Safety Data Sheet: Naphta Feedstock

Safety data sheet
NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 1/18
Revised : 01/03/2014
Supersedes : 01/08/2013
Version (en) nr : 13.3
GHS02
GHS08
GHS07
GHS09
1. Identification of the substance / mixture and of the company / undertaking

1.1. PRODUCT IDENTIFIER
Naphta (petroleum), full-range straight-run.
Trade name
NAPHTA FEEDSTOCK
SDS number
ATOF-030
Other names
64741-42-0
CAS number
64741-42-0
EINECS or ELINCS number
265-042-6
INDEX nr
649-265-00-X
Reach Number
Total Petrochemicals & Refining (01-2119474679-18-0034)
1. 2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE AND USES ADVISED AGAINST

Manufacture of substance
Distribution of substance
Formulation & (re)packing of substances and mixtures
Synthesis intermediate product
For the detailed uses of the product see annex of the safety data sheet
Recommended uses
Recommended to professional users
1.3. DETAILS OF THE SUPPLIER OF SAFETY DATA SHEET

Trade name of the firm
see below this page.

Email address: rc.fer-sds@total.com (For LOR: rm.gbmsds@total.co.uk)
( Safety data sheet )
1.4. EMERGENCY TELEPHONE NUMBER
Emergency call Carechem 24 International :

for English speaking countries: +44 (0) 1235 239 670
for Europe (in local languages): + 33 1 49 00 00 49
for Africa and Middle East: + 44 (0) 1235 239 671 for China:
+ 86 10 5100 3039 (to/from China) / + 86
532 8388 9090 (within China) for Asia Pacific (Hong-Kong,
Singapore, Taiwan, Philippines, India, Vietnam, Sri Lanka, Japan,
Korea, Malaysia, Indonesia, Thailand) :
+ 65 3158 1074
Official advisory body
UK: National Poisons Emergency Number: 0845 4647

IRL: National Poisons Information Centre
PO Box 1297, Beaumont Hospital, Beaumont Road
Dublin 9.
REFINING & CHEMICALS BRANCH
TOTAL PETROCHEMICALS & REFINING SA/NV
rue de l'Industrie 52 Nijverheidsstraat
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 2/18
Revised : 01/03/2014
Telephone: + 00 353 (0)1 809 2566 / + 00 353 (0)1 837 9964
2. Hazards identification
Dangerous substances
2.1. Classification of the substance

EC-GHS (CLP)
Classification according to the regulation EC 1272/2008 (EC-GHS) and

ATP
Class
Flam. Liq. 2
Asp. Tox. 1
Skin Irrit. 2
STOT SE 3
Muta. 1B
Carc. 1B
Repr. 2
STOT RE 2
Aquatic Chronic 2
H Phrase(s)
H225, H304, H315, H336, H340, H350, H361d, H361f, H373, H411
67/548/EEC & 1999/45/EC
Classification according to directives 67/548/EEC and 1999/45/EC.
Symbol(s) EC
F : Highly flammable
T : Toxic
N : Dangerous for the environment
EU: Carcinogen category 2: the substance is probably carcinogenic to
humans
EU: Mutagen category 2: the substance is probably mutagenic to
humans.
EU: Substances toxic to reproduction Category 3
R Phrase(s)
R 11 :Highly flammable.
R 38 :Irritating to skin.
R 45 :May cause cancer.
R 46 :May cause heritable genetic damage.
R 48/20/21/22 :Harmful :danger of serious damage to health by
prolonged exposure through inhalation , in contact with skin and if
swallowed
R 51/53 :Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
R 62 :Possible risk of impaired fertility.
R 63 :Possible risk of harm to the unborn child.
R 65 :Harmful: may cause lung damage if swallowed.
R 67 :Vapours may cause drowsiness and dizziness
S Phrase(s)
S 16 :Keep away from sources of ignition - No smoking.

S 23 :Do not breathe gas / fumes / vapour / spray
S 24 :Avoid contact with skin.
S 45 :In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 :Avoid exposure - obtain special instructions before use.
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 3/18
Revised : 01/03/2014
S 61 :Avoid release to the environment. Refer to special instructions /

safety data sheets.
S 62 :If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.
Main hazards
Highly flammable
Carcinogenic
May cause heritable genetic damage.
Dangerous for the environment
Adverse human health effects

Inhalation
Harmful by inhalation
narcotic in case of inhalation of high concentration of vapour
Skin contact
Harmful in contact with skin.

Irritating to skin
Eye contact
Contact with the liquid or exposure to vapours can be irritating to eyes.
Ingestion
Harmful if swallowed.
In case of accidental swallowing, due to its low viscosity, the product
may be aspired into the lung and induce a chemical pneumonitis
developing over a few hours
A medical surveillance is required for 48 hours
Adverse environmental effects
Toxic to aquatic organisms

Contains substances which may be dangerous for the aquatic
environment.
Adverse physicochemical effects
Highly flammable
In use, may form flammable / explosive vapour-air mixture.
the vapour is heavier than air and explosive mixtures can accumulate
in low spots: it may be ignited at some distance away from the spill
resulting in flashbacks.
flowing product can create electrostatic charge, resulting sparks may
ignite or cause an explosion.
2.2. Label elements

EC-GHS (CLP)
Classification according to the regulation EC 1272/2008 (EC-GHS) and

ATP
Signal word
Danger
Pictogram(s)
GHS02, GHS08, GHS07, GHS09
H Phrase(s)
H225
H304
H315
H336
H340
H350
Highly flammable liquid and vapour.

May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause drowsiness or dizziness.
May cause genetic defects
May cause cancer

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 4/18
Revised : 01/03/2014
H361d - Suspected of damaging the unborn child

H361f - Suspected of damaging fertility
H373 - May cause damage to organs through prolonged or repeated
exposure
H411 - Toxic to aquatic life with long lasting effects.
P Phrase(s)
P201 - Obtain special instructions before use.

P210 - Keep away from heat/sparks/open flames/hot surfaces. No
smoking.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face
protection.
P301/310 - IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P331 - Do NOT induce vomiting.
P303/361/353 - IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P309/311 - IF exposed or if you feel unwell: Call a POISON CENTER
or doctor/physician.
P403/235 - Store in a well-ventilated place. Keep cool.
2.3. Other hazards
no information available
3. Composition / information on ingredients

3.1. Substances (chemical name)
Concentration (%)
100 %
CAS number
64741-42-0
265-042-6
EC-GHS (CLP)
Class
Flam. Liq. 2, H225

Asp. Tox. 1, H304
Skin Irrit. 2, H315
STOT SE 3, H336
Muta. 1B, H340
Carc. 1B, H350
Repr. 2, H361d, H361f
STOT RE 2, H373
Aquatic Chronic 2, H411
67/548/EEC & 1999/45/EC

Symbol(s)
F
T
N
EU: Carcinogen category 2: the substance is probably carcinogenic to
humans
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 5/18
Revised : 01/03/2014
humans.
EU: Substances toxic to reproduction Category 3:
Substances which cause concern for human fertility or which cause
concern for humans owing to possible developmental toxic effects
R Phrase(s)
11-38-45-46-48/20/21/22-51/53-62-63-65-67
Substances presenting a health hazard

Name:
Pentane
Concentration (%)
< 35%
CAS number
109-66-0
203-692-4
EC-GHS (CLP)
Class
Flam. Liq. 2, H225

Asp. Tox. 1, H304
STOT SE 3, H336
EUH066
67/548/EEC & 1999/45/EC

Symbol(s)
F+
Xn
N
R Phrase(s)
12-51/53-65-66-67
Name:
n-Hexane
Concentration (%)
< 21%
CAS number
110-54-3
203-777-6
INDEX nr
601-037-00-0
EC-GHS (CLP)
Class
Flam. Liq. 2, H225

Asp. Tox. 1, H304
Skin Irrit. 2, H315
STOT SE 3, H336
Repr. 2, H361f
STOT RE 2, H373
67/548/EEC & 1999/45/EC

Symbol(s)
F
Xn
N
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 6/18
Revised : 01/03/2014

R Phrase(s)
11-38-48/20-51/53-62-65-67
Name:
Toluene
Concentration (%)
< 12%
CAS number
108-88-3
203-625-9
INDEX nr
601-021-00-3
EC-GHS (CLP)
Class
Flam. Liq. 2, H225

Asp. Tox. 1, H304
Skin Irrit. 2, H315
STOT SE 3, H336
Repr. 2, H361d
STOT RE 2, H373
67/548/EEC & 1999/45/EC

Symbol(s)
F
Xn
R Phrase(s)
11-38-48/20-63-65-67
Name:
Benzene
Concentration (%)
< 5%
CAS number
71-43-2
200-753-7
INDEX nr
601-020-00-8
EC-GHS (CLP)
Class
Flam. Liq. 2, H225

Asp. Tox. 1, H304
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Muta. 1B, H340
Carc. 1A, H350
STOT RE 1, H372
67/548/EEC & 1999/45/EC

Symbol(s)
F
T
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 7/18
Revised : 01/03/2014
EU: Carcinogen category 1:substance carcinogenic to human

humans.
R Phrase(s)
11-36/38-45-46-48/23/24/25-65
H Phrase(s) used
some of the components of this mixture are classified and have hazard
statements (H), but only their code are indicated in this rubric. you may
find the full text of them in rubric 16.
R Phrase(s) used
some of the components of this preparation are classified following the

European directives and have risk phrases (R), but only their code are
indicated in this rubric.
you may find the full text of them in rubric 16.
4. First-aid measures
4.1. Description of first aid measures
General instructions
Warning ! Flammable liquid
IN CASE OF HEAVY OR PERSISTENT DISTURBANCES, CALL A DOCTOR OR SEEK MEDICAL ADVICE URGENTLY
Route of exposure
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
seek medical advice immediately.
if necessary, give oxygen
Check for possible heart rate problems
if breathing has stopped: administer artificial respiration.
Keep under medical surveillance
Skin contact
Take off immediately all contaminated clothing

after contact with skin, wash immediately with plenty of water, for at
least 15 minutes.
in case of serious contamination, seek immediate hospital treatment
Eye contact
Do not wear contact lenses in any work area.

flush immediately with plenty of water, holding the eyelids open
Get medical advice (ophthalmologist)
Ingestion
give nothing to drink and do not induce vomiting (risk of pulmonary

aspiration).
Risk of serious damage if inhaled into lungs, (caused e.g by vomiting),
seek medical advice urgently.
If swallowed, rinse mouth with water (only if the person is conscious)
Protective equipment for first-aiders
if exposure is likely to exceed the occupational exposure limit, in a

ventilated space, use an approved respiratory protective equipment; in
confined space, use a autonomous breathing apparatus.
4.2. Most important symptoms and effects, both acute and delayed
refer to 11 for more details on effects.
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 8/18
Revised : 01/03/2014
4.3. Indication of any immediate medical attention and special treatment needed
5. Fire - fighting measures

Technical measures
call the safety and environment service immediately.

evacuate non-essential personnel
use fine spray or fog to control fire by preventing its spread and
absorbing some of its heat.
5.1. Extinguishing media

Suitable
carbon dioxide (CO2), dry chemicals, foam.
Not to be used
do not use water jets (stick jets) for extinguishing fire since they could
help to spread the flames
5.2. Special hazards arising from the substance
complete combustion, with an excess of oxygen forms: carbon dioxide

(CO2), water vapour
partial combustion forms also: carbon monoxide (CO), soot and
cracked products: aldehydes, ketones , carbon , polycyclic aromatic
hydrocarbons (PCA or PAH) , etc...
Special exposure hazards
fire may cause pressure rise with risk of bursting and subsequent
explosion
spreading of fire- and explosion hazard by liquid layers on the water
surface
5.3. Advice for firefighters

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
where exposure is likely, protective clothing must be worn including

gloves
goggles/spectacles
Avoid contact with skin and eyes and inhalation.
For emergency responders
wear suitable breathing equipment, in case of risk of exposure to

vapour or fumes.
6.2. Environmental precautions

installations must be designed to avoid accidental spill on soil and
water.
avoid discharge of the material in a stream or a sewerage system or
cause ground contamination.
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 9/18
Revised : 01/03/2014
6.3. Methods and material for containment and cleaning up

call the safety and environment service immediately.
evacuate non-essential personnel
avoid proximity or contact with hot surfaces, flames, electrostatic
charges or sparks.
no smoking
maintain the level of gases under the explosion limits by artificial
aeration.
on soil
containment and recovery by physical means.

never use dispersant.
take up small spills with dry chemical absorbent.
absorb product with an adequate material such as paper, rags,
sawdust,...
dispose safely in accordance with local or national regulations.
on water
use floating absorbent material to be removed mechanically.

if the material has been discharged into a stream or a sewerage
system, inform the authorities
dispose safely in accordance with local or national regulations.
6.4. refer to points 8 and 13
7. Handling and storage

Important
refer to any national measures that may be relevant.
7.1. Precautions for safe handling

handle under adequate ventilation
In use, may form flammable / explosive vapour-air mixture.
avoid producing or diffusing fumes, vapour or spray into the air.
(particulary during loading or unloading product)
gloves
Instructions for use
cleaning, inspection and maintenance of storage tanks requires the

implementation of strict procedures
working has to be made only on cold, degassed and ventilated storage
tanks. (risk of explosive atmosphere)
take precautionary measures against static discharge during blending
and transfer operations.
Use product only in a closed system.
use explosion proof electrical equipment
Do not use air for transfers
Use a slow speed of circulation (static electricity risk)
Take appropriate measures in case the use or processing of the
product forms stable emulsions with water
7.2. Conditions for safe storage, including any incompatibilities

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 10/18
Revised : 01/03/2014
can form explosive mixture with air particularly in empty uncleaned

receptacles
use only containers, joints, pipes, etc...made in a material suitable for
use with hydrocarbons.
store away from heating source. avoid static electricity build up with
connection to earth.
Keep away from sources of ignition - No smoking.
keep in a well-ventilated place.
Retain in the original container; if other containers are used: transfer, if
necessary, all labelling information to the new container
installations must be designed to avoid any propagation of burning
slick.
Incompatible materials
avoid contact with strong oxidizing materials, acids and bases
container
Suitable
stainless steel
7.3. SPECIFIC USE(S)
Recommended to professional users

For the detailed uses of the product see annex of the safety data sheet
refer to point 8
8. Exposure controls / personal protection

8.1. CONTROL PARAMETERS
OCCUPATIONAL EXPOSURE LIMIT
Benzene:
UK: HSE EH40/2007:
Long-term exposure limit (8-hour TWA reference period) : 1 ppm - 3.25
mg/m
IRL(2007): OEL (8h): 1 ppm - 3 mg/m
EC (1999): 1 ppm - 3.25 mg/m
US (ACGIH-2012): TLV-8h TWA: 0.5 ppm - 1.6 mg/m ; TLV-15 min
STEL: 2.5 ppm - 8 mg/m
Toluene:
UK: HSE EH40/2005:
Long-term exposure limit (8-hour TWA reference period) : 50 ppm - 191
mg/m
Short-term exposure limit (15-minute reference period): 150 ppm - 574
mg/m
IRL(2002): OEL (8h): 50 ppm - 188 mg/m ; (15 min): 150 ppm - 560
mg/m
US (ACGIH-2012): TLV 8h TWA: 20 ppm - 75 mg/m
EC (2006): VL (8h): 50 ppm - 192 mg/m ; (15 min) : 100 ppm - 384
mg/m
n-Hexane:
UK: HSE EH40/2007:
Long-term exposure limit (8-hour TWA reference period) : 20 ppm - 72
mg/m
IRL(2007): OEL (8h): 20 ppm - 70 mg/m
US (ACGIH-2012): TLV-8 h TWA: 50 ppm - 176 mg/m

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 11/18
Revised : 01/03/2014
EC (2006): VL (8h): 20 ppm - 72 mg/m

Pentane, all isomers:
US (ACGIH-2012): TLV-8 h TWA: 600 ppm - 1770 mg/mGB(2007):
TWA (8h): 600 ppm - 1800 mg/m
EC (2006): VL (8h): 1000 ppm - 3000 mg/m
DNEL
Exposure controls (workers):

DNELacute inhalation = 1300 mg/m/15 min. (Low Boiling Point
Naphtha, systemic effects)
DNELacute inhalation = 1100 mg/m /15 min. (Low Boiling Point
Naphtha, local effects)
DNELlong-term inhalation = 840 mg/m/8h (Low Boiling Point
Exposure controls (general population):
DNELacute inhalation = 1200 mg/m/15min. (Low Boiling Point
Naphtha, systemic effects)
DNELacute inhalation = 640 mg/m/15 min. (Low Boiling Point
DNELlong-term inhalation = 180 mg/m/24h (Low Boiling Point
PNEC
non established
8.2. EXPOSURE CONTROLS

Appropriate engineering controls
The substance is flammable and therefore the following conditions

must be met to ensure safe use: Risks are controlled by storage and
use under conditions which avoid all ignition sources.
Personal protection
Respiratory protection
local exhaust ventilation may be needed when working in a closed area

wear suitable breathing equipment, in case of risk of exposure to
vapour or fumes.
Hands protection
gloves resistant to aromatic hydrocarbons
In case of immersion:
recommended material: fluorinated polymer or polyvinyl alcohol

layer thickness : all thicknesses
penetration time according to norm EN 374-3 > 480 minutes
In case of contact with spray:
recommended material: nitrile

layer thickness > 0,45 mm
penetration time according to norm EN 374-3 > 30 minutes
Remarks:
Gloves may degrade in contact with this chemical.

Carefully check the glove for cracks or damage before reusing it,
dispose of gloves where the penetration time is exceeded.
The penetration time depends on temperature, glove material,
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 12/18
Revised : 01/03/2014
thickness and construction.

Penetration time is measured against EN 374 in laboratory conditions
corresponding to permanent static contact and is not necessarily
representative of the risk in the workplace.
Contact the gloves' supplier for further information on the selection and
resistance of gloves.
Skin and body protection
shower and eye fountain available.
Eye protection
goggles/spectacles
Do not wear contact lenses in any work area.
Other personal protection

gloves
safety non-slip shoes in areas where spills or leaks can occur.
safety shoes (keg / gas cylinder manipulation)
Industrial health measures

General use
avoid producing or diffusing fumes, vapour or spray into the air.

(particulary during loading or unloading product)
avoid splashes (suitable protective clothing, screen, aprons, etc...).
do not store near food products.
do not wipe hands with cloths or rags which have been used for
cleaning.
remove all contaminated clothing and remove protective clothing when
the work is completed.
Specific use
see annex to extented safety data sheet (eSDS)
Environmental exposure controls
handle in accordance with good industrial hygiene and safety

procedures
9. Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state at 20C
liquid
Colour
colourless to light yellow
Odour
solvent
Change in physical state at 1013 hPa

Initial boiling point
(C)
> 35
Final boiling point
(C)
< 185
Flash point (ASTM D 93) (C)
< 23
Auto-ignition temperature (C)
> 220
this value can be greatly reduced under specific conditions (slow
oxidation on finely divided material).
the values of auto-ignition temperature are given without guarantee.
indeed, these values vary widely depending on the source of
information.

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Explosion limits
(% vol)
Page : 13/18
Revised : 01/03/2014
Upper
7,600
Lower
0,800
Vapour pressure
(hPa)
40 (T = 20C)
940 (T = 50C)
Density, mass at 15C
(kg/m)
645 - 760
Behaviour with water at 20C
insoluble
Soluble in
Aliphatic hydrocarbons and Aromatic hydrocarbons
pH value (concentrated product)
not applicable
Viscosity
<1
(mm/s)
9.2. OTHER INFORMATION
10. Stability and reactivity

10.1. REACTIVITY
the product is combustible if heated above the flash point.
10.2. CHEMICAL STABILITY
stable under normal operating conditions of storage, handling and use
10.3. POSSIBILITY OF HAZARDOUS REACTIONS

Highly flammable
10.4. CONDITIONS TO AVOID
avoid proximity or contact with hot surfaces, flames, electrostatic

charges or sparks.
Keep away from sources of ignition - No smoking.
10.5. INCOMPATIBLE MATERIALS
avoid contact with strong oxidizing materials, acids and bases
10.6. HAZARDOUS DECOMPOSITION PRODUCTS

complete combustion, with an excess of oxygen forms: carbon dioxide
(CO2) and water vapour.
partial combustion, forms also: carbon monoxide (CO), soot and
cracked products: aldehydes, ketones
11. Toxicological information

11.1. Information on toxicological effects
ACUTE TOXICITY / LOCAL EFFECT
Symptoms related to use
Inhalation
Harmful by inhalation
prolonged or high concentrations exposure may cause respiratory
irritation and headache , dizziness , nausea , confusion , loss of
consciousness
narcotic in case of inhalation of high concentration of vapour
Rat inhalation LC50 / 4h
> 5610 mg/m

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Ingestion
Page : 14/18
Revised : 01/03/2014
Harmful if swallowed.
digestive troubles : diarrhoea and vomiting
Rat, oral LD50
(mg/kg)
Skin contact
> 5000 mg/kg

Harmful in contact with skin
Rabbit dermal LD50
(mg/kg)
> 2000 mg/kg
LOCAL EFFECT
Skin contact
Irritating to skin
Eye contact
Contact with the liquid or exposure to vapours can be irritating to eyes.
SENSITIZATION
SPECIFIC EFFECTS
Genotoxicity
this product has been found genotoxic in in-vivo and in-vitro assays
Carcinogenicity
Benzene is carcinogenic to man
Reproductive toxicity
Fertility
Possible risk of impaired fertility.
Foetal development
Toxic effects on foetal development
aspiration hazard
In case of accidental swallowing, due to its low viscosity, the product

may be aspired into the lung and induce a chemical pneumonitis
developing over a few hours
A medical surveillance is required for 48 hours
STOT specific target organ toxicity

STOT single exposure
May cause drowsiness or dizziness
STOT repeated exposure
May cause damage to organs through prolonged or repeated exposure

prolonged exposure through inhalation or by skin contact may cause
benzene intoxication.
psychic disturbances , digestive system , haematological system
12. Ecological information

Information on ecological effects
avoid losses to the environment whenever possible.
12.1. TOXICITY
AQUATIC TOXICITY
Toxic to aquatic organisms

Contains substances which may be dangerous for the aquatic
environment.
96 hours-LC50-fish
(mg/l)
> 8.2
48 hours-EC50-Daphnia magna (mg/l)
> 4.5
72 hours-IC50-Algae (mg/l)
> 3.1
TERRESTRIAL TOXICITY
12.2. PERSISTENCE AND DEGRADABILITY

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 15/18
Revised : 01/03/2014
Biodegradation
the product is inherently biodegradable the product is persistent in the

aquatic environment under anaerobic conditions
12.3. BIOACCUMULATIVE POTENTIAL
12.4. MOBILITY
water / air
the product evaporates into the atmosphere.
soil and sediments
the product may percolate into the soil.

it may pass through the soil and is likely to contaminate ground water.
water
the product spreads out on the surface of the water, a small fraction of
the constituents may be dissolved.
12.5. Results of PBT and vPvB assessment
non required
12.6. OTHER ADVERSE EFFECTS
13. Disposal considerations

13.1. Waste treatment methods
hazardous waste
dispose in a safe manner in accordance with local/national regulations.
authorized disposal
do not dispose off this product into the environment
Disposal of contaminated packaging
empty bags may contain flammable or explosive vapour

dispose in a safe manner in accordance with local/national regulations.
14. Transport information

Road (ADR) / Rail (RID)
14.1. UN Number
1268
14.2. Proper shipping name
PETROLEUM DISTILLATES, N.O.S. ( Naphta, middle aromatic )
Boiling point (C)
35 to 185
Vapour pressure at 50C (kPa)
<= 110
14.3. Class
classification code
F1
Hazard identification number
33
14.4. Packing Group
II
14.5. Dangerous for the environment
yes
14.6. Special requirements
Code tunnel
D/E
Label(s)
3+N

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Page : 16/18
Revised : 01/03/2014
Inland waterways (ADN)

14.1. UN Number
1268
14.2. Name and description
14.3. Class
classification code
F1
14.4. Packing Group
II
yes
Hazards
(3+N2+CMR+F)
Label(s)
Marine (IMO)
IMDG
14.1. UN Number
1268
14.3. Class or division
Subsidiary risk
14.4. Packing group
II
14.5. IMDG-Marine pollution
Marine pollutant
IMDG-Ems
F-E, S-E
IMDG-Label(s)
14.7. IBC code
Air transport (ICAO / IATA)

14.1. UN (or ID) Number
1268
14.3. Class or division
3
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030
Subsidiary risk
14.4. UN Packing group
II
yes
Hazard Label(s)
Class 3 - Flammable Liquid
Page : 17/18
Revised : 01/03/2014
15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Germany
Wassergefhrdungsklasse
WGK 2: hazard to waters
Registration
listed on the United States TSCA (Toxic Substances Control Act)

inventory
listed on the EEC inventory EINECS (European Inventory of Existing
Commercial Chemical Substances)
listed on the AICS (the Australian Inventory of Chemical Substances).
listed on the Canadian DSL (Domestic Substances List) inventory.
listed on the Korean ECL (Existing Chemical List) inventory.
listed on the ASIA-PAC inventory.
Other

The workers regularly in contact with this product have to be examined
by the doctor.
15.2. Chemical safety assessment
see annex to extented safety data sheet (eSDS)
16. Other information

Training advice
The use of this product requires specific training.

The user must receive all product information in order to handle the
product safely
(personal protection equipment and best practice standards)
R Phrase(s) used
R 11 :Highly flammable.
R 12 :Extremely flammable.
R 36/38 :Irritating to eyes and skin.
R 38 :Irritating to skin.
R 45 :May cause cancer.
R 46 :May cause heritable genetic damage.
R 48/20 :Harmful: danger of serious damage to health by prolonged
exposure through inhalation
R 48/20/21/22 :Harmful :danger of serious damage to health by
prolonged exposure through inhalation , in contact with skin and if
swallowed
R 48/23/24/25 :Toxic :danger of serious damage to health by prolonged
exposure through inhalation, in contact with skin and if swallowed
R 51/53 :Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Safety data sheet

NAPHTA FEEDSTOCK
Product :
ATOF-030

R
R
R
R
R
H Phrase(s) used
62
63
65
66
67
Page : 18/18
Revised : 01/03/2014
:Possible risk of impaired fertility.

:Possible risk of harm to the unborn child.
:Harmful: may cause lung damage if swallowed.
:Repeated exposure may cause skin dryness or cracking
:Vapours may cause drowsiness and dizziness
H225 - Highly flammable liquid and vapour

H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H340 - May cause genetic defects
H350 - May cause cancer
H361d - Suspected of damaging the unborn child
H361f - Suspected of damaging fertility
H372 - Causes damage to organs through prolonged or repeated
exposure
H373 - May cause damage to organs through prolonged or repeated
exposure
H411 - Toxic to aquatic life with long lasting effects
EUH066 - Repeated exposure may cause skin dryness or cracking
Safety data sheet conforms to the Regulation (EU) N 1907/2006

This information applies to the PRODUCT AS SUCH and conforming to specifications of TOTAL.
In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear.
The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. However the revision of some data is in progress.
Users are advised of possible additional hazards when the product is used in applications for which it was not
intended. This sheet shall only be used and reproduced for prevention and security purposes.
The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive.
It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning
the use, the possession and the handling of the product.
It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into
contact with the product. (usage, storage, cleaning of containers, other processes) the totality of the information
contained within this safety data sheet and necessary for safety at work, the protection of health and the protection
of environment.
The (*) indicate the changes made with respect to the previous version.

B- 1040
BRUSSELS
BELGIUM
phone : +32 (0)2.288.91.11 - fax : +32 (0)2.288.33.69
www.total.com
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
ExESS
Exposure scenario of Low Boiling Point Naphthas (Gasoline)

[Containing 1% to 5% benzene]
1 . Manufacture of Low Boiling Point Naphthas (Gasoline) industrial.................................................................... 2

2. Use of Low Boiling Point Naphthas (Gasoline) as intermediate industrial ......................................................... 6
3. Distribution of Low Boiling Point Naphthas (Gasoline) - Industrial ................................................................ 8
4. Formulation & (re)packing of Low Boiling Point Naphthas (Gasoline) - industrial ....................................... 12
1 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
1. Manufacture of Low Boiling Point Naphthas (Gasoline) industrial

1.1. Exposure Scenario
Section 1 Exposure Scenario Title Low boiling point naphthas (Gasoline) (containing equal to or greater than 1% to
5% benzene)
Title
Manufacture of substances
Use Descriptor
Sector(s) of Use
3, 8, 9
Process Categories
1, 2, 3, 8a, 8b, 15
Environmental Release Categories
1, 4
Specific Environmental Release Category
ESVOC SpERC 1.1.v1
Processes, tasks, activities covered
Manufacture of the substance within closed or contained systems. Includes incidental exposures during recycling /
recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (including
marine vessel/barge, road/rail car and bulk container).
Assessment Method
See Section 3.
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product
Liquid, vapour pressure > 10 kPa at STP OC5
Concentration of substance
Covers percentage substance in the product up to 100 % (unless stated
in product
differently) G13
Amount used
Not applicable
Covers daily exposures up to 8 hours (unless stated differently) G2
Frequency and duration of
use/exposure
Not applicable
Human factors not
influenced by risk
management
Other Operational
Operation is carried out at elevated temperature (> 20C above ambient
Conditions affecting
temperature). OC7. Assumes a good basic standard of occupational hygiene is
exposure
implemented G1.
Contributing Scenarios
Specific Risk Management Measures and Operating Conditions
General Measures (skin
irritants). G19.
Avoid direct skin contact with product. Identify potential areas for indirect skin
contact. Wear gloves (tested to EN374) if hand contact with substance likely.
Clean up contamination/spills as soon as they occur. Wash off skin contamination
immediately. Provide basic employee training to prevent / minimise exposures
and to report any skin effects that may develop. E3
2 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
General Measures
(carcinogens). G18.
Consider technical advances and process upgrades (including automation) for the
elimination of releases. Minimise exposure using measures such as closed
systems, dedicated facilities and suitable general / local exhaust ventilation. Drain
down systems and clear transfer lines prior to breaking containment. Clean / flush
equipment, where possible, prior to maintenance.
Where there is potential for exposure: Restrict access to authorised staff; provide
specific activity training to operators to minimise exposures; wear suitable gloves
(tested to EN374) and coveralls to prevent skin contamination; wear respiratory
protection when its use is identified for certain contributing scenarios; clear up
spills immediately and dispose of wastes safely.
Regularly inspect, test and maintain all control measures.
Consider the need for risk based health surveillance. G20.
3 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
CS15 General exposures

(closed systems). + CS56
With sample collection.
(closed systems).
CS36 Laboratory activities
CS14 Bulk transfers
CS39 Equipment cleaning
and maintenance
CS67 Storage.
Handle substance within closed systems. E47.

Sample via a closed loop or other system intended to avoid exposure. E8. Wear
suitable gloves tested to EN374. PPE15.
Provide extract ventilation to points where emissions occur. E54. Handle
substance within closed systems. E47.
Handle within a fume cupboard or implement suitable equivalent methods to
minimise exposure. E12.
Ensure material transfers are under containment or extract ventilation. E66.
Drain down and flush system prior to equipment break-in or maintenance. E55.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
ENVT4.
Clear spills immediately. C&H13.
Wear chemically resistant gloves (tested to EN374) in combination with
intensive management supervision controls. PPE18.
Store substance within a closed system. E84. Wear
suitable gloves tested to EN374. PPE15.
Section 2.2 Control of environmental exposure

Substance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a].
Amounts used
Fraction of EU tonnage used in region
Regional use tonnage (tonnes/year)
Fraction of Regional tonnage used locally
Annual site tonnage (tonnes/year)
Maximum daily site tonnage (kg/day)
Frequency and duration of use
Continuous release [FD2].
Emission days (days/year)
Environmental factors not influenced by risk management
Local freshwater dilution factor
Local marine water dilution factor
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM)
Release fraction to wastewater from process (initial release prior to RMM)
0.1
1.87E7
0.03
6.0e5
2.0e6
300
10
100
0.05
0.003
Release fraction to soil from process (initial release prior to RMM)

0.0001
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used [TCS1].
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
Prevent discharge of undissolved substance to or recover from wastewater [TCR14]. Risk from
environmental exposure is driven by humans via indirect exposure (primarily inhalation) [TCR1 k] Onsite
wastewater treatment required [TCR13].
Treat air emission to provide a typical removal efficiency of (%)
99.0
95.2
Treat onsite wastewater (prior to receiving water discharge) to provide the
required removal efficiency (%)
80.4
If discharging to domestic sewage treatment plant, provide the required onsite
wastewater removal efficiency of (%)
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed
[OMS3].
4 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
Conditions and measures related to municipal sewage treatment plant

Estimated substance removal from wastewater via domestic sewage
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (Msafe) (kg/d)
95.5
99.1
2.0e6
Assumed domestic sewage treatment plant flow (m3/d)

10000
Conditions and measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated [ETW4].
Conditions and measures related to external recovery of waste
During manufacturing no waste of the substance is generated [ERW2].
Additional information on the basis for the allocation of the indentified OCs and RMMs is contained in
Petrorisk file
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated. G21.
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model
[EE2].
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management
Measures/Operational Conditions outlined in Section 2 are implemented. G22.
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that
risks are managed to at least equivalent levels. G23.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available hazard data
do not support the need for a DNEL to be established for other health effects. G36. Risk Management Measures
are based on qualitative risk characterisation. G37.
4.2. Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling
may be necessary to define appropriate site-specific risk management measures [DSU1]. Required removal
efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination [DSU2].
Required removal efficiency for air can be achieved using onsite technologies, either alone or in combination
[DSU3]. Further details on scaling and control technologies are provided in SpERC factsheet
(http://cefic.org/en/reach-for-industries-libraries.html) [DSU4]. Scaled local assessments for EU refineries have
been performed using site-specific data [DSU6]. If scaling reveals a condition of unsafe use (i.e., RCRs > 1),
additional RMMs or a site-specific chemical safety assessment is required [DSU8]. Measured data have been
used to demonstrate that the PETRORISK predicted fence-line concentrations in air are overestimated. These
data support the conclusion that no refineries have RCRs>1
5 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
2. Use of Low Boiling Point Naphthas (Gasoline) as intermediate industrial

2.1 Exposure Scenario
Section 1 Exposure Scenario Title Low boiling point naphthas (Gasoline) (containing equal to or greater than 1% to
5% benzene)
Title
Use of substance as intermediate
Use Descriptor
Sector(s) of Use
3, 8, 9
Process Categories
1, 2, 3, 8a, 8b, 15
6a
ESVOC SpERC 6.1a.v1
Use of substance as an intermediate (not related to strictly controlled conditions) within closed or contained
systems. Includes incidental exposures during recycling/ recovery, material transfers, storage, sampling,
associated laboratory activities, maintenance and loading (including marine vessel/barge, road/rail car and
bulk container).
Assessment Method
See Section 3.
Section 2.1 Control of worker exposure
Concentration of substance in Covers percentage substance in the product up to 100 % (unless stated
product
differently) G13
Amount used
Not applicable
use/exposure
Not applicable
Human factors not
influenced by risk
management
Other Operational
Operation is carried out at elevated temperature (> 20C above ambient
temperature). OC7. Assumes a good basic standard of occupational hygiene is
implemented G1.
exposure
irritants). G19.
Avoid direct skin contact with product. Identify potential areas for indirect skin
contact. Wear gloves (tested to EN374) if hand contact with substance likely.
Clean up contamination/spills as soon as they occur. Wash off skin
contamination immediately. Provide basic employee training to prevent /
minimise exposures and to report any skin effects that may develop. E3
General Measures
(carcinogens). G18.
Consider technical advances and process upgrades (including

automation) for the elimination of releases. Minimise exposure using
measures such as closed systems, dedicated facilities and suitable
general / local exhaust ventilation. Drain down systems and clear transfer
lines prior to breaking containment. Clean / flush equipment, where
possible, prior to maintenance.
Where there is potential for exposure: Restrict access to authorised staff;
provide specific activity training to operators to minimise exposures; wear
suitable gloves (tested to EN374) and coveralls to prevent skin
6 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
contamination; wear respiratory protection when its use is identified for

certain contributing scenarios; clear up spills immediately and dispose of wastes
safely.
Sample via a closed loop or other system intended to avoid exposure. E8.
Wear suitable gloves tested to EN374. PPE15.
Provide extract ventilation to points where emissions occur. E54.
(closed systems).
CS67 Storage.
Store substance within a closed system. E84.
CS14 Bulk transfers
Ensure material transfers are under containment or extract ventilation.
E66.
Drain down and flush system prior to equipment break-in or maintenance.
and maintenance
E55.
Retain drain downs in sealed storage pending disposal or for subsequent recycle.
ENVT4.
Amounts used
0.1
2.21 E6
0.0068
1.5e4
5.0e4
300
10

100
0.025
0.003

0.001
environmental exposure is driven by freshwater sediment [TCR1b]. If discharging to domestic sewage
treatment plant, no onsite wastewater treatment required [TCR9].
80
92.9
0
If discharging to domestic sewage treatment plant, provide the required
onsite wastewater removal efficiency of (%)
7 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
Organisation measures to revent/limit release from site

[OMS3].
95.5
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite (domestic 95.5
treatment plant) RMMs (%)
Maximum allowable site tonnage (Msafe)
(kg/d)
7.8e4
2000
This substance is consumed during use and no waste of the substance is generated [ETW5].
This substance is consumed during use and no waste of the substance is generated [ERW3].
3.1. Health
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk
model [EE2].
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels. G23.
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. G32. Available
hazard data do not support the need for a DNEL to be established for other health effects. G36. Risk
Management Measures are based on qualitative risk characterisation. G37.
4.2. Environment
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures [DSU1].
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either
alone or in combination [DSU2]. Required removal efficiency for air can be achieved using onsite
technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies
are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html)
3. Distribution of Low Boiling Point Naphthas (Gasoline) - Industrial

8 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13

Section 1 Exposure Scenario Title Low boiling point naphthas (Gasoline) (containing equal to or greater
than 1% to 5% benzene)
Title
Distribution of substance
Use Descriptor
Sector(s) of Use
3
Process Categories
1, 2, 3, 8a, 8b, 9, 15
1, 2, 3, 4, 5, 6a, 6b, 6c 6d, 7
ESVOC SpERC 1.1b.v1
Bulk loading (including marine vessel/barge, rail/road car and IBC loading) of substance within closed or
contained systems, including incidental exposures during its sampling, storage, unloading, maintenance
and associated laboratory activities.
Assessment Method
See Section 3.
Section 2.1 Control of worker
in product
Amount used
use/exposure
Human factors not
influenced by risk
management
Other Operational
exposure
exposure

irritants). G19.
Avoid direct skin contact with product. Identify potential areas for indirect
skin contact. Wear gloves (tested to EN374) if hand contact with
substance likely. Clean up contamination/spills as soon as they occur.
Wash off skin contamination immediately. Provide basic employee
training to prevent / minimise exposures and to report any skin effects
that may develop. E3
Consider technical advances and process upgrades (including
automation) for the elimination of releases. Minimise exposure using
measures such as closed systems, dedicated facilities and suitable
general / local exhaust ventilation. Drain down systems and clear transfer
lines prior to breaking containment. Clean / flush equipment, where
possible, prior to maintenance.
General Measures
(carcinogens). G18.

differently) G13
Not applicable
Not applicable
Assumes use at not more than 20C above ambient temperature, unless
stated differently. G15. Assumes a good basic standard of occupational
hygiene is implemented G1.
I

certain contributing scenarios; clear up spills immediately and dispose of
wastes safely.
9 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13

(closed systems).
CS2 Process sampling
CS14 Bulk transfers + CS6
Drum and small package
filling
CS36 Laboratory activities.

Sample via a closed loop or other system intended to avoid exposure. E8
Sample via a closed loop or other system to avoid exposure. E8.
Avoid carrying out activities involving exposure for more than 1 hour OC 27

CS501 Bulk closed loading
E66.
and unloading.
and maintenance
E55.
Retain drain downs in sealed storage pending disposal or for subsequent
recycle. ENVT4.
CS67 Storage.
Ensure operation is undertaken outdoors. E69.
Amounts used
0.1
1.87E7
0.002
3.75E4
1.2E5
300
10

100
0.001
0.00001

0.00001
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation) [TCR1 k].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR9].
I reat air emission to provide a typical removal efficiency of (%)
90
12
0
10 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
[OMS3].
95.5
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite (domestic 95.5
treatment plant) RMMs (%)
Maximum allowable site tonnage (Msafe)
(kg/d)
1.1 E6
2000
External treatment and disposal of waste should comply with applicable local and/or national regulations
[ETW3].
External recovery and recycling of waste should comply with applicable local and/or national regulations
[ERW1].
3.1. Health
3.2. Environment
model [EE2].
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure
that risks are managed to at least equivalent levels. G23.
4.2. Environment
technologies, either alone or in combination [DSU3]. Further details on scaling and control technologies
are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html) [DSU4].
11 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
4. Formulation & (re)packing of Low Boiling Point Naphthas (Gasoline) - industrial

Section 1 Exposure Scenario Title Low boiling point naphthas (Gasoline) (containing equal to or greater
than 1% to 5% benzene)
Title
Formulation & (re)packing of substances and mixtures
Use Descriptor
Sector(s) of Use
3, 10
Process Categories
1, 2, 3, 8a, 8b, 15
2
ESVOC SpERC 2.2.v1
Formulation of the substance and its mixtures in batch or continuous operations within closed or
contained systems, including incidental exposures during storage, materials transfers, mixing,
maintenance, sampling and associated laboratory activities.
Assessment Method
See Section 3.
Section 2.1 Control of worker
in product
Amounts used
use/exposure
Human factors not
influenced by risk
management
Other Operational
exposure
Contributing
Scenarios
exposure

irritants). G19.
Avoid direct skin contact with product. Identify potential areas for indirect
skin contact. Wear gloves (tested to EN374) if hand contact with substance
likely. Clean up contamination/spills as soon as they occur. Wash off skin
contamination immediately. Provide basic employee training to prevent /
minimise exposures and to report any skin effects that may develop. E3

differently) G13
Not applicable
Not applicable
Assumes use at not more than 20C above ambient temperature, unless
stated differently. G15. Assumes a good basic standard of occupational
hygiene is implemented G1.
12 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13
General Measures
(carcinogens). G18.
Consider technical advances and process upgrades (including automation)

for the elimination of releases. Minimise exposure using measures such as
closed systems, dedicated facilities and suitable general / local exhaust
ventilation. Drain down systems and clear transfer lines prior to breaking
containment. Clean / flush equipment, where possible, prior to maintenance.
certain contributing scenarios; clear up spills immediately and dispose of
wastes safely.

(closed systems).
CS2 Process sampling
CS14 Bulk transfers
CS8 Drum/batch transfers
and maintenance

E66.
E66.
E55.
Retain drain downs in sealed storage pending disposal or for subsequent
recycle. ENVT4.
CS67 Storage.

Amounts used
Release fraction to wastewater from process (initial release prior to
RMM)
0.1
1.65e7
0.0018
3.0e4
1.0e5
300
10
100
0.025
0.002
0.0001
13 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13

Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to
soil
environmental exposure is driven by humans via indirect exposure (primarily inhalation) [TCR1 k].
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required [TCR9].
56.5
94.7
Treat onsite wastewater (prior to receiving water discharge) to provide
the required removal efficiency (%)
0
Prevent discharge of undissolved substance to or recover from wastewater [OMS1]. Do not apply
industrial sludge to natural soils [OMS2]. Sludge should be incinerated, contained or reclaimed
[OMS3].
treatment (%)
Total efficiency of removal from wastewater after onsite and offsite
(domestic treatment plant) RMMs (%)
Maximum allowable site tonnage (Msafe) (kg/d)
95.5
95.5
1.0E5

2000
External treatment disposal of waste should comply with applicable regulations [ETW3].
External recovery and recycling of waste should comply with applicable local and/or national
regulations [ERW1].
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated.
G21.
3.2. Environment
model [EE2].
4.1. Health
Where other Risk Management Measures/Operational Conditions are adopted, then users should
ensure that risks are managed to at least equivalent levels. G23.
4.2. Environment
technologies, either alone or in combination [DSU3]. Further details on scaling and control
technologies are provided in SpERC factsheet (http://cefic.org/en/reach-for-industries-libraries.html)
[DSU4].
14 - 14
Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13

Safety Data Sheet: Naphta Feedstock

Uploaded by

Copyright:

Available Formats

Safety Data Sheet: Naphta Feedstock

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Safety Data Sheet: Naphta Feedstock

Uploaded by

Copyright:

Available Formats

Safety data sheet

Version (en) nr : 13.3

1. Identification of the substance / mixture and of the company / undertaking

Naphta (petroleum), full-range straight-run.

EINECS or ELINCS number

Total Petrochemicals & Refining (01-2119474679-18-0034)

1. 2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE AND USES ADVISED AGAINST

Recommended to professional users

1.3. DETAILS OF THE SUPPLIER OF SAFETY DATA SHEET

see below this page.

1.4. EMERGENCY TELEPHONE NUMBER

Emergency call Carechem 24 International :

Official advisory body

UK: National Poisons Emergency Number: 0845 4647

Quick-FDS [17197-17173-15824-010388] - 2015-01-30 - 04:46:13