Forensic science has its origins in ancient China and 19th century Europe, with important early figures including Jean Servais Stas who developed methods for detecting poisons like nicotine in the body. Major advances were made in this era including the Marsh test for detecting arsenic and methods for identifying blood. Techniques like analyzing rifling patterns on bullets and fingerprint analysis became important forensic tools in the 20th century.
Forensic science has its origins in ancient China and 19th century Europe, with important early figures including Jean Servais Stas who developed methods for detecting poisons like nicotine in the body. Major advances were made in this era including the Marsh test for detecting arsenic and methods for identifying blood. Techniques like analyzing rifling patterns on bullets and fingerprint analysis became important forensic tools in the 20th century.
Forensic science has its origins in ancient China and 19th century Europe, with important early figures including Jean Servais Stas who developed methods for detecting poisons like nicotine in the body. Major advances were made in this era including the Marsh test for detecting arsenic and methods for identifying blood. Techniques like analyzing rifling patterns on bullets and fingerprint analysis became important forensic tools in the 20th century.
Forensic science has its origins in ancient China and 19th century Europe, with important early figures including Jean Servais Stas who developed methods for detecting poisons like nicotine in the body. Major advances were made in this era including the Marsh test for detecting arsenic and methods for identifying blood. Techniques like analyzing rifling patterns on bullets and fingerprint analysis became important forensic tools in the 20th century.
Early History • In 1248, a book in China with the Title “Hsi Yuan Lu” means washing away the wrongs was written. • Mentioned that Strangulation and death by drowning can be differentiated. • Jean Servais Stas (1813-18891) is known to work in the field of forensic science, same personality who determine atomic. • Work of Sir Arther conan Doyle (1859-1930) who wrote famous fictional novels “Sherlock Holmes” and other short stories. • Advances in 19th century. Doyle is shaved. Stas is the other one. “Achievements of Stas” • Described methods for detecting certain vegetable poisons in the body. • Developed the method for detecting nicotine in the human body which is the main work of Stas in his life. • Nicotine is an alkaloid ( soluble both in alcohols and water). How Nicotine was determined in the dead bodies by Stas? 1. Macerated organs until to pulp and then added acid or alcohol. 2. Heated that pulp until organic constituents precipitated out leaving alkaloids behind in the soln. 3. When added water to the residue, alkaloids dissolved. 4. Recovered alkaloids by evaporating water. Advances in 19th century
• Tests for blood.
• Bullet finger printing 1880s. • Marsh test for arsenic in 1832. Tests for bloods • “Shonbein” identified human blood by adding Hydrogen peroxide to bloodstain foams in 1863. • “Izaak van Deen” determined a method to check the presence of blood by adding ‘Guaiac’ herd that change its colour. Marsh Test • As2O3 a gray substance, tasteless solid, can easily be added to food as poison was very popular among criminals. • Jabir Bin Hayan (721-815) converted arsenic into As2O3. • Marsh in 1832 developed a test for identification of arsenous oxide in body fluids. Simple, by passing H2S through body fluids, if turned yellow, case is positive • Marsh showed the jury evidence of yellowish body fluid as a evidence of As2O3. • But the jury decided to go with the criminal as there was not the clear observation of gray solid. • He was disappointed and spent 4 years in developing a fool proof test. Marsh’s fool proof Method for detecting As2O3 1. Adding pure zinc and H2SO4 to sample. If arsenous oxide is present, it will directly be reduced by Zn.
2. Formation of Arsine gas. (AsH3)
3. Then this gas is allowed to pass through heated tube. Heat causes the arsine to decompose, yielding a silvery-black film of elemental As and H2.
- Main drawback is that all compounds
should be in there pure form, a slight change can alter the result drastically. Riffling Patterns and ballistic finger printing • There are special grooves in gun barrel to cause the rotatory motion of bullet. • These grooves form patterns on the bullets, which is known as riffling patterns and used in the identification. • In 1920s, a U.S army major (Calvin Goddard) invented a microscope to compare the patterns of two bullets. Scope of forensic Chemistry • A lot of things to discuss but mainly two are of vital importance and used extensively. 1. Criminalistics is the scientific analysis and examination of physical evidence, its interpretation and its presentation in court. 2. Finger print patterns.