Heat 1
Heat 1
Heat 1
THERMOMETRY
TEMPERATURE
The temperature of a body is a number which expresses its degree of hotness or coldness on
some chosen scale.
THERMOMETERS
Thermometric property
Is that property in which quantity value of a thermometer varies linearly and continuously
with temperature
The thermometric property is also called physical property of a thermometer.
(iv) High boiling point and low freezing point (if it is liquid)
TEMPERATURE SCALES
This is a temperature scale in which the fixed points are the temperatures at standard pressure
of ice in equilibrium with water (0 ) and water in equilibrium with steam (100 )
The scale between these two temperatures is divided into 100 equal parts and each part is
called a degree.
This is a temperature Scale in which the temperature of boiling water is taken as 212 and the
temperature of pure melting ice is taken as 32
The interval between these two reference temperatures is divided into 180 equal parts and each
part is called degree Fahrenheit ( )
The lowest possible temperature which can be measured by this scale is assigned the value zero
(OK) called absolute zero
It is the lowest temperature theoretically attainable at which the random motion of molecules
and atoms in a substance is at minimum.
The temperature of a substance cannot be lowered further by decreasing the random motion.
The physical property of a material should vary linearly and continuously with temperature.
Examples
(i) The length of liquid column in a glass tube varies linearly and continuously
with temperature.
Length temperature
=k +0
Compare y= +
(ii) The volume of a gas at constant pressure varies linearly and continuously
with temperature.
Volume temperature
V T
V=K T +0
Compare y= +
(iii) The pressure of a gas at constant volume varies linearly and continuously
with temperature
Pressure temperature
P T
P=K T +0
Compare y= +
Is the temperature at which pure ice can exist in equilibrium with water pure at standard
atmospheric pressure (i.e. at 760mmHg).
Is the temperature at which pure water can exist in equilibrium with its vapor at standard
atmospheric pressure.
Is that unique temperature at which vapor, liquid and solid phases of a substance exist in
equilibrium.
The triple point is particularly useful, since there is only one pressure at which all three
phases (solid, Liquid and gas) can be in equilibrium with each other.
Example, For water the triple point is 273.16K and it occurs at a pressure of 611.2Pa
Different materials do not expand in quite the same way over a wide range of temperatures.
Consequently, if we calibrate different kinds of thermometers by using ice point and steam point as the reference
marks they will not agree precisely (accurately).
Different results are obtained when different kinds of thermometers are used to measure the same temperature except
at the calibrated fixed point.
When there is a change of temperature, the physical property of a material also changes.
Since the physical property of a material varies linearly and continuously with temperature then
we have:
0 X0
100 X 100
CASE 1
= 100
Change in property = -
100 ( - )
100 = K( - ) …………………………….(1)
Change in temperature =
- )
= ……………………………..(2)
Dividing
Consider a physical property P of a material which varies linearly and continuously with
temperature.
Similarly T PT
T = kP T …………………………….(2)
Dividing
T = x T Trip
TYPES OF THERMOMETERS
There are so many types of thermometers but they all have common fact that they depend on
some physical property of a material which changes with temperature.
In this type of thermometer the length of mercury in a glass tube is the thermometric property
of a material when the temperature changes.
This means that in the temperature scale equation, becomes length
(ii) Its expansion is nearly uniform over the ordinary range of temperatures.
(iii) It can be easily seen through glass because it is opaque and shining liquid.
(iv) It does not wet glass no mercury remains on the sides of the glass tube
when the mercury level falls.
(v) It has low specific heat capacity. Therefore it does not absorb much heat
from the body whose temperature is to be measured.
B 3 is a glass tube containing mercury which is open the atmosphere at its upper end.
The volume of air in B 1 is maintained constant by raising or lowering the glass tube B 3 until the
mercury in B 2 is at the fixed mark “O”.
OPERATION
When the thermometer is in use the bulb is placed inside the enclosure whose
temperature is required.
Keeping the volume of air in B 1 constant by raising or lowering the glass tube B 3 , the
pressure of air in B 1 at ice point (0 ), steam point (100 ) and at the unknown temperature
( ) are determined.
If P denote pressure of a gas/air at constant volume, then one can talk of pressure at 0 ,
100 and as P 0 , P 100 and respectively
Gas thermometer is an ideal thermometer because the increase in volume or pressure of a gas
with temperature is independent of the nature of the gas.
(i) It is more sensitive than liquid in glass thermometer because the expansion
of gases is many times greater than that of any liquid.
(iv) It can be used to measure very low as well as very high temperatures.
Example
- Hydrogen gas thermometer can measure temperature from – 200 to 500
(ii) The air in the capillary tube is not at the temperature being measured.
(iii)The air in the capillary tube is not at the temperature being measured
The Platinum resistance thermometer is based on the principle that the electrical resistance of a
pure metal increases with increasing in temperature and vice versa.
Experiments show that the resistance of a pure metal at any temperature is given by:
2
In practice''b'' is much less than “a” and hence we can ignore the term b
= R 0 (1 + a )
Here “a” is called temperature coefficient of resistance of the material of the wire (symbol,
)
CONSTRUCTION
A sample from a platinum resistance thermometer consist of a platinum wire that would be
around the mica former.
The wire is enclosed in a protective tube of quartz, glass or porcelain tube depending upon the
type of application and temperature range.
The platinum wire is used because of its high temperature coefficient of resistance and high
melting point (1773 )
Therefore, considerable change in resistance occurs for a relatively small change in temperature.
OPERATION
The platinum resistance thermometer forms one of the four arms of the Wheatstone bridge.
R 1 and R 2 are fixed resistors while R 3 is a variable resistor.
The bridge is often kept at a considerable distance from the testing point
Under ordinary condition the bridge is balanced, that means the galvanometer shows no reading.
When the temperature changes the resistance r of the resistance thermometer also change
Consequently, the bridge no longer remains balance and some current flows through the
galvanometer.
The change in resistance (and hence current through G) is a measure of the magnitude of
temperature.
The accuracy of the platinum resistance thermometer depends on how accurately the bridge
can be balanced.
Let R 0 , R 100 and be resistance of platinum wire at ice point (0 ), steam point (100 ) and at
the unknown temperature respectively
(ii) Requires additional equipments such as the bridge circuit, power supply etc.
(iv)THERMOCOUPLE THERMOMETER
A thermoelectric ( ) is generated in the device when the ends are kept at two
different temperatures.
The magnitude of the generated is related to the temperature difference between the two
junctions.
One of the two junctions called the hot or measuring junction is placed at the temperature
to be measured.
The other junction( the cold or reference junction) is maintained at a known reference
temperature (usually 0 )
The amount of the generated depends upon the temperature difference between the
hot and the cold junction
The greater the the greater is the temperature difference between the junctions.
When the cold junction of a given thermocouple is kept constant at 0 and the hot
junction temperature 0 is varied. The e. m. f is found to relate with the temperature
difference between the junction by the equation
This is a parabolic equation and hence a graph of E against is a parabola of the nature shown
in the figure below.
Where Temperature of the cold junction
Neutral temperature
Inversion temperature
Neutral temperature ( )
Inversion Temperature
Is the temperature to which the hot junction of a thermocouple must be raised in order that the
thermoelectric e. m. f in the whole circuit becomes zero.
THERMOCOUPLE
- = -
+ = +
2 = +
From the relationship between E and
0 = A + 2B n
2B n
2
E=A –B
When E = 0 then =
(1) When the inversion temperature is exceeded the thermoelectric (e. m. f) in the
thermocouple is reversed.
(2) The use of a thermocouple is restricted in the temperature range between 0 and neutral
temperature It is because, beyond neutral temperature the thermoelectric e. m. f
decreases with increasing temperature
Therefore they have very little effect on the temperature of the body they are measuring.
(ii) As the output voltage is less than 10mV a very sensitive meter is
required.
In these instruments high temperatures are measured by observing the radiation from the hot
body.
The thermal radiation from the hot body is compared in terms of color with thermal radiation
from the lamp filament.
When a pyrometer is used a hot wire filament in the pyrometer is viewed against a glowing
object.
The filament current increased from zero until it makes the filament exactly the same color as
the following object.
A meter in series with the filament can then be calibrated directly in terms of source temperatures,
known using the laws of radiation.
A thermometer uses mercury as liquid in glass experiments show that the length of mercury at
0 and 100 are 5cm and 7cm respectively. At a certain temperature the length of the
mercury is found to be 6.5cm, find this certain temperature. (Answer = 75 )
Problem 02
The pressure recorded by a constant volume gas thermometer at a Kelvin temperature T is 4.80
x 104Nm-2.
Calculate T if the pressure at triple point 273.16K is 4.20 x 104Nm-2. (Answer. T = 312K)
Problem 03
What temperature will the platinum thermometer indicate when the temperature on a gas scale
is 200
Problem 04
The pressure of air in a constant volume gas thermometer is 80cm and 109.3cm at 0 and
100 respectively. When the bulb is placed in hot water, the pressure is 100cm. calculate the
temperature of hot water
Problem 05
Problem 06
A constant mass of a gas maintained at constant pressure has a volume of 200 at the
temperature of melting ice, 273.2 at the temperature of water boiling under standard
pressure and 525.1 at the normal boiling point of sulphur. A platinum wire has resistances
of 2.00 , 2.778 , and 5.280 at these temperatures. Calculate the values of boiling- point of
sulphur given by the two sets of observations and comment on the results.
Problem 07
In the thermocouple, the temperature of the cold junction is 10 while the neutral temperature
is 270 . What is the value of temperature of inversion?.
Problem 08
E = +
Where is the temperature of the hot junction and the cold junction being at 0 .
If = 10 V / and = V/ , find
Problem 09
Problem 10
The resistance of a platinum varies with temperature t according to the equation R 0 (1
+ 8000bt – bt2) where “b” is a constant.
Calculate the temperature on platinum scale corresponding to 400 on the gas scale
Problem 11
(b) The resistance of a platinum resistance thermometer is 1.20 when measuring a Kelvin
temperature T of a body and 1.00 at the triple point of water. Find T and its centigrade
equivalent.
Problem 12
(b) The resistance of a platinum wire at temperature T measured on a gas scale is given by
R (T) = R 0 ( )
What temperature will the platinum thermometer indicate when the temperature on the gas
scale is 200 ?
Problem 13
(a) Define
(iii) What are the advantages of gas thermometer over liquid in-glass
thermometers?
Problem 14
(a) (i) Describe how mercury in glass thermometer could be made sensitive.
(b) (i) Platinum resistance thermometer and constant volume gas thermometer are based on
different thermometric properties but they are calibrated using the same fixed points. To what
extent are the thermometers likely to agree when used to measure temperature near the ice
point and near the steam point.
(ii)The resistance of the element of a platinum resistance thermometer is 2.0 at ice point and
2.73 at steam point. What temperature on the platinum resistance scale would correspond to
resistance value of 8.34 and when measured on the gas scale the same temperature will
correspond to a value of 1020 ? Explain the discrepancy.
Problem 15
(b) Explain
(i) Why at least two (2) fixed points are required to define a
temperature scale?
(i) Conduction
(ii) Convection
(iii) Radiation
THERMAL CONDUCTION
This is the process in which heat flows from the hot end to the cold end of the solid body
without there being any net movement of the particles of the solid.
MECHANISM 1
The molecules of a solid vibrate about their fixed positions with an energy that increases with
temperature.
When a part of the solid is heated, the molecules there start vibrating more violently.
Since neighboring molecules are bound to each other, a molecule vibrating with larger energy
will transfer some of its energy to its neighbors which in turn will transfer energy to the next
neighbors and so on.
MECHANISM 2
In case of metals heat energy can also be transported by the free electrons.
Since the electrons are very small, they can travel rapidly around throughout the specimen
transferring energy by collision to other electrons and other molecules.
Hence, the electrons are more effective in transferring energy from the hotter part to the colder
part of the material than the mechanism explained above (mechanism 1)
This explains why thermal conduction in metals is much more than that in insulators
In metals heat energy is mainly carried by the free electrons although some energy is carried
by intermolecular vibration.
IMPORTANT TERMS
Symbol, or
Symbol ( - ) or d
Heat flows from the region of higher temperature to the region of lower temperature and if >
then,
Temperature difference = -
Symbol or
Temperature gradient = =
This is an equilibrium point in a material when at every point the temperatures are constant.
A material enclosed by an insulator (bad conductor of heat) so that the heat loss to the
surrounding is negligible.
A material which is not enclosed by an insulator so that the heat is lost to the surrounding.
1. UNLAGGED CONDUCTOR
Consider an unlagged metal bar AB whose ends have been soldered into the metal tanks H and
C
H contains boiling water and C contains ice water.
Heat flows from the hot end to the cold end of the bar and when the conditions are steady the
temperature are measured at points along the length of the bar.
This happens simply because some amount of heat is lost to the surrounding by convection and
radiation.
2. LAGGED CONDUCTOR
If the metal bar is well-lagged with a bad conductor of heat such as asbestos
and wool the temperature now falls uniformly from the hot end to the cold
end of the bar.
THERMAL CONDUCTIVITY
Let and be temperature on the opposite sides of the conductor with >
Experiments show that the heat flow per second from the hot sides to the cold side of the
conductor is:
- )
(iii) Inversely proportional to the perpendicular distance between the
concerned faces
Definition
The coefficient of thermal conductivity K of a material is the rate of flow of heat per unit area
per unit temperature gradient when the heat flow is perpendicular to the faces of a thin parallel
– sided slab of the material under steady state conditions.
UNIT OF K
From equation (2)
K=
……………………..(3)
The sign show that the heat flows in the direction of decreasing temperature i.e the
temperature diminishes as the length increases.
The value of K for some common substances at room temperature are as shown in the table
below:
Substance K in Wm -1K-1
Silver 418
Copper 385
238
Aluminum
Iron 80
Lead 38
Mercury 8
Brick -1
Rubber 0.2
Air 0.03
Substance for which k is large conducts heat rapidly and are said to be good conductors of heat.
COMPOSITE BARS
A composite bars is that bar consisting of two or more metal bars of different materials joined
end to end.
Assuming the bar is well – lagged so that no heat leaves from it.
Condition
At steady state condition, the heat flowing into one end of the bar is equal to that flowing out of
the other end.
The rate at which heat flows is one material is equal to that in the other material.
= K1A = K2A
Where , and are the temperatures at the ends of the bars respectively.
= KA
I =
From equation (1) and equation (2) above both and I are flow quantities.
In equation (1) the heat flows per second produced by a temperature difference .
In equation (2) the flow of current I ( = charge flow per sec) is produces by potential difference
V
K = Thermal conductivity
Alternative expression of R
= KA
But =