PANDIT DEENDAYAL PETROLEUM UNIVERSITY

SCHOOL OF TECHNOLOGY
COURSE STRUCTURE FOR B. TECH. CHEMICAL ENGINEERING
SEMESTER V
Sr
No

Course
Code

B.TECH. CHEMICAL ENGINEERING

Course Name

Teaching Scheme
L

4
5

CH 301T
CH 301P
CH 302T
CH 302P
CH 303T
CH 303P
CH 312
CH 305

CH 306

TP 210

2
3

Examination Scheme
Hrs/wk
MS

Theory
ES

IA

Practical
LW
LE/
Viva
--25
25
--25
25
--25
25
-----

Total marks

Chemical Processes
Technology II (Inorganic)
Energy Technology
Process Instrumentation

3
-3
-3
-3
3

1
-1
-0
----

-4
-4
-2
---

7
2
7
2
6
1
6
6

4
4
4
4
3
2
3
3

30
-30
-30
-30
30

60
-60
-60
-60
60

10
-10
-10
-10
10

Transport Phenomena

--

30

60

10

--

--

100

--

--

--

--

--

--

--

80

20

100

18

10

47

31

Chemical Reaction Kinetics

Industrial Orientation
(Evaluation)
Total

MS = Mid Semester, ES = End Semester;

100
50
100
50
100
50
100
100

850

* IA = Internal assessment (like quiz, assignments etc)

1|Page

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

CH 301T Chemical Reaction Kinetics

Teaching Scheme
T
P
C

--

Total
marks
100

UNIT I
Mole balance , Kinetics of Homogeneous reactions - Definition of the rate of reaction, type of reactions,
homogeneous and heterogeneous, Reaction mechanism, elementary and non-elementary reactions,
Temperature and concentration dependent term of a rate equation, searching for a reaction
mechanism.
UNIT II
Introduction to reactor design, Rate-Law and Stoichiometry - Basic definitions, Approach to reactor
sizing and design
Collection and Analysis of rate data, integral and differential method of analysis of data, Batch reactor
data, Variable and constant volume system, Method of initial rates, Method of half-life, Differential
reactors, Least square analysis
UNIT III
Isothermal Reactor Design - General mole balance equation, ideal reactor, Batch Reactors, Continuousflow reactors, Industrial reactors, Design for isothermal reactors, Scale up of liquid-phase batch reactor
data to the design of a CSTR, Tubular reactors, Recycle reactors
Conversion and Reactor Sizing - Definition of conversion, Design equations, Applications of the design
equations for continuous-flow reactors, Reactors in series
UNIT IV
Multiple Reactions Design for parallel reactions, Maximizing desired product in parallel reactions,
Maximizing desired product in series reactions, Temperature and pressure effect in single and multiple
reactions, Adiabatic reactor design.
Texts and References:
1. H. S. Fogler, Elements of Chemical Reaction Engineering, 3rd Ed, New Delhi-Prentice Hall, 2001
2. O. Levenspiel, Chemical Reaction Engineering Willey Eastern, 3rd Ed., 2000
3. J. M. Smith, Chemical Engineering Kinetics, 3rd Ed., McGraw- Hill, 1988

Page 2 of 11

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

CH 301P Chemical Reaction Kinetics

Teaching Scheme
T
P
C

--

--

Total
marks
50

List of experiments
1. To determine the activation energy of the reaction using Arrhenius Equation.
2. To determine order of reaction for the given reaction.
3. To measure the kinetics of a reaction under condition of excess reactant at room
temperature.
4. To determine the kinetics of the reaction at room temperature by the integral method of
analysis.
5. To determine the activation energy and frequency factor for reaction at room temperature & at
different temperature.
6. To determine the kinetics of the reaction at room temperature by the differential method of
analysis.
7. To determine the kinetics of the reaction between n- butyl acetate and sodium hydroxide at
room temperature by the differential method of analysis.

Page 3 of 11

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

CH 302T Mass Transfer I

Teaching Scheme
T
P
C
1

--

Hrs/Week
4

MS
30

Examination Scheme
Theory
Practical
ES
IA
LW
LE/Viva
60
10
---

Total
marks
100

UNIT I
Physico-chemical basis of separation processes, thermodynamic considerations
Diffusion - Ficks Law of diffusion equimolecular counter diffusion in fluids, diffusion in stationary gas.
Maxwells low of diffusion. Solid diffusion
UNIT II
Inter phase mass transfer - Mass transfer equilibrium, diffusion between two phases. Local mass
transfer coefficient, Local and average overall mass transfer coefficients. Simultaneous heat and mass
transfer. Steady state co and counter current processes
Material balance steady state co current and counter current processes stage wise and differential
contacts. Number of theoretical stages. Stage efficiency Height of mass transfer units.
UNIT III
Gas Absorption - Equilibrium solubilities of gases. Material balance for transfer of one component.
Counter current multistage operations for binary and multi component systems. Continuous contactors,
absorption with chemical reaction. Concept of HTU and NTU
Liquidliquid extraction - Calculations with and without reflux for immiscible and partially miscible
system.
UNIT IV
Leaching: Principle and theory, types of operations, Leaching single and multistage operations based on
solvent free co ordinates
GasLiquid operations - Sparged vessels (bubble columns), mechanically agitated vessels for a single
phase and gas liquid contact. liquid dispersed scrubbers, venturi scrubbers, wetted towers packed
towers. Mass transfer coefficients for packed towers co-current flow of gas and liquid end effect and
axial mixing.
Text and References
1. R. E. Treybal, Mass transfer operations, 3ed ed. McGraw Hill, 1980.
2. S. Foust et al. Principles of Unit Operations
3. J. M. Coulson and J. F. Richardson, Chemical Engineering, Vol. 1 ELBS, Pergaman press, 1970
4. J. M. Coulson and J. F. Richardson, Chemical Engineering Vol. 2 ELBS, Pergaman press, 1970

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P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

CH 302P Mass Transfer I

Hrs/Week
MS

--

--

Examination Scheme
Theory
Practical
ES
IA
LW
LE/Viva
25
25

Total
marks
50

List of Experiments
1. To determine the % extraction of diluted aqueous organic solution using suitable solvent.
2. To determine the diffusion co-efficient of CCl4 in air & its variation with temperature.
3. Determine mass transfer co-efficient of liquid (water) evaporation to atmospheric air at
elevated temperature.
4. To determine the efficiency of single stage leaching operation.
5. To find out the liquid side mass transfer coefficient KLa in the packed column.
6. To determine the mass transfer co-efficient for dissolution of benzene acid with and without
chemical reaction.
7. To prepare the ternary diagram for a system of three liquid one pair partially soluble system.
8. To study the (cross current) liquid-liquid extraction for binary system using solvent and
determine:
a) Efficiency stage wise & overall.
b) Advantage of multistage cross current extraction over single stage through A. Solvent
required to achieve the same recovery in single stage. B. % recovery when the same quality
of solvent is used in single stage.
c) % of acetic acid removed per stage & overall removal of acetic acid.
d) Minimum & maximum solvent in 1st sage
9. To determine the mass transfer coefficient in a stirred cell.
10. To determine the stage efficiency and the overall recovery for multistage cross current leaching
operation using solvent.
11. To determine the mass transfer co-efficient of vaporization of solid into air.

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P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

L
3

CH 303T Chemical Process Technology II (Inorganic)

Total
marks
100

UNIT I
Introduction to inorganic chemistry and concepts: periodic table and main group elements, Lewis
concept of acids and bases, Nomenclatures, structural isomers, stereoisomer.
Descriptive inorganic chemistry: coordination compounds, transition metal compounds, organometallic
compounds, cluster compounds, bioinorganic compounds, solid state compounds. Various theories.
Mechanistic inorganic chemistry.
Chemistry of raw materials used in industry: Glass, Refractory, Potteries, Ceramic coatings, Cement
concrete, Synthetic raw materials: Properties, characteristics, importance & synthesis of important raw
UNIT II
Electrolytic industries: Electrolytic processes for the manufacture of aluminum sodium magnesium,
chlorates and per chlorates.
Inorganic Chemicals: Acids, sulphuric acid (DOSA and DCDA process), nitric acid, hydrochloric acid
phosphoric acid and hydrofluoric acid.
UNIT III
Nitro-Fertilizers: Soda ash, Ammonia, urea, Ammonium sulphate and nitrate superphosphates and
mixed fertilizers. biofertilizers
ChlorAlkali Industries: Manufacture of soda ash, sodium bicarbonate chlorine and caustic soda calcium
hypochlorite sodium hypochlorite and sodium chlorite potassium chloride.
UNIT IV
Furnace Products: Furnace products such as lime, cement, magnesia, elemental, phosphorus, activated
carbon graphite etc.
Electrothermal Industries: Artificial abrasives, calcium carbide
Texts and References
1. George T. Austin, Shreves Chemical process Industries, 5th ed. McGraw Hill, 1984
2. C. E. Dryden, outlines of chemical technology edited and revised by M. Gopala Rao and Marshall
sitting end ed. Affiliated East-West press, New Delhi, 1973.
3. Kirk-Othmer, Encyclopedia of chemical Technology, 3rd ed. John-Willey, New York, 1981.
4. McKetta, Encyclopedia of Chemical Processing and Design, Marcel Dekker Inc., New York, 1994

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P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

L
--

CH 303P Chemical Process Technology II (Inorganic)

Total
marks
50

List of Experiments
1. To prepare sulphanilic acid from aniline.
2. To prepare hydrated lime from the given calcium carbonate powder.
3. To determine the acid value of the given sample of oil.
4. To determine the loss on igniting the cement sample.
5. To determine the total silica in the given sample.
6. To determine the amount of potassium in the given sample of fertilizer.
7. To determine the total insoluble residue in the cement sample.
8. To determine the adsorption isotherm of acetic acid by activated charcoal.
9. To determine the amount of Na2CO3 and NaHCO3 in the given mixture of sodium carbonate and
sodium bicarbonate.
10. To determine the amount of calcium in the given sample of fertilizer volumetrically.
11. Determination of percentage available chlorine in bleaching powder.

Page 7 of 11

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

CH 312 Energy Technology

L
3

--

--

Hrs/Week
3

MS
30

Examination Scheme
Theory
Practical
ES
IA
LW
LE/Viva
60
10
---

Total
marks
100

UNIT I
Introduction to Energy Sources (conventional & non-conventional), world production and reserve of
conventional energy sources, Indian production and reserves, Energy alternatives.
Solid Fuels: wood & charcoal, peat, lignite, sub-bituminous & bituminous coals, semi-anthracite and
anthracite coals, cannel & boghead coal, origin of coal, composition of coal, analysis & properties of
coal, problems
UNIT II
Processing of Solid Fuels coal preparation, wash ability curve, dry & wet washing methods of coal,
washer efficiency, gasification & liquefaction of solid fuels, problems
Solar Energy : solar constant, solar radiation & related terms, measurement of solar radiation, solar
energy collectors flat plate collector, air collector, collectors with porous absorbers, concentrating
collectors, applications & advantages of various collectors, selective absorber coatings, solar energy
storage systems (thermal, electrical, chemical & mechanical), solar pond, applications of solar energy
Wind energy: nature, power, forces, conversion and estimation. Components of wind energy system,
types, design considerations. Generation systems, safety and environment.
UNIT III
Energy from bio mass: Generation, conversion technologies and utilization of biogas, design of biogas
plants and gasifiers Fuel Cell Technologies
Geothermal Energy Systems. Tidal energy systems. Oceanic power generation. Design considerations,
Installation and Performance Evaluation. MHD power generations, Energy from Oceans: OTEC, methods
(open cycle & close cycle) energy from tides, components
UNIT IV
Fuel Cell: introduction, hydrogen oxygen fuel cell, ion exchange membrane cell, fossil fuel cell, molten
carbonate cell, advantages & disadvantages, conversion efficiency, polarisation, type of electrodes,
applications of fuel cells
Nuclear Energy: fission, fusion, fuel for nuclear fission reactor, storage & transportation, fast & slow
neutrons, multiplication factors & reactor control, uranium enrichment process, study of different
reactors
Text and References
1. Energy Sources 2Ed. by G. D. Rai, Khanna Publications, New Delhi
2. Fuels & combustion by Samir Sarkar, Orient Longmans(1974)
3. Solar Energy by Sukatame, Tata McGraw Hill, New Delhi
4. Energy Technology by Rao & Parulaker

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P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

Teaching Scheme
T
P
C

CH 305 Process Instrumentation

Total
marks
100

3
--6
UNIT I
Fundamentals of Measuring Devices: Introduction to measurements. Elements of measuring systems
and their functions. Characteristic and classification, error, accuracy, repeatability, drift, threshold etc
Measurement of Temperature: Temperature scales Mercury in glass thermometer, Bimetallic
thermometer, pressure spring thermometer, Thermoelectric temperature measurements,
thermocouples, thermal well and potentiometers, Resistance thermometer and pyrometers. working
principles and applications, advantages and disadvantages
UNIT II
Measurement of Pressure: Various Manometers, working principles and applications, Pressure and
vacuum gages, pressure transducer, working principles and applications, advantages and disadvantages
Measurement of liquid Level: Level measurements of open and pressure vessels measurement of
interface level, working principles and applications advantages and disadvantages
UNIT III
Measurement of density: Density measurements by displacement meter, hydrometer and densitometer,
working principles and applications advantages and disadvantages
Measurements of flow: Orifice, Venturi, Pitot, and Rota-meters, flow measurement of open channels.
UNIT IV
Instrumentation to flow plan symbols and chemical sensors. advantages and disadvantages
Measurement of pH, conductivity, composition of mixtures, working principles and applications,
advantages and disadvantages
Signal transmission. Transmitters electronic pneumatic etc.
Preparation of instrumentation diagram for equipment like distillation, heat exchanger, condensers
Text / References:
1. D. P. Eclaman, Industrial Instrumentation, Wiley Estern, 1989.
2. J. P. Bentley, Principles of Measurement Systems, 2nd ed. Longman London, 1988.
3. J. W. Dally, W. F. Riley and K. G. McConnell, Instrumentation, Engineering Measurements, John
Wiley and Sons, Singapore, 1984.
4. C. S. Rangan, G. R. Sarma and V. S. V. Mani, Instrumentation Devices and systems, Tata McGraw Hill,
New Delhi, 1983
5. B. C. Nakra and K. K. Chaudhary, Instrumentation Measurement and Analysis, Tat McGraw Hill, New
Delhi, 1985.
Page 9 of 11

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

Teaching Scheme
T
P
C

CH 306 Transport Phenomena

Total
marks
100

3
1
-7
UNIT I
The role of transport Phenomena in the understanding of Chemical Engineering, Equation of motion

Viscosity and mechanism of momentum transport, thermal conductivity and mechanism of energy
transport, diffusivity and mechanism of mass transport.
UNIT II
Shell Balance: Velocity distribution in laminar flow, temperature distribution in solids and laminar flow,
concentration distributions in solids and in laminar flow (restricted to rectangular and cylindrical coordinates only).
Equations of change: Isothermal systems, non-isothermal system, multi-component systems (restricted
to rectangular coordinate system).
UNIT III
More than one independent variable systems: Velocity distribution, temperature distribution,
concentration distribution (restricted to rectangular and cylindrical co-ordinates only).
Turbulent Flow: Velocity distribution, temperature distribution, concentration distribution.
UNIT IV
Interphase Transport: Isothermal systems, non-isothermal system, multi-component systems.
Analogies between Momentum, heat and mass transfer

Texts/References:
1. J. M. Coulson and J. F. Richardson, Chemical Engineering Vol. I Pergamon Press, 1970
2. R. B. Bird, W. E Stewart, and E. N. Lightfoot, Transport Phenomena, Edition-I John Wiley, 1960.
3. C. O. Bannet, and J. E. Myers, Momentum, Heat and Mass Transfer 3rd ed. McGraw Hill, 1982.

Page 10 of 11

P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g

Teaching Scheme
T
P
C
--

TP 210 Industrial Orientation

Total
marks
100

Evaluation of industrial Orientation

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P D P U / S O T / 5th S e m . B. T e c h . C h e m i c a l E n g i n e e r i n g