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Appendices

The document contains sample calculations and data from experiments standardizing a NaOH solution and determining the heat of adsorption of acetic acid onto activated charcoal from titration data. Standardization of NaOH involved titrating it against potassium hydrogen phthalate and calculating the molarity. Titration of acetic acid solutions of varying concentrations involved determining the final concentration of acetic acid and populating a table with experimental variables. The heat of adsorption was calculated using the logarithmic form of the Langmuir isotherm and was found to be -9785.79 J/mol.

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Christy Joy Retanal
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23 views

Appendices

The document contains sample calculations and data from experiments standardizing a NaOH solution and determining the heat of adsorption of acetic acid onto activated charcoal from titration data. Standardization of NaOH involved titrating it against potassium hydrogen phthalate and calculating the molarity. Titration of acetic acid solutions of varying concentrations involved determining the final concentration of acetic acid and populating a table with experimental variables. The heat of adsorption was calculated using the logarithmic form of the Langmuir isotherm and was found to be -9785.79 J/mol.

Uploaded by

Christy Joy Retanal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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VII.

APPENDICES
Data and Sample Calculations
Standardization of NaOH
m of KHP
Initial
RUN
(g)
(mL)

Final (mL)

Vol. NaOH(mL)

0.509

0.00

26.655

26.655

0.510

0.00

26.827

26.827

0.508

0.00

26.770

26.770

1 mol
)
204.232 g
M1 =
1L
26.770 mL (
)
1000mL

1 mol
)
204.232 g
M1 =
= 0.0935 M
1L
26.655 mL (
)
1000 mL
0.509 g(

1 mol
)
204.232 g
M2 =
1L
26.827 mL(
)
1000 mL
0.510 g(

= 0.0929 M

0.509 g(

= 0.0931 M

Mave = (M1 + M2 + M3)/3 = 0.0932

Titration Data
Flask
No.

m of CH3COO- (g)

Molarity of CH3COOH

Volume of aliquot (mL)

Average volume of
NaOH (mL)

1.008

0.15

25

34.01

1.015

0.12

25

25.19

1.007

0.09

25

22.63

1.013

0.06

25

15.12

1.001

0.03

25

6.94

1.004

0.05

25

4.85

1.000

25

0.04

0.03

25

8.05

Determining the final concentration of CH3COOH:

Cf=

( Volume of NaOH used ) (Concentration of NaOH )


(Volume of solution)

where the average conc. of the base is 0.0923 M and the volume of solution is 100 mL.
C = (Co CF)
x = C x Vsoln.
N = x / m ; m = mass of charcoal (1g)
Summary of Calculated variables
Flask
Co (M)
Cf (M)
No.

log N

log C

C/N

1
2
3
4
5
6
7
8

0.15
0.12
0.09
0.06
0.03
0.015
0.03

0.0316
0.0234
0.0210
0.0140
0.0064
0.0045
0.000037
0.00750

0.1183
0.0965
0.0689
0.0459
0.0235
0.0104
~0
0.0224

Heat of adsorption = ([ln(C)0.5]/7)RT


= (-3.8852)(8.314)(302.95)
= -9785.79 J/mol

0.01183
0.00965
0.00689
0.00459
0.00235
0.00104
0.00224

0.01183
0.00965
0.00689
0.00459
0.00235
0.00104
-

-1.9270
-2.0152
-2.1618
-2.1338
-2.6289
-2.9830
-

-0.9270
-1.0153
-1.1617
-1.1338
-1.6283
-1.9796
-1.6479

10
10
10
10
10
10
-

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