Jz/Ji J2: Model

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340 Ch.

6 Heisenberg Model

with respect to a , we obtain

if J2/J1 < 1/4


= { arccos(-J1/4J2)
lr
if Jz/Ji 2 1/4

The classical ground state is a spiral wave for J2> J1/4. As J ~ / J increases,
I
a gradually decreases from T towards n/2.
The Nkel-to-spiral transition predicted for the classical limit is destabilized
by quantum fluctuations. For S = 1/2, the quantum transition is between a
spin liquid and a dimer phase (see Sec. 6.3.2). Let us observe that studying the
classical limit does not give any hint of dimerization; the dimer order described
in Sec. 6.3.2 is a purely quantum phenomenon.

Figure 6.9: Construction of a class of king ground states. Two thirds of the sites
form a honeycomb lattice with perfect AF order. The spin states of the remaining
one third of the sites (circles) are free to choose.

Problem 6.5. A low-energy bond connects a site with S" = S to a site


with S" = -S; anything else is bad. In Sec. 6.3.4, we convinced ourselves
that every triangle must contain at least one unsatisfied bond. A subclass of
ground states with partial long range order is obtained by imposing AF order
on a sublattice holding 2L/3 sites in the form of a honeycomb lattice (Fig. 6.9).
L/3 sites are at the hexagon centres. Each of these has three neighbours with
Sz = S , and three with S" = -S, thus whatever the spin at the centre site is,
+
the energy remains the same. The centre spin can be chosen in (25 1) ways,
thus this subclass contains (2s + l ) L / 3 ground states, an exponentially large
number. Naturally, the total number of the ground states is larger, and most
of them show no recognizable order.
For S = 1/2, we constructed 2L/3ground states, thus (In 2 / 3 ) k ~= 0.231k~
is a lower bound for the zero point entropy density. The exact value is 0.3383k~
[438].

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