Basics of Semiconductors
Basics of Semiconductors
Basics of Semiconductors
Semiconductors are materials whose electrical properties lie between Conductors and Insulators.
e.g. : Silicon and Germanium
Types of Semiconductor
Semiconductors that are free of doping Semiconductors formed after adding impurities
impurities are called intrinsic semiconductors. are called extrinsic semiconductors.
Doping is a process of adding a certain amount of specific impurities called dopants to a pure semiconductor to increase its
electricity conductivity.
Intrinsic Semiconductor
• Semiconductor in pure form is known as Intrinsic
Semiconductor.
•Eg. Pure Germanium, Pure Silicon, Pure Gallilium,
pure Arsenic .
• At room temp. no of electrons* equal to no. of holes*.
*Holes and electrons are the two types of charge carriers responsible for current
in semiconductor materials.
Energy band gap in case of intrinsic semiconductor
Extrinsic Semiconductors are further classified as:
a. n-type Semiconductors.
b. p-type Semiconductors. Antimony impurity in n type
material.
n - type Semiconductor
When we add a pentavalent impurity to pure semiconductor we get n-
type semiconductor.
1.Drift process
2.Diffusion process
• Drift process
• Electrons move from external circuit and
in conduction band of a semiconductor.
•Holes
Diffusion processmove in valence band of a
•Moving of electrons from higher concentration
semiconductor.
gradient to lower concentration gradient is known as
diffusion process.
What are P-type and N-type ?
•The region around the junction is left with neither holes nor free
electrons.
•This neutral region which has no charge carriers is called the
depletion layer.
• This layer which has no charge carrier is a poor conductor of
electricity.
Forward Bias and Reverse Bias
□ Forward Bias: Connect positive of the Diode to positive of supply…negative of Diode to
negative of supply
□Reverse Bias: Connect positive of the Diode to negative of supply…negative of diode to
positive of supply.
Diode
Electronic devices created by bringing together a p-type and n-type region within the
same semiconductor lattice. Used for rectifiers, LED etc
Characteristics of Diode
Diode always conducts in one direction.
Diodes always conduct current when “Forward Biased” ( Zero resistance)
Diodes do not conduct when Reverse Biased (Infinite resistance)
Electronic devices created by bringing together a p-type and n-type region within same
semiconductor lattice.
Diodes are used for rectifiers and LEDs
I-V characteristics of Ideal diode
Schematic Symbol
●Operates in reverse bias and this gives rise to three regions. At either end of the diode are the
P and N regions. However around the junction is the depletion region where no current carriers
are available. As a result, current can be carried in the P and N regions, but the depletion region
is an insulator.
●Same as capacitor construction. It has conductive plates separated by an insulating dielectric.
●The capacitance of a capacitor is dependent on a number of factors including the plate area,
the dielectric constant of the insulator between the plates and the distance between the two
plates. In the case of the varactor diode, it is possible to increase and decrease the width of the
depletion region by changing the level of the reverse bias. This has the effect of changing the
distance between the plates of the capacitor.
Dr. Meenakshi Rana
Deptt- Physics
C – V CHARACTERISTICS MATERIAL CONSTRUCTION
History
Tunnel diode was invented in 1958 by Leo Esaki.
Also called Esaki diode.
Leo Esaki observed that if a semiconductor diode is heavily doped with impurities, it will
exhibit negative resistance.
In 1973 Leo Esaki received the Nobel Prize in physics for discovering the electron
tunneling effect used in these diodes.
Features of photodiode:
Excellent linearity with respect to incident light
Low noise
Wide spectral response
Mechanically rugged
Compact and lightweight
Long life
Basic principle of operation
In a conventional diode, forward conduction occurs only if the forward bias is sufficient to
give charge carriers the energy necessary to overcome the potential barrier.
When the tunnel diode is slightly forward biased, many carriers are able to tunnel through
narrow depletion region without acquiring that energy.
The carriers are able to tunnel because the voltage barrier is reduced due to high doping.
Forward Bias operation:
At first voltage begin to increase:
Electrons tunnel through pn junction.
2. Electron and holes states become aligned.
Voltage increases further:
1. States become misaligned.
2. Current drops.
3. Shows negative resistance (V increase, I decrease).
As voltage increase yet further:
1. The diode behave as normal diode.
2. The electrons no longer tunnel through barrier.
Reverse Bias Operation:
When used in reverse direction, they are called as Back Diodes. In this, i. The electrons in
valence band of p-side tunnel directly towards the empty states present in the conduction band of
n-side. ii. Thus, creating large tunneling current which increases with application of reverse
voltage.
I/V Characteristics
As forward bias is applied, significant I is produced. After continuous increase of
V, the current achieves its minimum value called as Valley Current. After further increase in V,
current start increasing as ordinary diode.
It is used as an ultra-high speed switch due to tunneling (which essentially takes place at
speed of light). It has switching time of nanoseconds or picoseconds.
Used as logic memory storage device.
In satellite communication equipment, they are widely used.
Due to its feature of –ive resistance, it is used in relaxation oscillator circuits.
Tunnel diodes are resistant to the effects of magnetic fields, high temperature and
radioactivity. That‟s why these can be used in modern military equipments, NMR machines.
Due to low power requirement, they are used in FM receivers.
Photo diode
A photo-diode is a reverse-biased silicon or germanium p-n junction in which reverse
current increases when the junction is exposed to light. The reverse current in a photo-
diode is directly proportional to the intensity of light falling on its p-n junction. This means
that greater the intensity of light falling on the p-n junction of photo-diode, the greater will
be the reverse current.
Schematic Symbol
Principle of Photodoide
When a rectifier diode is reverse biased, it has a very small
reverse leakage current. The same is true for a photo-diode.
The reverse current is produced by thermally generated
electron hole pairs which are swept across the junction by the
electric field created by the reverse voltage. In a rectifier
diode, the reverse current increases with temperature due to
an increase in the number of electron-hole pairs. A photo-
diode differs from a rectifier diode in that when its p-n
junction is exposed to light, the reverse current increases with
the increase in light intensity and vice-versa. This is
explained as follows. When light (photons) falls on the p-n
junction, the energy is imparted by the photons to the atoms
in the junction. This will create more free electrons (and more
holes). These additional free electrons will increase the
reverse current. As the intensity of light incident on the p-n
junction increases, the reverse current also increases. In other
words, as the incident light intensity increases, the resistance
of the device (photo-diode) decreases.
APPLICATIONS
Light emitting diode
LED
LEDs are available in red, orange, amber, yellow, green, blue and white. LEDs are
made from gallium-based crystals that contain one or more additional materials such
as phosphorous to produce a distinct color.
History
Paris, France 1962 - Nick Holonyack Jr. 1972 - Herbert Maruska and New Jersey 1976 - Thomas
develops the red LED, the first LED of Jacques Pankove develop the P. Pearsall develops special
visible light. violet LED using Mg-doped GaN high brightness LEDs for
films. fiber optic use.
Construction of LED
•SENSOR APPLICATIONS: Medical Instrumentation, Bar Code Readers, Color & Money Sensors,
Encoders, Optical Switches, Fiber Optic Communication
• MOBILEAPPLICATIONS: Mobile Phone, PDA's, Digital Cameras,Lap Tops, General Backlighting
•AUTOMATIVE APPLICATIONS: Interior Lighting - Instrument Panels & Switches, Courtesy Lighting,
Exterior Lighting - CHMSL, Rear Stop/Turn/Tail, Truck/Bus Lighting - Retrofits, New Turn/Tail/Marker
Lights
•SIGNAL APPICATIONS: Traffic Rail Aviation, Tower Lights, Runway Lights, Emergency/Police Vehicle
Lighting,LEDs offer enormous benefits over traditional incandescent lamps, including: Energy savings (up
to 85% less power than incandescent), Reduction in maintenance costs, Increased visibility in daylight and
adverse weather conditions
•ILLUMINATION: Architectural lightening, Machine Vision Retail Displays, Emergency Lighting (Exit
Signs) Neon Replacement, Bulb Replacements, Flashlights,Outdoor Accent Lighting - Pathway, Marker
Lights, Studies have shown that the use of LEDs in illumination applications can offer: Greater visual
appeal, Reduced energy costs, Increased attention capture, Savings in maintenance and lighting
replacements
•INDICATION: Household appliances, VCR/ DVD/ Stereo and other audio and video
devices,Toys/Games
Zener Diode
Characteristics
Circuit Symbol
Mechanism
1. Semiconductors are the basic materials used in the present solid state electronic devices
like diode, transistor, ICs, etc.
2. Metals have low resistivity (10–2 to 10–8 Ωm), insulators have very high, while
semiconductors have intermediate values of resistivity.
5. The number of charge carriers can be changed by „doping‟ of a suitable impurity in pure
semiconductors. Such semiconductors are known as extrinsic semiconductors. These are
of two types (n-type and p-type).
6. There are two distinct band of energies (called valence band and conduction band) in
which the electrons in a material lie. Valence band energies are low as compared to
conduction band energies. All energy levels in the valence band are filled while energy
levels in the conduction band may be fully empty or partially filled. The electrons in the
conduction band are free to move in a solid and are responsible for the conductivity. The
extent of conductivity depends upon the energy gap (Eg) between the top of valence band
(EV ) and the bottom of the conduction band EC. The electrons from valence band can be
excited by heat, light or electrical energy to the conduction band and thus, produce a
change in the current flowing in a semiconductor.
7. For insulators Eg > 3 eV, for semiconductors Eg is 0.2 eV to 3 eV, while for metals Eg ≈ 0.
8. p-n junction is the „key‟ to all semiconductor devices. When such a junction is made, a
„depletion layer‟ is formed consisting of immobile ion-cores devoid of their electrons or
holes. This is responsible for a junction potential barrier.
9. By changing the external applied voltage, junction barriers can be changed. In forward
bias (n-side is connected to negative terminal of the battery and p-side is connected to the
positive), the barrier is decreased while the barrier increases in reverse bias. Hence,
forward bias current is more (mA) while it is very small (μA) in a p-n junction diode.
10. Zener diode is one such special purpose diode. In reverse bias, after a certain voltage, the
current suddenly increases (breakdown voltage) in a Zener diode. This property has been
used to obtain voltage regulation.
11. p-n junctions have also been used to obtain many photonic or optoelectronic devices
where one of the participating entity is „photon‟:(a) Photodiodes in which photon
excitation results in a change of reverse saturation current which helps us to measure light
intensity; (b) Solar cells which convert photon energy into electricity; (c) Light Emitting
Diode and Diode Laser in which electron excitation by a bias voltage results in the
generation of light.
Some important key points
Solid are classified in three categories metals, semiconductors and non-metals depending upon their
conductivity.
Semiconductors have their conductivity in between those of metals and non-metals. Unlike metals they
have a negative temperature coefficient of resistivity. This mean with the rise of temperature there is a
decrease in their resistance and their conductivity increases.
Intrinsic Semiconductors: Semiconductors in their purest form possible are known as intrinsic
semiconductors. Even intrinsic semiconductors have free electrons and vacancy (i.e. hole) because some
of the electrons break their covalent bonds. This is because of the thermal energy acquired by these
electrons. For intrinsic semiconductor density of holes is equal to the density of the electrons.
Holes: When an electron gets free from a covalent bond it creates a vacancy in the bond. This vacancy
(center of electron deficiency) acts as a positive center know as hole.
Intrinsic semiconductors have very low conductivity as the number density of electrons and holes in pure
semiconductors is very low.
Extrinsic semiconductors: Semiconductors in their pure form are not very useful because of their low
conductivity. In order to increase their conductivity, impurities are added to them.
Doping: The deliberate addition of a desirable impurity is called doping and the impurity atoms are called
dopants. Such a material is also called a doped semiconductor/extrinsic semiconductor.
n – type semiconductor: An n -type material is created by introducing impurity elements that have five
valence electrons (pentavalent), such as antimony, arsenic, and phosphorus. The pentavalent dopant is
donating one extra electron for conduction and hence is known as donor impurity. For n-type
semiconductors, density of electrons is much higher than the density of holes i.e. .
p – type semiconductor: The p -type material is formed by doping a pure germanium or silicon crystal
with impurity atoms having three valence electrons. The elements most frequently used for this purpose
are boron, gallium, and indium. The trivalent dopant is deficient of one electron and thus creates a
vacancy. The resulting vacancy will readily accept a free electron: thus diffused trivalent impurities are
called acceptor atoms. For p-type semiconductors, density of holes is much higher than the density of
electrons i.e. .
n – type semiconductor: An n -type material is created by introducing impurity elements that have five
valence electrons (pentavalent), such as antimony, arsenic, and phosphorus. The pentavalent dopant is
donating one extra electron for conduction and hence is known as donor impurity. For n-type
semiconductors, density of electrons is much higher than the density of holes i.e. .
p – type semiconductor: The p -type material is formed by doping a pure germanium or silicon crystal
with impurity atoms having three valence electrons. The elements most frequently used for this purpose
are boron, gallium, and indium. The trivalent dopant is deficient of one electron and thus creates a
vacancy. The resulting vacancy will readily accept a free electron: thus diffused trivalent impurities are
called acceptor atoms. For p-type semiconductors, density of holes is much higher than the density of
electrons i.e. .
Extrinsic semiconductor like intrinsic semiconductors as a whole are neutral in nature. This is because the
total number of protons and the electrons are equal.
In an n-type material the electron is called the majority carrier and the hole the minority carrier. On the
other-hand in a p-type material the hole is the majority carrier and the electron is the minority carrier.
p-n junction: When a p-type semiconductor is suitably joined to n-type semiconductor, the contact surface
is called p-n junction. Most semiconductor devices contain one or more p-n junctions. The p-n junction is
of great importance because it is in effect, the control element for semiconductor devices.
Depletion Layer: When a p-n junction is formed this cause electron hole recombination near the junction.
As a result of this around the junction both p and n side are left with only immobile ions and all the charge
carriers are gone. These two layers of positive and negative charges form the depletion region (or
depletion layer). The term depletion is due to the fact that near the junction, the region is depleted (i.e.
emptied) of charge carries (free electrons and holes) due to diffusion across the junction.
Barrier Potential: There exists a potential difference across the depletion layer and is called barrier
potential ( ). The barrier potential of a p-n junction depends upon several factors including the type of
semiconductor material, the amount of doping and temperature. The typical barrier potential is
approximately: For silicon, = 0.7 V ; For germanium, = 0.3 V.
p-n junction diode: A semiconductor diode is basically a p-n junction with metallic contacts provided at
the ends for the application of an external voltage. It is a two terminal device.
Forward Biasing: When external d.c. voltage applied to the junction is in such a direction that it cancels
the potential barrier, thus permitting current flow, it is called forward biasing.
Reverse Biasing: When the external d.c. voltage applied to the junction is in such a direction that
potential barrier is increased, it is called reverse biasing.
Junction Breakdown: The process by which a depletion region at the p-n junction is destroyed
and allows a large reverse current is called depletion region breakdown. There are two main
mechanisms of junction breakdown, depending on the dopant concentration levels.
1. Avalanche breakdown 2. Zener breakdown
Avalanche breakdown: Avalanche breakdown occurs in moderately and lightly doped p-n
junctions with a wide depletion region. Electron hole pairs thermally generated in the depletion
region are accelerated by the external reverse bias. Electrons are accelerated towards then side
and holes towards the p side. These electrons can interact with other Si atoms and if they have
sufficient energy can knock off electrons from these Si atoms. This process is called impact
ionization and leads to production of a large number of electrons. This causes the rapid rise in
current.
Zener Breakdown: With increase in doping concentration the breakdown mechanism, changes
from Avalanche to a tunneling mechanism. This is called a Zener breakdown. This is because th
depletion width decreases with dopant concentration. Also, the reverse bias causes an offset in
the bands such that it is possible for carriers to tunnel across the narrow depletion region.
Zener Diode: It is a special purpose semiconductor diode, named after its inventor C. Zener. It
designed to operate under reverse bias in the breakdown region and used as a voltage regulator.
Tunnel Diode: The tunnel diode was first introduced by Leo Esaki in 1958. Its characteristics, are different
from any other diode as it has a negative-resistance region. In this region, an increase in terminal voltage
results in a reduction in diode current. It has a greatly reduced depletion region, of the order of magnitude
of cm, or typically about 1/100 the width of this region for a typical semiconductor diode. It is this thin
depletion region, through which many carriers can “tunnel” rather than attempt to surmount, at low
forward-bias potentials.
Varactor Diode: A junction diode which acts as a variable capacitor under changing reverse bias is known
as a varactor diode. The capacitance of varactor diode is found as
,
where = Total capacitance of the junction, Ɛ = permittivity of the semiconducting material A = Area of
cross section of the junction, = Width of the depletion layer
Photo diode: It is a reverse-biased silicon or germanium p-n junction in which reverse current increases
when the junction is exposed to light. The reverse current in a photo-diode is directly proportional to the
intensity of light falling on its p-n junction. This means that greater the intensity of light falling on the p-n
junction of photo-diode, the greater will be the reverse current.
LED: The light-emitting diode is a diode that gives off visible or invisible (infrared) light when energized.
In any forward-biased p – n junction there is, within the structure and primarily close to the junction, a
recombination of holes and electrons. This recombination requires that the energy possessed by the
unbound free electrons be transferred to another state. In all semiconductor p – n junctions some of this
energy is given off in the form of heat and some in the form of photons.
Some useful
links
FOR TYPES OF DIODES:
https://www.electrical4u.com/diode-working-principle-and-types-of-diode/
https://www.allaboutcircuits.com/video-lectures/diode-characteristics-
circuits/
https://www.khanacademy.org/science/electrical-engineering/ee-
semiconductor-devices/ee-diode/v/ee-diode
FOR BREAKDOWN:
https://www.youtube.com/watch?v=EzlSafjMltc