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    Aldehydes, Ketones, and Their Derivatives Carbocyclic and Heterocyclic Ketones Rule C-318

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    This document discusses nomenclature rules for naming carbocyclic and heterocyclic ketones. It describes using prefixes like 'oxo-' or the name of a carbonyl-containing radical to indicate carbonyl groups when another group has priority as the principal group. It also covers how to name compounds where two cyclic systems are directly linked by a carbonyl group and another group.

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    Aldehydes, Ketones, and Their Derivatives Carbocyclic and Heterocyclic Ketones Rule C-318

    Uploaded by

    ivan
    21 views3 pages
    This document discusses nomenclature rules for naming carbocyclic and heterocyclic ketones. It describes using prefixes like 'oxo-' or the name of a carbonyl-containing radical to indicate carbonyl groups when another group has priority as the principal group. It also covers how to name compounds where two cyclic systems are directly linked by a carbonyl group and another group.

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    r79_0289

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    This document discusses nomenclature rules for naming carbocyclic and heterocyclic ketones. It describes using prefixes like 'oxo-' or the name of a carbonyl-containing radical to indicate carbonyl groups when another group has priority as the principal group. It also covers how to name compounds where two cyclic systems are directly linked by a carbonyl group and another group.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    21 views3 pages

    Aldehydes, Ketones, and Their Derivatives Carbocyclic and Heterocyclic Ketones Rule C-318

    Uploaded by

    ivan
    This document discusses nomenclature rules for naming carbocyclic and heterocyclic ketones. It describes using prefixes like 'oxo-' or the name of a carbonyl-containing radical to indicate carbonyl groups when another group has priority as the principal group. It also covers how to name compounds where two cyclic systems are directly linked by a carbonyl group and another group.

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    Aldehydes, Ketones, and their Derivatives ACD/Name

    Carbocyclic and Heterocyclic Ketones Rule C-318

    318.1 - In the presence of a group having priority over carbonyl for citation as principal
    group, or when all the carbonyl groups cannot be included in the ketone functional class
    name, the presence of carbonyl-oxygen atoms is indicated by the prefixes "oxo-", "dioxo-
    ", etc., or by use of the name of a carbonyl-containing radical. Such radicals are: (a) acyl
    radicals, for example, acetyl, valeryl, hexanoyl, benzoyl (see also Rule C-318.2); (b) oxo-
    substituted radicals; (c) certain radicals denoted by trivial names.

    Examples to Rule C-318.1

    Trivial names of radicals (see c above)

    Complete names
    318.2 - When two cyclic systems are directly linked by a carbonyl group and another
    group is also present that has priority for citation as principal group, the compound is
    named by one of the following methods: (a) The cyclic component having the larger
    number of groups with such priority is named as parent and the other is named as part of
    an acyl group substituted in it. (b) If the ring systems are identical and have the same
    number of groups with such priority the nomenclature for assemblies of identical units
    (Subsection C-0.7) is used with the name "carbonyl" to denote the bivalent >CO radical.
    (c) If different cyclic components have the same number of groups with such priority, the
    senior ring system is named as parent and the other is named as part of an acyl group
    substituted in it.

    Examples to Rule C-318.2


    See Recommendations'93 R-5.6.2

    Next:
    Ketenes Rule C-321
    Acetals and Acylals Rule C-331, Rule C-332, Rule C-333

    This HTML reproduction of Sections A, B and C of IUPAC "Blue Book" is as close as possible to the published version [see
    Nomenclature of Organic Chemistry, Sections A, B, C, D, E, F, and H, Pergamon Press, Oxford, 1979. Copyright 1979
    IUPAC.] If you need to cite these rules please quote this reference as their source.

    Published with permission of the IUPAC by Advanced Chemistry Development, Inc., www.acdlabs.com, +1(416)368-3435
    tel, +1(416)368-5596 fax. For comments or suggestions please contact webmaster@acdlabs.com

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