Chapter 2-Polar Covalent Bonds Acids and Bases: Short Answer Exhibit 2-1

Chapter 2—Polar Covalent Bonds; Acids and Bases
SHORT ANSWER
Exhibit 2-1
Give the letter of the term that best matches the given definition.
Brønsted-Lowry Acid Ionic Bond

Brønsted-Lowry Base Covalent Bond
Lewis Acid Polar-Covalent Bond
Lewis Base Hydrophobic
Electronegativity Hydrophilic
1. _____ Any species that can accept electrons.

2. _____ A bond between two atoms differing in electronegativity by 0.5  2.
3. _____ A term used to describe a "water loving" species.
4. _____ A compound that can donate a proton.
5. _____ The ability of an atom to attract the shared electrons in a covalent bond.
6. _____ A term used to describe a "water fearing" species.
7. _____ Any species that can donate electrons.
8. _____ A bond between two atoms differing in electronegativity by < 0.5.
9. _____ A compound that can accept a proton.
10. _____ A bond between two atoms differing in electronegativity by > 2.
Exhibit 2-2
Calculate the formal charges on the indicated atoms in each compound below.
11. Refer to Exhibit 2-2. The formal charge on phosphorous (A) is ______.
12. Refer to Exhibit 2-2. The formal charge on oxygen (B) is ______.
13. Refer to Exhibit 2-2. The formal charge on carbon (C) is ______.
14. Refer to Exhibit 2-2. The formal charge on oxygen (D) is ______.
Exhibit 2-3
Phenylalanine is an amino acid that is essential to human nutrition. The representation below shows the
structure of phenylalanine at physiological pH. Consider this structure to answer the following
question(s).
1
Polar Covalent Bonds: Acids and Bases
15. Refer to Exhibit 2-3. Assign any formal charges to atoms in this representation of phenylalanine.
16. Refer to Exhibit 2-3. The oxygen atom labeled A. has ______ non-bonding electrons.
17. Refer to Exhibit 2-3. The oxygen atom labeled B. has _____ bonding electrons.
Exhibit 2-4
Use the convention and the crossed arrow to show the direction of the expected polarity of
the indicated bonds in the following compounds.
18. Refer to Exhibit 2-4. The CF bond in fluorobenzene,

19. Refer to Exhibit 2-4. The CSi bond in tetramethylsilane, (CH3)4Si
20. Refer to Exhibit 2-4. The CO bond in furan,
Exhibit 2-5
Label the acid, conjugate acid, base, and conjugate base in each reaction below.
21.
22.
Exhibit 2-6
Refer to the following equation to answer the question(s) below. Place the letter corresponding to the
correct answer in the blank.
23. Refer to Exhibit 2-6. The strongest Brønsted-Lowry acid in the equation is ______.
24. Refer to Exhibit 2-6. The strongest Brønsted-Lowry base in the equation is ______.
25. Refer to Exhibit 2-6. Will this reaction take place as written? Explain.
26. An acid with a low pKa:
2
Chapter 2
is a weak acid
is a strong acid
has a weak conjugate base
both b and c
27. Circle all the Lewis bases in the group of compounds below.
28. Put a box around all the Lewis acids in the group of compounds below.
29. Draw two resonance structures for the species below.
3
Exhibit 2-7
Consider the acidity constants below to answer the following question(s).
ACID STRUCTURE pKa
phenol 10.00
ethanol CH3CH2OH 16.00
water HOH 15.74
32. Refer to Exhibit 2-7. Which acid will be almost completely deprotonated by NaOH?
33. Refer to Exhibit 2-7. Which acid has the strongest conjugate base?
34. Refer to Exhibit 2-7. Explain why phenol has a much lower pKa than ethanol.
Exhibit 2-8
Consider the reaction below to answer the following question(s).
35. Refer to Exhibit 2-8. Using the curved arrow formalism, show the flow of electrons for this
reaction.
36. Refer to Exhibit 2-8. Label the acid and the base in the reaction.
Exhibit 2-9
Indole is pleasant smelling in highly dilute solutions and has been used in perfumery. Use the structure of
indole, below, to answer the following question(s).
37. Refer to Exhibit 2-9. Indole can function as a Brønsted-Lowry acid in the presence of strong bases.
Formulate a reaction, showing electron flow with arrows, that demonstrates this reactivity of indole.
38. Refer to Exhibit 2-9. Indole can function as a Lewis base in the presence of strong acid. Formulate
a reaction, showing electron flow with arrows, that demonstrates this reactivity of indole.
4
Chapter 2
39. The condensed structure for dimethyl ether looks symmetrical. However, dimethyl ether has a
dipole moment. Draw a structure that explains this and indicate the expected direction of the
molecular dipole moment.
Exhibit 2-10
Consider the acid-base reaction below to answer the following question(s).
40. Refer to Exhibit 2-10. Using the curved arrow formalism, show the flow of electrons for this
reaction.
41. Refer to Exhibit 2-10. Write the products of this Lewis acid - base reaction.
42. The following is a representation of the pain reliever, acetaminophen, the active ingredient in
Tylenol®. Indicate the positions of any multiple bonds. Atoms other than carbon and hydrogen are
labeled.
43. Use the curved arrow formalism to show the electron flow in the reaction of ammonia with water.
MULTIPLE CHOICE
1. In which series are the elements listed in order of increasing electronegativity?

Cl < S < P As < S < F
C< Si < Ge N < P < Br
2. Based on electronegativity values, in which of the following is the bond, represented by —, the
most polar?
H3C—I H3C—Cl
H3C—Na H3C—OH
3. Which of the following substances has a zero dipole moment?
5
CO2
Cl2C=CCl2
HOCH2CH2OH
HCl2CCHCl2
All have zero dipole moments.
4. The following shows a gray-scale image of an electrostatic potential map with the atoms labeled.
Which of the numbered regions would appear reddest in a color image?
1
2
3
4
1, 2, and 3 would be the same shade of red.
2, 3, and 4 would be the same shade of red.
5. How many resonance forms can be drawn for the NO 3– ion?
1
2
3
4
None, the nitrate ion does not exhibit resonance.
6. Which of the following would represent the strongest acid?
7. Which of the following substances would be expected to have the largest pKa?
8. Which of the following does not characterize the curved arrow formalism?
6
Chapter 2
The arrow shows the movement of electrons not atoms.

The atom at the head of the arrow is the electron pair acceptor.
The atom at the tail of the arrow is a Lewis acid.
The species containing the atom at the head of the arrow will have the smaller pKa.
All of these correctly describe the curved arrow formalism.
9. Which of the following substances would exhibit hydrogen bonding
a, b, and c
All would exhibit hydrogen bonding.
10. The structure for Vitamin K which is involved in blood clotting is shown below.
This vitamin would be:

classified as hydrophilic. fat-soluble.
water-soluble. both hydrophilic and hydrophobic.
11. The following is generic depiction of a reaction using the curve arrow formalism.
Which of these statements is not correct for this reaction?

Electrons move from C to B.
Electrons move from B to A.
In the products, a bond forms between C and B.
In the products, A would have a positive charge.

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Chapter 2—Polar Covalent Bonds; Acids and Bases

Brønsted-Lowry Acid Ionic Bond

1. _____ Any species that can accept electrons.

18. Refer to Exhibit 2-4. The CF bond in fluorobenzene,

20. Refer to Exhibit 2-4. The CO bond in furan,

26. An acid with a low pKa:

29. Draw two resonance structures for the species below.

30. Draw two resonance structures for the species below.

31. Draw two resonance structures for the species below.

ACID STRUCTURE pKa

ethanol CH3CH2OH 16.00

water HOH 15.74

1. In which series are the elements listed in order of increasing electronegativity?

6. Which of the following would represent the strongest acid?

The arrow shows the movement of electrons not atoms.

This vitamin would be:

Which of these statements is not correct for this reaction?

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