SS1 Chemistry 2nd Term Lesson Note PDF
SS1 Chemistry 2nd Term Lesson Note PDF
SCHEME OF WORK
WEEK TOPIC
2. Gaseous state and gas laws: State of matter, kinetic theory of gases,
applications of kinetic theory of gases, and phenomena to illustrate
kinetic theory of matter
3. Gaseous state and gas laws: Boyle’s laws, Charles’ law, general gas
law and ideal gas law
4. Gaseous state and gas laws: Gay- Lussac’s Law and Avogadro’s
Law, Graham’s law of diffusion, Molar volume of gases- Avogadro
number and the mole, concept, Dalton’s law of partial pressure
9. Revision
10. Examination
REFERENCE TEXTS:
1
2. New School Chemistry for Senior Secondary Schools by Osei Yaw Ababio
3. Chemistry for Senior Secondary Schools 1 by Magbagbeola O, et al; Melrose Books and
Publishers
WEEK 1
1. Revision of last terms work
WEEK 2
CONTENTS:
1. State of matter,
Matter is made up of very tiny particles such as atoms, molecules and ions.
Matter exists in three physical states namely; solid, liquid and gas. Matter has
mass and occupies space.
2
(i) Solid: The tiny particles in solid are packed very closely together hence they
cannot move about. The presence of forces of attraction among the tiny
particles of solid made them to be very closely packed together and allowing
only vibration among them instead of moving about. This is what makes the
solid to have a fixed shape and volume with high density. However, at high
temperature, the molecules gain more energy and break the forces of attraction
among the particles thereby causing the particles to move faster. As the
temperature increases more and more, the solid melts and turns to liquid.
Therefore, solid have fixed shape and volume, incompressible and very dense
with the least kinetic energy when compared with those of liquid and gasses.
(ii) Liquid: The particles in the liquid are slightly further a [art than those in a
solid and there exist among them weaker forces of attraction (weaker force of
cohesion); thus allowing them to vibrate rotate and move about. Liquid have
fixed volume and a fixed shape but takes the shape of its container. When the
liquid is heated, its temperature increases, the forces of cohesion / attraction
becomes progressively weaker. Eventually, a stage is reached when the
molecules acquire enough energy to escape as a gas. The temperature at which
this occurs is called the boiling point of the liquid. Therefore, the liquid have
fixed volume, no fixed shape, less dense and incompressible with kinetic energy
relatively higher than those of solid state.
(iii) Gas: The particles in the gaseous state are very freely with large distances
between them. The particles of gases have no fixed volume and shape,
compressible and least dense with the highest kinetic energy when compared
with particles of other states of matter.
EVLUATION
3
PERIOD 2: KINETIC THOERY OF GASES
The kinetic theory of matter postulates that the tiny Particles of matter are
continually moving and so possess kinetic energy. An increase in temperature
causes an increase in the average kinetic energy of the particle.
EVALUATION
The kinetic theory is useful in several respects and such aspects includes;
4
EVALUATION
1. Dispersion
2. Evaporation
3. Diffusion:
4. Brownian motion
5. Osmosis
6. Tyndall effect
7. Effusion
GENERAL EVALUATION
OBJECTIVE TEST:
ESSAY QUESTION:
5
5. Give assumptions of kinetic theory of matter.
WEEKEND ASSIGNMENT:
Read New School Chemistry for Senior Secondary Schools, by Osei Yaw Ababio
pages 584-594
WEEKEND ACTIVITY
Explain with at least three points what you understand by chemical industry
and also mention specifically five types of chemical industry.
REFERENCE TEXT:
1. New School Chemistry for senior Secondary Schools by Osei Yaw Ababio
6th edition
2. Comprehensive certificate chemistry by G.N.C Ohia, G.I, Amasiatiu, J.O
Ajagbe =, G.O. Ojokuku and U Mohammed. 2nd Edition
WEEK 3
CONTENTS:
I. Boyle’s law
2. Charles’ law
The relationship between volume and pressure of a gas was first started by
Robert Boyle in 1662.
Boyle’s law states that the volume of a given mass of gas is inversely
proportional to its pressure, provided that the temperature remains constant.
6
According to Boyle’s law, volume of a gas increases as the pressure decreases
and vice versa.
𝑘
∴ V=
𝑝
Or PV =k
K = a mathematical constant
For a given mass of a gas, the product of its pressure and its volume is always
a constant. If the pressure of a given mass of gas increases, its volume will
decrease by a similar proportion and vice versa, as long as the temperature
remain constant. This relationship can also be expressed mathematically as:
P1V1 = P2 V2
Boyle’s law can still be re-stated as: ‘The pressure of a given mass of gas is
inversely proportional to its volume, provided the temperature remains
constant. Boyle’s law can further be illustrated with the diagram below,
showing that when P is increasing, V is decreasing and when P is decreasing, V
is increasing.
P3
V3
P2
V2
P1
V1
P1 = Initial pressure
V1=Initial volume
7
Graphical representation of Boyle’s law
Worked examples
1. 375cm3 of a gas has a pressure of 770mmHg. Find its volume if the pressure
e is reduced to 750mmHg.
8
EVALUATION:
2. A given mass of gas at 550C has a pressure of 3.6 x 104Nm-2 and occupies a
volume of 1.8dm3. What volume will it occupy if its pressure is increased to 4.8
x 104Nm-2 if the temperature is kept constant?
The volume of the gas decreases as the temperature decreases, and increases
as the temperature increases.
V∝ T
∴ V = kT
𝑉
Or =k
𝑇
Where v= volume
T= Kelvin Temperature
K= mathematical constant
V1 V2 V3 V4
T1 T2 T3 T4
9
For a direct relationship, when the temperature increases, the volume will also
increase at the same rate and vice versa, at constant pressure .The diagram
above shows that when V is decreasing, T is also decreasing and when V is
increasing, T is also increasing thus, making the quotient constant.
ABSOLUTE ZERO
TEMPERATURE CONVERSION
10
1. To convert from Celsius scale to Kelvin scale, add 273 i.e. T= 0C + 273. This
is because O0C=273K.
Examples:
Solution
Recall: T= 0C + 273
Solution
0k = (0 – 273)0C = - 2730C
V1=20.0dm3
11
T1 = 273k
T2= 746
V2= ?
𝑉1 =𝑉2 𝑉1 𝑇2 20 ×746 =
Recall Charles’s law = V2= V2 = 40.0dm3
𝑇1 𝑇2 𝑇1 273
EVALUATION:
From the gas laws, we know that the volume of a gas depends on both its
temperature and pressure. The relationship between the three variable; i.e.
volume,, temperature and pressure can be summarized up as follows:
1
If V ∝ 𝑃 (Boyle’s law at constant temperature) and V ∝ T (Charle’s law at
constant pressure)
1 𝑃𝑉
V ∝ 𝑃 × T (both temperature and pressure may vary) or 𝑇 = K (a mathematical
constant for a fixed mass of gas)
𝑃𝑉
=k is often known as the general gas equation.
𝑇
General gas equation states that for fixed mass of a gas under any set of
𝑃𝑉
conditions of V, P and T, the value of must remain constant. If for a fixed mass
𝑇
of gas V1 is the volume at pressure
The general gas equation can be used to find the volume of a gas when both its
pressure and temperature change. Thus;
12
𝑃1 𝑉1 𝑇2
V2 = 𝑃2 𝑉2
The value of gases are sometimes given in standard temperature and pressure
(S. T. P). These values are standard temperature= 273k and standard pressure
= 760mmHg. The S.I unit of standard pressure when used is 1.01 × 103Nm-2
Examples
P2 = 726mmHg
T2 = New Temperature
𝑃2 𝑉2 T1
∴T2 =
𝑃1 𝑉1
13
𝑃1 𝑉1 𝑇2 0.92 ×850 ×273
∴V2 = = = 660.5𝑐𝑚3
𝑃2 𝑇1 1.01 ×103 ×320
EVALUATION
1. Explain the general gas equation.
The ideal gas: This is a gas sample whose properties correspond, within
experimental error, to the relationship PV =RT. An ideal gas must obey all the
rules guiding Boyle’s and Charles’s laws. Ideal gas conforms to the kinetic
theory of gases. Four quantities’ are important in all experimental work,
measurements or calculations involving gases. They are: (i) volume (ii) pressure
(iii) temperature and (iv) numbers of moles
The value of R for one mole of a gas at 273K, 1atm and volume 22.4dm3 is
0.0821atmdm3K-1mol-1 or 8.314JK-1mol-1
Examples:
Solution:
= 12.8dm3
Ideal gases only exist at experimental conditions of high pressure and low
temperature. Basically all gases are real
14
1. The forces of attraction in real gases are not negligible.
2. The volume of real gases are not negligible. Hence, real gases have their own
volume called excluded volume.
EVALUATION:
GENERAL EVALUATION
OBJECTIVE TEST
1. A gas occupies 30.0𝑑𝑚3 at S.T.P. What volume will occupy at 910C and
52662.5𝑁𝑚−2 . (a) 20.0𝑑𝑚3 (b) 40.0𝑑𝑚3 (c) 60.0𝑑𝑚3 (d) 76.96𝑑𝑚3
2. Gases can be easily compressed because. (a) the molecule are relatively far
apart (b) the molecule are quite close together (c) the molecule are very soft (d)
the molecules are in constant, rapid motion
3. A give mass of gas occupies 𝑋1 𝑐𝑚3 at Y1K. When the temperature is changed
to Y2K, the volume becomes X2𝑐𝑚3 , the pressure remaining constant. Which of
the following equations correctly express the relationship between
𝑋1 𝑋2
𝑋1 X2Y1andY2? (a) 𝑋1 Y1 = X2Y2 (b) = (c) 𝑋1 X2 =𝑋1 Y2 (d) 𝑋1 = X2Y1Y2
𝑌1 𝑌2
4. Kelvin temperature can be converted into Celsius temperature by. (a) oC= K –
0𝐶+273 𝑘+273
273 (b) k + 273 (c) (d)
𝑘 0𝐶
5. What will be the new volume (v) if the new pressure is halved and the initial
𝑃1 𝑉1 𝑃2 𝑉2
pressure remain the same. (a) 2𝑝1 𝑉1 = 𝑝2 𝑉2 (b) 𝑝1 𝑉1 =2𝑝2 𝑉2 (c) = (d)
2 2
𝑃2 𝑉2
𝑝1 𝑉1 = 2
ESSAY QUESTIONS
15
2. Draw the graphical representation of both Boyle’s and Charles’ law
respectively.
4. The volume of gas at 250C (298k) is 100𝑐𝑚3 . What will be the volume at (a.)
750C (348k) (b). 500C (223)k, pressure remaining constant?
WEEKEND ASSIGNMENT:
Read about Graham’s law, Avogadro’s number and the mole concept.
WEEK 4
CONTENTS:
Gay- Lussac’s law describes the combining volumes of gases that react
together. In his experiment, all temperatures and pressures were kept
constant:
A. STEAM: Gay- Lussac’s observed that two volumes of hydrogen reacted with
one volume of oxygen to yield two volumes of steam
16
Gay- Lussac’s noticed that the combining volumes as well as the volumes of
the products, if gaseous, were related by simple ratios of whole numbers. He
proposed the law of combining volume or gaseous volumes.
Hence; Gay- Lussac’s law combining volumes states that when gases react,
they do so in volumes which are in simple ratios to one another and to the
volumes of the products, if gaseous provide that the temperature and the
pressure remain constant.
EXAMPLES
2. 20𝑐𝑚3 of carbon(I) oxide are sparked with 20𝑐𝑚3 of oxygen. If all the volumes
of gases are measured at a S.T.P, calculate the volume of the residual gases
after sparking?
17
Equation of reaction 2𝐶𝑂𝑔 + 𝑂2𝑔 2𝐶𝑜2𝑔
Combining volume 2 : 1 : 2
Volumes before sparking 20𝑐𝑚 10𝑐𝑚 ,
3 3
20𝑐𝑚3
Volumes after sparking −10 20
Residual gases = un-reacted oxygen + carbon (IV) oxide formed
AVOGADRO’S LAW
Avogadro’s Law states that equal volumes of all gases at the same
temperature and pressure contain the same number of molecules.
This law means that for all of gases e.g. oxygen, hydrogen, Chlorine etc if
their volumes are the same, they will have the same number of molecules.
Volume: 2 1 2
Gay –Lussac’s: 2 : 1 : 2
Avogadro’s Law: 2 : 1 : 2
Example:
Solution
2H2 + O2 2H2O
18
From the equation, 2 molecules of hydrogen react with 1 molecule of oxygen
to produce 2 molecules of steam.
2𝐻2 + O2 2H2O
From the above information, when 2𝑐𝑚3 (2 vol) of 𝐻2 react, 1𝑐𝑚3 (1 vol) of
O2will react i.e. half of 𝐻2 vol, to give 2𝑐𝑚3 (2 vol) of H2O.
Thus, 10𝑐𝑚3 of 𝐻2 will react with 5 𝑐𝑚3 of O2 to produce 10𝑐𝑚3 of H2O and
so on.
From the question, we have 60𝑐𝑚3 of 𝐻2 and 20𝑐𝑚3 of O2, thus, when all the
20𝑐𝑚3 of O2react, only 40𝑐𝑚3 of𝐻2 will react to give 40𝑐𝑚3 of H2O,because
the volume of H2 is the same as that of H2O i.e.
2𝐻2 + O2 2H2O
2. What volume of propane is left unreacted when 80𝑐𝑚3 of oxygen and 20𝑐𝑚3
of propane react according to the equation below?
Solution
1vols 5vols
1𝑐𝑚3 5𝑐𝑚3
19
4𝑐𝑚3 20𝑐𝑚3
EVALUATION
Calculate: (a) volume of oxygen used (b) Volume of carbon(Iv) oxide produced
WEEKEND ACTIVITY:
(a) Define Graham’s law of diffusion.(b) What is mole and mole concept?
This law states that, at constant temperature and pressure, the rate of
diffusion of a gas is inversely proportional to the square root of its relative
molecular mass or square root of its vapour density.
Mathematically, Graham’s law of diffusion can be represented as:
20
𝑅1 𝑝2
∝ √𝑝1 Where R1 and R2 are the rates of diffusion and P1 and P2, the
𝑅2
EXAMPLES
Solution
𝑅 𝑀𝑥
O2 =
𝑅𝑥 𝑀𝑂2
𝑅 𝑡𝑥 𝑀𝑥
O2 = = =√
𝑅𝑥 𝑡𝑂2 𝑀𝑂2
𝑡𝑥 𝑀𝑥
( )=
𝑡𝑂2 𝑀𝑂2
𝑡𝑥 2 120 2
Mx= MO2 ×( ) = 32 ×( ) = 32 × 22
𝑡𝑂2 60
Mx = 32 × 4 = 128g
Solution
21
300𝑐𝑚3
× 4020
200𝑐𝑚3
(3 × 20) = 60seconds
𝑡1 𝑀1
=√
𝑡2 𝑀2
𝑀1 71
T2 = t1√ = 60√ = 60 √35.5 = 60 × 5.96
𝑀2 2
= 357.5sec
3. How many times the rate of diffusion of hydrogen is faster than that of
oxygen and what law do you use to get the answer? [ vapour density] of [H=1,
O=16]
Solution
𝐷𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑂2
√
𝐷𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝐻2
𝑅1 16 𝑅1 4
=√ = =
𝑅2 1 𝑅2 1
22
∴Hydrogen diffuses four times faster. The law used is Graham’s law of
diffusion.
The vapour density of a gas or vapour is the number of times a given volume
of gas (or vapour) is heavier than the same volume of hydrogen measured
and weighed under the same temperature and pressure
Example
Calculate the vapour densities of the following gases from the given data.
Solution
560𝑐𝑚3
∴ 560𝑐𝑚3 of hydrogen at 100𝑐𝑚3× 0.09
= 0.05g
23
𝑚𝑎𝑠𝑠𝑜𝑓𝑎𝑔𝑖𝑣𝑒𝑛𝑣𝑜𝑙𝑢𝑚𝑒𝑜𝑓𝑔𝑎𝑠
V.D=
𝑚𝑎𝑠𝑠𝑜𝑓𝑒𝑒𝑞𝑢𝑎𝑙𝑣𝑜𝑙𝑢𝑚𝑒𝑜𝑓ℎ𝑦𝑑𝑟𝑜𝑔𝑒𝑛
𝑚𝑎𝑠𝑠𝑜𝑓𝑎𝑔𝑖𝑣𝑒𝑛𝑣𝑜𝑙𝑢𝑚𝑒𝑜𝑓𝑔𝑎𝑠
Vapour density=
𝑚𝑎𝑠𝑠𝑜𝑓𝑒𝑒𝑞𝑢𝑎𝑙𝑣𝑜𝑙𝑢𝑚𝑒𝑜𝑓ℎ𝑦𝑑𝑟𝑜𝑔𝑒𝑛
4𝑔
= = 31.74= 32
0.126
EVALUATION
The molar volume of any gas is the volume occupied by one mole of that gas at
s.t.p. and is numerically equally to 22.4𝑑𝑚3 i.e. one mole of any gas at s.t.p.
occupies the same volume the value of which is 22.4𝑑𝑚3 . This value is called
molecular mass or molar mass.
24
From the Avogadro’s law, the molar volume for all gases contains the same
number of molecules. This number is called the Avogadro’s number or constant
and the value is 6.02 × 1023 at s.t.p
MOLE: The mole can be defined as the amount of substance which contain
as many elementary particles or entities e.g. ions, molecules, atoms,
electrons as the number of atoms in exactly 12 grams of carbon -12.
The mole of any substance represents 6.02 × 1023 particles of any substance.
Therefore, a mole refers to Avogadro’s number of particles of any substance.
The atomic mass of every element also contains Avogadro’s number of atoms.
The mole concept- This says that one mole of any substance contains the
same number of particles; which can be atoms, molecules or ions. This number
is 6.023 × 1023 𝑑𝑚3 (the Avogadro’s number)
Examples
Solution
N= amount in moles
𝑉
=𝑉
50
N= = 2.23mol
22.4𝑑𝑚 3mol−1
25
𝑀 158𝑔
Molar mass M of the gas = = = 70.8
𝑛 22.4𝑑𝑚 3 mol−1
20
20g of CaCO3 =100 ×1mole = 0.2moles
EVALUATION
1. Using the relationship between mole and Avogadro’s number. Define mole in
six ways.
Dalton’s law of partial pressure states that for a mixture of gases that do not
react chemically, the total pressure exerted by the mixture of gases is equal to
the sum of the partial pressures of the individual gases.
Ptotal = P1 +P2+P3 +………..+ Pn where Ptotal is the total pressure exerted by the
mixture of gases that dot not react, P1, P2, P3……Pn are partial pressure of the
individual gases.
Example:
26
If 20.0dm3 of hydrogen were collected over water at 17oC and 79.7kNm-2
pressure; Calculate the
Solution:
= 79.7 – 1.90
= 77.8 kNm-2
𝑃1 𝑉1 𝑃2 𝑉2
(b) =
𝑇1 𝑇2
77.9𝑋20 101.3𝑉2
=
290 273
𝑉2 = 14.5dm3
GENERAL EVALUATION
OBJECTIVE TEST
1. A liquid begins to boil when (a) Its vapour pressure is equal to the vapour
pressure of its solid at the given temperature (b) Molecules start escaping from
its surface (c) Its vapour pressure equals the atmosphere pressure (d) Its
volume is slightly increased.
27
2. Hydrogen diffuses through a porous plug (a) At the same rate as oxygen (b)
Twice as fast as oxygen (c) Three times as fast as oxygen. (d) Four times as fast
as oxygen
5. 200𝑐𝑚3 of oxygen diffused through a porous plug in 50secs. How long will
80𝑐𝑚3 of methane (CH4) take to diffuse through the same porous plug under
the same conditions (C= 12, O= 16, H=1) (a) 40sec (b) 20sec (c) 14sec (d) 7sec
ESSAY QUESTIONS
(a) Arrange the following gases in decreasing order of diffusion rate: Chlorine,
hydrogen chloride, hydrogen sulphide and Carbon(IV) oxide
[ H=1, C= 12, O=16, S= 32, Cl=35.5]
(b) If the volume of a given mass of gas at 298k and pressure of 205.2 ×
103 𝑁𝑚−2 is 2.12𝑑𝑚3 , what is the volume at S.T.P? Standard pressure= 101.3 ×
103 𝑁𝑚. Standard temperature= 273k
i. 16g of oxygen
28
ii. 67.2𝑑𝑚3 of nitrogen gas, and
WEEKEND ACTIVITY:
WEEK 5
CONTENTS:
COMPOUND
29
substance with entirely different properties from those of substances from which it is
formed. For example water is a compound of hydrogen and oxygen chemically
combined in the ratio 2:1 by mass respectively. Other example of mass are sound,
limestone, common salt, petrol, kerosene etc.
MIXTURE:
COMPOUNDS MIXTURES
4.The properties differ entirely from those The properties are the sum of those of its
of its components elements individual constituents
EVALUATION:
1. Define and give one example of (a) homogeneous mixture (b) heterogeneous mixture
30
PERIOD 2: SEPARATING A MIXTURE OF TWO SOLIDS
They following methods are employed in the separation of a mixture of two solids:
1. Sieving
2. Magnetic separation
3. Sublimation
3. Sublimation: Solids which sublime are separated from other solids that
sublime (i.e. they turn directly from solid to gas and ffrom gas to solid without
turning to liquid) are
Ammonium chloride
Aluminum chloride
Camphor
Iodine crystals
Solid CO2 (dry ice)
Purification by sublimation
31
EVALUION
1. (a) Define sublimation (b) Give three examples that can sublime
Centrifugation process
32
3. FILTRATION: As shown below, the mixture is poured into s porous material
(filter paper) folded inside a funnel. The solid particle that remains inside the
liquid that drips through the filter paper is known as the filtrate.
Filtration process
EVALUATION:
Evaporation is based on the large different between the boiling points of the
solid and solvent. For example common salt can be recovered from its aqueous
solution by complete evaporation of water. The solvent (liquid) is usually
sacrificed.
33
Evaporation process
Note: Evaporation method is not suitable for salts that can easily be destroyed
by heating.
Note: If all the liquid is evaporated a powder will be obtained and not crystals.
This powder might also contain impurities which otherwise would have
remained in the solution and not contaminate the crystals. Many crystals
formed on cooling saturated solution contain water which is chemically
combined and loosely bonded to the crystals. This water is called water of
crystallization. Salts which contain water of crystallization are said to be
hydrated. Those which do not are anhydrous. Those are often powders.
EVALUATION:
1. Outline the processes involved in recovery of salt from its aqueous solution.
34
GENERAL EVALUATION
OBJECTIVE TEST
2. A mixture of iodine crystals and common salt can be separated by. (a)
Sublimation (b) filtration (c) sieving (d) centrifugation
5. The following are subliming substances except (a) Ammonium chloride (b)
sulphur (c) Sodium chloride (d) Camphor
ESSAY QUESTIONS
A porous material like _________ can be used to separate ______ particles from
___________. After separation the liquid is called ________ while the particles are
called ____________.
35
WEEKEND ASSIGNMENT:
WEEKEND ACTIVITY:
Mix sand and water together in a container. Allow it to stand for some minutes.
What method would you use to separate the sand from the water?
WEEK 6
CONTENT:
1. FRACTIONAL CRYSTALLIZION:
36
In physical precipitation, two solids that are soluble in the same solvent are
separated by the addition of another solvent in which one of the solids is
insoluble, e.g. an aqueous solution of common salts (sodium chloride) and
green vitriol( a compound of iron). It is a method used to separate a solid which
has a difference in solubility in two different miscible liquids. For example,
ethanol and water are two miscible liquids. Iron(II) tetraoxosulphate(VI) is
soluble in water but not in ethanol. On addition of ethanol to a solution
containing a mixture of iron(II) tetraoxosulphate and water, the iron(II)
tetraoxosulphate(VI) will be precipitated out and can be separated by filtration.
1. DISTILLATION
A mixture of two liquids with widely differing boiling points can be separated by
evaporating one from the other and re-condensing it in a separate vessel. The
process is called simple distillation.
37
At the end of the distillation process the liquid that is collected at the end of
the Liebig condenser is called the distillate. The solutes and other impurities
are left behind in the distillation flask.
DISTILLATION EVAPORATION
Mixture of two or more miscible liquids are separated into, its component
parts. The liquids distil according to their boiling points starting with the liquid
38
with the lowest boiling point. The apparatus used is the same as in distillation
except for the presence of a fractionating column between the flask and the
condenser.
Note: For efficient fractional distillation, the difference in the boiling points
between successive fractions must be more than 100c.
EVALUATION:
39
EVALUATION:
Draw a labeled diagram to show how you would separate a mixture of kerosene
and water.
PERIOD 4: CHROMATOGRAPHY
As shown in the above diagram, the apparatus include: a glass jar with lid,
filter paper, clips, solvent (water or ethanol). The solution containing the
mixture of solutes to be separated is spotted unto the strips of paper near one
end.
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The paper is then suspended in a closed air- tight jar with the spotted end (but
not the spot) dipping into the solvent. As the solvent ascends the paper the
different solutes in the mixture gets dissolved and also more along the paper
strip at different speeds and hence become separated. The paper strip is
removed from the jar when the solvent has moved about three-quarters way up
the strip. It is dried and if necessary sprayed with appropriate chemical
reagents to locate the positions of the various along the strip. Each solute can
then be identified by the distance it has traveled. This is done by comparing its
distance with those of known standard substances.
GENERAL EVALUATION
OBJECTIVE TEST:
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3. Fractional distillation is used to separate (a) an insoluble substance from a
soluble volatile substance (b) substances which are absorbed differently and
which differ in their solubility in a solvent(c) Liquids with differing boiling
points (d) Gas, Liquid or solid impurities from a mixture
ESSAY QUESTIONS:
(1) Name the most suitable physical method for each of the following. (a)
Containing groundnut oil from a mixture of the oil and water. (b)
Obtaining pure water from sea water.
(2) Draw the laboratory set up most suitable for each of the following. (a)
Separating of a mixture of palm oil and water (b) Separate of pure liquid
from an impure liquid.
(3) State one industrial application of each of the following methods of
separation explaining clearly the procedure. (a) crystallization (b)
filtration (c) fractional distillation (d) evaporation
(4) With the aid of a labelled diagram only show how pure sample of ethanol
(alcohol) can be obtained from a mixture of ethanol and water.
(5) Why is sodium chloride solution regarded as a mixture? (b) Draw a
labelled diagram to show how pure sodium chloride can be obtained from
its solution.
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WEEKEND ASSIGNMENT:
WEEKEND ACTIVITY:
Get some impure water in a container and try to purify it by using Alum.
How will you separate the pure liquid after the precipitating process?
WEEK 8
CONTENTS:
1. FLOATATION
2. FROSTATION (FROTH FLOTATION)
3. PURE AND IMPURE SUBSTANCES
4. TEST FOR PURITY
PERIOD 1: FLOATATION:
PROCEDURE: Place the mixture in a beaker and add plenty of water. The sand
particles sink, while the wooden corks float.
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This method is specifically used to separate an ore of a metal from earthy
impurities.
PROCEDURE: The ore is crushed into powder and then mixed with water
containing detergent, in order to cause frothing (foaming).
Air is then blown into the mixture so that the earthy impurities sink while the
ore floats and mixes with the foam. The ore is finally recovered from the foam
PERIOD 3: PURE AND IMPURE SUBTANCES: The following are the criteria for
purity of chemical substances.
DENSITY: The density of a pure substance is definite and constant, while that
of an impure substance higher than expected.
MELTING POINT: The melting point of a pure solid is sharp and definite. The
presence of an impurity lowers the melting point of a substance, and spread its
melting point over a wide range of temperature.
FREEZING POINT: The freezing point of a pure liquid is sharp and definite; the
presence of an impurity lowers the freezing point.
BOILING POINT: The boiling point of a pure liquid is sharp and definite. An
impurity raises the boiling point of a pure liquid.
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is liquid) is determined (if the value obtained agrees with that given in a book of
data, then the substance is pure).
The apparatus below can be used to find the melting point of a solid.
NOTE: If impurities are present the mixture will melt slowly over a range of
temperatures below the melting point of the pure solid.
EVALUATION:
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The boiling point of a liquid is the temperature at which its vapour pressure
equals atmospheric pressure.
The apparatus shown above can be used to find the boiling points of liquids.
A pure sample of liquid will boil at a fixed temperature and the reading on the
thermometer will remain constant. If the light is not pure it will boil over a
range of temperature above the boiling point of the pure liquid.
Impurities lower the melting point of a substance and raise its boiling point.
EVALUATION:
GENERAL EVALUATION
OBJECTIVE TEST
2. The criteria to verify the purity of a solid substance are. I boiling point II
melting point III density IV refractive index
3. A pure dye will A: have a constant boiling point B: have many spots on a
chromatogram C:separate from camphor by evaporation method
ESSAY QUESTIONS
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1. (a) Define the term’ chromatography’. (b) Name the different types of
chromatography (c) Describe with the aid of a diagram how you would separate
a mixture of inks.
2. (a) List three physical properties that are common criteria for purity of
substances. (b) List five pieces of apparatus that are common to the
determination of melting and boiling points of a chemical substances
3. (a) State the importance of the measurement of melting and boiling points.
(b) Explain briefly why salt is always sprinkled can the icy roads in countries
where the temperature falls below 273k.
WEEKEND ASSIGNMENT:
WEEK 9: REVISION
NOTE: THE EDUCATORS ARE TO KNOW THAT THEY ARE TO USE SATURDAYS FOR ALL
PRACTICALS FROM SS1 TO SS3.
CHEMISTRY PRATICALS
CLASS: SS1
CONTENT:
(a) Introduction
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SUB-TOPIC1-INTRODUCTION:
Chemistry laboratory apparatus: Mostly all the apparatus are usually made up of
glass such as Pyrex (borosilicate)soda glass, beaker, test tube etc., metals, wood,
plastics, and porcelain. Some are improvised i.e. they are locally made such as bamboo
for making measuring cylinder, coconut shell for making beaker etc.
EVALUATION
i) What is the purpose of laboratory?
ii) List three materials that can be used to produce laboratory apparatus.
Sub-topic 2-CHEMISTRY LABORATORY APPARATUS AND THEIR USES
1. BEAKER: Commonly made of Pyrex glass. It has a flat bottom, cylindrical and
graduated, usually with lip for easy pouring.
Beakers
USE:Used to keep reagents for chemical tests.For holding and pouring liquids.it is also
used for measuring the volume of liquids.
2.SEPARATING FUNNEL:Made of glass with ashort stem, stopcork,and a stoper. It may
be conical, cylindrical,or spherical.
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USE:it is used in sepration of immiscible liquids,e.g.a mixture of kerosine and water.
1. EVAPORATING BASIN OR DISH: Is made of porcelain. It may be round –bottomed or
flat-bottomed, usually shallow, and with spout (lip).
5. DISTILLATION FLASK: has a flat or round bottom made of glass with a slanting side arm.
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USE: during distillation.
6. MORTAL AND PESTILE: are made of porcelain or agate.
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Chemistry Laboratory Common Equipment
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SUB-TOPIC 3:CHEMISTRY LABORATORY SET-UPS.
A laboratory set-up is the combination of two or more apparatus, which are arranged in such a
manner that the set-up is workable.
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1. FILTRATION 2. SIMPLE DISTILATION
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5.PAPER CHROMATOGRAPH
6.DESICCATORS
Generally it could involve the inhalation of dangerous substances or physical injury as the case
may be. Most of the laboratory accidents occur as follows:
1. GLASS CUT:
Report the situation to your facilitator and let him help the injured person.
There is always a possibility of infection, even with the most minor injury. For this
reason you should report any cut or scrape, even if there is no visible blood.
If there is blood at any laboratory station, move to your seat in the classroom area
until told it is safe to return to the laboratory.
2. FIRES:
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Laboratory burners are the source of most problems:
Bunsen burners have very few malfunctions. If a malfunction occurs, turn off the gas and
notify your facilitator- end of problem.
The flame from alcohol burners is hard to see. Pay close attention when using them.
Be aware when a burner is in use at your lab station. Be extremely careful during
that time.
Paper is the most common type of fire in the lab.
This type of fire is cause by carelessness and easily prevented. Take only one lab
sheet to your station to follow your written procedures and record data. Leave all
reference materials at your desk. If you need to refer to reference material, leave the
lab area to do so.
If a paper fire occurs, push the paper into the lab sink and turn on the water -
end of problem.
Clothing or Hair is the most dangerous type of fire in the lab.
Don't panic!
If you are the one involved in a fire - stay where you are - help is coming. "Stop,
drop, and roll" is still the best course of action. If the fire is not at your lab station -
stay away!
Our lab fire extinguisher is Type ABC, effective against Types A, B, and C.
The average fire extinguisher only operates about 10 seconds.Do not waste it!
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You must get close to the fire - as close as 5 or 6 feet!
3. ACID BURNS
5. EXPLOSION
6. ELECTRIC SHOCK
The following are the basic rules and regulations to guide your safety and hence prevent
accidents in the laboratory.
A. DANGER
i) Always handle glass wares being fragile, with care to avoid glass cuts.
ii) Never use sodium, potassium, phosphorus or concentrated (conc) acids and alkalis
unless you are specially instructed. These chemicals are corrosive. Always add
concentrated acid to water slowly, when diluting the acid, never add water to acid. This
is to avoid acid burns, explosion and fire.
iii) Do not taste or drink any chemical, and never smell any chemical directly .This is to
avoid swallowing or inhaling toxic chemicals.
iv) Do not mix chemicals aimlessly, or carry out any experiment except when instructed, to
avoid explosion or fire outbreak
v) Do not put a glowing splint or a burning paper in the waste bin, to avoid fire outbreak.
vi) Do not touch or hold any electric instrument with wet hands.
vii) All accident should be reported immediately to your facilitator.
viii) Laboratory coats must be worn to protect clothing from soiling, damage from accidents
of various sorts.
i) Pour liquids only down the sink or funnel, and never pour solids, to avoid blockage.
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ii) Clean the apparatus after use and replace them in their proper places.
iii) Wipe down your bench and leave it clean and dry.
iv) Do not light the Bunsen burner or other sources of heat until required. Turn it off when
no longer required.
v) Do not bring any food or drink in to the laboratory and avoid eating, drinking or smoking
in the laboratory.
It is almost impossible to remove contacts after chemicals have been splased into the eye.
Chemicals trapped under contacts will damage the eye even more than normal.
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The plastic used for some types of contact lensess is per meable to vapours found in the
laboratory.if these vapors found in the laboratory.if these vapour are trapped behind
the lens, extrnsiveirritationmay occur.
EVALUTION
ESSAY QUESTIONS
1.You are provided with the folllowing laborary appratus give one use for each of the
following pieces of apparatus.
(a) Reagent bottle(b) Water bath(c) Combustion boat(d) Wash bottle(e) Deflagratine
spoon(f) Evaporating dish(g) Desiccator(h) Tripod stand (i) Test tube rack(j) Liebig
condezer(k)Beam balance.
2.With the aid of diagram,draw the laboratory apparatus/set –up for drying solids in the
laboratory.
6.identfy the apparatus you would use to carry out the following in the laboratory
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