Oxyhalides Besides Standard Anions in Swimming Pool Water: IC Application Note S-326

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IC Application Note S–326

Oxyhalides besides standard


anions in swimming pool water

Swimming pool water needs to be disinfected thoroughly. Often ozone is used. As


a result of this strong oxidation, oxyhalides may build up and need to be analyzed.
Here, the separation and determination of oxyhalides besides standard anions is
performed on a Metrosep A Supp 5 - 250/4.0 column with subsequent sequential
suppression followed by conductivity detection.

Results
Anion Concentration Anion Concentration
[mg/L] [mg/L]
Chlorite < 0.01 Bromide <0.01
Bromate 0.02 Nitrate 23.2
Chloride 121 Phosphate 0.42
Chlorate 4.89 Sulfate 23.2
Sample Parameters
Swimming pool water Flow rate 0.7 mL/min
Injection volume 50 µL
Sample preparation Pmax 15 MPa
Filtration through 0.45 µm Recording time 32 min
Column temperature 25 °C

Columns

Metrosep A Supp 5 - 250/4.0 6.1006.530


Metrosep A Supp 1 Guard/4.6 6.1005.340

Solutions

Eluent 3.2 mmol/L sodium


carbonate
1.0 mmol/L sodium
hydrogen carbonate
Suppressor regenerant 100 mmol/L sulfuric acid
Rinsing solution STREAM

Analysis

Conductivity detection after sequential suppression

Instrumentation

930 Compact IC Flex 2.930.2560


Oven/SeS/PP/Deg
IC Conductivity Detector 2.850.9010
858 Professional Sample Processor 2.858.0020
MSM Rotor A 6.2832.000
IC Application Note S–326

www.metrohm.com
Version 1

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