Factsheet Physics: The Quantum Nature of Light
Factsheet Physics: The Quantum Nature of Light
Factsheet Physics: The Quantum Nature of Light
Light is part of the electromagnetic spectrum, which we commonly explain The Photoelectric Effect
as consisting of waves with different frequencies (e.g. gamma rays, X-rays,
radio waves, infra-red radiation and microwaves). We find that all parts of What is the Photoelectric Effect?
the electromagnetic spectrum show the same ‘wave-particle duality’ as light, When EM radiation falls on a metal surface, electrons are emitted so
so we commonly speak of ‘electromagnetic radiation’ (EM radiation) long as the frequency of the EM radiation is above a certain ‘threshold’
rather than ‘light’. value. The emitted electrons, called photoelectrons, have kinetic energies
ranging from zero to a maximum value.
What is the particle model of EM radiation?
By Plank’s theory, EM radiation (e.g. light) is considered to be composed
of a stream of small lumps or packets (quanta), which are called photons.
Each photon travels at the speed of light and has no mass and no charge. How is the Photoelectric Effect explained?
Each photon has a fixed amount of energy (E) which depends on the • Light consists of particles (photons) of energy; the higher the frequency,
frequency (f) of the EM radiation: the higher the frequency, the higher the the higher their energy.
energy of each photon: • One single photon collides with one electron and gives all its energy to
that electron.
E: Photon energy (J) • If this energy is enough to free the electron from the metal surface, then
E = hf h: Planck's constant (6.63× 10-34 Js) the electron will be released, otherwise it won’t be released.
f: frequence of EM radiation (Hz) • The minimum energy required to release an electron from a metal
surface is called the Work Function (W). This differs for different
The more photons (i.e. packets of energy) there are, then the more energy metals, as each metal surface binds the electrons with varying
there is arriving at a point each second. Thus, the power (defined as energy ‘strengths’.
per second) of the EM radiation depends on the number of photons arriving • Whether the electron is released or not depends on the energy of the
per second. If the power is measured over an area (e.g. 1m2), then we call it photon (E) in comparison to the metal work function (W):
intensity (Wm-2), which in the case of light is the same as its brightness.
♦ Electron just released (E=W). If the energy of a single photon
(E) is equal to the work function (W), it can just release one
To summarise the Particle Model of EM radiation: electron from the surface of the metal. We say the photon is at
• EM radiation comes in a stream of packets, known as photons. the threshold frequency, (fo), the minimum frequency of EM
• Each photon has no charge and no mass radiation required to just release electrons from a metal surface,
• The Energy of each photon depends on frequency only where E = hf0 = W; or rearraged f0 = W/h.
• The Power or Intensity of EM radiation of a fixed frequency depends ♦ Electron not released (E<W). If the EM radiation is below the
on the number of photons arriving each second (where Intensity
threshold frequency, one photon does not have enough energy to
= Power/area).
release one electron and no electrons are emitted.
♦ Electron released with energy to spare (E>W). A photon
above the threshold frequency not only has enough energy to
Exam Hint : If you are asked to explain "Wave Particle Duality" with
free the electron from the metal, but has excess energy which is
examples, ensure you give examples of light acting both as a particle and as
given to the electron as kinetic energy (KE). The largest value
a wave
this can take is given by Einstein’s Equation (see below).
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The Quantum Nature of Light Physics Factsheet
By using the principle of conservation of energy, we can also write an A simple demonstration of the Photoelectric Effect
equation for the transfer of energy from the photon to the electron This uses a gold leaf electroscope (Fig 2). The electroscope is initially
(pictorially represented in Fig 1). charged either positively or negatively, so the gold leaf is raised.
Gold Leaf
Photon energy → Energy to free electron from metal surface + Electron KE
hf = W + KEmax
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The Quantum Nature of Light Physics Factsheet
Photoemission
Electromagnetic radiation of a known frequency is directed on to one of the photocell plates.
• If it is above the threshold frequency (i.e. if it has sufficient energy), then photoelectrons are emitted.
• The number of photoelectrons emitted per second depends on the number of photons arriving per second, i.e. the Power, or Intensity, of the EM
radiation.
V decreases
(becomes more V<0 V=0 V>0 V increases
negative)
The current continues to A reverse potential gives Some electrons hit the The ‘receiving plate’ The current will
drop, until even the most the receiving plate a other metal plate, thus is given a positive continue to rise as the
energetic electrons (with negative potential completing the electrical potential by the battery, potential of the plate is
KE max ) are unable to (relative to the battery). circuit and allowing a attracting more of the made more positive,
overcome the potential Thus, some electrons are current to flow. photoelectrons towards until all the emitted
energy of the electric field. repelled from the plate, the plate. Thus the photoelectrons are
At this point, no electrons leading to a reduced zero
Zeroapplied
Applied voltage
Voltage current in the circuit attracted and captured.
will bridge the gap between current flowing through increases. At this point the
the plates and so the current the circuit electrons
electrons current reaches its
falls to zero. The reverse maximum value, called
potential required to reduce the saturation current,
the current to zero is II Is.
Photocell Plates
termed the stopping
voltage VS.
positive applied pp
voltage g
negative applied
Negative voltage
Applied Voltage
electrons
electrons
electrons
electrons
Current
positive potential
Positive potential
maximum
Maximum II
Saturation Photocell Plates
Stopping saturation
stopping
Voltage, V
I = I0A
= 0A voltage Vs s Saturation
Photocell Plates
Current, I s
Stopping
Voltage, Vs
Applied
- ve (reverse) 0 + ve Voltage
EM Energy Þ V S EM IntensityÞ I S
The stopping voltage depends only on the energy of the photoelectrons, which is determined by the photon energy (i.e. frequency) for a given metal.
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The Quantum Nature of Light Physics Factsheet
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The Quantum Nature of Light Physics Factsheet
Why does the Photoelectric Effect provide evidence for particle nature of light, rather than its wave nature?
Before studying this, make sure that you understand the differences between the wave and particle theories of light (see page 1). Also, remember that intensity
is defined as the power per unit area. The observations made in the Photoelectric Effect are unable to be explained using the wave theory of light. Therefore,
the particle theory was developed in order to explain what was observed. These are summarised in Table 1.
For a given metal, electrons are The greater the intensity (amplitude) of the EM • Light consists of photons with energy E = hf
only emitted above a certain radiation, the greater the energy that arrives at the • Minimum energy required to release an electron is
threshold frequency of the metal surface. So a high enough intensity should the work function (W)
EM radiation, irrespective of its cause electrons to be emitted regardless of the • To release electrons, E>W
intensity. frequency. The frequency should have no effect here. • Threshold frequency (f0) occurs when E=W; hf0 = W
The maximum KE of the The greater the intensity (amplitude) of the EM • For frequencies above the threshold frequency (f>f0),
emitted electrons depends only radiation, the greater the energy that arrives at the Einstein’s Equation gives: KEmax = hf – W
on frequency of the EM metal surface. So, more energy is given to each • Thus KEmax depends on the frequency
radiation. electron. The frequency should have no effect here.
The number of photoelectrons The intensity of the EM radiation relates to energy, • The number of photons arriving per second depends
emitted per second depends only not the number of waves arriving per second. So, on the intensity of the EM radiation
on intensity of the EM the number of emitted electrons depends on the • One photon can release one electron (assuming 100%
radiation, for a single frequency. number of waves arriving (i.e. the frequency) and efficiency)
not the wave energy (i.e. intensity). The intensity • Thus the number of electrons emitted per second
should have no effect here. depends on intensity
Low intensity EM radiation Low intensity EM radiation has low energy. So it • Intensity only relates to how many photons arrive
(above the threshold frequency) will take some time before enough energy builds up per second, so few arrive per second for low intensities
results in immediate emission on the metal surface to free one electron. • But, each photon has enough energy to release an
of electrons. electron (f>f0) so immediate electron emission occurs
Exam Workshop (c) Use the particle theory of light to explain why red light does not
have the same effect as ultra-violet light. [5]
This is a typical poor student’s answer to an exam question. The comments Red light doesn’t free electrons as it doesn’t have as much energy as UV
explain what is wrong with the answers and how they can be improved. 4. Energy comes in lumps that depends on the frequency 4.
The examiner’s answer is given below.
• Did not mention what the particle theory of light is (i.e. photons).
The photoelectric effect can be simply demonstrated by using an • Did not explain why electrons are released when UV light shines
electroscope which is negatively charged, as shown in the diagram. on the plate.
UV radiation • Needs to be specific about red light being below the threshold
frequency – too vague here to gain mark.
Zinc
Plate (d) If the metal has a work function of 2.3 eV, calculate the maximum
kinetic energy of the emitted electrons, in Joules, when light of 200
nm is used. [3]
KEmax = hf – W = h(200×10-9)/(3.0×108) – 2.3 = -2.3eV 6
Gold Leaf • Used λ not f in equation
• Calculated energy in eV, not Joules as asked
Examiner’s Answers
When ultra violet light is shone on the metal plate, the gold leaf (a) Both the foil and rod are negatively charged.4 Like charges repel,
gradually returns to the vertical. However, when red light alone is so the foil moves away from the rod.4
used, the foil remains displaced and does not return to the vertical. (b) The UV light frees electrons so they can escape from the metal plate
(the photoelectric effect) 4 so the negative charge on the metal plate
(a) Explain why the gold leaf is initially displaced from the vertical [2] and rod decrease 4. So, the repulsion between the foil and the rod
It’s Repelled 4 decrease and the foil drops due to gravity. 4
• Needs more detail for 2 marks (c) Light consists of packets (quanta) called photons 4. The energy of
each photon depends on its frequency, by E = hf 4. As red light has
a lower frequency than UV light, it has less energy 4. One photon
(b) Explain why the gold leaf gradually returns to the vertical when gives its energy to one electron 4. In order to release an electron,
UV is shone on to the metal plate? [3] the photon energy must be greater than or equal to the metal work
It becomes less negatively charged. 4 function: red light photons have less energy than this and so do not
The light takes the extra charge away.6 provide enough energy to free an electron 4.
• Not enough detail to gain 3 marks. (d) Use Einstein’s Equation: KEmax = hf – W,
• Be precise - light does not 'take the extra charge away'. where f = c/λ = (3.0×108)/(200×10-9) = 1.5×1015Hz 4
and W = 2.3eV × (1.6×10-19C) = 3.7×10-19J 4.
Substitute in the equation to get KEmax= 6.2×10-19J 4.
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The Quantum Nature of Light Physics Factsheet
Qualitative (Concept) Test (7) What is the stopping voltage? How can it be decreased for a given
Look in the text for the answers to the questions and use the hints! metal?
(1) Explain wave – particle duality. Include an example in your answer. (8) Describe an experiment to verify Einstein’s photoelectric effect.
(2) What is a photon? Explain how values for the metal work function and Plank’s constant
can be determined form this experiment.
(3) Describe the photoelectric effect.
(9) If visible light is incident on zinc, no electrons are emitted,
(4) How does the photoelectric effect provide evidence for the particle irrespective of how intense the light is. Explain this observation.
nature of electromagnetic radiation?
(10) Monochromatic electromagnetic radiation is incident on a metal
(5) What is the work function of a metal? Explain how this relates to surface, resulting in the emission of electrons.
the threshold frequency for the metal. (Hint: See "How is the Describe the effect on the maximum kinetic energy and on the
Photoelectric Effect Explained") number of electrons ejected per second for the following changes:
(a) increasing/decreasing the frequency of the incident radiation
(6) What is Einstein’s equation? What does it describe? Explain all (b) increasing/decreasing the intensity of the incident radiation
symbols used. (c) changing the metal for one with a greater/smaller work function
(Hint: See "saturation current and stopping voltage")