Cuoi Ky HK181-QT 8241

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8241

FINAL TEST
SUBJECT: GENERAL CHEMISTRY Test code: 8241
Date: Jan. 2019
Time: 70 min. No. of Questions: 40
This is a closed book examination
1. Phosphorous and chlorine gases combine to b. qrev/T
produce phosphorous trichloride: c. qrev
P2 (g)  3Cl2 (g)  2PCl3 (g) d. Tqrev
G at 298 K for this reaction is -642.9
kJ/mol. The value of G (kJ/mol) at 298 K 7. The normal boiling point of water is
for a reaction mixture that consists of 100.0 °C and its molar enthalpy of
vaporization is 40.67 kJ/mol. What is the
1.5 atm P2 1.6 atm Cl2 and change in entropy in the system in J/K
0.65 atm PCl3 is _____. Given R = 0.082 when 39.3 grams of steam at 1 atm
lit.atm/(molK) = 8.314 J/(molK) condenses to a liquid at the normal boiling
a. -44.2 point?
b. -649.5 a. +238
c. +649.5 b. 373
d. -708.4 c. -40.7
d. -238
2. In the Haber process, ammonia is 8. 2NO (g) = N2 (g) + O2 (g), H0298 = -180.8
synthesized from nitrogen and hydrogen: kJ. At standard condition at 25oC. Enthalpy
N2(g) + 3H2(g) ⇌ 2NH3(g) , G at 298 K of formation of NO (g) is :
for this reaction is -33.3 kJ/mol. Calculate a. + 90,4 kJ.
the value of G at 298 K for a reaction b. + 180,8 kJ.
mixture that consists of 1.9 atm N 2 , 1.6 c. -180,8 kJ.
d. -90,4 kJ.
atm H 2 , and 0.65 atm NH 3 .
9. Which one of the following will change the
a. -3.86 103 value of an equilibrium constant?
b. -7.25 103 a. adding other substances that do not
c. -104.5 react with any of the species involved
d. -40.5 in the equilibrium
b. varying the initial concentrations of
3. The thermodynamic quantity that expresses
products
the degree of disorder in a system is
c. changing the volume of the reaction
__________.
vessel
a. enthalpy
d. changing temperature
b. internal energy
c. bond energy
10. The equilibrium constant Keq for the gas
phase of the following reaction is 4.34×10-3
d. entropy
at 300oC. At equilibrium:
4. Which statement is correct at 25˚C and 1
N2 (g) + 3H2 (g) ⇌ 2NH3 (g)
atm?
a. Reactants predominate
a. ∆G˚f for Br2(g) = 0 kJ.mol–1
b. Products predominate.
b. ∆H˚f for I2(g) = 0 kJ.mol–1
c. Only product predominate
c. ∆G˚f for Cl2(g) = 0 kJ.mol–1
d. Roughly equal amount of product and
d. ∆H˚f for I2(l) = 0 kJ.mol–1
reactants are present.
5. In which of the following reactions, do you 11. For a reaction to be spontaneous under
expect to have an increasing in entropy? standard conditions at all temperatures, the
a. 2 IF(g) → I2(g) + F2(g) signs of H and S must be _______
b. Mn(s) + O2(g) → MnO2(s) and _______, respectively.
c. 2NH3(g) →N2(g) + 3H2(g) a. +, +
d. Hg(l) + S(s) → HgS (s) b. -, +
c. +, -
6. For an isothermal process, ΔS= _________. d. -, -
a. q

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12. The value of S for the formation of b. 3.65
phosphorous trichloride from its constituent c. -0.0376
elements, P2 (g)  3Cl2 (g)  2PCl3 (g) is d. 0.274
__________ J/K∙ mol. Given that: 18. For the endothermic reaction
CaCO3 (s) ⇌CaO (s) + CO2 (g)
Le Chätelier's principle predicts that
Subtance So, J/(mol.K)
__________ will result in an increase in the
P2 (g) 218.1
number of moles of CO2 .
Cl2 (g) 222.96
a. decreasing the temperature
PCl3 (g) 311.7
b. increasing the pressure
c. increasing the temperature
a. -129.4 d. removing some of the CaCO3 (s)
b. -263.6
c. +311.7
d. +129.4 19. Choose the CORRECT statement:
Reaction rate of the reaction:
13. Molality is defined as the __________. 2A + B  2C is v = k.CA2.CB, Thus:
a. moles solute/moles solvent . a. The overall reaction order is 3.
b. moles solute/liters solution. b. The reaction order is calculated
c. moles solute/kg solution. directly from the balance coefficients
d. moles solute/kg solvent of this reaction and equal 3
c. The above reaction is a complicated
14. Consider the reaction carried out at constant reaction
volume: 2SO2(g) + O2(g)  2SO3(g). d. (a) and (b) are CORRECT
For initial concentrations of SO2 and O2 of
2.0 M and 1.5 M, respectively. When 20. Choose the wrong statement:
equilibrium is established, the O2 a. Boiling point of a liquid is the
concentration is measured to be 0.80 M. temperature where its saturated vapor
What is the value of Kc for this reaction? pressure is equal to the surrounding
a. 2.9 pressure.
b. 0.34 b. Freezing point of a pure solvent is
c. 6.8 always lower than that of its solution.
d. 0.15 c. Boiling point of a solution contains
15. The Keq for the equilibrium below is 0.112 non-vapor solute is higher than that of
at 700oC. SO2(g) + ½O2(g) ⇌ SO3 (g). What pure solvent at the same pressure
is the value of K’eq for the following condition.
reaction at 700oC: d. Saturated vapor pressure of a solvent
2SO3(g) ⇌ 2SO2(g)+ O2(g). in solution is always lower than that of
a. 8.93 pure solvent at the same conditions.
b. 0.224 21. As the concentration of a solute in a
c. 79.74 solution increases, the boiling point of the
d. 0.112 solution __________ and the vapor
16. Given the following reaction at equilibrium, pressure of the solution __________.
a. increases, increases
if Kp =1.05 at 250.0 °C, K c = __________. b. decreases, increases
PCl5(g) ⇌ PCl3 (g) + Cl2 (g) c. increases, decreases
a. 3.9010-6 d. decreases, decreases
b. 2.4510-2 22. Choose the right statement:
c. 1.05 a. Dissolving A into liquid B, the
d. 42.9 saturated vapor pressure of solution
increases.
17. The Keq for the equilibrium below is b. Water is always boiled at 100oC
7.5210-2 at 480.0 °C. c. At boiling point of a liquid, saturated
2Cl2(g) + 2H2O(g) ⇌ 4HCl (g) + O2(g) vapor pressure of this liquid is equal to
What is the value of Keq at this temperature the environment pressure.
for the following reaction? d. Solution of salt in water is boiled at
2HCl(g) + 1/2O2(g) ⇌Cl2(g) + H2O (g) lower temperature than pure water.
23. Given Kb=0.52 0C/m and boiling point of
a. 13.3 solvent as 100oC. Solution of a non-
2
8241
ionizing solute boiled at 374.04K. The a. 23.13mmHg
molality of this solution is: b. 0.64mmHg
a. 0.01 c. 0.62mmHg
b. 2.0 d. 23.10mmHg
c. 10
d. 0.1
30. Nitrogen dioxide (NO2) decomposes to
nitric oxide (NO) and oxygen via the
reaction: 2NO2(g) 2NO (g)+ O2 (g)
24. The vapor pressure of pure water at 25 °C
In a particular experiment at 300 °C, [NO2]
is 23.8 torr. What is the lowering vapor
drops from 0.0100 to 0.00650 M in 100 s.
pressure (torr) of water above a solution
The rate of disappearance of NO2 for this
prepared by dissolving 18.0 g of glucose (a
period is __________ M/s.
nonelectrolyte, MW = 180.0 g/mol) in 95.0
a. 0.35
g of water?
b. 3.510-3
a. 24.3
b. 23.4 c. 3.510-5
c. 0.461 d. 710-3
d. 0.443 31. A particular first-order reaction has a rate
25. The vapor pressure of a liquid solution constant of 1.35102 s-1 at 25 oC. What is
__________. the magnitude of k at 95 oC if Ea=55.5
a. decreases with increasing temperature kJ/mol? R=8.314J/(mol×K)
b. increase with increasing concentration a. 9.56103
of solute b. 2.85104
c. increase with decreasing concentration c. 1.36102
of solvent d. 576
d. increases nonlinearly with increasing
temperature 32. Of the following, all are valid units for a
26. Boiling point of solution containing water reaction rate except __________.
and non-electrolyte solute is 100.26oC. The a. M/s
molality of this solution is: (Kb = 0.52, b. mol/hr
boiling point of water is 100oC) c. mol/L
a. 0.75 d. g/s
b. 1 33. The rate law of a reaction is rate = k[A][B].
c. 0.50 The units of the rate constant are
d. 0.52 __________.
a. mol× l-1×s-1.
27. A reaction was found to be zero order in A. b. s-1
Increasing the concentration of A by a c. mol× l-1
factor of 3 will cause the reaction rate to d. l×mol-1× s-1
__________. 34. The magnitudes of Kf and of Kb depend on
a. remain constant the identity of the __________.
b. increase by a factor of 27 a. solute
c. increase by a factor of 9 b. solvent
d. triple c. solution
d. solvent and on temperature
28. The half-life of a first-order reaction is 13 35. The decomposition of N2O5 in solution in
min. If the initial concentration of reactant carbon tetrachloride proceeds via the
is 0.085M it takes __________ min for it reaction: 2N2O5 → 4NO2 + O2
to decrease to 0.055 M. The reaction is first order and has a rate
a. 11 constant of 4.82 × 10-3 s-1 at 64°C. The rate
b. 8.2 law for the reaction is rate = __________.
c. 3.6
d. 0.048 a. k[N2O5]2
b. k[N2O5]
29. At 25oC, the vapor pressure of pure water is [𝑁𝑂2 ]4 [𝑂2 ]
23.76mHg. When 2.7 mol of glycerine is c. 𝑘 [𝑁2 𝑂5 ]2
dissolved into 100 mol of H2O at the same
temperature, the vapor pressure of the d. 2k[N2O5]2
solution is:

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36. A solution is prepared by adding 1.43 mol b. gases
of KCl to 889 g of water. Calculate the c. liquids
concentration of KCl in molality. d. gases and liquids
a. 622 39. Choose the correct answer. A solution with
b. 0.622 a concentration higher than the solubility is
c. 1.27× 103 __________.
d. 1.61 a. unsaturated
b. supercritical
37. Calculate the freezing point of a 0.055 m c. saturated
aqueous solution of glucose. The molal d. supersaturated
freezing-point-depression constant Kf of
water is 1.86 °C/m. Assume that the 40. The phrase "like dissolves like" refers to the
freezing point of water is 0 oC. fact that __________.
a. 0.0286 a. gases can only dissolve other gases
b. -0.1023 b. solvents can only dissolve solutes of
c. 0.1023 similar molar mass
d. -0.0562 c. polar solvents dissolve polar solutes
and nonpolar solvents dissolve
38. Pressure has an appreciable effect on the nonpolar solutes
solubility of __________ in liquids. d. condensed phases can only dissolve
a. solids other condensed phases
GOOD LUCK!

Head of Inorganic Chemical Engineering Division Examiner


Minh-Vien Le, Ph.D Minh-Vien Le, Ph.D

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