Electro Chemistry Pyq
Electro Chemistry Pyq
Vey
wsed m
cell whick was
N ame e type o C202)
me
A M-O2 ekecokssC2015s)
manb amoumt of
h 63kange ICumet
2 It aFfrockeccal eyuivalkent
i e Galvance cell in wkick he eatthow
Repusent place
2ca) + Cacs) take
ZnCs)+ C"caay) C203
2
Ans c a y ) lats)
Zn 2 Ca Catloole
Anode S
C 20S
Secondaty battesies
Deine bateues
wKick can be
As tRose Kougk
Th
They ane
pastng
eleubuic
cunent
wheek is bet
A and B ptedict
sing
Usong E value o
6 the sumbace o inonvent tonoion
Cnol Wk
coakng
- 0.44v] o pre -0.4V (2o
20
=
(B°"/BJ=
LECFe/e)
s-2.37
v
¬
ECAYA) potential wlR
be
eowen aeducton
Ans Metal Kaving ow a e d u i o n
A kaving
dnsed fust. Metal protet
i ë fao
0 connected
with uon
potekal pken
oaation amd pMevent
luD SLon
tomm
T Deme bheMolor conductvity CAm)
C2o15
males x 16soo
2 19300o C
Foel mg seaaon at cathode dning he
Occm
4 chlaide solcton
eke bosis o aaueous sibver 20IS)
o.80 v E
tv
Agcan) t e A
potentak CE
redutuon elo chode
and
On basis
Ch ob thuin stanol at CaMode aud Whz
basis of at
aibon iu feosle occn
kick se potential
neduton
Ans 2 E cellt.Iv
x llv
- 2x96Soo
300 J maL"
-212
-2/2.3 kImol
12 Wite the mame o Eie cell whick u genesall
used m inv entens. Wute Re Aeacions takinga
tkis cL. (20!t)
at the anode and tte catkode of
kace
Ans Lead stocage batey
Cs)+2e
At anoode P Pb SO4
Pb Cs t
So can)
Pb So Cs)
At Catkode Cayt4H*2e
So
Pbo Cs)+ +2H,oR)
Calcwlate the degsee o dissociation Co) o
Q13
aceb ociol us Molar condutivity CAm) 34.0S s
= 341 68 Sem mol C2014)
Gwen CH)
AC.CHCoo") 40.9 Scmm
* H + CHcoo3 9 0 . 5 8
390.58 Semmoe'
Stmmoe'
6?+40.4
341.66
390S8
34.0 o.
O.
G Pse dict the poduct of elecholpis of an aaueons
s0utron oh u2 wtk platnum
ekeutode
+0.34v E cu/ce) L36
Civen Ec/u
C2020
E / H o ) = l 2 3 v
:0.00V
t/Ha>, Pt
neauuDn
Calthoode Tuuo pos ULe
Aws At
Cu Cs)
Ht+e
t 2e Aeduvb
be daposted because t kas lekea Potentink
L
Coppe 4Ht+2e"
o,
2 t2e 2H.o
Atamode will be prefned
bht
eleubroake potential 4
Lowe KXadne aas
due o oveg potentiol o ouaen,
Libuateol
CIS b ime Condusbivity and Molan conduchivit bn ke
cuss ils vaiaton
wth
0lubon an eletolyte Dis
C201S)
Concentation?
k x k*
o l Cn leng
A k deneot a s secion
Condustamue
Wik
A Y weakelostoy.
dusociaon
dikaton the degaee Am
tARase m
Aes l ëm
m
mRe ases, mlaa londhuuvu
mmbea lons am
ndeoses steep
ekectoly onl small wudilutan
Stong Candutbnit
mhease
im mo lan doeshotkanse
nunmbea d ions C COmpletedusoir
becae
18 Calculate theo Aa deposited im Catfode
mam
obuon
when a Cnent o6 2A was pamed hougk
mamdAs- lodg w
Ag Nos n IS minubs chwen Molau
96Soo C m L2011
F
T:2A t S minuts
Ars ISa6o 9 oo seonod
6soOc lo83 4
ckange C8) [xT
2x90o
c o8
18o0C 16So
A+le Az
IMole
6soo
t
s aequu eol
vbicity
F oh ele deposit Inke KAg
gla Wade the mame o cell whick i genenalled n
hlaute tRe zeactions taling ploce at omode
kronsislin C2017)
amo catkode o his cele?
Ans Leclamche cetl Cbiyue)
At cabkoole NH
MnoCOH)+
MnatNH+
020 The 0.2 M olutnon k at 298k
20 Conduetivity o
s 0.025 S t . Colul ate te molon conducaitg
(2013
Ans k 0.025
Molasity 0.2M
kx looo
Molan condundivil
-
CAm) M
O.02 S xlodo
.2
2
n o -
12SS Om
(3m0nks )
Skort anses tupe I Guesiow
ehe cell et 248k
.21 Calcul ate EME
HC0.0IM)| HcgClba)|Pt6.
feCo.001M) || og 3 O.u4#1
Fe()| loa 3s
O.4
*(2022)
0.44V oq2 0.3010
hiven kat Ecell
Cell e a u i o r
A 2 H}?
Fe c t c a y
feco
lo
029s os o-
0.4-0.
Ecell-o.44V
ogc
Ecel E cell-o0S o.44-0.0245
o44-.0a 0.4loSv
0.44-
0.0215 og lo
022 The eleutical resstante ofcoumn o 0.0S M KDH
a
oluton o lengtk 500m amd ane a o uos se cton
3
CakonLate sesistiuita,tondutiya
0.625 oms 5xio*n C2020)
amd Moklaa conduutntt O.05M
Molamity
a = 0.62Som
Ans Conduetiei
R: 5x lo'n 62sO.016
nr'e'
L: 5oCm S 0.016S h
o
R tondutndz kXloc
Molor M
O.016 Aloo
0.oS
50
Resustuit 62.5 Um
823 Chromium metal u ele thopkated using an
acidiu
4oatuon onkaiming uoz acuonding to followmg enjuaiuon
&ts) +34,
aO3 Co) t 6H1+6e ele cto pkated b,.
Calculate am of clromimum l be
eletoplatu"1.
wiL it take to
b. How long 52q mal
2y000 wulom CAtomumas a
:
6x 96SooC: 524 52
52
1 6x1650ox.S
lc G x 9 6 SObo 52
te vibtakon of
tame
mcxease o s8 dogree 3
witk d l u i o n
because
actot
O.IM a cetii amd mumber
toh inae aA
disoiakon mene o m s
Onu mobie tes
a t 5o°e
kCR s 0 u o n
a r e tn
temperaiue
n h e asms wik mise
%2 S FOR tRe zeatuon
2Ages) H,2) t
Clatn) 2Agts)t t 24'Co./M)t2 to.(M)
G: T at 2Sc
-43600
(2018)
thetee?
Emf o
Cakculate Co.IM)+2u Co.I
Clatn) 2AgCs) +24t
As 2Ag lco +H,C2)
A G - n f E c e l e
0.226-0.OS1x-2
C2013
Lonu
condukrity of AL 3t 2
m AR +3 Am So
As Am AR,So, 2
3x 16o
AR+
858 2 Am
858-18o
3t
2 Am AR
AmAQ 328
1 8 9 sCmmo2
G27 Wauto luo odvamtage o H-o2 fuelcell o'
neathon (2ol4)
Ndonoay cell Explaun eleckode
AW OT Kas kigk 6iee astson aus
be use o by
cam
H o poolueeol
a dainkuna P >4H,OLL)+
Ge
+ 4oHcaa)
» 2 H,C)
At amode 40H CO)
Ca)
aHo+4e
>4OH
At Catkode
>
O
C)2HOC)
Ovall
a"Ca) +o
eashos
cetl. What Keppen i
28 Deme elesto themicak ha
beuomes reai
extemal potentad appheot (2016)
elerkockemicalcoll?
E cetl o chemmcal
Conv eat
at cam
onea
s
As The device o eletucal
chemical se auton
negy o
Caled electockemwcal celk. tha
bteomes gaeatr
exteemal voltoge cunent
i sevesed
o {low o
-
dureckion
he
E cell, eleutolt Cell.
bekave as
amd tell
029 Wen a stead Cunent o 2A was pamed rougk 2n so,
KuD elecbhokyto tole A omdB Contaunena elethoky catkode
keposiftct at
amd u SO4 connecte iw seues. 29
Cament {low. catkode Cell A
HOw long d d a t
3 2n
deposukeol
ws
az63.Sa
m)
What m ama CAtomic
mam
(2020)
Mas2Eauivalont wegkt 2a
Cu+2e" ^ a
Mas Eauivalent weiskt4
A
m 2 xIxT|
m Mx IXT 6S/2
33.572
Zn 6SX 2
2 6 3 S x 2 x 7
2 96so0o
63.S
T 2x96Soo 3o3
63.
8Uona
2.0
330 The tondutinity 0.20 molld goluduon of ll L s
ano
2.48x15*S Cm Calculate ts molan conduutnity
degree disociation Cor) sem-matand x W: 76s Sa he
S (207)
wea (k 1) 73.
k 2.111oSnm'
AN
Molaity o.20 molL'
73.S t F6.S
S C m e l "
Am kxlodo
M
2 . 4 x / o
x1ooo X: Am 24
O.2
24 SCmmel 0.82