data that indicated that it caused adverse developmental or fertility effects.
Handle in accordance with good industrial hygiene and safety practice.

SECTION 12 - ECOLOGICAL INFORMATION

12.1 Toxicity
This product contains components that are potentially toxic to freshwater and salt water ecosystems. The fuel oils in this product are not toxic to
fish but may coat gill structures resulting in suffocation if spilled in shallow, running water. They may be moderately toxic to amphibians by
preventing dermal respiration. They may cause gastrointestinal distress to birds and mammals through ingestion during pelage grooming. If
applied to leaves, distillates may kill grasses and small plants by interfering with transpiration and respiration.
12.2 Persistence and degradability
Organic materials in this product are expected to biodegrade over time.
12.3 Bioaccumulation potential
This material has the potential to bioaccumulate.
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
Additional ecological information
Do not allow material to run into surface waters, wastewater or soil.
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

SECTION 13 - DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Methods of disposal: The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some

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 product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff
and contact with soil, waterways, drains and sewers.
RCRA P-Series: No listings
RCRA U-Series: No listings

SECTION 14 - TRANSPORT INFORMATION

Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations
TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials
and methods of shipping.
USA DOT (Ground Transportation) - Bulk and Non-bulk
Not regulated for transport
IMO/IMDG (Water Transportation)
Not regulated for transport (Consult IMO regulations before transporting ocean bulk.)
ICAO/IATA (Air Transportation)
Not regulated for transport
RID/ADR (Rail Transportation)
Not regulated for transport
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
U. S. Federal Regulations
OSHA Hazard Communication Standard: This material is classified as hazardous in accordance with OSHA 29 CFR 1910-1200.
OSHA Process Safety Management Standard: This product is not regulated under OSHA PSM Standard 29 CFR 1910.119.
EPA Risk Management Planning Standard: This product is not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.
EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150.
Toxic Substance Control Act (TSCA) Inventory: All of the components of this product are either listed or exempt from listing on the TSCA
Inventory. It is not subject to TSCA 12(b) Export Notification.
Drug Enforcement Administration (DEA) List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.4(f)(2)) and Chemical Code Number
None listed
Drug Enforcement Administration (DEA) Lists 1 & 2, Exempt Chemical Mixtures (21 CFR 1310.12(c)) and Code Number: None listed
Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (CFATS) Chemicals: None listed
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: Acute Health Hazard
SARA 313 Information: None of the components of this product exceed the threshold (de minimis) reporting requirements of Section 313 of
the Emergency Planning and Community Right-to Know Act of 1986.
SARA 302/304 Extremely Hazardous Substance: No components of the product exceed the threshold (de minimis) reporting levels
established by of these sections of Title III of SARA.
SARA 302/304 Emergency Planning & Notification: No components of the product exceed the threshold (de minimis) reporting levels
established by of these sections of Title III of SARA.
Comprehensive Response Compensation and Liability Act (CERCLA): This product contains no CERCLA reportable substances.
Clean Air Act (CAA)
This product does not contain any substances listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112(b).
This product does not contain any Class 1 Ozone depletors.
This product does not contain any Class 2 Ozone depletors.
Clean Water Act (CWA)
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
The components of this product are classified as oils under Section 311 of the CWA and the Oil Pollution Act (OPA) of 1990.
U.S. State Regulations
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
This product contains no chemical(s) known to the State of California to cause cancer, birth defects or other reproductive harm.
Combustion products emitted when this product is burning may contain substances known to the state of California to cause cancer, birth defects
or reproductive harm.
Other U.S. State Inventories
None of the components of this product are listed on any State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air
Pollutants lists.
Canada
WHMIS Hazard Symbol and Classification: Combustible liquid. May be fatal if swallowed and enters the lungs.
Canadian National Pollutant Release Inventory (NPRI): None of the components of this product are listed on the NPRI.
European Economic Community
WGK, Germany (Water danger/protection): 1 (low hazard to waters)

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 Global Chemical Inventory Lists
Country Inventory Name Inventory Listing*
Canada Domestic Substance List (DSL) Yes
Canada Non-Domestic Substance List (NDSL) No
Europe Inventory of New and Existing Chemicals (EINECS) Yes
United States Toxic Substance Control Act (TSCA) Yes
Australia Australian Inventory of Chemical Substances (AICS) No
New Zealand New Zealand Inventory of Chemicals (NZIoC) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
Philippines Philippines Inventory of Chemicals and Chemical Substances (PICCS) No
*Yes - All components of this product are in compliance with the inventory requirements administered by the governing country.
No - One or more components of this product are not on the inventory or are exempt from listing.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out.

SECTION 16 - OTHER INFORMATION

Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA)

Health 1
Flammability
HMIS Hazard Rating Legend
Flammability 1 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious

Physical Hazard 0
4 = Severe * = Chronic Health Hazard 1
Personal Protection B NFPA Hazard Rating Legend
Health 1 0 Instability
0 = Insignificant 1 = Slight 2 = Moderate
B = Safety glasses and gloves 3 = High 4 = Extreme

Special
Abbreviation Key
ACGIH American Conference of Governmental Industrial Hygienists mppcf Millions of Particles Per Cubic Foot
ADR Accord Dangereux Routier (European regulations NA North America
concerning the international transport of dangerous NAERG North American Emergency Response Guide Book
by road) NIOSH National Institute for Occupational Safety
CAS Chemical Abstract Services NTP National Toxicology Program
CFR Code of Federal Regulations OSHA Occupational Safety and Health Administration
DOT Department of Transportation PBT Persistent, Bioaccumulating and Toxic
EMS Guide Emergency Response Procedures for Ships PEL Permissible Exposure Limit
Carrying Dangerous Goods PMCC Pensky-Martens Closed Cup
EPA Environmental Protection Agency ppm Parts Per Million
ERG Emergency Response Guide Book RCRA Resource Conservation and Recovery Act
FDA Food and Drug Administration RID Dangerous Goods by Rail
GHS Globally Harmonized System of Classification and RQ Reportable Quantity
Labelling of Chemicals (GHS) TCC/Tag Tagliabue Closed Cup
HCS Hazard Communication Standard TLV Threshold Limit Value
IARC International Agency for Research on Cancer TSCA Toxic Substance Control Act
IATA International Air Transport Association TWA Time-Weighted Average
ICAO International Civil Aviation Organization UN United Nations
IDLH Immediately Dangerous to Life and Health VOC Volatile Organic Compounds
IMDG International Maritime Dangerous Goods vPvB Very Persistent and Very Bioaccumulating
IMO International Maritime Organization WHMIS Workplace Hazardous Materials Information System

DISCLAIMER OF RESPONSIBILITY
The information on this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test
data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume damage or expense arising out of or in any way responsibility and expressly
disclaim liability for loss, connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product,
this SDS information may not be applicable.
Revision Date: 12 January 2018

<end of document>

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