Sig Fig Handout PDF
Sig Fig Handout PDF
Sig Fig Handout PDF
Romero 2006
Significant Figures
CHEM 30A
Significant figures convey the precision to which a number is known. They are a part of
any numerical answer, and are as important as the number itself and the units.
23,432 cars seems like a better answer than 23,000 cars, but do we really know that there are
23,432 cars in the parking lot? Which of these answers should we report? This depends on how
well we measured the number of cars. Did we estimate from the size of the parking lot, or did
we actually count every last car?
If we estimated that there are about 23,000 cars, but someone else could reasonably
estimate that there may be 24,000 cars or 22,000 cars, then we should only report 23,000 cars.
This tells any person who sees our number that we are certain that there are more than 20,000
cars, and we think that there are around 23,000 cars, give or take about a 1,000 cars. In other
words, our precision only goes to the thousands column.
If we counted every car to the best of our ability, then we should report 23,432 cars. This
way, anyone who sees our number knows that our confidence in our number goes all the way
down to the units column. If someone else were to count all the cars, they might count 23,431
cars or 23,433 cars, but the difference in the values would be in the units column.
23,000 cars has two significant figures (the 2 and the 3), while 23,432 cars has five
significant figures (the 2, 3, 4, 3, and 2). The more significant figures we report with a number,
the greater the precision we are claiming the measurement has. So if we report more significant
figures than we should, we are technically lying about how well we know, or how carefully we
measured, our number.
Rules for significant figures in our own measurements:
You can estimate (with some uncertainty) between the lines on glassware, a ruler, or a
scale, so you can report one more decimal place than the lines themselves have.
3 mL 5.0 mL
4.9 mL
2.6 mL 4.85 mL
4.8 mL
4.7 mL
2 mL 4.6 mL
Trailing zeros are significant only if there is a decimal point in the number
Numbers that have infinite significant figures:
Quantities that are measured (mass, volume, pressure, etc.) can only be measured with as
much precision as the measuring device allows. Therefore, these values should have the
appropriate number of significant figures associated with them as described above.
Some numbers, however, are “exact.” Meaning that they are exactly that number by
definition with no uncertainty. For example, there are exactly 60 seconds in one minute
by definition. Because there is no uncertainty, exact numbers have an infinite number of
significant figures, and they do not affect the significant figures of the final answer when
they are used in a calculation.
Often in conversion factors, one number is fixed as being exact, while the other is
measured relative to this exact number. For example,
if we use the information that approximately 82,500 82,500 cars 1 day
cars cross a bridge each day in a calculation, we could or
use either of the conversion factors shown to the right. 1 day 82,500 cars
We can define the time period as being exactly one day
(the 1 has ∞ sig.figs.), therefore it is the measured quantity, the 82,500 cars, which
would determine the significant figures of the conversion factor (3 sig.figs.).
The answer to a multiplication or division problem has the same number of significant
figures as the number used in the calculation with the least number of significant figures.
Example: An event takes approximately 4.2 years. How many seconds is this?
In the answer, we can only keep columns on the right side if each number used in the
calculation has a significant figure in that column.
We keep all columns on the left side, because dropping these columns would change the
value of the number, not just the precision to which the value is known.
138.8 86 1219.97
= 138.9 = 130
= 1.3 x 102
In calculations, we use all of the available digits to calculate the answer, and only
round the final answer to the appropriate number of significant figures.
Logarithms:
The answer to the logarithm of a number has the same number of places after the decimal
as the original number had significant figures.
The reverse is also true. The answer to a number raised to an exponent has the same
number of significant figures as the exponent had places after the decimal.
The answer should be calculated using all available digits to avoid compounding
rounding errors. Once the calculation is complete, the final answer should then be
rounded to the appropriate number of significant figures. To determine the appropriate
number of significant figures, retrace your steps through the calculation in order, keeping
track of how many significant figures the answer to each step should have, and
determining how that affects the significant figures in the next step, and so on.