SAFETY DATA SHEET

LITHIUM ION BATTERIES UN3480

1. Identification of Product and Company

Product Name: LITHIUM - ION BATTERY
Other names: LFP, LiFePO4, NMC, NiMnCo, Lithium Ion Battery.
Trade names: Sonnenschein Module Pro Sonnenschein Lithium, Sonnenschein Lithium Material
Handling Batteries, Sonnenschein@home Lithium, Light Traction Block, Light
Traction Block v2, , Equipment Li-Ion
Use: Lithium Ion batteries for the Motive and Network Power markets including electric
forklifts, mobility, rail, telecommunications, utilities, renewables, mining, remote
area power and standby power applications.
Supplier: GNB Industrial Power
ABN: 84 093 272 005
Street Address: 135 Nancy Ellis Leebold Drive
Bankstown NSW 2200
Telephone Number: (02) 9722 5700
Emergency Telephone Australia: 1800 033 111 (ALL HOURS)
Numbers: New Zealand: 0800 734 607 (ALL HOURS)
Ixom Emergency Response Service

2. Hazards Identification

Lithium Ion batteries are classified as an article and are not hazardous when operated in accordance with the
manufacturers recommendations. When used in accordance with recommendations, the electrode materials and
liquid electrolyte are non-reactive provided that the cell enclosure and the seals remain intact. Battery cells are
designed to withstand temperatures and pressures encountered during normal use. As a result, during normal use,
there is no physical danger of ignition, explosion or hazardous material leakage. The potential for exposure should
not exist unless the battery leaks, is exposed to high temperatures or is mechanically, electrically or physically
abused or damaged.

2.1 Classification of the substance or mixture

Not classified as hazardous according to Safe Work Australia criteria.

2.2 Label elements

No signal word, pictograms, hazard or precautionary statements have been allocated.
2.3 Other Hazards
• When recharging batteries, never use chargers which are unsuitable for the battery type.
• Do not short-circuit batteries.
• Do not inflict mechanical damage (puncturing, deforming, disassembling etc.).
• Do expose to heat or incinerate them.
• Keep batteries away from small children.
• Always store batteries in a dry and cool place.
• Contact with leaking battery substances may pose a danger to personal health and the environment. For
this reason, when coming into contact with batteries with a conspicuous appearance (leaking substances,
deformed, discoloured, dented or the like), adequate PPE and breathing protection is required. Lithium

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 batteries can, for example, react very strongly in combination with fire. This can result in battery components
being ejected with considerable force.
2.4 Handling and operational safety
Lithium batteries are always to be handled in accordance with the manufacturer's specifications. This is true
particularly for complying with the limits for maximum current load, charging and end-point voltages, and
mechanical and thermal loads.
Usually product packages are marketed that have already been matched. Such products are not to be modified
or tampered with, since that could result in substantial safety hazards. Use only the charging process tailored to
the respective cell type of a rechargeable battery.
2.5 Danger
As with other batteries, so also for lithium batteries it is true that even when thought to be discharged, they can
still represent a source of danger. They can deliver a very high short-circuit current, however, even in the state of
the minimum permitted end-point voltage lithium batteries with a high voltage (over 75 Volts) can pose a danger
of a lethal electric shock.
For most products, deep discharge beyond the documented limits leads to permanent damage. Deep-discharged
lithium batteries are no longer permitted to be re-charged or operated.
In all cases, avoid excessive charging voltages and overcharging. This can lead directly to critical situations, but
also have a negative impact on battery life.

3. Composition and Information on the main Ingredients

3.1 Battery Cells
The following components are found inside the sealed Li-ion cell. Cells have been further combined as larger battery
modules and systems using mechanical parts.

Component Chemical name CAS number

Cathode LFP: Lithium Iron Phosphate 15365-14-7
Lithium-Metal oxide NMC: Lithium Nickel 182442-95-1
Manganese Cobalt oxide
Anode Graphite 7782-42-5
Binder Polyvinylidene difluoride 24937-79-9
Electrolyte Ethyl acetate 141-78-6
Ethylene carbonate 96-49-1
Dimethyl carbonate 616-38-6

Cu Copper 231-159-6
Al Aluminum 231-072-3

3.2 Li-ion cell chemistry

The following Li-Ion cell chemistries are available from Exide:

LFP: LiFePO4, Lithium Iron Phosphate

NMC: NiMnCo, Lithium Nickel Manganese Cobalt

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 Cathode
Trade name
LFP NMC
Sonnenschein Lithium X
Sonnenschein Lithium Material Handling X
Batteries
Sonnenschein@home Lithium X
Light Traction Block X
Light Traction Block v2 X
Equipment Li-Ion X
Sonnenschein Lithium Module Pro X

3.2 Battery Management System (BMS)

Electronic Components
Contactor

3.3 Battery Tray (where applicable)

Steel

4. First Aid measures

When handled and stored in accordance with the manufacturer’s recommendations, lithium batteries are not
hazardous The chemicals listed in item 3 are enclosed in a sealed housing so that they cannot escape during normal
use. The following measures are only applicable if exposure has occurred to the components when a battery leaks, is
exposed to high temperatures or is mechanically, electrically or physically abused or damaged.
INGESTION: If the contents have been ingested, rinse mouth out with water. If swallowed, Do NOT induce vomiting.
Seek medical advice immediately as urgent hospital treatment is likely to be required. For advice, contact a Poisons
Information Centre (Phone Australia 131 126; New Zealand 0800 764 766) or a doctor at once. If vomiting occurs,
lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent
aspiration.
EYE: If the contents come into contact with the eyes, hold eyelids apart and flush the eye immediately with large
amounts of running water. Continue flushing for at least 15 minutes or until advised to stop by a Doctor. Check for
contact lenses. If there are contact lenses, these should be removed after several minutes of rinsing by the exposed
person or medical personnel if it can be done easily. As the content is rated as Causes severe eye damage, after
flushing, immediately call a Poisons Information Centre (Phone Australia 131 126; New Zealand 0800 764 766) or
doctor/physician.
SKIN CONTACT: If skin or hair contact has occurred with the contents, remove any contaminated clothing and
footwear, wash skin or hair thoroughly with soap and water. As the product is rated as a Corrosive that Causes
severe skin burns, after flushing, immediately call a Poisons Information Centre (Phone Australia 131 126; New
Zealand 0800 764 766) or doctor/physician.
INHALATION: If affected by content vapours, remove the patient from further exposure into fresh air, if safe to do so.
If providing assistance, avoid exposure to yourself - only enter contaminated environments with adequate respiratory
equipment. Once removed, lay patient down in a well-ventilated area and reassure them whilst waiting for medical
assistance. If not breathing, provide artificial respiration and seek immediate medical assistance. If unconscious,
place in a recovery position and seek immediate medical assistance. As the electrolyte is corrosive and
decomposition may cause corrosive and toxic vapours, if the person has inhaled vapours and is having difficulty
breathing, immediately call a Poisons Information Centre (Phone Australia 131 126; New Zealand 0800 764 766) or
doctor/physician.

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5. Firefighting measures
5.1 EXTINGUISHING MEDIA:
SUITABLE MEDIA: Use extinguishing media appropriate for surrounding fire. Use carbon dioxide, dry chemical or
water fog. If batteries are involved in a fire and the hazard situation is unclear, only extinguish with dry chemical
extinguishers.
UNSUITABLE MEDIA: Do not use water or foam extinguishers on ruptured batteries. Confining or smothering the fire
is recommended as reaction of the materials with water may produce flammable and explosive hydrogen gas as well
as corrosive hydrogen fluoride gas. Hydrofluoric acid can cause severe chemical burns, is extremely reactive and is
toxic by all routes of exposure.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
COMBUSTION HAZARDS: Combustion and thermal degradation of the battery may produce hazardous fumes of
lithium, cobalt and manganese, hydrofluoric acid, hydrogen and oxides of carbon as well as smoke and irritating
vapours.
5.3 ADVICE FOR FIREFIGHTERS:
FIRE: Electrolyte leakage or battery container rupture is possible under the conditions experienced in a fire. Keep fire
exposed surfaces, etc. cool with water spray.
HAZCHEM CODE: 4W.
EXPLOSION: Closed containers may explode, burst, rupture or vent when exposed to high temperatures
PROTECTIVE EQUIPMENT: In the event of a fire, wear full protective clothing and self-contained breathing
equipment with full-face piece operated in the pressure demand or other positive pressure mode.

6. Measures to be taken in case of accidental release

If the battery housing is damaged, electrolyte can leak. For small spills seal batteries in an airtight plastic bag, having
added dry sand, chalk powder (CaCO3) or vermiculite. Traces of electrolyte can be soaked up with dry paper
towels. When doing so, prevent direct contact with skin by wearing PVC safety gloves. Thoroughly rinse with water.

If mists or vapours are generated, an approved inorganic vapours and gases/acid gases/particulate respirator is
required. For large battery spill scenarios, or in confined spaces, a full chemically resistant body-suit with self-
contained breathing apparatus is required. For an incident involving more than one or two modules, only trained
personnel should deal with leaking battery incidents.

Ventilate area to dissipate vapours and extinguish and/or remove all sources of ignition. Never enter a spill area
unless you know the vapours have dissipated to make the area safe. Stop the leak if safe to do so. Avoid contact with
the spilled material.
In the event of a spill or accidental release, notify the relevant authorities in accordance with all applicable
regulations. Do not allow batteries or electrolyte to enter drains, surface water, sewers or watercourses - inform local
authorities if this occurs

7. Handling and Storage

7.1 Handling
Under normal operating conditions where the battery remains intact, it is not hazardous.
• Do not open the battery.
• Do not crush, disassemble, drop or solder.
• Incorrect handling can lead to explosion or fire.

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 • Protect the battery from rain
• Do not immerse in liquids or pressure wash
• Effectively prevent a short circuit of the battery poles by using suitable insulation. (e.g.: taping the terminals
with insulation tape).
• Do NOT use, charge or discharge damaged, defective or deformed batteries.
7.2 Storage
Lithium batteries are preferably stored at room temperature and in a dry location (for details, refer to the
manufacturer's specifications concerning the storage temperature range); large temperature fluctuations are to be
avoided. (For example, do not store in the vicinity of heating elements, do not expose to sunshine for long periods). If
substances leak out due to damage or improper handling, be sure to comply with the manufacturer's instructions.
This particularly includes the use of personal safety equipment.

8. Exposure limits and personal protective equipment

Lithium batteries are articles from which no substance is released when operated, handled and stored in accordance
with the manufacturers recommendations

Skin protection: Not necessary under normal conditions.

Hand Protection: Wear nitrile, neoprene, PVC or natural rubber gloves when handling an open or leaking battery.
Eye protection: Not necessary under normal conditions.
Respiratory protection: Not necessary under normal conditions. In the event battery case ruptured inside an
enclosed space, use a self-contained breathing apparatus.
Ventilation: Not necessary under normal conditions

9. Physical and Chemical properties

Appearance: Manufactured sealed battery unit
Colour: Various.
Odour: n.a. If leaking smells of medical ether
pH: n.a.
Flash point: n.a.
Flammability: n.a.
Density: n.a.
Solubility in Water: n.a
Stability: stable

10. Stability and Reactivity

Chemical Stability: The product is stable when operated, handled and stored in accordance with the manufacturers
recommendations.

Conditions to avoid:
• Do not open the battery.
• Do not crush, disassemble, drop or solder.
• Incorrect handling can lead to explosion or fire.
• Protect the battery from rain

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• Do not immerse in liquids or pressure wash
• Effectively prevent a short circuit of the battery poles by using suitable insulation. (e.g.: taping the terminals with
insulation tape).
• Do NOT use, charge or discharge damaged, defective or deformed batteries.
• Comply with the voltage limits defined for the battery during discharge and charge. If the limits are exceeded, the
battery may burst or even explode

Hazardous decomposition Products: Exposure to fire may cause emission of flammable and highly toxic gases.

Reactivity: n.a

11. Toxicological Information

11.1 Acute toxicity
The product is stable when operated, handled and stored in accordance with the manufacturers recommendations.
Unbroken cells or batteries do not represent toxicity hazard.

11.2 Irritation and corrosion

Risk of thermally or electrically abuse causing cells to rupture. Electrolyte is corrosive. It causes chemical burns on
contact with skin. Inhalation of fine mist or vapors is irritating to the respiratory system. Prolonged contact with the
skin or mucous membranes may cause irritation.
● Sensitization: No information is available at this time.
● Carcinogenicity: No information is available at this time.
● Reproductive toxicity: No information is available at this time.
● Teratogenicity: No information is available at this time.
● Mutagenicity: No information is available at this time

12. Ecological Information

12.1 Eco-toxicity
Not applicable for undamaged product.

12.2 Persistence and degradability

Not applicable

12.3 Bio-accumulative potential

Not applicable

12.4 Mobility in soil

Not applicable

12.5 Results from PBT –and vPvB assessment

Not applicable

12.6 Other adverse effects

In case of an accident emissions may be harmful to environment

13. Disposal Considerations

In accordance with EU Battery Directive and the respective national legislation, Lithium-Ion batteries are labelled with
a crossed-oust dust bin together with the ISO return/recycling symbol.

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The symbol reminds the end user that batteries are not permitted to be disposed of with household waste, but must
be collected separately.

Do not incinerate.
Dispose of in accordance with appropriate local regulations
Recycle or reuse where possible. Contact your state EPA or the manufacturer for additional information.

14. Transport Information

Road and Rail Transport

Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for
Transport by Road and Rail; DANGEROUS GOODS.

UN No: 3480
Proper Shipping Name: LITHIUM ION BATTERIES (including lithium ion polymer batteries)
Class-primary 9
Packing Group:
Special Provisions: 188, 230 310 348 376 377 384 387 390
Hazchem Code: 4W

Marine Transport

Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG
Code) for transport by sea; DANGEROUS GOODS.

UN No: 3480
Proper Shipping Name: LITHIUM ION BATTERIES (including lithium ion polymer batteries)
Class-primary 9
Packing Group:
Special Provisions: 188 230 310 348 376 377 384 387 390
Hazchem Code: 4W

Air Transport

Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by air; DANGEROUS GOODS.

UN No: 3480
Proper Shipping Name: LITHIUM ION BATTERIES (including lithium ion polymer batteries)
Class-primary 9
Packing Group:
Special Provisions: A88, A99, A154, A164, A181, A182, A183, A185, A201, P965, P966, P967, P968,
P969, P970
Hazchem Code: 4W

To assist shippers in understanding the complete requirements related to the transport of lithium batteries, including
packing instructions, IATA has prepared the updated Lithium Battery Guidance Document
https://www.iata.org/contentassets/05e6d8742b0047259bf3a700bc9d42b9/lithium-battery-guidance-document.pdf

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15. Regulatory Information

Poison schedule: A poison schedule number has not been allocated to this product using the criteria in the
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Classifications: Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification
and Labelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying
Hazardous Substances [NOHSC: 1008(2004)].

Hazard codes: None allocated

Risk phrases: None allocated
Safety phrases: None allocated
Inventory Listings: AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.

16. Other Information

16.1 Safety Data Sheet
The European Directive 91/155/EEC which described the requirements for Material Safety Data Sheets had been
repealed by the Regulation concerning the Registration, Evaluation, Authorization and Restriction of Chemicals on
st
June 1 , 2007 (REACH-Regulation 1907/2006/EC, Art. 31). The requirement to publish a Safety Data Sheet applies
to all suppliers of substances and preparations.
As already defined under the former Directive there is no requirement to develop and maintain a Safety Data Sheet
for products such as Batteries.
16.3 General
The information given above is provided in good faith based on existing knowledge and does not constitute an
assurance of safety under all conditions. It is the user’s responsibility to observe all laws and regulations applicable
for storage, use, maintenance or disposal of the product. If there are any queries, the supplier should be consulted.
However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
Date of preparation: March 2022 Date of last Review: March 2022

THIS SDS IS OFFERED ONLY FOR INFORMATION. GNB INDUSTRIAL POWER PROVIDES NO WARRANTIES EITHER EXPRESS OR IMPLIED
AND ASSUMES NO RESPONSIBILITY FOR THE ACCURACY OR COMPLETENESS OF DATA CONTAINED HEREIN.

VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY
PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET, AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE
OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE PROCEDURES ARE FOLLOWED.

ALL PERSONS USING THIS PRODUCT, ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED, AND ALL PERSONS
HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFORMATION SHOULD BE
EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT.

WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF, EXIDE
TECHNOLOGIES MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.
RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THEINFORMATION IS CURRENT, APPLICABLE, AND SUITABLE
FOR THEIR PARTICULAR CIRCUMSTANCES.

END OF SDS

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