Series Test 1 Chemistry Class Xii

SERIES TEST – 01 [2020-21]
Class – XII Science Time – 3hrs

Subject – Chemistry F.M - 70
SECTION A Short Answer Type 1 Questions [1 marks( 01 – 20])
1. Name a ferroelectric compound?
2. A compound formed by element A and B crystallizes in a cubic structure in which

A atoms are at the centre of the cube and B atoms are at the face centres. What is the
formula of the compound :
3. What is the co-ordination number of sodium in Na2O .
4.In a face centred cubic lattice, a unit cell is equally shared by how many faces?
5. What is the percentage of free space in body centred cubic unit cell .
6. Copper crystallizes in a face-centred cubic lattice with unit edge length of 361 pm.
What is the radius of copper atom in pm?
7. A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% solution of a

substance X. What is the molar mass of X .
8. 2.5 litres of 1 M NaOH solution is mixed with 3.0 litres of 0.5 m NaOH solution.
Find the molarity of the resulting solution :
9. What is the van’t Hoff factor for a solute that associates in solution ?
10. Calculate the Mole fraction of a solute in 2.0 molal aqueous solution .
11. 5.85 g of NaCl is dissolved in water and the solution is made upto 0.5 litre.
Calculate the molarity of solution .
12. KMnO4 is a strong oxidizing agent in acidic medium. To provide acidic medium,
H2SO4 is used instead of HCl. What is its reason ?
13. A current is passed through two cells connected in series. The first cell contains
X(NO3) (aq) and the second cell contains Y(NO3)2 (aq). The relative atomic masses
of X and Y are in the ratio 1 : 2. What is the ratio of the liberated mass of X to that
of Y ?
14. When 0.1 mole MnO4- is oxidized,calculate the quantity of electricity required
to completely oxidize MnO42- to MnO4- .
15. Calculate the time taken to completely decompose 36 g of water by passing 3

ampere current .
16. If 0.5 amp current is passed through acidified silver nitrate solution for 100
minutes then calculate the mass of silver deposited on cathode, (eq. wt. of silver
nitrate = 108) .
17. 60% of first order reaction was completed in 60 minutes. What is the time
required to complete 50% of the same reaction ?
18. In the first order reaction, half of the reaction is completed in 100 seconds. What
is the time for 99% of the reaction to occur ?
19. For a reaction A + 2 B → C, what is the amount of C formed by starting the

reaction with 5 moles of A and 8 moles of B ?
20. In a first order reaction, the concentration of the reactant decreases from 0.6 M
to 0.3 M in 30 minutes. Calculate the time taken for the concentration to change from
0.1 M to 0.025 M .
SECTION B Short Answer Type 2 Questions [2 marks (21 -30)]
21. Define the term ‘amorphous’. Give a few example of amorphous solids.
22. How many lattice points are there in one unit cell of each of the following lattices
(a) face centred cubic (b) body centred cubic ?
23. (a) What is meant by the term coordination number ?
(b) What is the co-ordination number of atoms
(i) in a cubic close packed structure
(ii) in a body centred cubic structure ?
24. A cubic solid is made of two elements elements P and Q. Atoms Q are at the
corners of the cube and P at the body centre. What is the formula of the compound
? What is the co-ordination number of P and Q ?
25. Calculate the percentage composition in terms of mass of a solution obtained by
mixing 300 g of a 25 % and 400 g of a 40 % solution by mass.
26. State Henry’s law and mention some of its important applications.
27. Define conductivity and molar conductivity for the solution of an electrolyte.
Discuss their variation with concentration.
28. The conductivity of 0.20 m solution of KCl at 298 K is 0.0248 S cm-1. Calculate
its molar conductivity.
29. From the rate expression for the following reactions determine the order of the
reaction and the dimensions of the rate constant.
(a) 3NO(g) → N2O(g) + NO2(g) ; Rate = k [NO]2
(b) CH3CHO(g) → CH4(g) + CO(g) ; Rate = k [CH3CHO]3/2
30. The rate of decomposition of NH3 on platinum surface is zero order. What are
rate of production of N2 and H2 if k = 2.5 x 10-4 Ms-1?
SECTION C Short Answer Type 3 Questions [3 marks (31-40)]
31. Classify each of the following solids as ionic, metallic, molecular, net
work(covalent) or amorphous:
(a) Tetra phosphorus decoxide (P4O10) (b) Graphite (c) Brass
(d) Ammonium phosphate(NH4)3PO4 (e) SiC (f) Rb
32. The vapour pressure of water is 12.3 kPa at 300K. Calculate the vapour pressure
of 1 molal solution in it.
33. Calculate the amount of benzoic acid (C6H5COOH) required for preparing 250
mL of 0.15 M solution in methanol.
34. Arrange the following metals in the order in which they displace each other from
their salts.
Al, Cu, Fe, Cu
35. Given the standard electrode potentials
K+/K = - 2.93 V , Ag+/Ag = 0.80 V
H2+/Hg = 0.79 V ; Mg2+/Mg = -2.37 V , Cr3+/Cr = - 0.74 V

Arrange these metals in increasing order of their reducing power.
36. Depict the galvanic cell in which the reaction
Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place. Further show :
(i) which electrode is negatively charged ?
(ii) the carriers of the current in the cell.
(iii) individual reaction at each electrode.
37. Write the Nernst Equation and calculate e.m.f. of the following cells at 298 K :
(i) Mg(s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu(s)
(ii) Fe(s) | Fe2+ (0.001 m) || H+ (1M) | H2(g) (1 bar) | Pt(s)
38. How much charge is required for the reduction of :
(i) 1 mol of Al3+ to Al (ii) 1 mol of Cu2+ to Cu (iii) 1 mol of MnO4- to Mn2+
39. A first order reaction takes 40 minutes for 30% decomposition. Calculate its half
life period.
40. The rate of a particular reaction quadruples when the temperature changes from
293 K to 313 K. Calculate the energy of activation of the reaction (R = 8.314 JK -
1
mol-1).

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SERIES TEST – 01 [2020-21]

Class – XII Science Time – 3hrs

1. Name a ferroelectric compound?

2. A compound formed by element A and B crystallizes in a cubic structure in which

3. What is the co-ordination number of sodium in Na2O .

7. A 5% solution of cane sugar (molar mass = 342) is isotonic with 1% solution of a

15. Calculate the time taken to completely decompose 36 g of water by passing 3

19. For a reaction A + 2 B → C, what is the amount of C formed by starting the

SECTION B Short Answer Type 2 Questions [2 marks (21 -30)]

(a) face centred cubic (b) body centred cubic ?

23. (a) What is meant by the term coordination number ?

(b) What is the co-ordination number of atoms

(i) in a cubic close packed structure

(ii) in a body centred cubic structure ?

(a) 3NO(g) → N2O(g) + NO2(g) ; Rate = k [NO]2

(b) CH3CHO(g) → CH4(g) + CO(g) ; Rate = k [CH3CHO]3/2

SECTION C Short Answer Type 3 Questions [3 marks (31-40)]

K+/K = - 2.93 V , Ag+/Ag = 0.80 V

H2+/Hg = 0.79 V ; Mg2+/Mg = -2.37 V , Cr3+/Cr = - 0.74 V

36. Depict the galvanic cell in which the reaction

Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place. Further show :

(i) which electrode is negatively charged ?

(ii) the carriers of the current in the cell.

(iii) individual reaction at each electrode.

(i) Mg(s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu(s)

(ii) Fe(s) | Fe2+ (0.001 m) || H+ (1M) | H2(g) (1 bar) | Pt(s)

38. How much charge is required for the reduction of :

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