UNIT III: Solutions NAME _____________________

Review Packet for Exam....next Monday

LAB SECTION _____________

Part I. USE THE ION TABLE & SOLUBILITY TABLE (pink)

________ 1. In the following reaction what substance is the precipitate?

1 Zn(NO3)2(aq) + 1 Na2CO3(aq) à 2 NaNO (aq) + ZnCO (s)

3 3

________ 2. In the following reaction what substance is the precipitate?

2 AgNO3(aq) + 1 CaBr2(aq) à 2 AgBr + Ca(NO ) 3 2

________ 3. What precipitate is formed when Mg(IO3)2(aq) and BaCl2(aq) are combined?

________ 4. What precipitate is formed when AgNO3(aq) and SrS(aq) are combined?

________ 5. Is strontium hydroxide SOLUBLE or INSOLUBLE?

________ 6. Is tin(IV) hydroxide SOLUBLE or INSOLUBLE?

________ 7. What is the formula for sodium sulfate?

________ 8. What is the formula for magnesium phosphate?

________ 9. What is the formula for chromium(III) oxide?

________ 10. What CATION forms when sodium phosphate, Na3PO4, is dissolved in water: Na3+ or Na+?

________ 11. What ANION forms when phosphoric acid, Na3PO4, is dissolved in water: PO43- or 4 PO3-

________ 12. What CATION forms when potassium nitrate, KNO3, is dissolved in water: K- or K+?

________ 13. What ANION forms when potassium nitrate, KNO3, is dissolved in water: NO3- or 3 NO-?
________ 14. What are the ions and correct number of ions when Al(NO3)3 is dissolved in water:

3 Al3+ + (NO3)3- or Al3+ + 3 NO3-?

________ 15. Show the correct ionization reaction for lithium sulfate, Li2SO4(aq).

____________________________________________________________________

________ 16. When aluminum sulfate, Al2(SO4)3(s), is dissolved in water you get the following ionization
reaction:

Al2(SO4)3(s) à 2 Al 3+ 2-
+ 3 SO4

What is the total number of IONS produced by the ionization of one molecule of Al2(SO4)3(s) in water?

________ 17. Which of the following pairs of reactants will produce an ionic (precipitation) reaction?

a. NaCl(aq) + Mg(s) à
b. Na2SO4(aq) + NH4NO3(aq) à
c. KCl(aq) + Na2SO4(aq) à
d. Pb(NO3)2(aq) + NaBr(aq) à
e. CH4(g) + O2(g) à

PART II. CONDUCTIVITY STUFF

_________ 1. List two general substances that will NOT form free ions when they dissolve in water.

_________

_________ 2. Which of the following compounds will NOT form free ions when dissolved in water?

a. NaI c. HCH3COO, vinegar

b. CH3CH2OH, alcohol d. (NH4)3PO4

________ 3. Which of the following will light the light bulb or beep the beeper, when tested with the
conductivity testers that you have seen or used in this unit.

a. NaCl(s) b. NaCl(aq) c. BOTH

Define a STRONG ELECTROLYTE: _________________________________________________________

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Define a WEAK ELECTROLYTE: __________________________________________________________

Define a NON-ELECTROLYTE: ___________________________________________________________

________ Ionic compounds will conduct an electric current when they are

a. solidified c. frozen
b. dehydrated d. dissolved in water

PART III. Types of Equations

1. Write in the equations for the following

Sodium sulfate + silver nitrate à ?

Total balanced equation

Total ionic equation

Net ionic equation

Is this a chemical change? How do you know?

2. Write the balanced net ionic equation for the formation of the white precipitate, lead sulfate, PbSO4(s).

__________________________________________________________

3. Write the balanced net ionic equation for the formation of the white precipitate, strontium phosphate,
Sr3(PO4)2(s).

__________________________________________________________

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Part IV: Phase changes

The following questions refer to the graph below. The graph was created by collecting data with a method
similar to the Heating & Cooling Curves experiment EXCEPT the substance changed from a SOLID to a LIQUID
to a GAS.

80

D E
Temp oC 60

40 B C

20

A
0
10 20 30
Time in Minutes
1. The portion of the graph between C and D represents the time the substance is:

A. being warmed as a solid

B. being warmed as a liquid
C. changing from solid to liquid at its melting temperature
D. changing from a liquid to gas at its boiling temperature

2. The portion of the graph between D and E represents the time the substance is:

A. being warmed as a liquid

B. being warmed as a gas
C. changing from solid to liquid at its melting temperature
D. changing from liquid to gas at its boiling temperature

3. Which of the following statements does not agree with the above graph:

A. The substance sublimes at 80oC.

B. The substance freezes at 40oC.
C. The liquid range (temperature at which this substance is a liquid is (40 - 65).
D. The boiling point for this substance is lower than that of water.

4. Hot water evaporates faster than cold water because

A. the average velocity of the water molecules decreases upon heating.

B. the average kinetic energy of water molecules increases upon heating.
C. water expands when heated.
D. the density of water increases upon heating.

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5. Circle which of the following are intensive properties:

A. melting point B. mass C. density D. boiling point E. volume

6. Which phases changes that we discussed are exothermic?

7. Which phase change is from a solid to a gas?

8. What is the difference between an extothermic and endothermic process?

Part V: Balancing Equationa and Types of Reactions

1. You should know the 5 types of chemical reactions and be able to identify the type of reaction when
given a reaction.

List the names of the 5 types here.

a. _________________ b. _________________ c. _________________

d. _________________ e. _________________

Which type of reaction are the following:

2 H2(g) + O2(g) ® 2 H2O(l)

Al(s) + 3 AgNO3(aq) ® 3 Ag(s) + Al(NO3)3(aq)
AgNO3(aq) + NaCl(aq) ® AgCl(s) + NaNO3(aq)
2 H2O2(l) ® O2(g) + 2 H2O(l)
C7H16(l) + 11 O2(g) ® 7 CO2(g) + 8 H2O(g) + energy

2. Which of the following chemical reactions is not balanced?

(A) 2 C8H18 + 25 O2 ® 18 H2O + 16 CO2 + energy

(B) S8 + 8 O2 ® 8 S O2
(C) 16 HCl + 2 KMnO4 ® 8 H O + 2 KCl + 2 MnCl
2 2 + 5 Cl2
(D) 1 NaCl + 1 AgNO3 ® 1 AgCl + 1 NaNO 2

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 3. Write the balanced equation for the complete combustion of heptane, C7H16(l), one of the components
in car gasoline.

4. When silver nitrate, AgNO3(aq), reacts with sodium chloride, NaCl(aq), what is the white chemical product
that is soluble in water.

(A) AgCl (B) Ag (C) NaNO3 (D) NaCl

5. Balance the following equation:

___ Pb(C2H3O2)2 + ____ (NH4)3PO4 ® ____ Pb3(PO4)2 + ____ NH3(g) + ____ HC2H3O2

6. Balance the following reaction if the mole ratio of

__10_ C(s) + ___ SiO2(s) + ___ Ca3(PO4)2(s) ® __1_ P4(s) + ___ CaSiO3(s) + ___ CO(g)

7. Balance this reaction:

____ SiO2(s) + ____ C(s) ® ____ SiC(s) + ____ CO(g)

8. Explain where to find products and reactants in a chemical equation.

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