Chemistry Xii Revision

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Class XII CHEM

Points to Remember

1.Lead storage cell

2.Hydrogen –Oxygen fuel cell

3.Reaction in rusting of iron

4.When concentration approaches zero, the molar conductivity is known as


limiting molar conductivity
5.Kohlrausch law of independent migration of ions: The law states that
limiting molar conductivity of an electrolyte can be represented as the sum of
the individual contributions of the anion and cation of the electrolyte.

6.The number of collisions per second per unit volume of the reaction
mixture is known as collision frequency (Z).
7.Pseudo first order reaction: the reaction in which rate of reaction depends
only on one reactant due to presence of very large amount of other reactant.
8.The most probable kinetic energy: kinetic energy of maximum fraction of
molecules
9.The collisions in which molecules collide with sufficient kinetic energy (called
threshold energy*) and proper orientation, so as to facilitate breaking of bonds
between reacting species and formation of new bonds to form products are
called as effective collisions.
10.Molecularity:The number of reacting species (atoms, ions or molecules)
taking part in an elementary reaction, which must collide simultaneously
in order to bring about a chemical reaction is called molecularity of a
reaction.
11.Order:the sum of powers of the concentration of the reactants in the
rate law expression is called the order of that chemical reaction.

11.

12. hence
conducts electricity
13.
14.Balancing reactions
15. Preparation of potassium permanganate

16.When heated potassium permanganate it decomposes as

17.Ligand which can ligate through two different atoms is called ambidentate
ligand. Examples of such ligands are the NO2 – and SCN– ions.

18.When a di- or polydentate ligand uses its two or more donor atoms to bind a
single metal ion, it is said to be a chelate ligand.

19.

20 configuration in d orbitals:
21
22. SN-2 mechanism

23.SN-1 mechanism

24.DDT

25. Reimer-Tiemann reaction

26.Kolbe’s reaction

27.Cannizaro’s reaction:(having no α-hydrogen atom)

28.H V Z reaction:
29.Diazotization: The conversion of primary aromatic amines into diazonium
salts is known as diazotisation.

30. coupling reaction:

31. anomers of glucose(differ in configuration at one carbon)

32. anomers of fructose

33 .hydrolysis of maltose give two unit of D-glucose.


hydrolysis of sucrose give α-D-glucose and β-D-fructose
hydrolysis of lactose give β-D galactose and β -D-glucose.

34. zwitter ion

35.Vulcanisation of rubber:This process consists of heating a mixture of raw


rubber with sulphur and an appropriate additive at a temperature range
between 373 K to 415 K. On vulcanisation, sulphur forms cross links at the
reactive sites of double bonds and thus the rubber gets stiffened.

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