BLR – CO SINDHUBHAVAN

SAHAKARNAGAR, BANGALORE

JEE MAINS

MATHS
PHYSICS
CHEMISTRY
MATHEMATICS
 MATH

DPP -1

1. A wire of length 2 units is cut into two parts which are bent respectively to form a square of side = x
units and a circle of radius = r units. If the sum of the area of the square and the circle so formed is
minimum, then
A) x = 2r B) 2x = r C) 2x     4  r D)  4    x  r

2. Let k and K be the minimum and the maximum values of the function f(x) =
1  x 0.6 in [0, 1]
1  x 0.6
respectively, then the ordered pair (k, K) is equal to


A) 20.4 ,1  
B) 20.4 , 20.6  
C) 20.6 ,1  
D) 1, 20.6 
3. If x = -1 and x = 2 are extreme points of f  x    log x  x 2  x then

1 1 1 1
A)   2,    B)   2,   C)   6,   D)   6,   
2 2 2 2
x
 5 
4. For x   0,  , define f  x    t sin t dt . Then f has
 2  0

A) local minimum at  and 2  B) local minimum at  and local maximum at 2

C) local maximum at  and local minimum at 2 D) Local maximum at  and 2 

k  2x, if x  1
5. Let f : R  R defined by f  x    If f has a local minimum at x = -1, then a possible
2x  3, if x  1
value of k is
1
A) 0 B)  C) -1 D) 1
2
6. Given P  x   x 4  ax 3  bx 2  cx  d such that x = 0 is the only real root of P '  x   0 . If P  1  P 1 ,

then in the interval [-1, 1]

A) P(-1) is not minimum but P(1) is the maximum of P
B) P(-1) is the minimum but P(1) is not the maximum of P
C) Neither P(-1) is the minimum nor P(1) is the maximum of P
D) P(-1) is the minimum and P(1) is the maximum of P
7. The maximum value of the function f  x   3x 3  18x 2  27x  40 on the set S   x  R : x 2  30  11x
is :

1) 122 2) -122 3) -222 4) 222

8. The number of points in  ,   for which x 2  x sin x  cos x  0 , is

A) 6 B) 4 C) 2 D) 0
2 2
9. Let f, g and h be real valued functions defined on the interval [0, 1] by f  x   e x  e  x ,
2 2 2 2
g  x   xe x  e  x and h  x   x 2e x  e x . If a, b and c denote respectively, the absolute maximum of

f, g and h on [0, 1], then

A) a = b and c  b B) a = c and a  b C) a  b and c  b D) a = b = c

 x , for 0  x  2
10. If f  x    . Then at x = 0, f has
1 , for x0

A) a local maximum B) no local maximum C) a local minimum D) no extremum

75
11. On the interval [0, 1], the function x 25 1  x  takes its maximum value at the point

A) 0 B) 1/4 C) 1/2 D) 1/3

12. The function f  x   2 x  x  2  x  2  2 x has a local minimum or a local maximum at x is equal

to
2 2
A) -1 B) C) 2 D)
3 3
13. If f(x) is twice differentiable function such that f(a) = 0, f(b) = 2, f(c) = 1, f(d) = 2, f(e) = 0, where a < b
2
< c < d < e, then the minimum number of zeroes of g  x   f '  x   f ''  x  .f  x  in the interval [a, e]

is
A) 4 B) 5 C) 6 D) 7

14.  
If the function f  x   x 3  3  a  7  x 2  3 a 2  9 x  2 has a positive point of maximum, then a > 0 lies

in
 29 
A)  0,   B) (1, 7) C)  3,   D)  3, 
 7
15. How many real solutions does the equation x 7  14x 5  16x 3  30x  560  0 have ?
A) 7 B) 1 C) 3 D) 5
16. If x and y be two real variables such that x > 0 and xy = 1. Then, find the minimum value of x + y.
A) 3 B) 4 C) 5 D) 2

17. The maximum value of the function f  x   2x 3  15x 2  36x  48 on the set A  {x \ x 2  20  9x} is

A) 7 B) 6 C) 9 D) 5
  a4  5
18. The set of all values of a for which f  x     1 x  3x  log 5, a  1 decreases for all real x is
 1  a 

 3  21   5  27 
A)  4,   1,   B)  3,    2,  
 2   2 

C)  , 4  D) none of the above

2x
19. Total number of critical points of f  x   are equal to
x2
A) 3 B) 2 C) 1 D) 4
ln    x 
20. The function f  x   , x  0 is
ln  e  x 

       
A) increasing on  0,  and decreasing on  e ,   B) decreasing on  0, e  and increasing on  e ,  
 e
C) increasing on  0,   D) decreasing on  0,  

21. The function f  x   ax  b  c x x   ,   , where a > 0, b > 0, c > 0, assumes it’s minimum value

only at one point of

A) a  b B) a  c C) b  c D) a  b  c

22. f  x   2x  cot 1 x  log 1  x 2  x is

A) increasing in  ,   B) decreasing in  ,  

C) increasing in  0,   and decreasing in  , 0  D) decreasing in  0,   and increasing in  , 0 

23. If f  x   x 3  ax 2  bx  c attains it’s local minima at certain negative real number, then

A) a 2  3b  0, a  0, b  0 B) a 2  3b  0, a  0, b  0

C) a 2  3b  0, a  0, b  0 D) a 2  3b  0, a  0, b  0

24. The equation of a curve is y = f(x). The tangents at  , f     , , f    and  , f     make angles

  
, and respectively with the positive direction of the x-axis. Then the value of
6 3 4
 

 f '  x  .f ''  x  dx   f ''  x  dx is equal to

 

1 1
A)  B) C) 0 D) none of these
3 3

 min .f  t  : 6  t  x , x   6, 0 

25. f  x   x 2  4 x and g  x    then f(x) has
 max . f  t  : 0  t  x  , x   0, 6 
A) exactly one point of local minima B) exactly one point of local maxima
C) no point of local maxima, one point of local minima
 D) neither a point of local maxima nor minima

26. If a > b > 0, then maximum value of

 
ab a 2  b2 sin x cos x
 
in  0,  is
2 2 2 2
a sin x  b cos x  2

a 2  b2 a 2  b2
A) a 2  b2 B) C) D) none of these
2 2
27. Let x , y be positive real numbers and m , n positive integers. The maximum value of the expression
xm yn
is :
1  x2 m 1  y 2 n 
mn 1 1
1) 2) 3) 1 4)
6mn 2 4

28. If the function f  x   2x 3  9ax 2  12a 2 x  1 , where a > 0, attains its maximum and minimum at p and q

respectively such that p 2  q , then a equals

1
A) B) 3 C) 1 D) 2
2
29. The maximum volume (in cu.m) of the right circular cone having slant height 3m is :

4
1) 3 3 2)  3) 2 3 4) 6
3

30. If the function f given by f ( x)  x3  3  a  2  x2  3ax  7 , for some a  R is increasing in (0,1] and
f ( x)  14
decreasing [1,5) , then a root of the equation, 2
 0  x  1 is :
 x  1
1) 7 2) – 7 3) 6 4) 5

KEY

1-10 A A A C C A C C D A

11-20 B B C D B D A A B D

21-30 B A D A D B B D C C

SOLUTIONS
1. 4x  2r  2  2x  r  1
S  x 2  r 2
2
 1  r  2
S   r
 2 
dS  1  r   
 2    2r
dr  2  2 
  2 r 1 2
   2r  0  r  x  x  2r
2 2 4 4
 3 2 3  2 
3  3
3  1  x  1  x  5  1  x  5  x 5 
5

1  x  5  5 5  
2. Let f  x   3
and x  0,1  f  x    
2
 
 3 
1 x5 1  x 5 
 
 
 3 3
  3 3 2 
3 
2
3
  1  x 5  1  x  5  1  x  5 x 5   
 1  x 5

1  x  5

5   5 2 2 
  1  x  5 
   x 5
 
2 2
x5  x 1 x x5 1
= 2
 2
0
2 2
x5 1  x  5 x 5
1  x  5

Also, f  0   1  f  x    20.4 ,1

f(a) = 20.4
3. Let f  x    log x  x 2  x


Differentiate both side, f '  x    2x  1
x
Since x = -1 and x = 2 are extreme points therefore f '  x   0 at these points.

Put x  1 and x  2 in f '  x  , we get   2  1  0    2  1 … (i)


 4  1  0    8  2...(ii)
2
1
On solving (i) and (ii), we get 6  3    
2
  2

4. f '  x   x sin x

f ' x   0

 x  0 or sin x  0
 x  2, 
1 1
f ''  x   x cos x  sin x   2x cos x  sin x 
2 x 2 x
At x  , f ''  x   0

Hence, local maxima at x  

At x  2, f ''  x   0

Hence local minima at x  2

 k  2x, if x  1
5. f x  
 2x  3, if x  1

This is true where k = -1

6. We have P  x   x 4  ax 3  bx 2  cx  d  P '  x   4x 3  3ax 2  2bx  c

But P '  0   0  c  0

P  x   x 4  ax 3  bx 2  d

As given that P  1  P  a   1  a  b  d  1  a  b  d  a  0


Now P '  x   4x 3  3ax 2  2bx  x 4x 2  3ax  2b 
As P '  x   0 , there is only one solution x = 0, therefore 4x 2  3ax  2b  0 should not have any real

roots i.e. D < 0

9a 2
 9a 2  32b  0  b  0
32
Hence a, b > 0  P '  x   4x 3  3ax 2  2bx  0  x  0

 P(x) is an increasing function on (0, 1)

 P(0) < P(a)
Similarly we can prove P(x) is decreasing on (-1, 0)
 P(-1) > P(0)

So we can conclude that Max P  x   P 1 and Min P  x   P  0 

 P  1 is not minimum but P(1) is the maximum of P.

7. S : x 2  11x  30  0
 x  6  x  5   0
5 x 6


f '  x   3.3x 2  18.2x  27  9x 2  36x  27  9 x 2  4x  3 
For maximum & minimum f '  x   0 at x  1, x  3

But in [5, 6] f '  x   0

So f  x   function

maximum at x = 6
 3 2
3  6   18  6   27  6   40  122

8. The given equation contains algebraic and trigonometric functions called transcendental equation. To
solve transcendental equations we should always plot the graph for LHS and RHS
Here, x 2  x sin x  cos x

Let f  x   x 2 and g  x   x sin x  cos x

We know that, the graph for f  x   x 2

To plot, g  x   x sin x  cos x

g '  x   x cos x  sin x  sin x

g '  x   x cos x …(i)

g '  x    sin x  cos x ….(ii)

Put g '  x   0  x cos x  0

 3 5 7
 x  0, , , ,
2 2 2 2

3 7
At x = 0, , ,…, f ''  x   0 , so minimum
2 2
 5 9
At x  , , ,...., f'  x   0 , so maximum
2 2 2
So, graph of f(x) and g(x) are shown as
 So, number of solutions are 2
2 2 2 2 2
9. Given function, f  x   e x  e  x , g  x   xe x  e  x and h  x   x 2e x are strictly increasing on [0, 1].

1
Hence, at x = 1, the given function attains absolute maximum all equal to e 
e
 abc
10. It is clear from figure that at x = 0, f(x) is not continuous

Here, f(0) > RHL at x = 0 and f(0) > LHL at x = 0

So, local maximum at x = 0
75
11. Let f  x   x 25 1  x  , x  0,1
75 74
 f '  x   25 x 24 1  x   75 x 25 1  x 
74
 25x 24 1  x  1  x   3x 
74
 25x 24 1  x  1  4x 
For maximum value of f(x), put f '  x   0
74
 25x 24 1  x  1  4x   0
1
 x  0, 1,
4
Also, at x = 0, y = 0
1
At x = 1, y = 0 and at x  , y  0
4
1
 f(x) attains maximum at x =
4
 x, if x  0  x  a, if x  a
12. We know that, x    x a  
 x, if x  0   x  a  , if x  a
 And for non-differentiable continuous function, the maximum or minimum can be checked with graph
as

2x   x  2    x  2  , if when x  2

 2x  x  2  3x  2, if when  2  x   2
 3

Here, f  x   2 x  x  2  x  2  2 x   2
 4x, if when   x  0
3

 4x, if when 0  x  2
 2x  4, if when x  2

2x  4, if x  2

 2x  4, if  2  x   2
 3

 2
 4x, if   x  0
3

 4x, if 0  x  2
 2x  4, if x  2

Graph for y = f(x) is shown as

d
13. Let g  x    f  x  .f '  x  
dx 
To get the zero of g(x), we take function h  x   f  x  .f '  x  between any two roots of h(x), there lies

atleast one root of h '  x   0 .

 g  x  0  h  x  0

 f  x   0 or f '  x   0
 If f(x) = 0 has 4 minimum solutions, f '  x   0 has 3 minimum solutions.

h(x) = 0 has 7 minimum solutions.

 h '  x   g  x   0 has 6 minimum solutions.

14. 
f ' x   3 x 2  2 a  7 x  a 2  9 
f '  x   0  x  7  a  58  14a

The maximum corresponds to the smaller root.

7  a  58  14a  0
29
 7  a 2  58  14a  a  3 . But 58  14a  0  a 
7
15. Conceptual
16. Let f(x) = x + y, where xy = 1
1
f x  x 
x
1 x 2 1
 f ' x   1 
x x
2
Also, f ''  x  
x3
On putting f '  x   0 , we get x  1 , but x > 0 [neglecting x = -1]

f ''  x   0, for x  1

Hence, f(x) attains minimum at x = 1, y = 1

 (x + y) has minimum value 2
x  x 
17. Given, A   2  20  9x      4, 5
x  x 


Now, f '  x   6 x 2  5x  6 
Put f '  x   0  x  2,3

f  2   20, f  3  21, f  4   16, f  5   7

From graph, maximum value of f(x) on set A is f(5) = 7

  a4  4
18. f '  x     1 5x  3
 1  a 
For f(x) to be a decreasing function for all real x, f '  x   0  x  R

[Here, f '  x  may be zero but at most one point]

a4
 1  0
1 a
 a4 
 If  1  0, then f '  x   0from large x 
 1 a 

 a  4  1  a, 4  a  1

 a  4  1  a, a 1

(i) a  4  1  a true for all a > 1

(ii) a  4  1  a,  4  a  1

 a  4  1  a 2  2a  a 2  3a  3  0 and  4  a  1

3  21 3  21
a or a  and  4  a  1
2 2
3  21
 4  a 
2
3  21
From (A) and (B) all possible values of a are given by 4  a  or 1  a  
2
2  x  4 1
 x 2 , x  2   x 3  x 2 , x  2
19. f x    f 'x  
x  2 , x  2  1  4 , x  2
2
 x  x 2 x 3
1 1
f ' 2  0   , f '  2  0 
4 4
Thus, f(x) is non-differentiating at x = 2
4 1
If f '  x   0 , then 3
 2 x4
x x
Thus, there are two critical points namely x = 2, 4.
(Note that x = 0 is not the critical point as x = 0 is not in the domain).
 ex 
ln   x   e.ln  e  x    .ln    x  
 x
20. f 'x  2
 ln  e  x  
 e x 
Now,   x  e  x  ln    0, f '  x   0
  x 
Thus, f(x) is decreasing.
 
 b   a  c  x, x0

 b
21. f  x    b   c  a  x, 0  x 
 a
 b
 a  c  x  b, x
a

These figures clearly indicate that for exactly one point of minima a  c ,

1 1  x  1  2x 2 1 1  2x 2  1  x 2
22. f 'x  2     1     0
1 x2 1  x 2  x  1  x2  1  x2 1 x2 1 x2

 1  x 2  1  x 2 1  2x 2  1  x 2 
 
Hence, f(x) is an increasing function in  ,   .

23. f '  x   3x 2  2ax  b  3  x  x1  x  x 2  where x1  x 2 clearly, f '  x   0  x   x1 , x 2  and

f '  x   0  x   , x1    x 2 ,  

Thus, x  x1 is the point of local maxima and x  x 2 is the point of local minima.

Thus, bigger root of f '  x   0 must be negative.

Hence, a 2  3b  0, a  0, b  0
1
24. Given, f '  x   , f '     3, f '     1
3
  
1 2 
Now,  f '  x  f ''  x  dx   f ''  x  dx    f '  x     f '  x   
  2 

1 2 1 2 1 1 1
  f '      f '     f '     f '     1  3  1  
2 2 2 3 3
25. Bold line represents the graph of y = g(x). Clearly, g(x) has neither a point of local maxima nor a point
of local minima
 
26. 0x 
2
 tan > 0, cot x > 0

Now, f  x  
 
ab a 2  b 2 sin x cos x


ab a 2  b 2 
a 2 sin 2 x  b 2 cos2 x a 2 tan x  b 2 cos2 x



ab a 2  b 2 
2
a tan x  b cot x   2ab
2
f(x) will be maximum when a tan x  b cot x   is minimum. But its minimum value is zero.

 Maximum value of f  x  

ab a 2  b 2 a 2
 b2
2ab 2
x m yn
27.
1  x 1  y 
2m 2n

x m yn
 1   1 
x m  m  x m  yn  n  yn 
x  y 
1 1 1
For max.  
 min  min   2  2 4

28. f  x   2x 3  9ax 2  12a 2 x  1

f '  x   6x 2  18ax  12a 2 ; f ''  x   12x  18a

For max. or min.

6x 2  18ax  12a 2  0  x 2  3ax  2a 2  0

 x  a or x  2a. At x = a max. and at x = 2a min
 p  a and q  2a

As per question p2  q

 a 2  2a  a  2 or a  0 but a  0, therefore, a  2
29.

1
V  r 2 h
3
 (Given h 2  r 2  9 )
1
V   9  h 2  h
3
dV 1 2
  9  3h 
dh 3
dV
For maximum & minimum 0
dh
9  3h 2
h2  3
d2 V 1
   6h   0
dh 2 3
Maximum at h  3

r2  9  h2
r2  9  3
r2  6
1
Vmax   6  3  2 3
3
30. f  x   x 3  3  a  2  x 2  3ax  7

f  x   3x 2  6  a  2  x  3a  0, x  0,1 also f '  x   0, x  1,5

Hence f '  x   0 at x  1

f '  x   3x 2  6  a  2  x  3a

f ' 1  3  6  a  2   3a  0  1  2a  4  a  0

 a  5at a  5

f  x   x 3  9x 2  15x  7
2
f  x   14  x 3  9x 2  15x  7   x  1  x  7
f  x   14
 x 7
 x  12
Root of equation x = 7

DPP-2

 1  1 
1. The minimum value of  1  n  1   is
 sin    cos n  
2
A) 1 B) 2 
C) 1  2 n / 2  D) none of these
 b
2. If ax 2   cx  0 , where a > 0, b > 0, then
x
A) 27ab 2  4c3 B) 27ab3  4c3 C) ab2  c3 D) ab3  c3

3. If f  x   x  ln x and f(0) = 0, then the value of  for which Rolle’s theorem can be applied in [0, 1] is

A) -2 B) -1 C) 0 D) 1/2
4. If f '  x   x  x , where {x} denotes the fractional part of x, then f(x) is decreasing in

 1   1   1   1 
A)   , 0  B)   , 2  C)   , 2  D)   ,  
 2   2   2   2 
4 1  
5. The least value of ‘a’ for which   a , has at lest one solution in the interval  0,  is
sin x 1  sin x  2
A) 9 B) 8 C) 4 D) 1

6.
   
The global maxima of f  x    2  x 2  x  1  is (where {x} denotes fractional part of x, and [.]

denotes greatest integer function)

A) 2 B) 1 C) 0 D) none of these
7. If the line y  mx  2 cuts the parabola 2y  x 2 at points  x1, y1  and  x 2 , y 2  x1  x 2  ,then value of
x2
 x2 
m for which   mx  2   dx is minimum, is
x1 
2 

8 1
A) 2 B) C) D) 0
3 3

 2 3
 x  3x  a, 0  x  2 3
8. Let f  x    . If f(x) has a local maxima at x  , then
 2x  3, 3 2
x
 2
9 9
A) a  0 B) a   C) a  D) none of these
4 4
9. The angle of intersection of curves y   sin x  cos x  and x 2  y 2  5 , where [.] denotes the greatest

integer function, is

1  1 
A) tan 1 2 B) tan 1  
2
C) tan 1  2 D) tan 1 
 2


10. If the normal to the curve y = f(x) at x = 0 be given by the equation 3x  y  3  0 , then the value of
1

x 0
      
lim x 2 f x 2  5f 4x 2  4f 7x 2 is

1 1 1 1
A)  B)  C)  D) 
5 4 3 2
11. The fuel charges for running a train are proportional to the square of the speed generated in mile/h and
costs Rs. 48 per h at 16 miles/h. The most economical speed if the fixed charges i.e., salaries, etc.
Amount to Rs. 300 per h
A) 10 miles / h B) 20 miles/h C) 30 miles/h D) 40 miles/h
12. Let f :  a, b  R be a function such that for   a, b  , f '  c   f ''  c   f '''  c   f iv  c   f v  c   0, then

A) f has local extremum at x = c

B) f has neither local maximum nor local minimum at x = c
C) f is necessarily a constant function
D) it is difficult to say whether (a) or (b)
13. In which of the following graphs is x  c the point of inflexion ?

A) B) C) D)

14. If the line ax + by + c = 0 is a normal to the curve xy = 1. Then

A) a > 0, b > 0 B) a > 0, b < 0 C) a  0, b  0 D) a < 0, b < 0

15.  
If   x  is larger of e x  1 and (1 + x) ln 1  x  for x   0,   , then the value of 502 ln    4   1

must be
A) 2004 B) 2006 C) 2008 D) 2010
16. The slope of the normal to the curve x 3  y 3  8xy at the point, other than origin, where it meets the

curve y 2  4x is
A) -1 B) 1 C) 2 D) -2
17. Two rods OA and OB intersect at an angle of 60 . A car driver approaches O from A where OA = 800
m at a uniform speed of 20 m/sec. Simultaneously another car moves from O towards B at a uniform
2
speed of 25 m/sec. If t is the time when the two cars are closest, then  t  is equal to …….

A) 114 B) 25 C) 256 D) 9
1/ x
 f  x 
18. Let f(x) be a polynomial of degree 6, which satisfies lim  1  3   e 2 and has local maximum at x
x 0
 x 
= 1 and local minimum at x = 0 and 2 then 5f(3) is equal to
A) 224 B) 220 C) 226 D) 228

19. If the greatest and least values of the function f  x   x 3  6x 2  9x  1 on [0, 2] are  and  , then the

value of  4   8 must be
A) 626 B) 624 C) 625 D) 620

20. The number of points of extrema of f  x   2x  3x 2/ 3 is

 A) 0 B) 1 C) 2 D) 3
21. Let p(x) be a polynomial of degree 3 satisfying p(-1) = 10, p(1) = 6 and p(x) has a maximum at x = -1
and p’(x) has a minimum at x = 1. If the distance between the local maxima and local minima of the
d 
curve is d, then the value of   , where [.] represents the greatest integer function is …….
4

A) 1040 B) 1045 C) 1140 D) 1145

22. The number of points on the curve 5x 2  8xy  5y 2  4 whose distance from the origin is maximum or
minimum is …..
A) 1 B) 1 C) 3 D) 4
23. A man 1.6 m high walks at the rate of 30 m per minute away from a lamp which is 4 m above ground. If
k
k is the rate at which the man’s shadow is lengthening, then the value of is …….
4
A) 10 B) 6 C) 5 D) 8
24. A wire of given length l is cut into two portions which are bent into the shapes of a circle and a square
respectively. If the sum of the area of the circle and the square will be least when (side of square) = 
(diameter of circle), then the value of 2008  must be ……
A) 502 B) 2008 C) 4016 D) 1004
n
25. 
The function f  x   x 2  4  x 2

 x  1 , n  N assumes a local minimum value at x = 2. Then the

least positive integral value of n is…..

A) 1 B) 2 C) 3 D) 5
  
26. The tangent to the curve y  e kx at the point (0, 1) meets the x-axis at  a, 0  , a   2, 1 . If k   , 
8 4
then  is
A) 2 B) 4 C) 6 D) 8

ax 2  
27. If the point on y  x tan   2 2  0     , where the tangent is parallel to y = x, has an
2u cos   2

u2
ordinate then the value of  is
4a
   
A) B) C) D)
2 6 3 4
28. The curve x 4  2xy 2  y 2  3x  3y  0 cuts the x-axis at (0, 0) at the angle of
   
A) B) C) D)
4 2 6 3
3
29. If the relation between subnormal SN and subtangent St at any point S on the curve by2   x  a  is

2 p
p  SN  = q  ST  , then =
q
 a 8a 8b 8b
A) B) C) D)
27b 27b 27a 27
x4
30. The number of values of c such that the straight line 3x + 4y = c touches the curve  x  y is
2
A) 0 B) 1 C) 2 D) infinte
KEY

1-10 C A D A A B D B A C

11-20 D D D B C B C A A C

21-30 A D C B B B C A D B

SOLUTIONS
 1  1  1 1 1
1. f      1  n  1  n   1 n   n
 sin   cos   sin  cos  sin  cosn 
n

n cos  n sin  n
f '     n 1
 n 1
 n 1 n 1
 cos 2   sin 2  
sin  cos  sin  cos 

f '  x   0  cos   sin   0, f '     ve
4

 
4
 2

f    1  2 /2
4

b
2. Let f  x   ax 2  c
x
b
f '  x   2ax 
x2
b
If f '  x   0  2ax  0
x2
1/3
 b 
 x   0
 2a 
But, f  x   0  x  0

  b 1/3 
 f     0
  2a  
 
2/3 1/3
 b   2a 
 a.    b  c
 2a   b 
1/3
b  b 
 a.  b  c. 
2a  2a 
 1/3
 b   b 
 3b  2c    27b3  8c3  
 2a   2a 
 27ab 2  4c 3
3.  f  x   x  ln x

ln[0, 1]  f(0) = 0 = f(1)

 The function has to be continuous in [0, 1]
 f  0   lim f  x   0
x 0 

 lim f  0  h   0
h 0

 lim h  ln h  0
h 0

log h
 lim  0
h 0 h 
1/ h
By L ' Hospital’s value lim  0
h 0  h 1

h
 lim  0
h 0 
a 0
4.  f '  x   x  x

 f(x) is decreasing
f '  x   0

x  x  0  x  x

 1 
It is clear from the figure x    , 0 
 2 
4 1
5. f x   a
sin x 1  sin x

4 cos x cos x  1 4 
f 'x     cos x   
sin 2 x 1  sin x  2  1  sin x 2 sin 2 x 
 
 1 4  
f '  x   0  2
 2
 0 as cos x  0in  0, 
1  sin x  sin x  2

2
This given sin x 
3
Substituting this in eq. (i), we get a = 9
6.   
 0  x 2  x  1  1  0  2 x2  x  1  2 
 
 2  x 2  x  1   0,1

 Global maximum of f(x) is 1

7. By symmetry, Area  ADE  = Area  ADM 

So, integral is minimum when m = 0

3
8. f 0
2
9 9
 lim x 2  3x  a  0  a 0 a  
x
3 4 4
2

9. 1  sin x  cos x  2

y   sin x  cos x   1

 2  sin x 2  cos x  2

sin x  cos x  sin x  cos x  1  sin 2x   1)

Let P and Q be the points of intersection of given curves.
Now, solving y = 1 and x 2  y 2  5

 x2 1  5
 x  2
P   2,1 and Q   2,1

Clearly, the slope of line y = 1 is zero

x 2  y 2  5
dy
2x  2y 0
dx
dy x
 
dx y
  dy   dy 
   2 and    2
 dx  2,1  dx  2,1

Thus, the angle of intersection is tan 1  2 and tan 1  2

10. y  f  x 

dy
  f ' x 
dx
dy
  f '0
dx x 0

1 1
 Slope of normal =  3  f '0  
f '  0 3

x2
Now, lim
x 0
f  x   5f  4x   4f  7x 
2 2 2

Replacing x 2 by x , then
x x
lim  lim
x 0 f  x   5f  4x   4f  7x  x 0
 
 f  x   f  0   5  f  4x   f  0    4  f  7x   f  0  
1 1
lim 
x 0  f  x   f  0    f  4x   f  0    f  7x   f  0  
   5  4  4   7
 x0   4x  0   7x  0 
1 1 1 1
=    3 
f '  0   20f '  0   28f '  0  9f '  0  9 3

11. Let the speed of the train by v and distance to be covered be x so that total time taken is s/v hours, cost
of fuel per hour = kv 2 (k is constant)
Also, 48  k.16 2 by givn condition,
3
k 
16
 3
 Cost of fuel per hour =   v 2
 16 
Other charges per hour = 300
3 2 s 300s
Total charge = v  
16 v v
 3 300 
Or C  s  v  
 16 v 
dC  3 300 
  s  2 
dv  16 v 
dC
For max. or min. 0
dv
 v = 40 miles/h
 d2C
Then 0
dv 2
 Most economical speed v = 40 miles/h
12. If even derivative is +ve, then minima and if even derivatives is –ve, then maxima
But here f ''  c  is not given

Hence, it is difficult to say maximum or minimum i.e., a or b.

13. At the point of inflextion, concavity of the curve change irrespective of any other factor.
14. xy = 1
dy 1 a a
   2 , slope of normal = x 2    0   0
dx x b b
15.  
Let f  x   e x  1  1  x  ln 1  x 

f '  x   ex  1  ln 1  x   g  x 

g  x   e x  1  ln 1  x 

1
 g '  x   ex   0  for x   0,   
1  x 
 g(x) is increasing function.
x  0

g  x   g  0   g  x   0

Then, f '  x   0

 f(x) is increasing function f(x) > f(0)

 e x  1  1  x  ln 1  x   0  e x  1  1  x  ln 1  x 

  x   ex  1    4   e4  1    4   1  e 4

ln    4   1  4

Then, 502 ln    4   1  502  4  2008

16. The curves are x 3  y3  8xy and y 2  4x

Solving eqns. (i) and (ii), we get x 3  4xy  8xy

3
3 3
 32  2
 x  4xy  x  4x2 x  x  x  8   0
 
3
 x  0 or x 2  8  23  x  0 or x  22  4

Now, when x = 0, we get y = 0 and when x = 4, we get y 2  16 or y  4 .

But x = 4 and y = -4 do not satisfy eq. (i)
Thus (0, 0) and (4, 4) are the points of intersection of equations (i) and (ii)
 dy 8y  3x 2
Differentiating eq. (i), we get 
dx 3y 2  8x
dy
At (4, 4),  1
dx
Hence, the equation of the normal to the curve (i) at (4, 4) is  y  4   1 x  4  or y  x  0

17. Let the distance between two cars after t seconds be s. Distance covered by first car in t seconds is 20 t,
so its distance from O will be (800 – 20t m) and the distance covered by second car will be 25t m.
2 2
1  800  20t    25t   s2 2
 cos 60   s 2   800  20t   625t 2   40  t  250t
2 800  20t  25t

ds
For s to be minimum we have 0
dt
 40  800  20t   1250t   40  t  250  250t  0

 42000  2550t  0
840
t sec so  t   16
51
d 2s
It is easy to check 0
dt 2
18. The given limit will exist only if there is no constant term, one degree, two degree and three degree
terms in f(x). Let f(x) = ax 4  bx 5  cx 6 . In this case, the given limit can be written as
1/ x

lim 1  ax  bx 2  cx 3
x 0

1
 a  bx cx2 
 
 lim 1  x a  bx  cx
x 0
2
  x a  bx  cx 2   e a so a  2

Thus f  x   2x 4  bx 5  cx 6  f '  x   x 3 8  5bx  6cx 2 ,  

Since, f(x) has local extremum at x =0, 1, 2
2 12
So f '  0   f ' 1  f '  2   0  c  , b  
3 5
12 5 2 6 224
Hence, f  x   2x 4  x  x  f  3 
x 3 5
19. Given, f  x   x 3  6x 2  9x  1

 f '  x   3x 2  12x  9  3  x  1 x  3

 For maxima or minima f '  x   0

 x = 1, 3 but 3   0, 2

 Only one critical point in [0, 2] is x = 1

 Greatest value  = max. f  0  , f 1 , f  2   max.1,5, 3  5

and least value   min .f  0  , f 1 , f  2   max 1,5,3  1

  4  8  54  18  625  1  626
2
20. f  x   2x  3x 3

2

f '  x   2  3  x1/3  2 1  x1/3
3

2
Let f '  x   0, therefore, x1/3  1  0  x  1  f '  1   x 4/3
3
Also f(x) is non-differentiable at x = 0.
From the graph it can be seen that x = 0 is the point of local minima.

21. Let p  x   ax 3  bx 2  cx  d

p  1  10  a  b  c  d  10

p(1)  6  a  b  c  d  6
p(x) has a maximum at x = -1
 p '  1  0  3a  2b  c  0

p '  x  has a minimum at x = 1

 p '' 1  0  6a  2b  0

Solving equations (i), (ii), (iii) and (iv) we get

From eq. (iv), b = -3a
From eq. (iii), 3a + 6a + c = 0  c = -9a
From eq. (ii), a – 3a – 9a + d = -6  d = 11 a – 6
 From eq. (i), -a – 3a + 9a + 11a – 6 = 10
 16a = 16  a = 1
 b = -3, c = -9, d = 5
 p  x   x 3  3x 2  9x  5

So p '  x   0  3x 2  6x  9  0

 3  x  1 x  3  0

 x = -1 is a point of maxima (given) and x = 3 is a point of minima.

( maximum and minimum occur alternatively0.
Points of local maximum is (-1, 10) and local minimum is (3, -22).
2 2
And the distance between them is equal to 3   1    22  10   16  1024  1040

22. Let  r,   be the polar co-ordinate of any point P on the curve where r is the distance of the point from

origin.
4
 
 r 2 5 cos 2   sin 2   8sin  cos   4  r 2 
5  4sin 2
r 2 is maximum when 5 – 4 sin 2 is minimum = 5 – 4 = 1 when sin 2  1
 2  90    45  r  2  45
Again r 2 is minimum when 5 – 4 and 2 is maximum = 5 + 4 = 9 when
3 3 2 3
sin 2  1  2    r   , 
2 4 3 4
Hence, the points are  r cos , sin  where r,  are given by eqns. (i) and (ii).

 2 2  2 2
Thus, we get the four points as  
2, 2 ,  2,  2 ,   ,  ,  
3   3 3 
, 
 3
23. Let PQ = 4 m be the height of the pole and AB = 1.6 m be the height of the man
Let the end of the shadow be R and let it be a ta distance of 1 from A when the man is at a distance x
from PQ at some instant.
PQ PR 4 x 1
Since, PQR and ABR are similar, we have     2x  3l
AB AR 16 l

dx dl  dx  dl 2
2  3  Given,  30m / min     30 m / min  20 m/ min
dt dt  dt  dt 3
24. Let r be the radius fo the circle and x be the side of the square
Then, l  2r  4x … (i)
Let S be the sum of the area of the circle and the square, then
2
2  l  4x 
2 2 1 2
S  r  x     x   l  4x   x 2
 2  4

dS 2 2 d 2S 8
  1  4x  4   2x    l  4x   2x and 2   2  0
dx 4  dx 
 S is least
dS 2 1
For max. or min.  0    l  4x   2x  0 or x 
dx  4
From eqns (i) and (ii) 4x  x  2r  4x  x  2r
  1
Then, 2008  2008
n
25. f  x  x2  4   x 2

 x  1 and f  2  0

Now, x 2  x  1 , x
n n
2 2
 
f 2 lim x 2  4
x 2
  x 2

 x  1  lim  h  2   4   3  3lim  h  2   4 
h 0   h 0  
n

3lim 4h  h 2
h 0
 0

n n n
2
f  2 ''  lim x 2  4
x 2
   
x 2  x  1  3lim  h  2   4   3lim h 2  4h
x 0   x 0

n
= 3  (very small negative value)

For x = 2 to be the point of minima, we must have f  2   0 for which n must be an even integer.

dy
26.
dx

 ke kx
 0,1
k 
Equation of tangent is : y  1  kx

 ka  1

1
 a   2, 1  2   1
k

1
  k 1
2

 1
  or   4
8 2

ax
27. Given m  1  tan   1
u cos 2 
2

x
 tan   1 u 2 cos2 
a
 Substitute x and y values in given equation

u2 u2  2 1 
 sin   2     3
4a a

28. (i) x 4  2xy 2  y 2  3x  3y  0

Differentiating w.r.t. x, we get
(ii) 4x 3  2y 2  4xyy ' 2yy ' 3  3y '  0
At origin, we have 0  0  0  0  3  3y '  0 or y '  1


4
3
29. by2   x  a 

Differentiating both sides w.r.t. x,

dy 2
2by  3  x  a  .1
dx
2
dy 3  x  a 

dx 2 by
2
dy 3  x  a 
Length of subnormal = SN  y 
dx 2 b

dx 2by 2
Length of subtangent = ST  y 
dy 3  x  a 2

2
p  ST 
 (given)
q  SN 
2
 2by  .2b
2
2
8b  x  a 3

2 2

27 6 using by 2 3
 x  a 
3 x  a   .3  x  a 
2 x  a

8b

27
p 8b
 
q 27

x4
30. xy
2
dy 3
  1  2x 3   (As tangent is parallel to 3x + 4y = c)
dx 4
1
x
2
15
Putting this value in equation of curve, we get y  
32
Hence, only one value of ‘c’ exists
 DPP-3

1. Minimum distance between the curves y 2  4 x and x 2  y 2  12 x  31  0 is

A) 5 B) 21 C) 28  5 D) 21  5

3 
2. The shortest distance between the point  , 0  and the curve y  x ,  x  0  , is :
2 

3 5 3 5
1) 2) 3) 4)
2 2 2 4

f x  sin x 2  3x , x  0
 
3. Let f(x) be a function defined as , then at x = 0, f(x)
2
 6x  5x , x0

1) has a local maximum 2) has local minimum

3) is discontinuous 4) can’t be said

4. If  denotes the acute angle between the curves, y  10  x 2 and y  2  x 2 at a point of their
intersection, then tan  is equal to :

4 8 7 8
1) 2) 3) 4)
9 17 17 15

 
5. The equation of the line tangent to the curve x sin y + y sin x =  at the point  ,  , is
2 2

A) x  y   B) x  y  0 C) 2x  y  D) none of these
2
6. The lines tangent to the curve x 3  y 3  x 2 y  yx 2  3x  2y  0 and x 5  y 4  2x  3y  0 at the origin
intersect at an angle  equal to
   
A) B) C) D)
6 4 3 2
7
7. The tangent to y  ax 2  bx  at 1, 2  is parallel to the normal at the point (-2, 2) on the curve
2
y  x 2  6x  10. Then the value of 2ab is

A) 4 B) 5 C) -4 D) -5
3 2
8. The lines y   x and y   x intersect the curve 3x 2  4xy  5y 2  4  0 at the points P and Q
2 5
respectively. The tangents drawn to the curve at P and Q
A) intersect each other at angle of 45 B) are parallel to each other
C) are perpendicular to each other D) none of these
9. If the function f  x   x 4  bx 2  8x  1 has a horizontal tangent and a point of inflection for the same

value of x then the value of b is equal to

A) -2 B) -6 C) 6 D) 3
10. If a curve with equation of the form y  ax 4  bx 3  cx  d has zero gradient at the point (0, 1) and also
touches the x-axis at the point (-1, 0) then the values of x for which the curve has a negative gradient are
A) x > -1 B) x > 1 C) x < -1 D) 1  x  1
11. The portion of the tangent at any point on the curve x  at 3 , y  at 4 between the axes is divided by the
abscissa of the point of contact externally in the ratio
1 3 3 2
A) B) C) D)
4 4 2 5
12. Cosine of the acute angle between the curves y = 3x 1 loge x and y  x x  1 is

3 1
A) 0 B) 1 C) D)
2 2
1 x  x  1
13. If 3x + 2y = 1 is a tangent to y = f(x) at x = , then lim
2 x 0  e 2x   e 2x 
f 
  f 
 2   2 
1 1 1 1
A) B) C) D)
3 2 6 7
14. If the equation of the normal to the curve y = f(x) at x = 0 is 3x – y + 3= 0 then the value of

x2
lim is
x 0
      
f x 2  5f 4x 2  4f 7x 2

1 1
A) -3 B) C) 3 D) 
3 3
x
15. The rate of change of x 2  16 with respect to at x = 3 is
x 1
11 12
A) 1 B) C) D) -3
5 5
16. The function f  x   x  x  3 e  x / 2 satisfies all the conditions of Rolle’s Theorem on [-3, 0]. The value

of c which verifies Rolle’s Theorem, is

3
A) 0 B) -1 C) -2 D)
2
2/3
17. For f(x) = 4   6  x  in [5, 7]

A) Lagrange’s theorem is applicable B) Rolle’s theorem is applicable

C) Lagrange’s theorem is applicable but not the Rolle’s theorem
D) both theorems are not applicable
1/3
18. if a   28  3  b , then (a, b) is
  1 1   1 1   1 1 
A)  ,  B)  ,  C) (27, 28) D)  , 
 28 27   27 28   27 26 
19. For   1 , the equation x log x  x   has

A) no solution in 1,  B) at least one solution in 1, 

C) at most one solution in 1,  D) none of these

20. If the tangent to the curve 2y 3  ax 2  x 3 at the point (a, c) cuts off intercepts  and  on the

coordinate axes, (where  2   2  61 ) then the value of a is

A) 40 B) 10 C) 20 D) 30
21. Let f  x   a 5 x 5  a 4 x 4  a 3 x 3  a 2 x 2  a1x , where a 'i s are real and f(x) = 0 has a positive root 0 . Then

A) f '  x  = 0 has a root 1 such that 0  1   0 B) f '  x  = 0 has at least one real root

C) f ''  x  = 0 has at least one real roots D) all the above

2
22. For a twice differentiable function f(x), g(x) is defined as g  x    f '  x    f  x  f ''  x  , on (a, e). If

a  b  c  d  e, f  a   0, f  b   2, f  c   1, f  d   2, f  e   0 , then the minimum number of roots of

the equation g(x) = 0 is

A) 4 B) 5 C) 6 D) 7
23. If x, y, z  0 such that x + 2y + 3z = 15, then the maximum value of 6 1  x  yz  x  2y  3z  is

A) 115 B) 120 C) 200 D) 240

ax  b
24. If f  x   has a turning value at (2, -1), then its minimum value is
 x  1 x  4 
1 1 1 1
A)  B) C)  D) 
3 4 6 9
25. A wire of length 2 m is cut into two pieces to form a square and a circle. The minimum value of total
area of the square and circle is
1 1 1 2
A) B) C) D)
2 3 4 5
26. An open box is to be made by cutting out four squares from the four corners of a square tin sheet of area
36 m 2 and then folding up the flaps. The maximum volume of the box is
35
A) 15 B) 16 C) D) 18
2
27. A circular cylinder is inscribed in a sphere of radius r. If the volume of the cylinder is maximum, then its
height is
2r 3r
A) B) r C) D) 2r
3 2
28. A cone is inscribed in a sphere of radius r. The height of the cone when its volume is maximum is
 3r 2r 4r
A) 2r B) C) D)
2 3 3

 at 
29. The maximum distance from origin of a point on the curve x  a sin t  b sin   ,
b
 at 
y  a cos t  b cos   , both a, b > 0 is
b

A) a – b B) a + b C) a 2  b2 D) a 2  b2
x dx
30. Let f ( x)   , x  R , where a, b and d are non – zero real constants. then :
a2  x2 2
b  d  x
2

1) f is decreasing function of x

2) f is neither increasing nor decreasing

3) f ' is not a continuous function of x

4) f is an increasing function of x

KEY

1-10 A B B D A D D C B C

11-20 B B A D C C D A B D

21-30 D A C D C B A D B A

SOLUTIONS
1. Centre and radius of given circle is p  6, 0  and 5 respectively. Equation of normal for y 2  4 x at

t 2
, 2t  is y   xt  2t  t 3 . It must passes through (6,0) in order that it gives minimum distance between
the two curves.

0  t 3  4t  t  0 (or ) t  2

2.  t, t   32 , 0 
2
3  2 5
 distance 2    t   t   t  1 
2

2  4
5
square of minimum (distance) = at (1, 1)
4

5
minimum distance =
2
3. f 0  sin 0  0 ; f 0  0 , f 0  0
   
 Thus f 0  f 0 and f 0  f 0
   
 x = 0 is a point of minima.

4. y  10  x 2 y  2  x2

10  x 2  2  x 2
8  2x 2
x2  4
x  2,  2
Points are (2, 6), (-2,6)
 dy 
   2x  4
 dx  2,6 

 dy 
   2x  4
 dx  2,6 

4   4  8 8
tan    
1  4  4  1  16 15

5. x sin y  y sin x  
Differentiating w.r.t. x, we have
dy dy
sin y  x cos y  sin x  y cos x  
dx dx
  dy
When x  and y  , we have 1  0
2 2 dx
 y '  1

  
So, the equation of the tangent line is y     x   or x  y  
2  2

6. x 3  y 3  x 2 y  yx 2  3x  2y  0

Differentiating w.r.t. x, we get 3x 2  3y 2 y ' x 2 y ' 2xy  x 2 y ' 2xy  3  2y '  0

Putting x = y =0, we get 3  2y '  0 or y '  3 / 2

Also, x 5  y 4  2x  3y  0

Differntiating w.r.t. x, we get 5x 4  4y 3 y ' 2  3y '  0

Putting x = y = 0, we get 2  3y '  0 or y '  2 / 3
Hence, curves are orthogonal
7
7. y  ax 2  bx 
2
dy
  2ax  b
dx
Point (1, 2) lies on the curve.
 7 3
2  a b or a  b 
2 2
dy
Also,  2a  b
dx 1,2

y  x 2  6x  10

dy
  2x  6
dx
dy
 2
dx  2,2

1
 Slope of normal = 
2
1
So, according to the question, 2a  b  
2
5
Solving (i) & (ii), we get a = 1 and b = 
2
3 2
8. Given lines : y   x, y   x and curve : 3x 2  4xy  5y 2  4  0
2 5
Differentiating w.r.t to x, we get 6x  4y  4xy ' 10yy '  0
dy 2y  3x
 
dx 2x  5y
3 dy 2 dy
If y   x, then  0 and if y   x, then 
2 dx 5 dx
Hence, tangents are perpendicular to each other.
9. According to the question we must have f '  x   0 and f ''  x   0 for the same x  x 0 now

f '  x   4x 3  2bx  8

 f '  x 0   2  2x 30  bx 0  4   0 (i)

and f ''  x 0   2 6x 02  b   0 (ii)

From (ii) b  6x 02

 
Substituting this value of b in (1) 2x 30  6x 20  4  0  4x 30  4

 x 0  1  b  6

10. y  ax 4  bx 3  cx  d

dy
  4ax 3  3bx 2  c
dx
Point (0, 1) satisfies the curve  d = 1
  dy 
Also   0c0 (1)
 dx  0,1

(-1, 0) satisfies the curve  a  b  c  1  0 (2)

 dy 
Also   0c0
 dx  1,0

 4a  3b  0 and a  b  1
 a  3, b  4

 The curve is y  3x 4  4x 3  1

dy
  12x 3  12x 2
dx
dy
For  0 we have x 3  x 2  0  x 2  x  1  0  x  1
dx
dy 4t
11. 
dx 3
4t
Tangent is y  at 4 
3

x  at 3 
at 3
x – intercept =
4

at 4
y – intercept =
3
 at 3   at 4 
the point of intersection of tangent with the axes are  , 0  and  0,  
 4   3 

m 3
 
n 4
12. Point of intersection of curves is (1, 0).
y  3 x 1 ln x

3x 1
 y'   3x 1 .log e 3.log e x
x
m1  1

y  xx 1

dy
  x x 1  log e x 
dx
m 2  1

11
 Angle between curves is given by tan    0    0  cos 0  1
11
3
13. Slope of 3x  2y  1 is
2
  1  3
 f '  
2 2
x  x  1 2x  1 1 1
 lim 2x 2x
 lim 2x 2x
 
x 0 e  e   e  2x  e  1 1 3
f f   e 2x .f '    e f '  f '  2   f '  2 
 2   2   2   2 
14. y = 3x + 3 is normal to the curve at x = 0
Slope of normal is 3
1
 Slope of tangent at x = 0 is f '  0   
3

x2 0 
Now lim  form 
x 0
f  x   5f  4x   4f  7x 
2 2 2 0 

2x
= lim
x 0
   
2xf ' x 2  40xf ' 4x 2  56xf ' 7x 2  
1
lim
x 0 f '  0   20f '  0   28f '  0 

1 1 1
  
9f '  0  1 3
9 
3

15. u  x 2  16
du 2x x
  
dx 2 x 2  16 x 2  16
x
v
x 1
dv 1
 
dx  x  12

du
du dx 12
  
dv dv 5
dx
16. f ' x   0

  x  3 e  x / 2  xe  x / 2   x / 2  x  3 e x / 2  0

 x2  x  6  0
 x  2,3

 c  2   3, 0 
2/3
17. f x  4  6  x in 5,7
 2 1
f ' x   1
3
 6  x 3
Clearly, f '  x  does not exist at x = 6.

Hence none of the theorems is applicable

18. Let f  x   x1/ 3 , x   27, 28

1
 f ' x  
3x 2 / 3
By LMVT, we have
1 1
 28 3   27  3  f 'c
28  27
2/3 1
  28  3 
3c 2 / 3
Now, 27  c  28
2/3
 9  c2 / 3   28
1


1

1

1

 28  3 . 1 
1
2 2
27 3 28 28
3.c 3 3  28 3
1 1 1
  2/3

28 3  c  27

1 1/ 3 1
From (i),   28   3 
28 27
19. Consider f  x    x    log x for 1  x  

The function f is continuous on 1, 

x 
And f '  x   log x  for all x  1,  
x
Also, f 1  0 and f     0

So, by Rolle’s theorem there is c  1,   such that f '  c   0

c
 log c  0
c
 c log c   c     0

 c log c  c  

Hence, log x + x =  has at least one solution in 1, 

20.  2y 3  ax 2  x 3

dy
 6y 2  2ax  3x 2
dx
 dy  2ax  3x 2 
  
dx  6y2 

dy 5a 2 5
  2 
dx  a,a  6a 6

So, equation of tangent is

5
ya  x  a
6
Or 6y – 6a = 5x – 5a
Or -5x + 6y = a
x y
Or  1
 a / 5   a / 6 
x y
  1
 a / 5   a / 6 
2 2
 a   a 
      61 given 
 5  6

61a 2
  61
 302
 a  30

21. Clearly, f(0) = 0. So, f(x) = 0 has two real rots 0 and  0   0  .

Therefore, f’(x) = 0 has a real root 1 lying between 0 and 0 . So 0  1   0

Again, f '  x   0 is a fourth – degree equation. As imaginary roots occur in conjugate pairs, f '  x   0

will have another real roots, 2 . Therefore, f ''  x   0 will have a real root lying between 1 and  2 .

As f(x) = 0 is an equation of the fifth degree, it will have at least three real roots and hence, f '  x  will

have at least two real roots.

22.
a e
b c d

f  b  f  c   0, f  c  f  d   0

But intermediate value property, f(x) = 0 has atleast one root c1 in (b, c) and atleast one root c 2 in (c, d)

 f(x) = 0 has atleast 4 roots a, c1 , c 2 , e

By Rolle’s theorem f '  x  has 3 roots in  a, c1  ,  c1 , c 2  ,  c2 , e 

d
 f  x  f '  x   0 has atleast 4 + 3 = 7 roots and g  x  
dx
 f  x  f '  x    0 has atleast 6 roots.
23. 6 1  x  yz  x  2y  3z   1  x 1  2y 1  3z   1   x  2y  3z 
 3
 1  x  1  2y  1  3z 
 16  1  x 1  2y 1  3z   16   
 3 

 16  63  200 (by A.M. & G.M. inequlity)

24. f  2   1, f '  2   0  2a  b  2, b  0, a  1

x  2  x  2  x  , f ' 2  0, f ' 2  0
f x 
 x  1 x  4 
, f ' x  
 x  12  x  4 2
   
 f(x) is maximum at x = 2

 
f '  2   0, f ' 2  0, f  x  is minimum at x = -2

2 1
f min  
 3 6 9
25. Let x be the radius of the circle and y be the side of the square.

1  x
2x  4y  2  y 
2
1 dA 2
A  x 2  1  x 2 ,  0  2x  1  x 
4 dx 4
2
1  1   4 1
x ,A 2
 1    2

4    4 4    4    4   4
2
26. Let x be the side of the square cut V  x  6  2x 

dv 2
  6  2x   4x  6  2x   12  3  x 1  x 
dx
dv
 0  x  1, maximum V  16
dx
27. Let x be the radius and y the height of the cylinder.
 y2
Now, x 2  r 2 
4
 y3  dV 3y 2 2r
Volume, V  x 2 y    r 2 y     0  r2  y
 4  dy 4 3

28.

Let x be the radius of the base and y the height of the cone
2
Now, x 2  r 2   y  r   2ry  y2

1 1 dV 4r
V  x 2 y   2ry 2  y3 
3 3

dy
 0  4ry  3y 2  y 3

 at 
29. Distance of origin from  x, y   x 2  y 2  a 2  b 2  2ab cos  t  
 b

   at   
 a 2  b 2  2ab  cos  t     1  a  b
  b  min 
 Maximum distance from origin = a + b

2 2  d  x  1
x2  a2  x
1
3x  1 b2   d  x   d  x 
2
2 x2  a2 2 b2   d  x 
30. f 'x  
 x2  a2  b2   d  x 
2

f ' x  
x2  a2  x 2


 b2   d  x    d  x 
2 2

3/ 2 2 3/ 2
 x2  a2  b  d  x  
2

a2 b2
f 'x    0  xR
2 3/ 2 2 3/ 2
x 2
a  b 2
 d  x  
f(x) is an increasing function
 DPP-4

1. A spherical balloon is being inflated at the rate of 35cc/min. The rate of increase in the surface area (in
cm 2 / min .) of the balloon when its diameter is 14 cm, is

A) 10 B) 10 C) 100 D) 10 10
2. If a metallic circular plate of radius 50 cm is heated so that its radius increases at the rate of 1 mm per
hour, then the rate at which, the area of the plate increases (in cm 2 /hour) is
A) 5 B) 10 C) 100 D) 50
3. Consider a rectangle whose length is increasing at the uniform rate of 2 m/sec, breadth is decreasing at
the uniform rate of 3 m/sec and the area is decreasing at the uniform rate of 5 m 2 / sec . If after some
time the breadth of the rectangle is 2 m then the length of the rectangle is
A) 2m B) 4m C) 1m D) 3m
4. Two points A and B move from rest along a straight line with constant acceleration f and f’ respectively.
If A takes m sec more than B and describes ‘n’ units more than B in acquiring the same speed then
1 1
A)  f  f ' m 2  ff 'n B)  f  f '  m 2  ff 'n C)  f  f '  m  ff 'n 2 D)  f ' f  n  ff 'm 2
2 2
5. A lizard, at an initial distance of 21 cm behind an insect, moves from rest with an acceleration of
2cm / s 2 and pursues the insect which is crawling uniformly along a straight line at a speed of 20 cm/s.
Then the lizard will catch the insect after
A) 20 s B) 1 s C) 21 s D) 24 s
6. A point on the parabola y 2  18x at which the ordinate increases at twice the rate of the abscissa is

9 9  9 9 
A)  ,  B) (2, -4) C)  ,  D) (2, 4)
8 2  8 2
7. Let f and g be two differentiable functions on R such that f '  x   0 and g '  x   0 for all x  R . Then

for all x
A) f  g  x    f  g  x  1  B) f  g  x    f  g  x  1 

C) g  f  x    g  f  x  1  D) g  f  x    g  f  x  1 

8. How many real solutions does the equation x 7  14x 5  16x 3  30x  560  0 have ?
A) 7 B) 1 C) 3 D) 5
9. A tangent to the curve, y = f(x) and P(x, y) meets x-axis at A and y-axis at B. If AP : BP = 1 : 3 and
f(a) = 1, then the curve also passes through the point
1  1   1  1 
A)  , 24  B)  , 4  C)  2,  D)  3, 
3  2   8  28 

10. The tangent at the point (2, -2) to the curve, x 2 y2  2x  4 1  y  does not pass through the point

 1
A)  4,  B) (8, 5) C) (-4, -9) D) (-2, -7)
 3
  1  sin x    
11. Consider f  x   tan 1   , x   0,  . A normal to y = f(x) at x  also passes through the
 1  sin x   2 6

point
     2 
A)  , 0  B)  , 0  C) (0, 0) D)  0, 
6  4   3 

12. If the tangent at a point P, with parameter t, on the curve x  4t 2  3, y  8t 3  1, t  R , meets the curve
again at a point Q, then the coordinates of Q are


A) 16t 2  3,  64t 3  1  
B) 4t 2  3,  8t 3  2  
C) t 2  3, t 3  1 
D) t 2  3,  t 3  1
 
13. The equation of a normal to the curve, sin y  x sin   y  at x  0 is
3 

A) 2x  3y  0 B) 2x  3y  0 C) 2y  3x  0 D) 2y  3x  0

14. If the tangent to the conic, y – 6 = x 2 at (2, 10) touches the circle, x 2  y2  8x  2y  k (for some fixed

k) at a point  ,   ; then  ,   is

 7 6  4 1  6 10   8 2
A)   ,  B)   ,  C)   ,  D)   , 
 17 17   17 17   17 17   17 17 
15. If an equation of a tangent to the curve y  cos  x  y  , 1  x  1  , is x + 2y = k then k is equal to

 
A) 1 B) 2 C) D)
4 2
16. A function y = f(x) has a second order derivative f ''  x   6  x  1 . If its graph passes through the point

(2, 1) and at that point the tangent to the graph is y = 3x – 5, then the function is
2
A)  x  1 B)  x  13 C)  x  1
3
D)  x  1
2

2
17. The tangent to the curve, y  xe x passing through the point 1, e  also passes through the point :

5  4 
1)  3, 6e  2)  2,3e  3)  , 2e  4)  , 2e 
3  3 

18. A helicopter is flying along the curve given by y  x 3/ 2  7,  x  0  , A soldier positioned at the point
1 
 , 7  wants to shoot down the helicopter when it is nearest to him. Then this nearest distance is :
2 

1 7 1 5 1 7
1) 2) 3) 4)
6 3 2 6 3 3

19. A lane of width 27 m runs at right angle out of a road of width 64 m. The maximum length of a pole
which can be carried from the road to the lane keeping it horizontal is
A) 128 B) 125 C) 120 D) 105
20. Three sides of a trapezium are each equal to 2m. The maximum area of the trapezium is

A) 5 3 B) 4 3 C) 3 3 D) 2 3
 2
21. If f  x1   f  x 2    x1  x 2  , x1 , x 2  R . Then the equation of tangent to the curve y = f(x) at the

point (1, 2)
A) y + 2 = 0 B) x – 1= 0 C) y – 2 = 0 D) x - 2 = 0
y
22. 
The equation of the normal to the curve y  1  x   sin 1 sin 2 x at x  0 
A) y  x  1  0 B) y  x  1  0 C) y  x  1  0 D) y  x  1  0
6
xr
23. The number of real roots of the equation  r!  0 is
r 0

A) 0 B) 2 C) 4 D) 6
24. The volume of the greatest right circular cone, that can be described by the revolution about a side or a
right angled triangle of hypotenuse 1 unit is
2 2 2 4
A) B) C) D)
3 3 3 9 3 9 3
25. If the volume of a right circular cone is given, then its curved surfaced area is minimum when the rate of
its height to its base radius is

1 3
A) 1 B) 2 C) D)
2 2

x 2 y2 x 2 y2
26. The curves   1 and   1 will cut orthogonally if
a b a1 b1

a a1
A) ab  a1b1 B)  C) a  b  a1  b1 D) a  b  a1  b1
b b1

a  a  a2  x2 
27. The tangent at any point P on the curve y  ln    a 2  x 2 meets the x-axis at A and y –
2  a  a 2  x 2 

axis at B. Then
a a
A) PA = a B) PB = a C) PA = D) PB =
2 2
n n
x y  x  y
28. The line   2 is a tangent to the curve       2 . The number of values of n is
a b a  b
A) 0 B) 1 C) 2 D) >2
3x 2  12x  1, 1  x  2
29. If f  x    then
 37  x, 2x3

A) f(x) increases on [-1, 2] B) f(x) is continuous on [-1, 3]

C) f '  2  does not exist D) f(x) has maximum at x = 2

x
30. Let g  x   2f    f  2  x  and f ''  x   0  x   0, 2  . Then g(x)
2
A) increases in (0, 1) and decreases in (1, 2) B) decreases in (0, 1) and increases in (1, 2)
  4 4   4 4 
C) increases in  0,  and decreases in  , 2  D) decreases in  0,  and increases in  , 2 
 3 3   3 3 
KEY

1-10 A B D D C A B B C D

11-20 D D B D D B D A B C

21-30 C B A C B D B D A C

SOLUTIONS
4 3
1. Volume of sphere V  r
3
dV 4 dr
 ..3r 2 .
dt 3 dt
dr dr 35
35  4r 2 . or 
dt dt 4r 2

Surface area of sphere = S = 4r 2

dS dr dr
 4 2r   8r.
dt dt dt
dS 70

dt r
Now, diameter = 14 cm, r = 7
dS
  10
dt
2. Let A  r 2 be area of metallic circular plate of r = 50 cm.
dr 1
Also, given  1mm  cm
dt 10
A  r 2
dA dr 1
  2r  2.50.  10
dt dt 10
Hence, area of plate increases in 10 cm 2 / hour
3. Let A be the area, b be the breadth and  be the length of the rectangle
dA d db
Given  5 , 2,  3
dt dt dt
We know, A    b
dA db d
  .  b.  3  2b
dt dt dt
 5  3  2b
When b = 2, we have
 9
5  3  4     3m
3
4.
u 0 f
  s+n
A V
t+m

u 0 f'
  s
B V
t

As per question if point B moves s distance in t time then point A moves (s + n) distance in time (t + m)
after which both have same velocity v.
Then using equation v = u + at we get
fm
v  f t  m  f ' t  t 
f ' f
Using equation v 2  u 2  2 , as we get
fn
v 2  2f  s  n   2f 's  s 
f ' f
1 1
Also for point B using the equation s  ut  at 2 , we get s  f ' t 2
2 2
Substituting values of t and s from equations (1) and (2) in the above relation, we get

fn 1 f 2m 2
 f'
f ' f 2  f ' f  2

1
  f ' f  n  ff 'm 2
2
5. Let the lizard catches the insect after time t then distance covered by lizard = 21cm + distance covered
by insect
1
 ft 2  4  t  21
2
1
  2  t 2  20  t  21
2
 t 2  20t  21  0
 t  21sec
dy dy 9
6. y 2  18x  2y  18  
dx dx y
dy 9 9
Given 2 2 y
dx y 2
9
Putting in y 2  18x  x 
8
9 9
 Required point is  , 
8 2
7. Since f’(x) > 0 and g’(x) < 0, therefore f(x) is increasing function and g(x) is decreasing function.
 f  x  1  f  x  and g  x  1  g  x 

 g f  x  1   g  f  x   and f  g  x  1   f  g  x  

Hence option (b) is correct

8. Let f  x   x 7  14x 5  16x 3  30x  560

 f '  x   7x 6  70x 4  48x 2  30  0,  x  R

 f is an increasing function on R
Also lim f (x)   and lim f (x)  
x  x 

 The curve y = f(x) crosses x-axis only once.

 f(x) = 0 has exactly one real root.
9.

P
(x
, y)

X
A

Let y = f(x) be a curve slope of tangent = f’(x)

Equation of tangent (Y – y) = f’(x) (X – x)
Put Y = 0
 y 
 X   x  
 f '  x  

Put X = 0
 Y  y  x f ' x 

 y 
 A   x  , 0  and B   0, y  x f '  x  
 f ' x  

 AP : PB  1: 3

3 y 
 x   x  
4 f '  x  

3y
x
f ' x 
 dy 3y
 
dx x
dy 3dx

y x
C
y
x3
 f a   1

C 1

1  1
y 3
is required curve and  2,  passing through
x  8
1
y
x3
10. x 2 y 2  2x  4  4y
Differentiate w.r.t. ‘x’
dy dy
2xy 2  2y. x 2 .  2  4.
dx dx
dy

dx
 
2y. x 2  4  2  2x . y 2

dy 2  224 14 7
   
dx 2,2 2  2   4  4 12 6

 Equation of tangent is
7
 y  2    x  2  or 7x  6y  26
6
 (-2, -7) does not passes through the required tangent.
 x x
2 
    x
 1  sin x   sin  cos   1  tan 
1   2 2  2
11. f(x) = tan 1    tan 
1
  tan  
 1  sin x   x x
2
 1  tan
x 
  sin  cos  
  x 2   2
 
   x 
 tan 1  tan    
  4 2 
 x
y 
4 2
dy 1
 
dx 2
1
Slope of normal =  2
 dy 
 
 dx 
    
At  ,  
 6 4 12 
    
y      2  x  
 4 12   6
4 2
y  2x 
12 6
 
y  2x 
3 3
2
y  2x 
3
 2 
This equation is satisfied only by the point  0, 
 3 

12. 
P 4t 2  3, 8t 3  1 
dy / dt dy
  3t  slope of tangent at P 
dt / dt dx


Let Q = 4 2  3, 8 3  1 
Slope of PQ = 3t

8t 3  83
 3t
4t 2  4 2
 t 3  3 2 t  2 3  0

 t    .  t 2  t  2 2   0

 t   2 .  t  2   0
t
t    or   
2
 Q  t 2  3,  t 3  1
 
 
13. Given curve is sin y  x sin   y 
3 
dy     dy
Diff with respect to x, we get cos y  sin   y   x cos   y 
dx 3  3  dx
 
sin   y 
dy 3 
 
dx   
cos y  x cos   y 
 3 

dy 3
at  0, 0  
dx 2
 Equation of normal is y – 0
 2
  x  0
3

 2x  3 y  0

14. x2  y  6  0
dy dy
2x  0  2x
dx dx
dy
4
dx  x,y  2,10 

equation of tangent y – 10 = 4(x – z)

4x – y + z = 0
Tangent passes through  ,  

4   z  0    4  z … (a)
And 2x  2yy ' 8  2y '  0
2x  8 2  8
y'    4 …. (b)
2  2y 2  2
From (a) and (b)
8 2
 ,
17 17
 8 2 
 , 
 17 17 
15. Let y = cos (x + y)
dy  dy 
   sin  x  y  1  
dx  dx 
Now, given equation of tangent is x + 2y = k
1
 slope 
2
dy 1 1  1
So,  put this value in (1), we get   sin  x  y   1  
dx 2 2  2
 sin  x  y   1

 
xy  y x
2 2

Now,  x  cos  x  y 
2

x and y  0
2

Thus x  2y  k  k
2
 f ''  x   6  x  1 . Integrating, we get f '  x   3x 2  6x  c
16.
Slope at  2,1  f '  2   c  3

[ slope of tangent at (2, 1) is 3]

2
 f '  x   3x 2  6x  3  3  x  1
3
Integrating again, we get f  x    x  1  D
3
The curve passes through (2, 1)  1   2  1  D  D  0
3
 f  x    x  1
2
17. y  xe x
dy 2 2
 e x  x e x .2x
dx
 dy 
   e   e  2   3e
 dx 1,e 

Equation of tangent is, y – e = 3e(x – 1)

4 
Passing through  , 2e 
3 
3
18. y  x  7  x  0
2

1
dy 3 2
 x
dx 2
 
3   7 y 
 x    1
2   1 x
2 
3 2 1
x  x
2 2
 x  1 3x  1  0
x  1,  But x  0 

1
x
3
3/2
1
Now, y  7  x 3/ 2  7   
3
2 2
 1 1   1  7 1 7
 nB       
 2 3   3 108 6 3

19. Let AB be the pole

 AB  f     a sec   b cos ec

f '    0

 a sec  tan gq  b cos ec cot   a sin 2   b cos3 

cos 2  sin 2  1
 2
 2
 2 2
a3 b3 a3  b3
1
 2 2 2
a  a  b3 
3 1

a   2 2 2 2
   1
  a 3  a 3  b3 
cos   
a3  
1 3
2  2 2 2  2 2 2
b a b
Similarly  b3 3 3
 a  b  . Maximum AB     a  b3 
3
cos    cos  sin   
   
3
 2 2 2 3
  64  27 3   16  9  2  125
3
 
 
20. BC = CD = DA = 2
Draw CE parallel to DA. ABC    EB  4 cos , AB  2  4 cos 

1
Area = f      AB  DC  CM  4 1  cos   sin   4sin   2sin 2
2

f '     0  cos   cos 2  0,  
3

  1 3
f    4 1   3 3
3  2 2
2
21. As f  x1   f  x 2    x1  x 2  , x1 , x 2  R
  f  x1   f  x 2   x1  x 2
2 as x 2  x 2 
 

f  x1   f  x 2 
  x1  x 2
x1  x 2

f  x1   f  x 2 
 lim  lim x1  x 2
x1x 2 x1  x 2 x1 x 2

 f '  x1   0, x1  R

 f '  x   0 , which shows f '  x   0 [as modulus is non negative or f '  x   0 ]

 f '  x   0 or f(x) is constant function.

y2
 Equation of tangent at (1, 2) is  f 'x
x 1
Or y  2  0  as f '  x   0
 y – 2 = 0 is required equation of tangent.
y
22. 
Given, y  1  x   sin 1 sin 2 x 
y
Let y = u + v, where u = 1  x  , v = sin 1 sin 2 x .  
dy du dv
On differentiating w.r.t. x, we get   ….. (i)
dx dx dx
y
Now, u  1  x 

On taking logarithm both sides, we get

loge u  y loge 1  x 

1 du y dy
   log e 1  x 
u dx 1  x dx
du y  y dy 
  1  x    log e 1  x  
dx  1  x dx 


Again, v  sin 1 sin 2 x 
 sin v  sin 2 x
dv
 cos v  2sin x cos x
dx
dv 1
   2 sin x cos x 
dx cos v

dv 2sin x cos x 2sin x cos x

  
dx 1  sin 2 v 1  sin 4 x
dy y y dy  2sin x cos x
From Eq. (i),  1  x    log e 1  x   
dx 1  x dx  1  sin 4 x
 y 1 4
dy y 1  x   2sin x cos x / 1  sin x
  y
dx 1  1  x  log e 1  x 
At x = 0,
y
y  1  0   sin 1 sin  0   1

11
dy 11  0   2sin 0.cos 0 / 1  sin 0
 
4
  
dy
1
1
dx 1  1  0  log e 1  0  dx

1
Again, the slope of the normal is m    1
dy
dx
Hence, the required equation of the normal is y  1   1 x  0 

i.e. y  x  1  0
6
xr
23. Let f  x    attains a minimum at x  
r 0 r!

5
r 6
 f '   0    0  f     0  f x  0 x
r 0 r! 6!
Hence f(x) = 0 has no real roots

1 dV
24. V   sin 2  cos   0
3 d

sin 2  cos 2 
 2sin  cos 2   sin 3   
2 1
sin 2   cos 2  1 2 1 2
  Maximum V  
2 1 3 33 3 9 3
25. Let x be the radius and y be the height
1
V  x 2 y
3

9V 2 9V 2
S  x x 2  y 2  x x 2    x4 
2 x 4 2 x 2
1
dS 18V 2  3V  3
 0  4x 3  2 3  x   
dx  x  2 
 1
1
3V  6v  3 y
y 2   ,  2 2
x    x
  3  2

x 2 y2 x 2 y2
26.   1... 1 and   1 ...(2)
a b a1 b1

1 1  21 1  x 2  a1  a  y 2  b1  b 
1   2   x 2   y    0  … (3)
 a a1   b b1  a1a b1b

x ym1
Differentiating (1),  0
a b

 bx b x bb x 2 b b
 m1  , m 2  1 , m1m 2  1 2    1   1
ay a1y aa1 y  a1  a 
b1  b  a1  a  a  b  a1  b1

a x x  1 x  a2  x2
27. y'    .  
2  a  a2  x2 a  a2  x2  a2  x 2 a2  x2 x

 a 2  x12
Tangent at P  x1 , y1  , y  y1   x  x1 
x1

 xy 
 A 1 1
 a2  x2  
 x1 , 0  , B 0, y1  a 2  x12 
 1 

P  x1 , y1  , PB  x12  a 2  x12  a

28. We observe that the line and the curve pass through the point (a, b).
n 1 n 1
nx ny
Differentiating the equation of the curve,      y'  0
aa bb
b x y
x  a, y  b  y '   for all n. For all n,   2 is a tangent
a a b
29. f '  x   6x  12  0 on [-1, 2]

lim f  x   35  lim f  x 
x 2 x2

 f  x  is continuous f 1  2   24, f ' 2  1 

 f '  2  does not exist

f(2) = 35, the maximum value

x x
30. g '  x   f '    f '  2  x   0 if f '    f '  2  x 
2 2
x
  2  x [Because f '  x  is a decreasing function  f ''  x   0  ]
2
4  4
x  4  2x, x  . If x   0,  , g(x) increases.
3  3
PHYSICS
 PHYSICS
DPP-1
1. Two rods (one semi-circular and other straight) of same material and of same cross-sectional area are
joined as shown in the figure. The points A and B are maintained at different temperature. The ratio of
the heat transferred through a cross-section of a semi-circular rod to the heat transferred through a cross
section of the straight rod in a given time is

1) 2 :  2) 1 : 2 3)  : 2 4) 3 : 2
2. Ice starts forming in lake with water at 0 o C and when the atmospheric temperature is  10 o C . If the time
taken for 1 cm of ice be 7 hours, then the time taken for the thickness of ice to change from 1 cm to 2 cm
is
1) 7 hours 2) 14 hours 3) Less than 7 hours 4) 21 hours
3. Three rods of identical area of cross-section and made from the same metal form the sides of an
isosceles triangle ABC , right angled at B . The points A and B are maintained at temperatures T and
2 T respectively. In the steady state the temperature of the point C is TC . Assuming that only heat
TC
conduction takes place, is equal to
T
1 3 1 1
1) 2) 3) 4)
( 2  1) ( 2  1) 2( 2  1) 3 ( 2  1)

4. A solid cube and a solid sphere of the same material have equal surface area. Both are at the same
temperature 120 o C , then
1) Both the cube and the sphere cool down at the same rate
2) The cube cools down faster than the sphere
3) The sphere cools down faster than the cube
4) Whichever is having more mass will cool down faster
5. A black metal foil is warmed by radiation from a small sphere at temperature T and at a distance d . It is
found that the power received by the foil is `P'. If both the temperature and the distance are doubled, the
power received by the foil will be
1) 16P 2) 4P 3) 2P 4) P
6. Three rods of same dimensions are arranged as shown in figure. They have thermal conductivities K1 , K 2

and K 3 .The points P and Q are maintained at different temperatures. For the heat to flow at the same
rate along PRQ and PQ then which of the following option is correct
1
1) K3  (K 1  K 2 ) R
2

2) K 3  K1  K 2 K1 K2

K1 K 2
3) K3 
K1  K 2 Q
P K3

4) K 3  2(K 1  K 2 )

7. A solid sphere and a hollow sphere of the same material and size are heated to the same temperature and

allowed to cool in the same surroundings. If the temperature difference between each sphere and its

surroundings is T , then

1) The hollow sphere will cool at a faster rate for all values of T

2) The solid sphere will cool at a faster rate for all values of T

3) Both spheres will cool at the same rate for all values of T

4) Both spheres will cool at the same rate only for small values of T

8. A cylindrical rod with one end in a steam chamber and the other end in ice results in melting of 0.1gm of
ice per second. If the rod is replaced by another with half the length and double the radius of the first
1
and if the thermal conductivity of material of second rod is that of first, the rate at which ice melts in
4

gm / sec will be
1) 3.2 2) 1.6 3) 0.2 4) 0.1
9. A solid copper sphere (density  and specific heat capacity c) of radius r at an initial temperature 200K
is suspended inside a chamber whose walls are at almost 0K. The time required (in  s) for the
temperature of the sphere to drop to 100 K is
72 rc 7 rc 27 rc 7 rc
1) 2) 3) 4)
7  72  7  27 

10. The temperature of the two outer surfaces of a composite slab, consisting of two materials having

coefficients of thermal conductivity K and 2K and thickness x and 4x, respectively are T2 and T1 (T2 >

 A(T2  T1 )K 
T1). The rate of heat transfer through the slab, in a steady state is  f , with  which equal to
 x 

(area of cross section is A)

 T2 K 2K T1

x 4x

1 2 1
1) 1 2) 3) 4)
2 3 3

11. Five identical rods are joined as shown in figure. Point A and C are maintained at temperature 120°C
and 20°C respectively. The temperature of junction B will be

1) 100°C 120°C
C
2) 80°C A B
20°C
3) 70°C
4) 0°C

12. The top of insulated cylindrical container is covered by a disc having emissivity 0.6 and thickness 1 cm.
The temperature is maintained by circulating oil as shown in figure. If temperature of upper surface of
disc is 127°C and temperature of surrounding is 27°C, then the rate of heat loss per unit area to the
17
surroundings will be (Take    10  8 W / m 2 K 4 )
3

Oil
1) 595 J/m2  sec
2) 595 cal/m2  sec Oil
2
3) 991.0 J/m  sec
4) 440 J/m2  sec
13. The following figure shows two air-filled bulbs connected by a U-tube partly filled with alcohol. What
happens to the levels of alcohol in the limbs X and Y when an electric bulb placed midway between the
bulbs is lighted
1) The level of alcohol in limb X falls while that in limb Y rises Black Painted

2) The level of alcohol in limb X rises while that in limb Y falls

Bulb
3) The level of alcohol falls in both limbs Y

4) There is no change in the levels of alcohol in the two limbs

Alcohol

14. The graph. Shown in the adjacent diagram, represents the variation of temperature (T) of two bodies, of
same material x and y having same surface area, with time (t) due to the emission of radiation. Find the
correct relation between the emissivity (e) and absorptivity (a) of the two bodies
1) e x  e y & a x  a y
T
2) e x  e y & a x  a y y

3) e x  e y & a x  a y x

4) e x  e y & a x  a y t
15. Following graph shows the correct variation in intensity of heat radiations by black body and frequency
at a fixed temperature

1) 2)

3) 4)

16. The spectrum of a black body emission at two temperatures 27oC and 327oC is plotted as E versus  .
A2
Let A1 and A2 be the areas under the two curves respectively. The value of is
A1

1) 1 : 16 2) 4 : 1 3) 2 : 1 4) 16 : 1
17. Heat is flowing through a conductor of length l from x = 0 to x = l. If its thermal resistance per unit
length is uniform, which of the following graphs is correct ( T is temperature at x )

1) 2)

3) 4)

18. Radius of a conductor increases uniformly from left end to right end as shown in fig.

T1 T2

Material of the conductor is isotropic and its curved surface is thermally isolated from surrounding. Its
ends are maintained at temperatures T1 and T2 (T1 > T2): If, in steady state, heat flow rate is equal to H,
then which of the following graphs is correct

1) 2) 3) 4)
19. Which of the following graphs correctly represents the relation between ln E and ln T where E is the
amount of radiation emitted per unit time from unit area of a body and T is the absolute temperature

1) 2)

3) 4)

20. A hollow copper sphere S and a hollow copper cube C, both of negligible thin walls of same area, are
filled with water at 90°C and allowed to cool in the same environment. The graph that correctly
represents their cooling is

1) 2)

3) 4)

21. A refrigerator is working between 260K and 300K. It takes 500cal of heat from sink. Heat rejected to
the source at higher temp. for this refrigerator is
1) 400 cal 2) 477 cal 3) 377 cal 4) 577 cal
22.. Two Carnot engines A and B are operated in succession. The first one, A receives heat from a source at
T1  800 K and rejects to a sink at T2 K . The second engine B receives heat rejected by the first engine

and rejects to another sink at T3  300 K . If the efficiencies of two engines are equal, then the value of

T2 is

1) 489.4K 2) 469.4K 3) 449.4K 4) 429.4K

23. An ideal gas heat engine operates in Carnot’s cycle between 227ºC and 127ºC. It absorbs 6.0 104 cal at
higher temperature. The amount of heat converted into work is equal to :

1) 4.8 104 cal 2) 3.5 104 cal 3) 7.2 104 cal 4) 1.2 104 cal
24. A refrigerator works between 30C and 40ºC. To keep the temperature of the refrigerator constant, 600
calories of heat are to be removed every second. The power required is :
1) 33.78 watt 2) 337.8 watt 3) 7.77 watt 4) 10.77 watt

25. An ideal heat engine is working between temperature T1 and T2 has efficiency  . If both the
temperatures are raised by 100 0 K each, the new efficiency will be

1)  2) less than  3) more than  4) cannot be predicted

26. The efficiency of a Carnot engine is 1/6. In reducing the sink temperature by 65K, the efficiency
1
becomes . The initial and final temperature between which the engine works, are
3

1) 1170 C,520 C 2) 2170 C,520 C 3) 3170 C,520 C 4) 170 C,520 C

27. For which of the following process is the entropy change zero?

1) Isobaric 2) Isothermal

3) Adiabatic 4) None of these, since S  0 for all processes

28. One mole of an ideal gas is originally at Po Vo and To .The gas is heated at constant volume to 2To , then

allowed to expand at constant temperature to 2Vo , and finally it is allowed to cool at constant pressure to

To , The net entropy change for this ideal gas is

1) S  (5R / 2) In 2 2) S  5R / 2 3) S  R In 2 4) S  0

29. A block of aluminum originally at 800 C is placed into an insulated container of water originally at
250 C .After a while the system reaches an equilibrium temperature of 310 C

During this process

1) Salu min um  0 2) Salu min um  0

3) S alu min um  0 4) Insufficient data to assess change in entropy

D
2 p3

TJ
V
VJ 2 0

30. Which of the following is a consequence of the second law of thermodynamics?

 1) With in a closed system, entropy change for a process is positive

2) Objects in contact will tend toward having the same temperature

3) Any system that produces order from disorder must have an external influence

4) All on the above

KEY

1-10 1 4 2 2 2 3 1 3 4 4

11-20 3 1 1 3 3 4 3 2 4 1

21-30 4 1 4 2 2 1 3 4 3 4

SOLUTIONS
dQ KA 
1.  , For both rods K, A and  are same
dt l
dQ 1 (dQ / dt )semi circular lstraight 2r 2
  So    .
dt l (dQ / dt)straight lsemicircular r 
L 2 2
2. t (x 22  x 12 )  t  (x 2  x1 )
2 K

3.  TB  TA  Heat will flow B to A via two paths (i) B to A (ii) and along BCA as shown.
Rate of flow of heat in path BCA will be same (T)A
Q Q
i.e.     a 2
 t  BC  t  CA
a
k ( 2 T  TC ) A k (TC  T ) A
 
a 2a 2T a C(Tc)
B
TC 3
 
T 1 2

 A (T 4  T04 )
4. Rate of cooling of a body R 
t mc
A Area
 R 
m Volume
1
 For the same surface area. R
Volume
Volume of cube < Volume of sphere
 RCube  RSphere i.e. cube, cools down with faster rate.
5. Energy received per second i.e., power P  (T 4  T04 )

 P  T4 ( T0  T )
1
Also energy received per sec (p) 
d2
(inverse square law)
4 2
T4 P1  T1   d 2 
 P      
d2 P2  T2   d1 
2 2
P  T   2d  1
       P2  4 P.
P2  2 T   d  4

6. The given arrangement of rods can be redrawn as follows

 2 K1 K 2
K
K1  K 2
H1 H1 K1 K2
l l

K3
H H2 H

It is given that H1 = H2
 KA ( 1   2 ) K 3 A(1   2 )
  K 3  K  K1 K 2
2l l 2 K1  K 2

 A (T 4  T04 )
7. Rate of cooling 
t mc
As surface area, material and temperature difference are same, so rate of loss of heat is same in both the
spheres. Now in this case rate of cooling depends on mass.
 1
 Rate of cooling 
t m
m solid  m hollow . Hence hollow sphere will cool fast.
Q KA  mL K(r 2 )
8.   
t l t l

 m  Kr 2
 Rate of melting of ice  
 t  l

1
Since for second rod K becomes th r becomes double and length becomes half, so rate of melting will
4
m  m 
be twice i.e.    2    2  0. 1  0 .2 gm / sec .
 t 2  t 1

dT  A
9.  (T 4  T04 ) [In the given problem fall in temperature of body dT  (200  100 )  100 K , temp. of
dt mcJ
surrounding T0 = 0K, Initial temperature of body T  200 K].
100  4r 2
 (200 4  0 4 )
dt 4 3
r  c J
3
r c J r c 4 .2
 dt   10  6 s  .  10  6
48   48
7 r c 7 r c
  s ~– s [As J = 4.2]
80  72 
l1  l2 x  4x 5
10. Equation of thermal conductivity of the given combination Keq 
l1 l2

x 4x
 K. Hence rate of flow
  3
K1 K 2 K 2K
of heat through the given combination is
5 1
K A (T2  T1 ) K A (T2  T1 )
Q K eq . A(T2  T1 ) 3 3
  =
t (x  4 x ) 5x x
1
On comparing it with given equation we get f
3
11. If thermal resistance of each rod is considered R then, the given combination can be redrawn as follows
 R 2R
R
120°C R
C
A B
20°C
R R
2R

R  R
A C
120°C B 20°C

(Heat current)AC = (Heat current)AB

(120  20 ) (120   )
    70 C
R R
12. Rate of heat loss per unit area due to radiation i.e. emissive power e   (T 4  T04 )
17
 0.6   10  8  [(400 )4  (300 )4 ]
3
 3. 4  10 8  (175  10 8 )  3. 4  175  595 J / m 2  sec

13. Black bulb absorbs more heat in comparison with painted bulb. So air in black bulb expands more.
Hence the level of alcohol in limb X falls while that in limb Y rises.
 dT 
14. Rate of cooling   emissivity (e)
 dt 

 dT   dT 
From graph,       ex  ey
 dt  x  dt  y

Further emissivity (e)  Absorptive power (a)  a x  ay

(  good absorbers are good emitters).

1
15. According to Wein's law m   m  T . As the temperature of body increases, frequency
T
corresponding to maximum energy in radiation (m) increases this is shown in graph (c).
16. Area under given curve represents emissive power and emissive power  T4  A  T 4
4
A 2 T24 (273  327 )4  600  16
     =
A1 T14 (273  27 )4  300  1
dQ d
17.   KA
dt dx
dQ
,K and A are constants for all points
dt
 d  dx ; i.e. temperature will decrease linearly with x.
18. Since the curved surface of the conductor is thermally insulated, therefore, in steady state, the rate of
flow of heat at every section will be the same. Hence the curve between H and x will be straight line
parallel to x-axis.
19. According to Stefan's law E  T 4
 log E  log   4 log T  log E  4 log T  log 

on comparing this equations with y  mx  C

we find that graph between log E and log T will be a straight line, having positive slope (m = 4) and
intercept on log E axis equal to log 
d   A 3
20.  40 
dt mc
 T2
21.  
T1  T2
Q2
 
W
W ?
Q1  Q2  W

T2 T
22. 1  1 3
T1 T2
23. W    Q1
Q2 T2
24.  
W T1  T2
W ?
W
P
t
T21
25. 1  1
T11
T2
  1
T1
T2
26.   1
T1

dQ
27. (3) dQ  0 and ds 
T
28. (4) Initial & final states are same
29. (3) dQ is negative hence ds is negative
30. (4) According to the second law statement all the conclusions can be made
DPP-2

1. A cylinder of radius R made of a material of thermal conductivity K1 is surrounded by a cylindrical

shell of inner radius R and outer radius 2R made of a material of the thermal conductivity K 2 . Two ends

of combined system are maintained at two different temperatures. Combined effective thermal
conductivity of system with its cylindrical surface insulated is
K1  3K 2 K1 K 2 3K1  K 2
a) K1  K 2 b) c) d)
4 K1  K 2 4

2. The coefficient of apparent expansion of mercury in a glass vessel is 153 × 10–6/ºC and in a steel
vessel is 144 × 10–6/ºC. If  for steel is 12 × 10–6/ºC, then that of glass is
A) 9 × 10–6/ºC B) 6 × 10–6/ºC C) 36 × 10–6/ºC D) 27 × 10–6/ºC

3. Three rods of same material and having same cross – section have been joined as shown
 Each rod is of same length with one end kept at a constant temperature as marked. Temperature of
junction of the three rods will be
a) 450 C b) 600 C c) 300 C d) 200 C
4. Six identical conducting rods are joined as shown in the figure.

F
A B E
D

End A and F are maintained at 2000 C and 00 C respectively. Temperature of point B in steady state
will be
a) 1000 C b) 55.560 C c) 66.670 C d) 800 C
5. Water in a lake starts freezing at t = 0 when the outside temperature is -  0C . The time intervals in
which thickness changes from 0 to y, from y to 2y, from 2y to 3y and so on, will be in ratio
a) 1 : 2 : 3 b) 1 : 4 : 9 c) 1 : 3 : 5 d) 1 : 9 : 25
6. A room is maintained at 250 C by using a heater of 20 and 200 V supply. Room is well insulated
from every where except for a glass window of area 1m 2 and glass pane of thickness 0.2cm. thermal
conductivity of glass is 0.2 cal m 1 0C 1 s 1 Assuming heat conduction takes place through window
only, outside temperature will be
a) less than 160 C b) less than 200 C but more than 160 C
c) exactly 200 C d) above 200 C
7. Coefficient of thermal conductivity
a) depends upon nature of the material of the body
b) is independent of dimensions of the body
c) both a and b d) depends on temperature difference.
8. Ratio of heat current, when rods are in parallel to heat current, with when rods are in series (in given
case) will be
 16 11 6 66
a) b) c) d)
3 5 5 5
9. A steel scale measures the length of a copper wire as 80.0 cm, when both are at 20C (the
calibration temperature for scale). What would be the scale read for the length of the wire
when both are at 40C ? (Given steel  11 106 per°C and copper  17  106 per C )
(a) 80.0096cm (b) 80.0272cm (c)1cm (d) 25.2cm
10. Two identical rods AB and CD are connected across the end points of a diameter of a ring as shown in
the figure.

A B C D

Radius of ring is equal to length of rod AB (or CD) and area of cross – section is same every where in
the assembly. Rods and ring also have same material. If point A is maintained at 1000 C and point D is
maintained at 00 C , then temperature of point C will be
a) 620 C b) 370 C c) 280 C d) 450 C
11. Spectral energy density distribution E of a black body at two different temperature T1 and T2 is shown

in the figure. If areas under the curves are in the ratio 16 : 1 and T2 is 2000 K, then value of

temperature T1 will be

a) 32000K
b) 16000K
c) 8000K
d) 4000K
12. Energy spectrum of a body shows a maxima around a wavelength of 0 . Temperature of this body is
3
increased and it is found that energy maxima now occurs around a wavelength 0 . Power radiated by
4
the black body now increased by a factor of
256 64 16 4
a) b) c) d)
81 27 9 3
13. Two hollow metallic spheres of the same metal and radii R and 2R are at temperatures 2T and T
respectively. The ratio of total energy radiated per second by the spheres is
a) 1 : 1 b) 4 : 1 c) 16 : 1 d) 8 : 1
14. A solid cuboid with edges 1cm, 2cm and 3cm is suspended in vaccum, its temperature falls from
1000 C to 900 C in 100s. Another solid cuboid of same material and similar surface finish is kept in
same enclosure. If sides of cuboid are 2cm, 4cm and 6cm, then time taken for this cuboid to cool from
1000 C to 900 C will be
a) 100s b) 150s c) 50s d) 200s
15. Ram wants to drink tea, when it is at 500 C . He ordered tea which arrives at a temperature 800 C . Tea
takes one minute to cool from 800 C to 600 C . If room temperature 300 C , how long he has to wait to
drink the tea?
a) Less than one minute b) Two more minutes
c) Half a minute d) Nearly three minutes
16. A body, initially at 64 C cools to 52 C in 10 minutes. Temperature of surroundings is 160 C .
0 0

Temperature of body after 10 more minutes is

a) 480 C b) 430 C c) 350 C d) 500 C
17. Earth receives about 1400Wm 2 from the sun. distance of sun from earth is about 1.4  1011 m and the
radius of sun is 7  108 m. surface temperature of sun can be approximated (Take,   5.6  10 8 Jm 2 s 1 )
15
a) 104 K b) 103 K c) 10 4 K d) 5883K
18. A glass flask of volume one litre at 0°C is filled, level full of mercury at this temperature. The
flask and mercury are now heated to 100°C. How much mercury will spill out, if coefficient of
volume expansion of mercury is 1.82  10 4 / C and linear expansion of glass is 0 .1  10 4 / C
respectively
(a) 21.2 cc (b) 15.2 cc (c) 1.52 cc (d) 2.12 cc
19. Consider an ideal gas confined in an isolated closed chamber. As the gas undergoes an adiabatic
expansion, the average time of collision between molecules increases as V q , where V is the volume of
 C 
the gas. The value of q is    P 
 CV 

3  5 3  5  5  1
a) b) c) d)
6 6 2 2
20. An open glass tube is immersed in mercury in such a way that a length of 8cm extends above the
mercury level. The open end of the tube is then closed and sealed and the tube is raised vertically up by
additional 46cm. what will be length of the air column above mercury in the tube now? (Atmospheric
pressure= 76 cm of Hg)
a) 16 cm b) 22 cm c) 38 cm d) 6 cm
21. The given p – V diagram represents the thermodynamic cycle of an engine operating with an ideal
monatomic gas. The amount of heat, extracted from the source in a single cycle is
 13 
a) p0V0 b)   p0V0
 2
 11 
c)   p0V0 d) 4 p0V0
2
22. Helium gas goes through a cycle ABCDA (consisting of two isochoric and isobaric lines) as shown in
the figure. Efficiency of this cycle is nearly (assume the gas to be close to ideal gas)
a) 15.4%
b) 9.1%
c) 1.5%
d) 12.5%
23. A carnot engine, whose efficiency is 40%, takes in heat from a source maintained at a temperature of
500K. it is desired to have an engine of efficiency 60%. Then, the intake temperature for the same
exhaust (sink) temperature must be
a) efficiency of carnot engine cannot be made larger than 50%
b) 1200K c) 750 K d) 600K
24. A container with insulating walls is divided into two equal parts by a partition fitted with a valve. One
part is filled with an ideal gas at a pressure p and temperature T, whereas the other part is completely
evacuated. If the valve is suddenly opened, the pressure and temperature of the gas will be
p p T T
a) ,T b) , c) p, T d) p,
2 2 2 2
25. A thermally insulated vessel contains an ideal gas of molecular mass M and ratio of specific heats  . It
is moving with speed v and its suddenly brought to rest. Assuming no heat is lost to the surroundings, its
temperature increases by

a)
  1 Mv 2 K b)
 Mv 2
c)
  1 Mv 2 K d)
  1 Mv 2 K
K
2 R 2R 2R 2    1 R

1
26. A carnot engine operating between temperatures T1 and T2 has efficiency . When T2 is lowered by
6
62K, its efficiency increases to 1/3. Then, T1 and T2 are respectively
a) 372 K and 330 K b) 330 K and 268K
c) 310 K and 248K d) 372K and 310K
27. Three perfect gases at absolute temperatures T1 , T2 and T3 are mixed. The masses of molecules are

m1 , m2 and m3 and the number of molecules are n1 , n2 and n3 respectively. Assuming no loss of energy,
the final temperature of the mixture is
n1T1  n2T2  n3T3 n1T12  n2T2 2  n3T3 2
a) b)
n1  n2  n3 n1T1  n2T2  n3T3

c)
n12T12  n2 2T2 2  n3 2T32
d)
T1  T2  T3 
n1T1  n2T2  n3T3 3

28. 5.6L of helium gas at STP is adiabatically compressed to 0.7L. Taking the initial temperature to be T1 ,

the work done in the process is

9 3 15 9
a) - RT1 b) RT1 c) RT1 d) RT1
8 2 8 2
29. An ideal gas expanding such that pT 2  constant. The coefficient of volume expansion of the gas is
1 2 3 4
a) b) c) d)
T T T T
30. A monoatomic gas undergoes a process given by 2d U  3d W  0 then what is the process.
a) Isothermal b) adiabatic c) isobaric d) polytrophic
 KEY

1-10 B A B C C D C D A C

11-20 D A B D A B C B D A

21-30 B A C A C D A A C D

SOLUTIONS
R1 R2
1. Rnet 
R1  R2

2. real = app. + vessel

So (app. + vessel)glass = (app. + vessel)steel
 153 × 10–6 + (vessel)glass = (144 × 10–6 + vessel)steel
Further, (vessel)steel = 3 = 3 × (12 × 10–6) = 36 × 10–6/ºC
 153 × 10–6 + (vessel)glass = 144 × 10–6 + 36 × 10–6
 (vessel)glass = 3 = 27 × 10–6/ºC   = 9 × 10–6/ºC

90   90     0
3.  
R R R

4. Equivalent combination

A R 2R C
2000C B 00C

pL 2
5. t
2k
 y2  y12 

6. Rate of heat generated = Rate of heat flow

V2   
t  KA  t
JR  l 

7. K depends only on nature of material

R1 R2
8. case (i) RP 
R1  R2

Case (ii) RS  R1  R2

H P RS

H S RP

9. With temperature rise (same 25°C for both), steel scale and copper wire both expand. Hence
length of copper wire w.r.t. steel scale or apparent length of copper wire after rise in
temperature
 Lapp  L 'cu  L 'steel  [ L0 (1   Cu  )  L0 (1   s  )
 Lapp  L0 ( Cu   s ) 

 80(17  106  11 106 )  20 = 80.0096 cm

10.

T  R

11. E  T 4

4
E1 A1  T1 
  
E2 A2  T2 

12. T  const.

13. Q  P.t   At 4  t 

T A
14. 
t m

1   2  1   2 
15.   
t  2 

d k
16.    0 
dt mc

T T 
 2.303log10  1 0   kt
 T2  T0 

 T 4 .4 R 2
17.  1400
4 r 2

18. Due to volume expansion of both liquid and vessel, the change in volume of liquid relative to
container is given by V = V0 [ L   g ]
Given V0 = 1000 cc, g = 0.1×10–4/°C
  g  3 g  3  0.1  10 4 / C  0.3  10 4 / C

 V = 1000 [1.82 × 10–4 – 0.3 × 10–4] × 100 = 15.2 cc


19. Average time taken collision t 
vrms

1
N
2 d2
t V
3RT
M
 V V2
t T 
T t2

Adiabatic process TV  1  K

V 2  1
V k
t2
  1
2
t V

20. PV
1 1  PV
2 2

P  P0   gh

21. Heat supplied = nCV  T   nCP  T 

W area under P-V diagram

22.  
Q  Q  AB   Q BC
T2
23.   1
T1

24. internal energy of gas remains const

1
25. MV 2  nCv dT
2

T2
26.   1
T1

f f f f
27. n1KT1  n2 KT2  n3 KT3   n1  n2  n3  KT
2 2 2 2

nRT
28. w
 1

29. PT 2  K  constant

 nRT  2 3 1
 V  T  T V  constant
 

30. dQ  dU  dW

2dU dU 1 1 3 nRdT
dQ  dU    nCV dT  .n. RdT 
3 3 3 3 2 2

1 dQ R
C 
n dT 2

R
C
2
CHEMISTRY
 CHEMISTRY

DPP-1

1. The major product of the following reaction is

A) B)

C) D)
2. The major product of the following reaction is

Cl

A) B) C) D)
3. The major product of the following reaction is

OH
CH3

A) B) C) D)
4. The compounds A and B in the following reaction are, respectively
HCHO + HCl AgCN
A B

A) A = Benzyl alcohol, B = Benzyl isocyanide B) A = Benzyl cloride, B = Benzyl isocyanide

C) A = Benzyl alcohol, B = Benzyl cyanide D) A = Benzyl chloride, B = Benzyl cyanide
5. How many of the following reactions are correctly matched
 i) ii)

iii) iv)
A) i & ii B) i & iii C) i , ii & iii D) i , ii, iii & iv

6.
In above reactions x, y are respectively

Cl Cl

A) B) C) D)

7. The compound X in the reaction,

A) B) C) D)

8. The rate of o-nitration of the above compounds, I) toluene, II) 2-D-toluene and III) 2, 6-D2- toluene are
is in the following order

A) I > II > III B) II > I > III

C) III > I > II D) the rate is the same for all the three compounds
9. The product ‘N’ of the following reaction is
 A) B) C) D)
10. The best sequence of reactions for the following conversion is

A) i) 1 mol Br2 / FeBr3 ii) KMnO 4 ,heat iii) HNO3  H 2SO 4

B) i) HNO3  H 2SO 4 ii) 1 mol Br2 / FeBr3 iii) KMnO 4 ,heat

C) i) KMnO 4 ,heat ii) HNO3  H 2SO 4 iii) 1 mol Br2 / FeBr3

D) i) 1 mol Br2 / FeBr3 ii) HNO3  H 2SO 4 iii) KMnO 4 ,heat

11. The order of reactivity of the following compounds in electrophilic monochlorinatic

the most favorable position is
CH3

I) OCH3 II) III) IV)

A) I < II < IV < III B) III < IV < I < II C) IV < III < II < I D) III < II < IV < I
12. At which position nitration mainly takes place?
2
1
3 H
N NO2+

Mono nitration
N O
4 H

A) 4 B) 3 C) 2 D) 1
13. The best sequence of reactions for preparation of the following compound from benzene is

A) i) CH 3COCl / AlCl 3 ii) Oleum iii) (CH 3 )2 CH  Cl (1  mole ) / AlCl 3

B) i) (CH 3 )2 CH  Cl (1  mole ) / AlCl 3 ii) CH 3COCl / AlCl 3 iii) Oleum

C) i) Oleum ii) CH 3COCl / AlCl 3 iii) (CH 3 )2 CH  Cl (1  mole ) / AlCl 3

D) i) (CH 3 )2 CH  Cl (1  mole ) / AlCl 3 ii) Oleum iii) CH 3COCl / AlCl 3

14. The alkene limonene has the following structure
 What product results from the reaction of limonene and chlorine water (excess)?

A) B) C) D)
15. The peroxide effect occurs by
A) ionic mechanism B) hemolytic fission of double bone
C) heterolytic fission of double bond D) free radical mechanism
16. Benzene does not readily undergo
A) halogenation B) nitration C) sulphonation D) oxidation
17. In Friedel-Craft acylation, the amount of AlCl3 that must be taken is
A) In catalytic amount B) one equivalent
C) More than one equivalent D) amount does not matter
18. For a Friedel-Craft reaction using AlCl3, which compound can be used as solvent, benzene or
nitrobenzene?
A) nitrobenzene but not benzene B) benzene but not nitrobenzene
C) both benzene and nitrobenzene D) neither benzene nor nitrobenzene
19. Which of the following compounds will form significant amount of meta product during mono nitration
reaction?

A) B) C) D)
20. The major product formed upon addition of 1 mole of HBr in the following reactions is

HBr(1 mole)
Major product?

Br

Br
A) B) C) D)
21. The major product in the following reaction is

A) B) C) D)
22. Identify the alkene which will not provide the following alcohol upon oxymercuration demercuration.
 A) B) C) D)
23. Cyclohexene reacts with limited amount of bromine in the presence of light to form product X
(C6H5Br). The statement correct about X is
A) it is a racemate B) it is a product of an addition reaction
C) it is formed through a cationic intermediate D) it is optically active24.
24. Which isomer of xylene can give three different monochloro derivatives?
A) o-xylene B) m-xylene
C) p-xylene D) mylene cannot give a monochioro derivative 26.
A) B) C) D)

25.
The ‘product’ in the above reaction is :

Br

A) B) Br

Br

C) Br D) this reaction cannot take place

26. The major product of the following reaction is

Cl

A) B) C) D)
27. The major product of the following reaction is

A) B) C) D)
28. The major product in the following conversion is

A) B)
 HO CH2 CH CH3
C) Br D)
29. The major product in the following conversion is
O

O Br2 (1 eqv)

MeOH
O

A) B) C) D)

30.
The correct name of the product obtained is
A) cis-1, 2-dibromocyclohexane B) cis-1,4-dibromocyclohexane
C) trans-1, 2-dibromocyclohexane D) trans-1, 4-dibromocyclohexane

KEY

1-10 D B C B D B B D A A

11-20 B A B D D D C A D B

21-30 A D A B B C C A A C

SOLUTIONS
1. carbocation rearrangement followed by Electrophilic substitution reaction
2. HCl addition followed by Electrophilic substitution reaction

3.
Keep in mind first alkylation will takes place followed by acylation
-OH group is o,p-directing group in prescence of AlCl3
4. first step is chloromethylation, second step is SN2 reaction,but here N acts as nucleophile
5. All are Electrophilic substitution reactions
6. With strong lewis acid carbo cation rearrangement will takes place, where as with week lewis acid no
carbo cation rearrangement
7. Iodonation with I2 is reversible, where as ICl its not a reversable
8. attack of electrophile is RDS step and removal of proton is fast step so there on KIE
9. alkyl benzenes are oxidized to corresponding carboxylic acids using KMnO4 and them COOH is meta
directing group, which directs the electrophile in to meta position
10. It seems to be like what is wrong with option C there while doing nitration methyl group also will direct
that so some amount of other product also will be formed.
11. in forst molecule both are o,p directing but but its not a additive, where as in second case both are
additive so second is more reactive than first one. Remaining two are having electron withdrawing
groups
12. In given structure one of the N is amine nitrogen, another one is amide nitrogen and one more thing
There are n number of nitrating agents are so in this they did not mention the nitrating mixture
13. In multisyep synthesis of aromatic compounds better to introduce first ring activating group, followed
by deactivating group
14. Hypohalous addition folloes markonikoff rule
15. Karshak effect
16. It’s a highly stable aromatic system, it is relectent to undergo oxidation
17. The product acyl benzene also coordinate with lewis acid that’s why more than one equivelnt we have to
use
18. Nitrobenzene is inactive towards nitration
19. nitration mixture is a strong acidic medium, aniline is a base so aniline will give significant amount of
meta nitration product
20. Double bond which is more nucleophilic will undergo more readily in Electrophilic addition
More alkyl substituted double bond is more reactive than less substituted double bond
21. Additopn water in anti markonikoff rule
22. addition of water in markonikoff way with out carbon skleten rearrangement
23. Its an allylic bromination and during the reaction we are generating chiral centre so product is racemic
mixture
24. Out of three xylenes meta xylene only having three different positions
25. Addition will go via more stable carbocation
26. Here we can expect the ring expansion, but there is no option with that so we can go direct addition
27. Addition of halogen should be done in non nucleophilic solvent. If there is a nucleophilic solvent that
will open the cyclobromonium ion
28. Electrophilic addition followed by ether cleavage
29. Cyclo bromonium ion formation followed by opening with methanol
30. Br2 addition is anti addition so both the Br atoms should be diaxial if it undergo ring flipping di
equatorial. So trans dibromo cyclo hexane
 DPP-2

1. The major product of the following reaction is

A) a hemiacetal B) an acetal C) an ether D) an ester

2. Acid catalyzed hydration of alkenes except ethane leads to the formation of
A) mixture of secondary and tertiary alcohols
B) mixture of primary and secondary alcohols
C) secondary or tertiary alcohol
D) primary alcohol
3. Which of the following reaction will yield 2,2-dibromopropane?

A) CH 3  C  CH  2 HBr  B) CH 3  CH  CHBr  HBr 

 

D) CH 3  CH  CH 2  HBr 
C) CH  CH  2 HBr 
 

4. Statement-1 : Bromobenzene upon reaction with Br2 / Fe gives 1,4-dibromobenzene as the major
product.
Statement-2: In bromobenzene, the inductive effect of the bromo group is more dominant than the
mesomeric effect in directing the incoming electrophile
A) statement -1 is true, statement-2 is true; statement-2 is a correct explanation for statement-1
B) statement -1 is true, statement-2 is true; statement-2 is NOT a correct explanation for statement-1
C) statement-1 is true, statement-2 is false
D) statement-1 is false, statement-2 is true
5. The compounds P, Q and S were separately subjected to nitration using HNO3 / H2SO4 mixture. The
major product formed in each case respectively, is

A)

B)

C)
 D)
6. Presence of a nitro group in a benzene ring
A) activates the ring towards electrophitic substitution
B) renders the ring basic
C) deactivates the ring towards nucleophilic substitution
D) deactivates the ring towards electrophilic substitution

7. The electrophile, E attacks the benzene ring to generate the intermediate  -complex. of the following
which  -complex is of lowest energy?

A) B) C) D)
8. The reaction of propene with HOCl (Cl2 + H2O) proceeds through the intermediate
 
A) CH 3  CH  CH 2  Cl B) CH 3  CH (OH )  CH 2
 
C) CH 3  CHCl  CH 2 D) CH 3  CH  CH 2  OH

9. HBr reacts with CH 2  CH  OCH 3 under anhydrous conditions at room temperature to give

A) CH 3CHO and CH 3Br B) BrCH 2CHO and CH 3Br

C) BrCH 3  CH 2  OCH 3 D) H 3C  CHBr  OCH 3

10. The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly
A) o-and p-chlorotoluene B) m-chlorotoluene
B) benzoylchloride D) benzyl chloride
11. Which of the following reactions is not an electrophilic addition reactions

A) B)

C) D)
12. The relative rates of mononitration of R  C 6H 5 , where R  CH 3 , NO 2 , OH , Cl are

A) CH 3  OH  NO 2  Cl B) OH  Cl  CH 3  NO 2

C) OH  CH 3  NO 2  Cl D) OH  CH 3  Cl  NO 2

13. Allylic bromination of an olefin is

A) Nucleophilic substitution B) Electrophilic substitution
C) Free radical substitution D) Electrophilic addition
14. The correct statements with respect to the following reactions is/are?

COOH Br2
HOOC (X)
(P)

Br2
(Y)
HOOC (Q) COOH

A) it’s a nucleophilic addition reaction B) X is meso isomer and Y is racemix mixture

C) X is optically active and Y is meso isomer D) Each of P & Q gives a mixture of X & Y

15. Choose the major product of the following reaction sequence

O
CH3
Cl S CH3
-
1.BH 3 O I
Major product
- Pyridine
2.H 2O 2,OH

Me
Me I Me Me
I I

A) B) C) D) I

alc. KOH (E 2)
Reactant Ph H
-HCl

H3C CH 2Ph
16.
Ph Ph Ph Ph
H3C H H3C Cl H CH3 H CH3
H Cl H H Cl H H Cl

PhH2C PhH2C
A) B) C) PhH2C D) PhH2C
O O O O
1.O 3 (excess)
? H3C CH3 H3C CH3
2.H 2O 2 O O O
3.Na 2CO 3,then CH 3I
+
CH3
H3C
17.
CH3
CH3

H3C CH3
H3C CH3

A) B)
CH3
CH3

H3C CH3
H3C CH3

C) D)
18. Addition of HBr to 2,3-dimethyl-1,3-cyclohexadiene may occur in the absence or presence of peroxides.

In each case two isomeric C8 H13Br products are obtained. Which of the following is a common product
from both reactions?
Br Br Br
Br
H3C H3C H3C H3C

A) H3C B) H3C C) H3C D) H3C

19. 1,3-pentadiene and 1,4-pentadiene are compared with respect to their intrinsic stability and reaction with
Hl. The correct statement is
A) 1,3-pentadiene is more stable and more reactive than 1,4-pentadiene
B) 1,3-pentadiene is less stable and less reactive than 1,4-pentadiene
C) 1,3-pentadiene is more stable but less reactive than 1,4-pentadiene
D) 1,3-pentadiene is less stable but more reactive than 1,4-pentadiene
NOCl
20. CH 2  CH  CH 3   X , X is

A) B) C) D)
21. 1,3-butadiene is more stable due to conjuation and also more reactive with HI due to formation of allyl

carbocation

A) B) C) D)
22. Among the following, reaction donot give tert-butyl benzene as the major product is (are)

H2SO4
A) B) C) D)
23. In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-markovnikov
addition to alkenes because
A) both are highly ionic
B) one is oxidizing and the other is reducing
C) one of the steps is endothermic in both the cases
D) all the steps are exothermic in both the cases
24. The reagent system for preparing propan-1-ol from propene is
A) Hg (OAc )2 / H 2O followed by NaBH 4 B) H 2SO 4 / H 2O

C) B 2 H 6 Followed by H 2O2 D) HCO2 H / H 2SO 4

25. Major organic product of the given reaction is?

 Br
Br
OH
A) B) C) D)
26. The rate of Electrophilic addition reaction with HBr will be

Ph MeO
i) ii) iii) iv)
A) iv > i > iii > ii B) i > ii > iii > iv C) i > iii > ii > iv D) iv > i > ii > iii
27. One mole of symmetrical alkene on ozonolysis gives two moles of an aldehyde having molecular mass
of 44u. The alkene is
A) propene B)2-butene C)1-butene D) ethene
28. Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the
presence of
A) an isopropyl group B) any acetylinic triple bond
C) two ethylenic double bonds D) a vinyl group
29. 2-hexyne gives trans-2-hexene on treatment with
A) Pt/H2 B)Li/NH3 C)Pd/BaSO4 D)LiAlH4
30. Which compound would give 2-keto-2-methyl hexanal upon ozonolysis

A) B) C) D)
KEY

1-10 B C A C C D C A A A

11-20 C D B C C D D B A B

21-30 D A C C B A B D B B

SOLUTIONS
1. If any carbon attached with two ether groups, then we can call that as an acetal
2. other than ethylene all other alkene will give either 2º or 3º alcohol as a major
3. Addition of HBr to alkyne gives mainly gem dibromides and it follows markonikaff rule if alkyne is
unsymmetrical
4. in Br inductive effect is dominanting, but there is no relation between inductive effect and directing the
electrophile, so second statement is wrong.
5. orientation of Electrophilic substitution reaction.
6. Nitrogroup is –M and –I group
7. NO2 is a meta directing group so the complex formed
8. In HOCl Cl is an electrophile, in electrophilic addition first electrophile will go and add and that ti that
will add in such a way that will result in more stable carbocation.
9. Along with HBr addition hydrolysis of ether also takes place
10. O/P ration in toluene is very less so we will get the mixture of products
11. HBr in prescence of peroxide follows the free radical mechanism
12. OH activating, o,p, CH3 week activating o,p, Cl deactivating o, p –NO2 deactivating meta
13. allylic bromination is a free radical mechanism
14. to cis alkene anti addition is will give erytho, where as for trans alkene anti addition will give threo
15. hydroboration is syn addition followed by SN2 reaction
16. E2 reaction follows anti elimination
17. oxidative ozonolysis followed by esterification
18. in both the case 1,4-addition is major
19. 1,3-butadiene is more stable due to conjuation and also more reactive with HI due to formation of allyl
carbocation
20. in NOCl NO+ is electrophile and Cl- is nucleophile
21. in case of isoprene irrespective of the temperature 1,4-addition is major
22. in first option tertiary butyl bromide and sodium ethoxide combination will give alkene as a product
23. peroxide effect will be observed only in HBr in remaining all follows ionic mechanism
24. Hydroboration oxidation process is addition of water to alkene in antimarkonikoff rule
25. Intial cyclobromonium ion will be opend by internal alcohol
26. During the reaction carbocation is the intermediate which will form more stable carbo cation that is
more stable
27. aldehyde with molecular mass 44 is acetaldehyde and alkene should be symmetrical with this clue
answer should be 2-alkene
28. Terminal alkene will give the formaldehyde as a one of the product in ozonolysis
29. alkynes can be converted in to alkene using birch reduction

30.
DPP-3
1. The major organic product formed by the reaction of 1,1,1-trichloroethane with silver powder is
A) 2-butene B) Acetylene C) Ethene D) 2-butyne
2. In the reaction of chlorine with propene at 4500C, the major product is

A) B) C) D)
3. The compound which does not react with bromine easily at room temperature is
A) phenol B) 2-butyne C) chlorobenzene D) 1-pentene
4. The product obtained from the following sequence of reactions is
HgSO4 NaBH 4
H 3C  C  CH 
H 2SO 4
A  B

A) propanal B) 2-propanol C) 1-propanol D) propane

5. The hydrocarbon that cannot be prepared effectively by Wurtz reaction is

A) B)

C) D)
6. 3-Methylpentane on monochlorination gives four possible products. The reaction follows free radical
0 0 0
mechanism. The relative reactivitives for replacement of –H are 3 : 2 : 1  6 : 4 : 1 .

Relative amounts of A, B, C and D formed are

A) 6/31, 16/31, 6/31, 3/31 B) 16/31, 6/31, 6/31, 3/31
C) 6/31, 16/31, 3/31, 6/31 D) 6/31, 3/31, 6/31, 16/31
7. The number of chiral compounds produced upon monochlorination of 2-methylbutane is
A) 2 B) 4 C) 6 D) 8
Cl 2 /hv Fractional
(CH 3 )2 CH  CH 2CH 3  [N ]  [P ]
8. distillation

The number of possible isomers [N] and number of fractions [P] are
A) (6,6) B) (6,4) C) (4,4) D) (3,3)
9. Different possible thermal decomposition pathways for peroxyesters are shown below. Match each
pathway from List I with an appropriate structure from List II and select the correct answer using the
code given below the lists.

List – I List – II
 P. Pathway P 1.

Q. Pathway Q 2.

S. Pathway R 3.
O
O CH3
O
C6H5 CH3
S. Pathway S 4. C6H5

Code:
P Q R S P Q R S
A) 1 3 4 2 B) 2 4 3 1
C) 4 1 2 3 D) 3 2 1 4
10. Identify incorrect products which will be obtained on hydrogenation(consider hydrogenation is a syn
addition) of
D
D
Raney Ni / H 2
 
D

D D D D
D D D D

A) D B) D C) D D) D

11. Which of the following is/are possible products of given reaction?

14
Na
CH 2 = CH - C H 2 - Br 
Dryether
 Product(s)

14 14 14 14
i) CH 2 = CH - C H 2 - CH 2 - CH = C H 2 ii) CH 2 = CH - C H 2 - C H 2 - CH = C H 2

14 14 14 14
iii) C H 2 = CH - C H 2 - C H 2 - CH = C H 2 iv) C H 2 = CH - C H 2 - C H 2 - CH = C H 2

A) only i B) only ii C) ii & iii D) i, ii, iii & iv

12. Compound that on hydrogenation produces optically inactive compound is

H Br
A) B) C) D)
13. In which of the following reactions number of carbons changed in the product with respect to reactant?
 Zn-Hg /conc.HCl
R CH  Δ
 R C R NH 2 -NH2 +ethylene glycol,KOH
 Δ
A) O B) O

Zn; HCl NaOH, CaO/ Δ

C) R - X   D) RCOOH  

14. What is the sum of positions of methyl substituents and chlorine substituent in the IUPAC name of the
major product obtained on monochlorination of isopentane?
A) 2 B) 3 C) 4 D)5
15. How many different alkenes of molecular formula C6H12 will give 2-methylpetane on hydrogenation?
A) 3 B) 4 C) 5 D)6
16. How many carboxylic acids will give isopentane as product on sodalime decarboxylation?
A) 3 B) 4 C) 5 D) 6
17. One mole of 1,1-dibromopropane on heating with ‘x’ moles of NaNH2 followed by reaction with
ethyl bromide gives pent-2-yne . What is the value of ‘x’?
A) 2 B) 3 C) 4 D) 5
18. Acetone (CH3COCH3) is the major product in

H 3O H 2 SO4 ; HgSO4
i) CH 2  C  CH 2   ii) CH 3  C  CH  
( i ) BH 3 ;THF 
CH 3  C  CH 
( ii ) H O / OH 
 KMnO4 / H
CH 3  C  CH  
iii) 2 2 iv)
A) i & ii B) ii C) ii & iv D) i, ii & iv
19. The best yield of product ‘X’ can be obtained by using which of the following sequence of reagents and
reactants
X = CH 3  C  C  CH (OH )  CH (CH 3 )2
NaNH ( CH ) CHCHO H O
A) CH 3  C  CH 
2

3 2
 
3

NaNH CH I
B) (CH 3 )2 CH  CH (OH )  C  CH 
2

3

NaNH CH I
C) CH 3  CH 2CH (OH )  C  C  CH 3 
2

3

CH MgI CH I
D) (CH 3 )2 CH  CH (OH )  C  CH 
3
 
3

20. The end product of following reaction is

Ph D

H H

A) B) C) D) D Ph
21. Which of the following ketones cannot be prepared by hydration of an alkyne?
 O O

A) B) C) D)
22. Phenylacetylene on reaction with bromine (1 mole) in water forms mainly
A) C6H5COCH2Br B) C6H5CH2CHO C) C6H5CBrCHBr D) C6H5CBr2CH3
23. How many of the following reactions are correctly matched?

i) ii)

iii)
A) i &ii B) ii & iii C) i &iii D) i, ii &iii
24. Hydrocarbons that were used as starting materials for preparing the war gases lewisite and mustard gas
are respectively
A) Ethylene and acetylene B) acetylene and ethylene
C) Acetylene for both D) ethylenes for both
25. 2-pentyne and 1-pentyne can be distinguished by
A) Br2 water B) Amm.AgNO3 C) H2 / Ni D) NH4Cl
26. 1-pentyne when heated with alc.KOH gives the major product
A) 1,2-pentadiene B) 2-pentyne C) 1,3-pentadiene D) 2-pentanone
27. Nitration of alkane is governed by
A) electrophilic substitution B) nucleophilic substitution
C) free radical substitution D) electrophilic addition
28. The boiling point of isobutene is
A) lower than n-butane B) higher than n-butane
C) equal to n-butane D) there is no relation
29. Select the correct decreasing order of energy of activation in halogenation of alkanes
A) Fluorination > chlorination > bromination B) chlorination > bromination > fluorination
C) bromination > chlorination > fluorination D) bromination > fluorination > chlorination
30. Isopropyl bromide is treated with lithiumcuprate in dry ether. The alkane formed is
A)pentane B) hexane C) 2-methylbutane D) 2,3-dimethylbutane
KEY

1-10 A C C B B C B B A D

11-20 D B D D C D B D A B

21-30 D A D B C A C A C C
 SOLUTIONS

1.
2. At very high temperature it will go though the freeradical substitution reaction
3. Cl group is deactivating ortho, para directing group so Br required lewis acid to react with this
4. HgSO4/H2SO4 condition is for the addition of water to alkyne in markonikoff rule followed by
ketoenol tautomerism will give acetone. Acetone upon reduction with NaBH4 will give secondary
alcohol
5. Symmetrical alkanes can be prepared easily than unsymmetrical alkanes, in given option option B is
unsymmetrical alkene
6. Calculation of yield

7. out of all these two are chiral and from each one we can write
two enantiomers
8. diastreomeric pairs can be separated using fractional distillation
9. Conceptual
10. Hydrogenation is a syn addition so we can expect AB option C is another representation of B
11. Basic reaction is wurtz reaction, allylic radical undergo rearrangement
12. After hydrogenation in option B two groups are identical
13. decarboxylation of CO2 takes place in option D so loss of carbon atom takes place
14. 5

Sol: the relative amount of each product is determined by multiplying the number of
hydrogens that can be removed that will lead to the formation of that product by the
relative rate for formation of the radical. Thus, the major product is 2-chloro-3-
methylbutane.

15.

;
; ; ;

(trans) (cis)

16.
 COOH
COOH * ; * ;
;
COOH
COOH

17.

18. Conceptual
19. The Pka of the hydroxyl group is 16, whereas pka of NaNH2 is 35, so there is a chance of O-alkylation
Also Grignard reagent pKa 45 so that will also pick the –OH proton.
20. Final product should be meso.
21. In option D we cannot construct alkyne because both the sides isopropyl groups are there
22. Br2/H2O means HOBr addition followed by keto enol tautomerism
23. All three reactions are correctly matched it’s a trimerization and tetramerization reactions
24. Conceptual
25. Terminal alkynes will give white precipitate with Ammonical silver nitrate
26. Terminal alkynes can be isomerized in to internal alkyne using Alc.KOH
27. Alkanes generally inert so it can undergo only free radical substitution
28. more the surface area more the boiling point
29. Conceptual
30. from lithium diethyl cuprate ethyl group acts as a nucleophile and attack the isopropyl bromide