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Solution to Advanced Level Problem Solving-2207

JEE 2022 | Chemistry
Electrochemistry, Chemical Kinetics, Surface Chemistry, Coordination
Compounds, Metallurgy, Stereochemistry, d-Block Elements,
Aromatic Compounds, Environmental Chemistry & Chemistry in Everyday Life

1.(B) Let the formula of mercury ion is Hg nn  then the formula of mercury nitrate would be Hg n  NO3 n . The
reactions occurring at two electrodes are

Cathode: Hgnn  
C
 ne 
 Hg

A Anode : nHg     ne
 Hg nn 
A


Net reaction:  Hgnn   

  Hgnn  
C A

Thus, the given cell is electrolyte concentration cell.

0.0591  1   1 
Ecell  log   /    n2
n  2   20 
It means mercury ion exists as Hg 22 . So the formula of mercury nitrate will be Hg 2  NO3 2

2.(C) Let the radius of sphere that fits the void at centre of edge of BCC lattice be r ' then
a  2r  2r '
3 a  4r

3a
a  2r '
2
3a
2r '  a   0.134a
2

3.(A) Sodium aluminium silicate (zeolite) acts as an ion exchange medium. Calcium and magnesium cations
in hard water are exchanged for the sodium ions of the zeolite.

4.(B) K[Co(CH3 NH 2 ) 2 Cl4 ]

Potassium tetrachloridodi(methylamine)cobalatate (III)
5.(D) 6.(A) 7.(BD) 8.(A)

9.(C) Fe2 FeO2  2H 

 2Fe3  H2O; E10  0.616V ....….(i)
Fe3  Ag  H2O 
 FeO2  2H  Ag(s);E02  0.439V ....….(ii)
On adding these equations,

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Fe2 Ag 
 Fe3 Ag; E30 ....….(iii)
nFE30  nFE10  nFE02

1 F  E   1 F  0.616  1 F  0.439

0
3

E30  1.055V
E30  E0  E0Ag |Ag
Fe2 |Fe3

 1.055  E0  0.799
Fe2 |Fe3

E0  0.256V
Fe2 |Fe3

E0  0.256V
Fe3 |Fe2

Tf 1.86
10.(B) for urea solution Tf  mk f  k f    1.86 for acetic acid solution
m 1
Tf  imk f
Tf 0.02046
i   1.1
m.k f 1.86  0.01

CH3COOH CH3COO   H 
1  

 
i  1        1.1    0.1  H   C.  0.01 0.1  103

pH  3

11.(B) Silver sol is an example of lyophobic colloid.

12.(D) 100 mL of a 10 M solution of AgNO3  1 mole AgNO3

[Co(NH3 )6 ]Cl3   OnemoleAgCl
1mole
AgNO 3

[CoCl(NH3 )5 ]Cl2   OnemoleAgCl

1mole
AgNO3

[CoCl2 (NH3 )5 ]Cl2   OnemoleAgCl

1mole
AgNO 3

(Above reaction AgNO3 is a limiting reagents)

13.(B) 14.(A) 15.(ABCD)

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16.(A) Magnetic moment is 5.9 BM. It indicates presence of 5 unpaired electrons.

 MnX24 is sp3 hybridized

17.(B) 18.(C)

19.(A) (Where K W is the ionic product of water)

H2O H  OH  ; G10  RT ln K W
1
H e  H2 ; G 02  nFE0 
2 H |H2
1
H2O  e  H 2  OH  ; G30  nFE0
2 H2O|H2 ,OH

Since, E 0   0, so G 02  0
H |H 2

Thus, G10  G30

RT ln K w  nFE 0
H 2O|H 2 ,OH 

RT
 E0  ln K w  since, n  1
H2O|H2 ,OH F

20.(A) i  1   n  1 a  1  4  0.5  3
  3 0.1 0.0821 300  7.38

21.(C) 22.(ABD) 23.(B)

24.(A) When Freshly precipitated Fe(OH)3 is shaken with little amount of dilute solution of FeCl3 electrolyte,
peptization process takes place by converting the Fe(OH)3 precipitate into positively charged colloidal
solution of Fe(OH)3 .

25.(B) Complex No. of unpaired electrons

Ni(CO) 4 0
[Mn(CN)6 ]4 1
[Cr(NH3 )6 ]3 3
[CoF6 ]3 4
Magnetic moment I < II < III < IV
26.(B) 27.(C)

28.(D) The reactions involves are

At node:  H 2S2 O8  2H   2e 
2H 2SO4 

 4H  O 2  4e 
2H 2 O 

At cathode: 2H 2 O  2e  
 2OH   H 2
 Equivalents of H2S2O8  Equivalent of O 2 = Equivalents of H 2
2  5.6
Equivalents of H 2   0.5 equivalent ( 22.4 litre = 1 mole = 2 equivalents of H 2 )
22.4
1.4  4
Equivalents of O2   0.25 equivalents ( 22.4 litre = 1 mole = 4 equivalents of O 2 )
22.4

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Equivalents of H2S2O8  0.5  0.25  0.25 equivalents

m 0.25 194
WH2S2O8  0.25    24.25g
n 2

29.(C) A  0.25 B  0.75

PA0 7 3
  PB0  PA0
PB0 3 7
3 1 9 
PT  0.25  PA0  0.75  PA0     PA0
7  4 28 
X0.25  1/ 4 
    7
y A PT  PA0 X A  y A       7  9   & y B 
1 9 9
 4 28   28  16 16
 
 
7 9 3 7 27 
PT1   PA0   PA0  PA0   
16 16 7  16 16  7 
7
16 7 16  7 49
y1A PT1  PA0 X1A  y1A   
 49  27  16  49  27  76
 
 16  7 
49 0 27 3 0  49  7  81 
PT11   PA   PA  PA0  
76 76 7  7  76 
PA0  49 / 76 49  7  76
A PT  PA A  y A 
y11 
11 0 11 11
 49  7  81  76  49  7  81
PA0  
 7  76 

A  0.8089  0.8
y11
There will be 3 repeated distillation to get XA  0.8

30.(A)

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31.(D)

32.(C) 33.(C)

34.(B) At anode:  Ni 2   2e 
Ni 
At cathode: Cu 2  2e 
 Cu
Net reaction Ni  Cu 2 Ni2  Cu

0.05
0.05  x x x
E 0.337   0.250  0.587 V
0

nFE 0cell  RT ln K c

2  96500  0.587
 log K c   19.8
2.303  8.314  298
 K c  7.16 1019

Since, the value of equilibrium constant is very high, this means that almost entire Cu 2  will go in the
form of Cu 2  left will be very small.
Let it be x ' M
 Ni 2 
 K c  7.16 10 19
    0.05  x '  6.828  10 22 M
Cu 2  x'
 

35.(C) Boiling point of solution = boiling point Tb  100  Tb

Freezing point of solution = freezing point Tf  0  Tf
Difference in temperature (given)  100  Tb   Tf 
103.57  100  Tb  Tf  100  molality  K b  molality  Kf
103.57  100 3.57 moles 1000 moles 1000
Molality    1.5m and molality  ;1.5 
2.38 2.38 Wgm(solvent) 500

1.5  500
Moles of solute   0.75 moles
1000

36.(D) 37.(CD) 38.(B)

39.(C) Rubber plating and chrome tanning are based on electrophoresis.

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40.(A) [Co(H 2 O)3 (NH3 ) 2 (NO3 )]Br2  Cannot show linkage isomerism as it does not have ambidentate
ligand.

41.(C) 42.(B)

0.059 PH2
43.(C) 2H   2e  H 2  RP  0.0  log 2
2 H 
 

44.(A) Higher freezing point  lesser Tf

 lesser molality
 lesser number of particles

45.(C)

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46.(C) Given complexes are Cis-trans isomers.

47.(B) 48.(C)

49.(C) w  Zit
197 i  20  60
2 
3 9650
i  2.448amp.
[V.f for Au = 3]

x 1000 0.2
50.(B)  molality i   ….(i)
100 Kf
x 1000 0.25
 molality f   .…(ii)
w Kf
(i)/(ii)
0.2 w
So,   So, w  80gm
0.25 100
Hence ice separated = 20 gm

51.(D) 52.(BD) 53.(A)

1
54.(A) Gold number 
protective power

55.(A) Only I and III are optically active due to absence of plane of symmetry.

56.(ABCD) 57.(D)

58.(C) G 0f  5x1F ; G 20  2x 2 F

G 30  G10  G 20 ; G 30  2x 2 F  5x1F  3xF

5x1  2x 2
 x
3

59.(C) Pressure of air  750  100  mmof Hg

On compressing Pf  650  3mmof Hg
 1950mmof Hg
So, PT  1950  100  2050mmof Hg

60.(B)

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61.(A) Cis [PtCl2 (NH 3 ) 2 ] is used in cancer Chemotherapy. It is also known as Cis-platin.

62.(B) 63.(B)

0  0  0
CO  NH3 4 Cl2  ClO4  COO  NH3 4 Cl2    ClO4   50  70  120
64.(B) 
   
1000K
CO  NH3 4 Cl2  ClO4 
 
M
1
KG    0.20
33.5
1000  0.20
CO  NH3 4 Cl2  ClO4  120  33.5  M
 

1000  0.20
M  49.75 m mol / L
33.5  120

65.(A) Let volumes taken to be ‘x’ & ‘y’ litres,

0.1x  0.4y
So  0.34 ….(i)
xy
So, y  4x so for maximum volume
1
y  2L & x  L
2

66.(C) 67.(BCD) 68.(D)

69.(C) Both absorption and viscosity are bulk phenomenon.

70.(B) (I) Mond’s process for purification of Ni  [Ni(CO) 4 ]

(II) Removal of unreacted AgBr from photographic plate- [Ag(S2O3 )2 ]3
(III) Removal of lead poisoning from body [Pb(EDTA)]2

71.(B) 72.(C)

73.(A) Ksp  AgBr    Ag    Br 


12  1014  S  107 S 
S  3  10 7

K
106

0  M   0  M   0  M 
1000 Ag Ag Br Br NO3 NO3 
K
106
1000

4 103  4 107  6 103  3 107  5 103 107 
K  39 1013 106  39 107 sm1

74.(B) As m  0, NaHSO4 will generate three particles while NaCl will generate only two particles.

75.(A)

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76.(D) Due to absence of vacant atomic orbital as well as  * molecular orbital, O22 does not as  acid ligand.

77.(D) 78.(A)
m
79.(D)   0.043  and  m  0.00033  50  103  33  50  102


33  50 102
So    383.72  384
0.043
80.(A) 3S S3
1 0

 2
1   i  1
3 3
2 
Now 0.11    0.08    0.3 Hence 30% trimerization
 3 

81.(D) 82.(ABC) 83.(B)

84.(D) Colloidal particle range  1nm to 1000nm.

85.(A) In metal carbonyls :

Higher the negative oxidation state of central metal, more will be the synergic bonding.
As extent of synergic bonding increases, bond order of CO decreases and bond length of CO increases.

86.(C) 87.(C)

88.(B) Anode : Ag  s   Ag  aq   1e

Cathode : Ag  aq   1e  Ag

1e
Net : AgAgBr  
 AgAg
2CO3 

 
 KSP AgBr 
  Br   
  
log 
0.059 KSP AgBr KSP Ag 2 CO3
0  0  
1 KSP Ag 2 CO3 
 Br  CO32 
   
CO32 
 
 Br    Br  
4 1013    
    2 107
12 CO32  CO32 
8 10
   

 0.849 
 
89.(A) 1.24  34.3  M   M  469.68 90.(D)
 0.050 
 

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