Material Safety Data Sheet: F108 EZEFLO F108 Surfactant

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MATERIAL SAFETY DATA SHEET

(USA)

(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)


Version: 4 Revision date: 03 March 2010
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product code: F108


Product name: EZEFLO F108 Surfactant
Company identification: Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873

Emergency telephone number: USA: +1-281-595-3518 (24hr)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

WARNING

Main physical hazards: No classified physical hazards.


Main health hazards: Causes eye irritation. May cause skin irritation.
Main environmental hazards: Toxic to algae.
Other Information: Contaminated surfaces will be extremely slippery.
Precautions: Avoid contact with eyes. Do not get on skin or clothing. Wash thoroughly
after handling.
HMIS classification: Health: 2 Flammability: 1 Physical hazard: 0

Form: Liquid Color: Colorless Odor: Amine-like


Principle routes of exposure:
Skin contact. Eye contact.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No Weight % - Range


Amine derivative Proprietary 10 - 30

4. FIRST AID MEASURES

Eye contact: Immediately flush eyes with water for 30 minutes while holding eyelids
open.
Skin contact: Wash off immediately with soap and plenty of water removing all
contaminated clothes and shoes. Seek medical attention if irritation occurs.
Ingestion: Seek medical attention. Never give anything by mouth to an unconscious
person.
Inhalation: Move to fresh air. Consult a physician if necessary.

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 1 of 7
Product code: F108 Revision date: 03 March 2010

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5. FIRE-FIGHTING MEASURES

Fire hazard: Negligible.


Flash point: Does not flash.
Autoignition temperature: No data available.
Flammability limits in air:
Lower: Not applicable
Upper: Not applicable
Oxidizing properties: None.

Suitable extinguishing media:


Extinguish with carbon dioxide, dry chemical, foam or waterspray.

Extinguishing media which must not be used for safety reasons:


None known.

Special exposure hazards arising from the substance or preparation itself, its combustion
products, or released gases:
When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.

Other information:
Solutions extremely slippery when spilled.

Special protective equipment for firefighters:


Wear protective fire fighting clothing and avoid breathing vapors. Use self-contained breathing apparatus in
closed areas.

NFPA rating:
Health: 2
Flammability: 1
Instability: 0
Special: None

6. ACCIDENTAL RELEASE MEASURES

Main physical hazards: No classified physical hazards.


Other Information: Contaminated surfaces will be extremely slippery.
Personal precautions: Avoid contact with eyes. Do not get on skin or clothing. Wash thoroughly
after handling. Wear suitable protective equipment.
Methods for cleaning up: Dam up. Absorb spill with inert material (e.g. dry sand or earth), then place
in a chemical waste container.
Environmental precautions: Keep out of waterways.

7. HANDLING AND STORAGE

Handling:
Precautions: Avoid contact with eyes. Do not get on skin or clothing. Wash thoroughly
after handling.
Safe handling advice: Wear suitable protective equipment.
Technical measures/ Store in well ventilated area out of direct sunlight.
storage conditions:
Packaging requirements: High density polyethylene (HDPE) drum or can.
Incompatible products: Oxidizing agents.

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 2 of 7
Product code: F108 Revision date: 03 March 2010

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures Control the source.


to reduce exposure:
Hygiene measures: Avoid contact with skin, eyes and clothing. Wear suitable protective
equipment.
Respiratory protection: None normally needed.
Eye protection: Tightly fitting safety goggles.
Hand protection: Impervious gloves. PVC. Neoprene.
Skin and body protection: Chemical resistant apron.

Occupational Exposure Limits


ACGIH - TLVs OSHA - PELs
Com ponent TWA / Ceiling STEL ACGIH - Skin TWA / C STEL Final PELs
- Skin
Amine derivative - - - - - -

Particles Not Otherw ise Regulated/Specified [PNOR or PNOS] (insoluble or poorly soluble):
- OSHA PEL's for Inert or Nuisance Dust are covered by PNOR limits: respirable fraction: 5 mg/m3; total dust 15 mg/m3.
ACGIH PNOS Recommendations: airborne concentrations should be kept below 3 mg/m3, respirable particulate, and 10 mg/m3,
inhalable particles.

9. PHYSICAL AND CHEMICAL PROPERTIES

Chemical characterization: Surfactant. Aqueous dispersion of organic compounds.


Fire hazard: Negligible.
Form: Liquid
Color: Colorless
Odor: Amine-like
Odor threshold: No information available.
pH: 6.5 - 8.0
Boiling point/range: ~100°C / 212 °F
Flash point: Does not flash.
Flammability limits in air:
Lower: Not applicable
Upper: Not applicable
Bulk density: Not applicable.
Melting point/range: (1.7-3.3) °C / (35-38) °F
Decomposition temperature: No data available.
Solubility:
Water solubility: Soluble.
Fat solubility: No information available.
Partition coefficient <0
(n-octanol/water):
Relative density: 1.0
Vapor pressure: Similar to water.
Vapor density: Similar to water.
Viscosity: Approximately 5 mPa.s
Evaporation rate: Similar to water.
% Volatile (VOC): None.

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 3 of 7
Product code: F108 Revision date: 03 March 2010

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10. STABILITY AND REACTIVITY

Stability:
Stable under recommended storage conditions.

Conditions to avoid:
None reasonably foreseeable.

Incompatibility with other substances:


Oxidizers.

Hazardous decomposition products:


Carbon oxides. Nitrogen Oxides (NOx).

Hazardous polymerization:
Hazardous polymerization does not occur.

Other Information:
Contaminated surfaces will be extremely slippery.

11. TOXICOLOGICAL INFORMATION

PRODUCT TOXICOLOGICAL INFORMATION

Information given is based on data on the components and the toxicology of similar products.

Acute Health Hazard

Eye contact: Severe eye irritation. Causes pain and redness. Prolonged or repeated
contact may cause mild burn.
Skin contact: Irritant; may cause pain, redness, dermatitis.
Ingestion: Swallowing large amounts may be harmful.
Inhalation: This is an unlikely route of exposure.
Sensitization - lung: Not known to cause allergic reaction.
Sensitization - skin: Not known to cause allergic reaction.

Chronic Health Hazard

Carcinogenic effects: Not known to cause cancer in humans.


Mutagenic effects: Not known to cause heritable genetic damage.
Teratogenic effects: Not known to cause birth defects or have a deleterious effect on a
developing fetus.
Reproductive toxicity: Not known to adversely affect reproductive functions and organs.
Target organ effects: See COMPONENT TOXICOLOGICAL INFORMATION below.

COMPONENT TOXICOLOGICAL INFORMATION

Com ponent Target Organ Effects LD50 / LC50


Amine derivative - -

Com ponent IARC Group 1 or 2: ACGIH - OSHA Listed NTP:


Carcinogens: Carcinogens
Amine derivative - - - -

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 4 of 7
Product code: F108 Revision date: 03 March 2010

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Com ponent OTHER TOXICOLOGICAL INFORMATION


Amine derivative Risk of serious damage to eyes. Causes eye irritation.

12. ECOLOGICAL INFORMATION

PRODUCT INFORMATION

Main environmental hazards: Toxic to algae.

COMPONENT INFORMATION

Amine derivative
Bioaccum ulation: log Pow = < 0
Persistence / degradability: Readily biodegradable.
Algae toxicity: 72h EC50= 0.22 mg/l (Skeletonema costatum)

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:


Dispose of in accordance with local regulations.

Contaminated packaging:
Dispose of in accordance with local regulations. If reusable containers are used, send them back to the
product supplier, after the required rinsing.

EPA RCRA Hazardous Waste Code:


None

14. TRANSPORT INFORMATION

DOT:
CERCLA RQ: None

Hazard class: Not regulated.


Proper shipping name: Not regulated
Label(s): None required.

IMDG/IMO
Shipping name: Not regulated.

UN number: None

ICAO/IATA
Shipping name: Not regulated.

UN number: None

TDG (Canada):
Shipping name: Not regulated.
PIN: None

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 5 of 7
Product code: F108 Revision date: 03 March 2010

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Note 1:
For the applicab le placard selection refer to the appropriate transport regulations; the selection may vary
depending on the cargo size and categories of other hazardous materials in the cargo.

15. REGULATORY INFORMATION

International Chemical Inventories

USA, Toxic Substances Control This product complies with TSCA requirements.
Act inventory (TSCA):
IMPORTS, USA: No import volume restrictions.
Canada, Domestic Substance This product complies with DSL requirements.
List (DSL):
IMPORTS, Canada: No import volume restrictions.
U.S.A. Regulations

OSHA Hazard Communication Standard:


(Complies with USA OSHA 29 CFR 1910.1200 and ANSI Z 400.1)

EPA RCRA Hazardous Waste Code:


None

EPA, Sections 311 and 312 - Material Safety Data Sheet Requirements (40 CFR 370):

Immediate (Acute) Health Hazard: YES


Delayed (Chronic) Health Hazard: None
Fire Hazard: None
Sudden Release or Pressure Hazard: None
Reactive Hazard: None

EPA, Sections 313 - List of Toxic Chemicals (40 CFR 372):


This product contains the following substance(s), which appear(s) on the List of Toxic Chemicals:

Additional Regulatory Information


Amine derivative
EPA, CERCLA Section 102a/103 Hazardous Substances (40 CFR 302.4): None
CERCLA/SARA - Hazardous Substances and their RQs: None
EPA, SARA TITLE III Section 304, Extremely Hazardous Substances (40 CFR 355.40): None
California Proposition 65: None

International Hazard Class


WHMIS Hazard Class:
D2B (Other Toxic Effects - Toxic Material)

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 6 of 7
Product code: F108 Revision date: 03 March 2010

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16. OTHER INFORMATION

Current references:
1. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices.
American Conference of Governmental Industrial Hygienists, Cincinnati OH.
2. IARC Monograms on the Evaluation of the Carcinogenic Risk of Chemicals to Man. World Health
Organization, International Agency for Research on Cancer. Geneva, Switzerland.
3. Annual Report on Carcinogens. National Toxicology Program. U.S. Department of Heath and Human
Services, Pub lic Health Service.
4. NIOSH Registry of Toxic Effects of Chemical Substances (RTECS). National Institute for Occupational safety
and Health. Cincinnati, OH.
5. LOLI Database.

Explanation of terms:
ACGIH: American Conference of Governmental Industrial Hygienist
ACGIH-TL: Threshold Limit Value
DSL: Domestic Substance List
HMIRC: Hazardous Materials Information Review Commission
IARC: International Agency for Research on Cancer
NTP: National Toxicology Program
NIOSH: National Institute of Occupational Safety & Health
NIOSH-REL: Recommended Exposure Limit
OSHA: Occupational Safety & Health Administration
OSHA-PEL: Permissible Exposure Limit
TSCA: Toxic Substance Control Act (Inventory)

Occupational Exposure Limits indicators: TWA - Time Weighted Average; STEL - Short Term Limit; C - Ceiling
Limit;units: [mg/m 3]

ACGIH Notations:
"Skin" refers to the potential significant contribution to the overall exposure by the cutaneous route, including
mucous membranes and the eyes, either by contact with vapors or by direct skin contact with the substance.
"A" notation indicates carcinogenicity as follows:
ACGIH classification: A1 - Confirmed Human Carcinogen; A2 - Suspected Human Carcinogen; A3 - Confirmed
Animal Carcinogen with Unknown Relevance to Humans; A4 - Not Classifiable as a Human Carcinogen; A5 - Not
suspected as a Human Carcinogen.
"SEN" refers to the potential for an agent to product sensitization as confirmed by human and animal data.

Section(s) revised: 9

Prepared by: Chemical Regulatory Compliance (CRC)

Revision date: 03 March 2010

The information and recommendations contained herein are based upon tests believed to be reliable. How ever, Schlumberger
does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY,
WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required.
Schlumberger assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits
arising from the use of these data. No w arranty against infringement of any patent, copyright or trademark is made or implied.

End of the Material Safety Data Sheet

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110 Schlumberger Drive, Sugar Land, Texas 77478, USA. Phone (281) 285-7873 Page 7 of 7

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