AVA S.p.A.

Via Salaria 1313/c

00138 Roma (Italy)

SAFETY DATA SHEET

CE 1272/2008 Regulation

AVOIL SE-LT

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY

1.1. Substance Identification
Product Name: AVOIL SE-LT
1.2. Substance Use
Application: Secondary emulsifier with low toxicity for OBM
1.3. Company Identification
Name: Ava S.p.A.
Address: Via Salaria 1313/C
City/Country: 00138 ROMA (Italy)
Phone numbers: +39 06 885611386 / +39 06 885611324 / +39 06 8856111
Fax: +39 06 8889363
1.4. Emergency Phone Numbers
+39 06 885611386 +39 06 885611324 +39 06 8856111
1.5. Responsible Person E-Mail Address
e-mail: laboratorio.roma@newpark.com

2. HAZARDS IDENTIFICATION
2.1. Substance/Mixture Classification
Indication of hazards specific for human health and environment:
THE SUBSTANCE/MIXTURE IS CLASSIFIED AS DANGEROUS IN ACCORDANCE TO FOLLOWING REGULATIONS
Classifications according to CE Regulation n. 1272/2008 - (CLP)

Skin Sens. 1
GHS07
H317: May cause an allergic skin reaction

Classification according to Directive 67/548/CEE (DPP) or Directive 1999/45/CE (DSP)

Xi - Irritant R43: May cause sensitization by skin contact

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2.2. Label Elements

Label according to CE Regulation n. 1272/2008 (CLP)

Hazards Identification: GHS07

Skin Sens. 1
H317: May cause an allergic skin reaction
P261: Do not breathe dust/fume/gas/mist/vapors/spray
P272: Contaminated work clothing should not be allowed out of the workplace
Precautionary
P280: Wear protective gloves/ protective clothing/eye protection/face protection
Statements:
P363: Wash contaminated clothing before reuse
P333+P313: If skin irritation or rash occurs: Get medical advice/ attention
Disposal P501: Dispose of contents/container to an approved waste disposal plant
2.3. Other Hazards
---

3. COMPOSITION / INFORMATION ON INGREDIENTS

3.1. Chemical Properties of Substance or Mixture
Composition: Mixture
Contains: As per following table
Chemical nature: Static accumulator
Molecular Formula: ---
EC Number: ---
UN Number: ---
REACH Number: ---
3.2. Hazardous Components
Hazard
Name CAS No. EC No. Quantity Classification Symbols
Statements
Fatty acids, tall-oil,
reaction products with
diethylenetriamine,
maleic anhydride, H317
tetraethylenepentamine 68990-47-6 273-601-0 70-80% Skin Sens. 1
and
GHS07
triethylenetetramine
REACH No. 01-
2119496070-42-XXXX

Hydrotreated
64742-47-8 265-149-8 5-10% Asp. Tox. 1 H304
petroleum distillates
GHS08
(2-
Methoxymethylethoxy) 34590-94-8 252-104-2 15-25% --- --- ---
propanol

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4. FIRST AID MEASURES

4.1. Description of First Aid Measures
In case of diseases, get medical attention. Show to the doctor this Material Safety
General information:
Data Sheet
Move to fresh air. If symptoms persist, call a physician. In case of shortness of breath,
Inhalation:
give oxygen
Take off contaminated clothing and shoes immediately. Wash off immediately with
Skin contact: plenty of water. Wash contaminated clothing before re-use. If skin irritation persists,
call a physician
Flush eyes with water at least 15 minutes. Get medical attention if eye irritation
Eye contact:
develops or persists. Remove contact lenses
Do not induce vomiting without medical advice. Never give anything by mouth to an
Ingestion:
unconscious person. Consult a physician if necessary
Other information: N.a.
4.2. Main symptoms and effects, both acute and delayed
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat,
Symptoms: airways), lung irritation, central nervous system depression (dizziness, drowsiness,
weakness, fatigue, nausea, headache, unconsciousness), lack of coordination
confusion, irregular heartbeat, narcosis (dazed or sluggish feeling), convulsions and
coma
4.3. Indication of any immediate medical attention and special treatment needed
Medical surveillance during job not required. In case of disease or accident, consult
Medical surveillance:
immediately a doctor and show him this MSDS
Special intervention means: ---

5. FIREFIGHTING MEASURES
5.1. Extinguishing Media
Precautions in case of fire: In case of fire respect following instructions:
Suitable extinguishing media: In case of fire use ABC powder, carbon dioxide (CO2), dry chemical, water mist
Unsuitable extinguishing media: Halons
Hazardous thermal Amines, carbon dioxide and carbon monoxide, hydrocarbons, nitrogen oxides
decomposition products (NOx)
In the event of fire, wear self-contained breathing apparatus. Use personal
Special fire-fighting equipment:
protective equipment
Keep containers and surroundings cool with water spray. Prevent fire
extinguishing water from contaminating surface water or the ground water
Additional information:
system. Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations

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6. ACCIDENTAL RELEASE MEASURES

6.1. Personal Precautions
Wear personal protective equipment (gloves, glasses and coverall). Persons not
Protective equipment: wearing protective equipment should be excluded from area of spill until clean-
up has been completed
Emergency procedures: Prevent further leakage or spillage if safe to do so
6.2. Environmental Precautions
Contain spillage with non-combustible absorbent material, (e.g. sand, earth,
Containment media:
diatomaceous earth, vermiculite)
Contain spillage, and then collect with non-combustible absorbent material,
Containment methods: (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for
disposal according to local / national regulations
Additional information: Keep in suitable, closed containers for disposal

7. HANDLING AND STORAGE

7.1. Precautions for Handling
Do not breathe vapors or spray mist. Provide sufficient air exchange and/or
Precautions for handling: exhaust in work rooms. Avoid exceeding of the given occupational exposure
limits
7.2. Precautions for Storage
Storage conditions: Keep away from heat and sources of ignition
Storage area specifications: Store in a dry and well- ventilated areas
Containers specifications: Store in original container. Keep container tightly closed
Incompatibility: Stable under recommended storage conditions
7.3. Particular Uses:
Particular uses: N.a.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Exposure Limits
Substance (methyl-2-methoxyethoxy) propanol CAS No. 34590-94-8
TLVCeling: ---
3
TLVTWA: 50 ppm 308 mg/m
TLVSTEL: ---
Biological limit: ---
8.2. Professional Exposure Controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to
Plant protections: maintain exposure below level of overexposure (from known, suspected or
apparent adverse effects)
Collective protections: General ventilation is required, eyewash station and safety shower nearby
When workers are facing concentrations above the exposure limit they must use
Respiratory:
appropriate certified respirators
Individual Eyes: Safety glasses with side-shields
protections:
Hand: Wear resistant gloves such as: nitrile rubber, butyl-rubber
Body: Full body protective coverall and safety shoes
8.3. Environmental Exposure Controls
Exposure Scenarios: Prevent further leakage or spillage if safe to do so

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9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. General Information
Form: Liquid
Appearance: Liquid
Color: Dark amber
Odor: Characteristic
Olfactory threshold: N.a.
9.2. Information about Health, Safety and Environment
pH: N.a.
Melting point: N.a.
Boiling temperature: > 65°C
Flash point: > 65°C
Flammability (solid, gas): N.a.
Auto ignition temperature: N.a.
Decomposition temperature: N.a.
Danger of explosion: N.a.
Upper flammability limit: N.a.
Lower flammability limit: N.a.
Vapor pressure: N.a.
Density at 25 °C: N.a.
Apparent density (20°C): N.a.
Relative density: N.a.
Vapor density: N.a.
Evaporation rate: N.a.
Solubility in water (20°C): Insoluble
Distribution coefficient (n-Octanol): N.a.
Viscosity (40 °C): N.a.
9.3. Other Information
Other information: N.a.

10. STABILITY AND REACTIVITY

10.1. Reactivity
Conditions to be avoided: Do not allow evaporation to dryness. Heat, flames and sparks. Exposure to air
10.2. Chemical Stability
Acids, aluminum, Oxygen, salts of strong bases, strong bases, Strong oxidizing
Incompatible materials:
agents, strong reducing agents
Possibility of dangerous reactions: Stable under recommended storage conditions
10.3. Hazardous Decomposition Products
Aldehydes, Amines, carbon dioxide and carbon monoxide, Hydrocarbons,
Other information
nitrogen oxides (NOx), ketones

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11. TOXICOLOGICAL INFORMATION

11.1. Acute Toxicity
Substance Hydrotreated petroleum distillates CAS No. 64742-47-8
Acute oral toxicity: LD50 (Rat): > 8000 mg/kg
Acute inhalation toxicity: LC50 (Rat): > 2500 ppm, 4h
Acute dermal toxicity: LD50 (Rabbit): > 4000 mg/kg
Substance (methyl-2-methoxyethoxy) propanol CAS No. 34590-94-8
Acute oral toxicity: LD50 (Rat): > 5000 mg/kg
Acute inhalation toxicity: LC50 (Rat female) 8h: > 553 ppm
Acute dermal toxicity: LD50 (Rat): > 5000 mg/kg
Mixture
Acute oral toxicity: N.a.
Acute inhalation toxicity: N.a.
Acute dermal toxicity: N.a.
11.2. Corrosively
Skin: N.a.
Eyes: N.a.
11.3. Primary Irritability
Skin: N.a.
Eyes: N.a.
11.4. Harmfulness
Ingestion: N.a.
Inhalation: N.a.
11.5. Sensitization
Skin: N.a.
Eyes: N.a.

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12. ECOLOGICAL INFORMATION

12.1. Toxicity
Fatty acids, tall-oil, reaction products with diethylenetriamine, maleic anhydride,
Substance
tetraethylenepentamine and triethylenetetramine CAS No. 68990-47-6
Toxicity in the water: LC50 (Fish) 96h: >100 mg/l
Toxicity in the air: N.a.
Toxicity in the soil: N.a.
Substance (methyl-2-methoxyethoxy) propanol CAS No. 34590-94-8
LC50 (Fish) 96h: > 10000 mg/l
Toxicity in the water: LC50 (Daphnia magna) 48h: 1919 mg/l
EC50 (Alga) 72h: > 969 mg/l
Toxicity in the air: N.a.
Toxicity in the soil: N.a.
12.2. Persistence and Degradability
Other information: 75 %, Exposure time: 28 days
12.3. Bio cumulative Potential
Other information: The bioaccumulation potential cannot be determined
12.4. Mobility in Soil
Other information: N.a.
12.5. Results of PBT e vPvB Assessment
PBT: N.a.
vPvB: N.a.
12.6. Other Adverse Effects
Other information: N.a.
Mixture
Toxicity in the water: N.a.
Toxicity in the air: N.a.
Toxicity in the soil: N.a.
12.7. Persistence and Degradability
Other information: N.a.
12.8. Bio cumulative Potential
Other information: N.a.
12.9. Mobility in Soil
Other information: N.a.
12.10. Results of PBT e vPvB Assessment
PBT: N.a.
vPvB: N.a.
12.11. Other Adverse Effects
Other information: N.a.

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13. DISPOSAL CONSIDERATIONS

13.1. Waste Treatment Methods
Dispose of in accordance with the European Directives on waste and hazardous
waste. Do not contaminate ponds, waterways or ditches with chemical or used
Advices
container. Container hazardous when empty. Dispose of in accordance with
local regulations
Waste code: N.a.
13.2. Packaging Disposal Methods
Empty remaining contents. Dispose of as unused product. Empty containers
should be taken to an approved waste handling site for recycling or disposal.
Advices:
Do not re-use empty containers. Do not burn, or use a cutting torch on, the
empty drum
Other recommendations: N.a.

14. TRANSPORT INFORMATION

14.1. Land/Rail Transport (ADR/RID)
UN Number: No dangerous goods under transport regulations
UN shipping norms: N.a.
Hazard class: N.a.
Packaging group: N.a.
Official transport name: N.a.
Gallery restriction code: N.a.
14.2. Maritime Transport (IMDG)
UN Number: No dangerous goods under transport regulations
EMS Number: N.a.
Danger class: N.a.
Packaging Group: N.a.
Marine pollutant: N.a.
Official transport name: N.a.
14.3. Air Transport (ICAO-TI and IATA-DGR)
UN Number: No dangerous goods under transport regulations
ICAO/IATA Class: N.a.
Label: N.a.
Packaging group: N.a.
Official transport name: N.a.
14.4. Bulk Transport
Annex II of MARPOL73/78: No dangerous goods under transport regulations
IBC Code: N.a.

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15. REGULATORY INFORMATION

15.1. Health, Safety and Environment Regulations/Legislation Specific for the Substance or Mixture
D.Lgs. 3/2/1997 n. 52 (Classification, packaging and labeling of hazardous substances)
D.Lgs. 14/3/2003 n. 65 (Classification, packaging and labeling of hazardous mixtures)
D.Lgs. 2/2/2002 n. 25 (Risks due to chemical agents during the work)
D.M. Lavoro 26/02/2004 (Professional exposure limits)
D.M. 03/04/2007 (Implementation of the Directive n. 2006/8/CE)
CE Regulation n. 1907/2006 (REACH)
CE Regulation n.1272/2008 (CLP)
CE Regulation n.790/2009 (adaptation to technical and scientific progress of CLP Regulation)
CE Regulation nº 453/2010 (Modification of REACH Regulation)
Directive 1999/45/CE (DSP)
Directive 67/548/CEE (DPP)

16. OTHER INFORMATION

16.1. Main Bibliographic Sources
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition – Van Nostrand Reinold
ACGIH - Threshold Limit Values - 2009 edition
16.2. Declarations
This sheet completes the technical bulletin without to substitute it. The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication.
The information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
This material safety datasheet only contains information relating to health and safety. The product has to be used in applications consistent with
AVA technology. Individuals handling this product should be informed of the safety precautions and should have access to this information.
This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU.
This MSDS cancels and replaces any preceding release.
16.3. Abbreviations and Acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
GHS: Globally Harmonized System of Classification and Labeling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
ACGIH: American Conference of Industrial Hygienists
EC50: median effective concentration
LC50: median lethal concentration
LD50: median lethal dose
NOEC: no observable effect concentration
PNEC: predicted no-effect concentration
PBT: persistent, bio accumulative, toxic chemicals
vPvB: very persistent, very bio accumulative chemicals
TLV-TWA: Threshold limit value – Time weighted average; professional exposure limit average on 8 hours
TLV-STEL: Threshold limit value – Short Term exposure limit ; professional exposure limit at short term
TLV–C : Threshold limit value – Ceiling

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16.4. Other Information

Full text of hazard phrases used in the previous sections
H304: May be fatal if swallowed and enters airways
H317: May cause an allergic skin reaction
R43: May cause sensitization by skin contact
R65: May cause lung damage if swallowed
Full text of Precautions / safety phrases used in the previous sections
P261: Do not breathe dust/fume/gas/mist/vapors/spray
P272: Contaminated work clothing should not be allowed out of the workplace
P280: Wear protective gloves/ protective clothing/eye protection/face protection
P363: Wash contaminated clothing before reuse
P333+P313: If skin irritation or rash occurs: Get medical advice/ attention
P501: Dispose of contents/container to an approved waste disposal plant

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