CHAPTER-1 Finalised
CHAPTER-1 Finalised
CHAPTER-1 Finalised
INTRODUCTION
1.1 Water Scarcity
Water is a basic necessity of a man along with food and air. Fresh water resources usually
available are rivers, lakes and underground water reservoirs. About 71% of the planet is covered
in water, yet of all of that water is found in oceans, only 2.5% of the earth’s water is freshwater
and 98.8% of that water in ice and groundwater. Less than 1% of all freshwater is in rivers, lakes
and the atmosphere.
Distillation is one of many processes available for water purification, and sunlight is one of
several forms of heat energy that can be
used to power that processes. To dispel a
common belief, it is not necessary to boil
water to distill it. Simply elevating its
temperature, short of boiling, hastens the
distillation process it also can force
unwanted residue into the distillate,
defeating purification.
Globally, 15% of patients develop an infection during a hospital stay, with the proportion
much greater in low-income countries. Inadequate management of urban, industrial and
agricultural wastewater means the drinking-water of hundreds of millions of people is
dangerously contaminated or chemically polluted. Natural presence of chemicals, particularly in
groundwater, can also be of health significance, including arsenic and fluoride, while other
chemicals, such as lead, may be elevated in drinking-water as a result of leaching from water
supply components in contact with drinking-water.
Some of the important facts from recent articles regarding water are
In 2020, 5.8 billion people used safely managed drinking-water services – that is, they
used improved water sources located on premises, available when needed, and free from
contamination.
The remaining 2 billion people without safely managed services in 2020 included - 1.2
billion people with basic services, meaning an improved water source located within a
round trip of 30 minutes.
368 million people taking water from unprotected wells and springs.
122 million people collecting untreated surface water from lakes, ponds, rivers and
streams.
Fig 1.3 water Scarcity
In this separation technique, the mixed components in water are separated by the application of
heat. It is based on the differences in boiling points of the individual components. The boiling
point characteristics depend on the concentrations of the components present. Thus, the
distillation process depends on the vapor pressure characteristics of liquid mixtures. The basic
principle described as the input of heat energy raises vapor pressure. When the vapor pressure
reaches its surrounding pressure, the liquid mixture boils and distillation occurs because of the
differences of volatility in the mixture.
Distilled water purification technology was originally developed for industrial purpose.
However, it came eventually for home use. Since, this process is not very effective in removing
organic chemicals so the carbon filter system must be added to make the water really safe to
drink. The carbon filters require regular changing because they can quickly become breeding
grounds for bacterial growth.
1.3.1a Benefits
Removes a broad range of contaminants (toxic chemicals, heavy metals, bacteria, viruses,
parasites).
The process is not very effective which are of lower volatility (viz. organics) compared to
water.
1.3.2 Adsorption
In this physical process, dissolved contaminants adhere to the porous surface of the solid
particles. It is the surface phenomena and the outcome of surface energy. With the material, all
the bonding requirements of the constituent atoms of the material are filled with other atoms.
However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent
atoms and physical attractive force results. It can be physisorption (originates from vanderwaals
forces) and chemisorption (originates from co-valet forces).
The adsorbent systems are added directly to the water supply or via mixing basin.
Adsorbents combine chemical and physical processes to remove the compounds that impart
color, taste, and odor to water. In principle, all microporous materials can be used as adsorbents.
However, those with well controlled and highly microporous are the most preferred). The porous
solids, e.g., activated carbon, silica gels, alumina’s, zeolites, etc. contain many cavities or pores
with diameters as small as a fraction of a nanometer is useful.
The most commonly used adsorbent is activated carbon—a substance which is quite similar to
common charcoal. Actually, the active carbon is much more efficient because of its high porous
character. The high porous character is generated by treating carbon to steam and high
temperature (1300 °C) with or without oxygen in the presence of inorganic salts (physical
method). The carbon may be of petroleum coke, bituminous coal, lignite, wood products, and
coconut/peanut shells. At high temperature, parts of carbon are oxidized in CO2 and steam. The
gases are evacuated and micro fractures and pores are generated in the carbon structure. It
dramatically increases the carbon surface area, making a useful material for the removal of
contaminants.
1.3.2a Benefits
Activated charcoal is effective for trapping carbon-based impurities (volatile organic
chemicals), chlorine (including cancer-causing by-product tri halo methane’s) as well as
colors and odors.
1.3.2b Limitations
In GAC scheduled filter replacements, it is important to eliminate the possibility of
‘channeling’ which reduces the contact between the contaminant and the carbon.
Therefore, it reduces efficiency, and the accumulation of bacteria in the filter.
The microfiltration and ultrafiltration membranes have a pore size in the range of >10 and 1–
100 nm, respectively, whereas in the case of Nano filtration and reverse osmosis membranes are
in the range of ~1 and <1 nm. Size selective separation operates in case of micro and
ultrafiltration, whereas the size and charge selective separation operate in the latter two. The
membranes are generally based on natural and synthetic polymers (cellulose acetate, cellulose
triacetate, polysulfide, polyamide, etc.). The most popular RO membrane is thin film composite
membranes.
1.3.3a Benefits
Eco-friendly as they do not produce or use any harmful chemicals; compactness and
space requirements are less compared to distillation, and can be designed according to the
requirement.
Ability to remove almost all kinds of contaminates like Cl −, NO3−, F−, SO4, Pb2+, Na+, K+,
Mg2+, organics as well as microorganisms.
No alteration in the taste and smell of water and effective removal of microbes and
toxins.
1.3.3b Limitations
The purified water obtained after reverse osmosis treatment is devoid of useful minerals.
Membrane may become clogged after prolonged use and, hence, requires periodical
replacement of the membrane.
1.3.4a Benefits
1.3.4b Limitations
1.3.5a Benefits
Reusability of the catalyst as it is unchanged during the process.
1.3.5b Limitations
Post-separation of the semiconductor catalysts after water treatment is important and
failing results in catalyst poisoning.
The catalysts with their fine particle size and large surface area to volume ratio create a
strong catalyst agglomeration tendency during the operation.
A spherical solar still consists of a shallow circular basin of diameter that is made of steel. The
circular absorber basin is coated with black paint for maximum absorption of incident solar
radiation. The circular basin is fixed at the middle of the spherical aluminum mesh at radial
height. The saline water is stored in a basin and basin in the spherical solar still is fitted without
having any physical contact with the top cover made of low-density polyethylene (LDPE) sheet.
The LDPE sheet of thickness approximately 0.107 mm is spread over the spherical mesh. A gap
of nearly 0.03 m is maintained between the circular basin and top cover. The evaporated water,
which is condensed on the top cover, passes between this gap, and drips down towards the
A hole in the basin’s sidewall allows saline or wastewater filling, as well as collecting the
condensed water. Moreover, this is also used for inserting the thermocouple wires required for
temperature measurements. When the still is in operation, the hole is closed with an insulating
material to avoid heat and vapor losses.
They should be sturdy enough to resist wind change and slight earth movements
They should be nontoxic and not emit vapors or instill an unpleasant taste to the water
under exposed temperatures.
1. By doping the SiO2 nanoparticles into black paint at the weight concentration ranging
from 10 to 40%, The solar still was tested in a bright sunny climatic condition of
Chennai, Indian (lat. 13° 08′ N and long. 80° 27′ E). Under transient heat flux conditions,
water, basin, and TSS glass temperatures with and without fin were measured. The rate of
heat transfer by convection between the water and absorber plate was increased. Results
revealed that the basin and water temperatures were improved by 10.49% and 10.88%,
respectively when using black paint with SiO2 nanoparticle in the concentration of 20%,
coated on the absorber plate compared to that when using the ordinary black paint, while
using the fins on the absorber plate enhanced the potable water produced by 55.18%
when using 20% SiO2 nanoparticle compared to that of conventional TSS. The cost per
liter of water produced using the flat and finned absorber coated using 20% SiO 2
nanoparticle in black paint is found as 0.0187 and 0.012 $/L respectively.
2. A single slope still (PSS) with egg shells of breed Gallus domesticus cascara as Sensible
heat storage (SHS) material was made in comparison with the conventional solar still
(CSS) to evaluate the productivity of fresh water under the same ambient conditions.
Comparatively, this PSS has higher thermal conductivity than the CSS. The yield
obtained from the PSS is 2.46 L/m2, while the yield from the CSS is 2.07 L/m2. The
average rate at which the rise of output fresh water obtained from the PSS is 18% more
than the fresh water output obtained from the CSS. The daily energy efficiency of the
PSS is 26.07%, and for the CSS, it is only 22.25%. The daily exergy efficiency of the
PSS is 2.36%, and for the CSS, it is only 1.67%. Since using the egg shell will employ as
organic waste management and modification in this still is economical, less initial, and
maintenance cost.
3. With carbon nanotubes (CNT), enhanced with paraffin as a novel energy storage material
for desalination application. The thermo-mechanical properties like density, melting
point, thermal conductivity, etc., of CNT enhanced paraffin were first analyzed and then
integrated with solar desalination application. Three solar desalination stills: (i)
conventional solar still, (ii) solar still loaded with fossil paraffin and (iii) solar still loaded
with CNT-doped paraffin were fabricated and experimented at Chennai, India (Lat. 13°
08′ N, Long. 80° 27′ E). From the investigation, it is inferred that there is a significant
increase (of about 26%) observed in the thermal conductivity of CNT-doped paraffin as
compared to fossil paraffin. The cumulative yield of the conventional still, solar still with
paraffin and solar still with CNT enhanced paraffin was found to be 2.5 kg/m2,
3.4 kg/m2 and 5.8 kg/m2, respectively. There was 41.4% and 26.4% enhancement,
respectively, observed in the daily yield of the solar still with CNT-doped paraffin as
compared to conventional still and the still with virgin paraffin. The productivity
efficiency was 46.45% for the still with CNT blended paraffin contributing to 24% and
19.6% increase in the efficiency as compared to the other two stills considered for
experimentation in this study. Thus, it is concluded that CNT enhanced paraffin is
identified as a better potential energy storage material as compared to conventional
paraffin in solar desalination application.
4. Reflective mirrors and reflective aluminum foil sheet were fixed on inner surfaces of the
single-slope solar distiller, leading to more water production. The presence of reflective
mirrors and reflective aluminum foil sheet on inner surfaces of the solar distillate permits
the reflection of solar radiation falling inside the basin. Experiments were carried out on
three stills: the first distiller is conventional solar still with black painted walls; the
second distiller is conventional solar still with reflective aluminum foil sheet walls; and
the third distiller is conventional solar still with reflective glass mirror walls. The
maximum total drinking water productions from the Conventional solar still (CSS), CSS-
RAFW and the CSS-RGMW are 3.41, 5.1 and 5.54 kg/m 2, respectively. Compared to the
CSS-BPW, the production of drinking water was increased by 68.57% when using the
reflective glass mirrors and 48.57% when using the reflective aluminum foil sheet.
Physical tests
Chemical tests
Bacteriological tests
a) Colour: Colour in water may be caused by the presence of minerals such as iron and
manganese or by substances of vegetable origin such as algae and weeds. Colour tests
indicate the efficacy of the water treatment system.
b) Turbidity: Turbidity in water is because of suspended solids and colloidal matter. It may
be due to eroded soil caused by dredging or due to the growth of micro-organisms. High
turbidity makes filtration expensive. If sewage solids are present, pathogens may be
encased in the particles and escape the action of chlorine during disinfection.
c) Odour and Taste are associated with the presence of living microscopic organisms; or
decaying organic matter including weeds, algae; or industrial wastes containing
ammonia, phenols, halogens, hydrocarbons. This taste is imparted to fish, rendering them
unpalatable. While chlorination dilutes odour and taste caused by some contaminants, it
generates a foul odour itself when added to waters polluted with detergents, algae and
some other wastes.
PH, hardness, presence of a selected group of chemical parameters, biocides, highly toxic
chemicals, and B.O.D are estimated.
1.7 Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is
the reverse of vaporization. The word most often refers to the water cycle. It can also be defined
as the change in the state of water vapor to liquid water when in contact with a liquid or solid
surface or cloud condensation nuclei within the atmosphere. When the transition happens from
the gaseous phase into the solid phase directly, the change is called deposition.
1. Filmwise condensation
2. Dropwise condensation
A Fresnel lens is a type of composite compact lens developed by the French physicist Augustin-
Jean Fresnel (1788–1827) for use in lighthouses. It has been called "the invention that saved a
million ships. The design allows the construction of lenses of large aperture and short focal
length without the mass and volume of material that would be required by a lens of conventional
design.
A Fresnel lens can be made much thinner than a comparable conventional lens, in some
cases taking the form of a flat sheet. The simpler dioptric (purely refractive) form of the lens was
first proposed by count buffoon and independently reinvented by Fresnel. This form of the lens,
entirely invented by Fresnel, has outer elements that use total internal reflection as well as
refraction; it can capture more oblique light from a light source and add it to the beam of a
lighthouse, making the light visible from greater distances.
Dimensions: 97.5 cm x 74 cm
Material: Acrylic
The Fresnel lens reduces the amount of material required compared to a conventional lens by
dividing the lens into a set of concentric annular sections. An ideal Fresnel lens would have an
infinite number of sections. In each section, the overall thickness is decreased compared to an
equivalent simple lens. This effectively divides the continuous surface of a standard lens into a
set of surfaces of the same curvature, with stepwise discontinuities between them.
In some lenses, the curved surfaces are replaced with flat surfaces, with a different angle
in each section. Such a lens can be regarded as an array of prisms arranged in a circular fashion,
with steeper prisms on the edges, and a flat or slightly convex center. In the first (and largest)
Fresnel lenses, each section was actually a separate prism. 'Single-piece' Fresnel lenses were later
produced, being used for automobile headlamps, brake, parking, and turn signal lenses, and so
on. In modern CNC machines and 3-D printers might be used to manufacture more complex
lenses.
Fresnel lens design allows a substantial reduction in thickness (and thus mass and volume of
material), at the expense of reducing the imaging quality of the lens, which is why precise
imaging applications such as photography usually still use larger conventional lenses. Fresnel
lenses are usually made of glass or plastic; their size varies from large (old historical lighthouses,
meter size) to medium (book-reading aids, OHP viewgraph projectors) to small (SLR camera
screens, micro-optics). In many cases they are very thin and flat, almost flexible, with
thicknesses in the 1 to 5 mm range. Most modern Fresnel lenses consist only of refractive
elements. Lighthouse lenses, however, tend to include both refracting and reflecting elements,
the latter being outside the metal rings seen in the photographs. While the inner elements are
sections of refractive lenses, the outer elements are reflecting prisms, each of which performs
two refractions and one total internal reflection, avoiding the light loss that occurs in reflection
from a silvered mirror.