Particles (Electrons, Neutrons or Protons) or Electromagnetic Waves (Gamma Rays, X
Particles (Electrons, Neutrons or Protons) or Electromagnetic Waves (Gamma Rays, X
Particles (Electrons, Neutrons or Protons) or Electromagnetic Waves (Gamma Rays, X
The simplest atom is common Hydrogen See below: Protium, atomic mass or weight
of 1, has 1 proton and one electron. There are two other, rarer, forms of Hydrogen:
Deuterium (mass=2) and Tritium (mass=3). They are called isotopes (different forms
according to mass but with the same atomic numbers) of Hydrogen because they all
have one positive proton and one negative electron. All unreacted or uncombined
atoms have # protons = # electrons to create a 0 electrical charge. How many
neutrons does Protium, Deuterium and Tritium have?
Radioactive atoms have unstable nuclei (e.g., Tritium above) that emit radiation (forms
of energy) as atomic
particles (electrons, neutrons or protons) or electromagnetic waves (gamma rays, X-
rays,
ultra-violet light or radio waves). See p. 29 of text.
X-rays, gamma rays and ultraviolet rays are mutagenic; that is, they mutate DNA,
the chemical in our cells that carries the messages of inheritance that regulate cell
growth,
reproduction and metabolic activities. See http://en.wikipedia.org/wiki/Gamma_ray
See: http://www.epa.gov/enviro/html/erams/legal.html
http://www.cpc.ncep.noaa.gov/products/stratosphere/uv_index/uv_nature.shtml
Some medical Imaging techniques use forms of radiation produced by decaying atomic
nuclei. Some forms are more dangerous than others. In general, short wavelength forms
have very high energy and can therefore mutate the chemical of inheritance, DNA, and
cause cancers or the death of cells.
If food is bathed by gamma rays (as in sterilization/preservation), does that make the
food
radioactive?
To study the radiation effects of the atomic bombs dropped on Japan, see
http://www-sdc.med.nagasaki-u.ac.jp/n50/disaster/medical-E.html
Are there any medical procedures or treatments which do not have risk?
Is it contradictory that x-rays are used to treat cancer but that they can cause cancer?
Some heavier atoms are cooked up in stars, such as Carbon, Iron, Silicon,
Nitrogen, Sulfur, Phosphorus, Aluminum, Copper, etc. Since these atoms
are in our tissues, Carl Sagan calls us "Star Stuff." There are several types
of energy which are important for Anatomy and Physiology.
Some heavier atoms are cooked up in stars, such as Carbon, Iron, Silicon, Nitrogen,
Sulfur,
Phosphorus, Aluminum, Copper, et c. Since these atoms are in our tissues, Carl Sagan
calls us
"Star Stuff." There are several types of energy which are important for Environmental
Sciences.
Atomic energy is stored in atoms, it literally holds the atomic nucleus together.
When atoms are split (as in an Uranium or Plutonium fission bomb or nuclear reactor)
or fused (as in the Sun or laser fusion devices)some mass is converted to energy.
Why is it easier to dissolve corn starch or table salt in warm water rather than cold
water?
1
22
M
8g
2
24.
3
Draw the following atoms. Include the correct number of protons, neutrons and
electrons in
their shells.
N O
If one eats plants that have soaked up I-131, Sr-90 and Cs-137, does one's radioactivity
level increase?
Chemical Bonds
The reason why atoms react or combine to form molecules is that in reacting, they reach
a more
stable outer shell electron arrangement, 8, the magic number for atoms stability (and
lower
energy level). See p. 33-39.
Ionic bond - If a Na gives away an electron to Cl which keeps it, notice that both atoms
have 8
electrons in their outer shell. Now Na+ has a +1 electrical charge because it lost one
negative
electron and; Cl- has an extra electron and thus has a -1 negative charge. Charged atoms
are
called Ions. See page 35//34 of Text. Ionic bonds are formed when atoms give away or
receive
electrons. When atoms lose electrons , an oxidation results, if atoms gain electrons ,
they
undergo reduction;
Nonmetals generally have 4-8 electrons in the outer shell hold on to their electrons and
generally "grab for more". Metals are weak electronegative atoms mean that the atoms
which
give up electrons readily; i.e., Metals generally have 1-3 electrons in their outer
shells .
Look at your periodic chart. Are Li, Na, K, Mg, Al and Au (gold) metals? _____ How
about S, O,
Cl and Ar. What are they, metals or nonmetals? _____
If you dissolve the ionic compound NaCl in water, Na+ and Cl - ions will float free
and
be surrounded by spheres of water molecules. See page 42//41.
NaCl -----> Na + (+) Cl -
Nonpolar Covalent, where electrons are shared equally by all atoms, e.g., Methane,
CH4
H
|
H -- C -- H; O=C=O is Carbon dioxide
|
H
Both of these heavy gases of our atmosphere, along with SO2 and NO2 , contribute to
the
greenhouse effect - abnormal warming of the earth (global warming) is thought to
occur when these gases,
which concentrate close to the earth's surface, trap heat energy (infra-red radiation) .
CH4 is
also an ozone layer destroying gas. The ozone (03 ) layer is thought to protect the earth
from
harmful ultraviolet waves which are thought to mutate DNA in skin cell and cause skin
cancer.
Nonpolar bonds cannot normally form ions (electrically charged atoms) because they
continue
to share electrons. Electrons must be given away and retrieved to form ions.
Polar Covalent bonds have at least one atom which is an electron "bully"; the highly
electronegative atom (usually Oxygen) has a greater share of the negatively charged
electrons. .
Because H--O--H is polar as a molecule, meaning that the Oxygen side of the molecule
has a
negative charge and the Hydrogen side has a positive charge. This characteristic helps
water
dissolve NaCl or table salt. See pg. 36-37.
Water Molecule:
Characteristics:
Types of Mixtures:
a. True Solution - the solid portion or gas (called solute) particles are very small
(atoms or
b. Colloid - larger particles that do not settle out but will scatter light (Tyndall
Effect), e.g.,
c. Suspension - still larger particles which will be affected by gravity and thus
settle out,
In the intestine, large pools of fat are broken into small droplets. This is an
important process
for the digestion of fats in the intestines.
Fat is nonpolar. Water is polar. Normally nonpolar compounds do not mix with polar
liquids. A
rule is "like dissolves like!" So nonpolar cholesterol dissolves in nonpolar fat. Some
emulsifying compounds are combinations of polar and nonpolar atom groups, e.g., a
phospholipid which can be dissolved in fat and water simultaneously. How is blood an
emulsion?
1. Water sticks to itself: It is cohesive. Because of the polar covalent nature of
water,
electronegative oxygen atoms will attract or pull on the positive Hydrogen atoms
of
adjacent water molecules, creating weak hydrogen bonds between water
molecules.
This makes water hard to boil for it's low molecular weight of 18 (2H @1 each
=2,
1 -0 @16 =16).
To determine the molecular weight of a molecule, add the atomic mass numbers
of each atom found in Periodic Chart in Appendix C.
1. Water boils at 100 degrees C, Acetone with a molecular weight of 58, boils
at 58 degrees C!
3. Water has a high specific heat (1 Calorie/1 degree C/1 gram) which means that it
will store heat and thus it acts as a moderator of climate in the summer. The Earth is
also warmer in the Winter because oceans release stored heat.
1. Because water molecules bond to each other, the ones on the surface draw inward
(hydrogen bonding) toward their fellow molecules down below. This creates a film-like
surface or surface tension on which certain water bugs walk.
3. Water will adhere to the inside walls of small hollow tubes such as capillaries which
are the smallest of blood vessels. This is called capillarity - it helps to draw blood
into capillaries that serve tissues with nutrients.
4. Water will adhere to hydrophilic (water loving) atoms or atom groups such as, Ions,
strongly electronegative atoms like Oxygen, Nitrogen, et c.. Some substances which are
filled with nonpolar covalent bonds, like oils and fats, are hydrophobic (water
fearing).
They are repelled by water.
6. Water makes a very small but equal number of H + and OH - ions (10 -7 or one
10 millionth of a Mole each).
7. Pure water is a poor conductor of electricity unless you dissolve ions in it. Generally
covalent compounds are poor conductors. Ionic solutions are called electrolytes and are
necessary for the operation of the nervous system.
8. Water, combined with proteins and phospholipids in mucus and serous secretions, is
a lubricant.
Anecdote
A freshman at Eagle Rock Junior High won first prize at the Greater
Idaho Falls Science Fair, April 26. He was attempting to show how
conditioned we have become to alarmists practicing junk science and
spreading fear of everything in our environment. In his project he
urged people to sign a petition demanding strict control or total
elimination of the chemical "dihydrogen monoxide."
Acids are substances which produce H+ ions in solution, they are proton donors . For
example,
HCl is a polar covalently bonded gas molecule but when dissolved in water makes
H + ions and Cl -
ions. Because more molecules of HCl ionize (about 96% generally), HCl (found in our
stomach)
is a strong Acid, However, H 2CO3 , Carbonic acid, is a weak acid because only about
3% of it's
molecules ionize when in water solution. Carbonic acid is weak; it is found in
carbonated
beverages and your blood! An important point is: the more H+ ions, the more acid is
present.
Are H+ ions also protons? ________
100 HCl (in H2O) yields ---> 96 H+ ions + 96 Cl - (Chloride) ions: 96 of 100 HCl
molecules
break into ions.
Bases are the opposites of acids, or have OH- ions, or will bond to H+ ions/protons. For
example, if a solution had a lot of H+ ions, you could add OH- ions, react the two and
form
HOH or water. NaOH or lye is a common base used for making soap and cleaning sink
drains.
Bases are opposites of acids, they may make OH- ions, all will bond to H+ ions/protons.
For example, if a solution had a lot of H ions, you could add OH- ions, react the two and
form
HOH or water. NaOH or lye is a common base used for making soap and cleaning sink
drains,
e.g., NaOH (in H2O) ---> Na + (+) OH - Any compound which produces OH- is a base.
But is NH3 (Ammonia) a base because NH3 + H + ---> NH4+ (The answer is yes!)
Bases react with acids to produce water or Acid + Base ---> Salt and H2 O
This is called neutralization.
Measure of Acidity
Remember: Acid (+) Base yields Salt (+) Water. This is neutralization. The pH will be 7
if it
was a complete neutralization with equal amounts of H+ and OH- resulting.
Buffers are substances which, when added to a water solution, resist changes in
pH. Amino acids, above, are buffers because they both, soak up some acid H + ions
and prevent lowering of pH, or they neutralize OH- base ions with their
carboxylic/organic acid group (-COOH).
This buffer pair is found in the blood: H2CO3 (a weak acid) and the basic salt of a weak
acid,
NaHCO3 . The weak acid neutralizes bases and the salt neutralizes acids. Identify the
acid and base
in NaH2P04 /Na2HP04 , NH4+ /NH3 , NH2---/---COOH- .
pH Scale
( H+ ) = hydrogen ion concentration; (OH- ) = hydroxide ion concentration
Hint: since pH numbers are log rhythmic, log of the number 1 = 0, log of 0.1 = -1;
log 0.01 = -2, log .001 = -3, etc.
Examples of Use:
Sugars - the most basic energy storing food material of cells is glucose, C6H12O6 .
Why do cells need glucose and oxygen? To make ATP! See below.
<>
Starches - have alpha bonds between long chains of glucose molecules twisted into a
coil.
Complex carbohydrates are "branched starches" that have side chains branching off of
the 6th
carbon atom. Glycogen (liver or muscle cell starch) is a branched polysaccharide.
Cellulose or food fiber- notice the different bonding pattern (beta glucose
bonds). There are two types:
soluble (to some degree) and insoluble. They are thought to interfere with cholesterol
absorption.
Lipids - oily compounds that will dissolve in nonpolar solvents. See page 47.
Triglycerides - or neutral fats are composed of 3 monomers of fatty acid and one
monomer of
glycerol, an organic alcohol. They are joined by dehydration synthesis making ester
bonds.
Unsaturated fats have one or more double bonds between C atoms in the chain of fatty
acids.
What happens to unsaturated fats when they are "hydrogenated" as when vegetable oils
are
made in solids for use in "stick" margarines?
The precise sequence of amino acid molecules(20 types for cells) is
Primary -
determined by the "genetic code" in DNA..
Characteristics:
The globular protein shapes of enzymes are changed by heat into stringy solid
forms
(like cooking an egg white). Remember, "a boiled egg won't hatch a chicken."
3. Enzymes bond on to their specific substrates by a Lock and Key Process. The
substrate bonds into a specific spot on the enzyme called the active site.
Therefore if the enzyme is changed in shape, what happens to the reaction? If you
use the wrong shaped substrate, what happens to the reaction?
1. Each enzyme has a pH range of action. Consider the pancreatic enzyme
Trypsin
However, Pepsin, first secreted in the stomach glands as the protein pepsinogen,
Must bond with H+ ions in order to have any activity in digesting protein. In this case
H+ ions are cofactors for the Pepsin enzyme.
ATP - the source of most chemical energy stored and used in cells. It is made
in the mitochondria of cells.
DNA - the chemical of inheritance is significant because it can replicate exactly (with
the help of enzymes) and it can direct the synthesis of structural, gene regulatory and
enzymatic proteins. See p. 54-56 of textbook.
-
The building blocks (monomers) of DNA (deoxyribonucleic acid) are called
nucleotides. Each
nucleotide is composed of (1.) a deoxyribose (5C) sugar, (2.) a phosphate (PO4-3)
group, and
(3.) a nitrogenous base of 4 kinds: Cytosine and Guanine that bind together with 3
hydrogen
bonds, and Thymine and Adenine that bind together with 2 hydrogen bonds. Adenine
and
Guanine have two rings of mostly carbon atoms and are called purines, cytosine and
thymine
have one ring and are called pyrimidines.
Study Questions
1. What is a radioactive isotope? How is it different from the most common form of the
atom?
2. What forms of electromagnetic radiation are dangerous?
3. What are the building blocks of sucrose, lactose, maltose, starch, cellulose, glycogen,
protein,
neutral fat, DNA, and steroids? Learn to visually recognize each.
4. Compare and contrast the four levels of protein structure.
5. List and explain 4 characteristics of enzymes.
6. Compare hydrolysis and dehydration synthesis (condensation) reactions. Where does
each occur for starches and proteins?
7. Explain how ATP stores and releases energy.
8. How is the genetic code derived from the structure of DNA?
9. How can blood be a solution, suspension and an emulsion at the same time?