SALT NUMBER -4 LEAD ACETATE

Preparation of salt solution:

To a small amount of salt in a test tube added 2to3ml of water,shake it if not dissolved heated gently
this solution is called“originalsolution”or salt solution
ANALYSIS OF CATION
GROUP ZERO
1ml of the original salt solution add No chocolate brown ppt is
1 ed about 1ml of NaOH solution and Absence of ammonium
formed.
heated,followed by addition of Ion.
Nesslers reagent.
GROUP I
Take about 1 ml of the salt solution in
a test tube Added about 1mL of dil Presence of 1st group
2 A White ppt is formed.
HCl,and shake it metal ion(Pb2+)
Conformation of lead ion
 Test for Lead:
To salt solution added about iml of
1 K2CrO4 A yellowppt is obtained Presence o fLead

To another portion of the solution added

A yellow ppt is
about1ml of KI.To they ellow ppt add ed
obtained.Theyellow ppt
about 1ml of water,boil and cool.
dissolves on boiling , and on Presence of lead is
2
cooling golden spangles confirmed.
appeared

RESULT-The given salt is LEAD ACETATE

SYSTEMATIC ANALYSIS OF SIMPLE SALT-5[COPPER SULPHATE]

SNO Experiment Observation Inference

Analysis of anion
Colour: May be copper
1 Noted the colour of the salt Blue
sulphate
Action of heat:
A small amount of a salt is heated in a Blue Changes intoWhite Maybe copper
2.
tes ttube duetodehydration sulphate

Action of dil.H2SO4 Absence of

3 Small amount of salt+1mL of No Charactristic gas evolved Carbonate,Nitrate,A
dil.H2SO4 CETATE
ActionofConc.H2SO4:
Small amount of a sal tin a Absence of
4 drytesttube+Conc.H2SO4and gently No Charactristic gas evolved
Chloride,Bromide,
heated. Nitrate
Due to absence of ions in dil H2SO4 and Conc H2SO4 ,it may be an independent ion
Testwithbariumchloride:One ml of A white ppt insoluble in
the salt solution + dil. Acetic acid+ 1ml dil H2SO4 is formed
Prsence of sulphate is
5 of
Barium chloride solution and mixed Confirmed.
Test with lead acetate:
1ml of the salt solution A whit ppt soluble in
6 + 1ml of dil acetic acid and heat it + 1ml of excessofammonium acetate Presence of sulphateis
Lead Acetate added isf ormed confirmed
Preparationof saltsolution:
To a small amount of salt in a test tube added 2to3ml of water,shake it if not dissolved heated gently this
solution is called“originalsolution”or salt solution
ANALYSIS OF CATION
 GROUP ZERO
1ml of the original salt solution add ed No chocolate brown ppt is
about 1ml of NaOH solution and Absence of ammonium
obtained.
heated,followed by addition of Nesslers
reagent.
GROUP- I
Take about1ml of the sal tsolution in a Absence of 1st group
2 test tube Added about 1ml of dil HCl,and No ppt is formed.
metal ion (Pb2+)
shaked it
GROUP -II
To the above solution added sodium Presence of 2nd group
3 sulphide solution, A Blackppt is formed
metal ion(Cu2+)

Analysisof II group ion

Test for copper:

i). To one portion of the solution added No ppt is obtained, but the
1 Presence of Copperion
ammonium hydroxide solution is blue
ii) To the blue coloured solution added
about 1ml each of acetic acid and
Presence of Copper
potassium ferro cyanidesolution. A red brown ppt is
Confirmed
obtained(chocalate brown ppt)

Result:
The AnionPresent :
SULPHATE ThecationPresent
:COPPER
TheGivensimplesalt : COPPERSULPHATE
SYSTEMATICANALYSISOFSIMPLESALT-6 [COPPER CHLORIDE]

Experiment Observation Inference

Analysisofanions

Colour: May beCopper

Note thecolour of the salt Green salt
Chloride
Action of dil.H2SO4 no colourless, odourless gas
Small amount of salt+1mL of evolved as a brisk Effervescence Absence of carbonate
dil.H2SO4 is added and turns limewatermilky

ActionofConc.H2SO4: A colourless gas evolves. It Prsence o fChloride

Small amount of a salt in a dry test gives a dense white fumeswhen
tube+Conc.H2SO4and gently heated a glass rod dipped inliquid
ammonia is brought close to its
mouth
To the salt solution added dil HNO3
Silver White ppt appeared Presence of chloride
nitrate followed by silvernitrate solution confirmed
test
Preparation of salt solution:
To a small amount of salt in a test tube added one ml water shake gently this solution is
called“originalsolution”or salt solution
ANALYSIS OF CATION .
GROUP ZERO
1ml of the original salt solution add ed No chocolate brown ppt
1 about 1ml of NaOH solution and Absenceofammonium
isobtained.
heated,followed by addition of Nesslers
reagent.
GROUP I
Take about1ml of the salt solution in a Absence of 1st group
2 test tube Add about 1ml of dil HCl,and No ppt is formed.
metal ion (Pb2+)
shaked it

GROUP II
To the above solution 1 ml of Presence of 2nd group
3 sodiumsulphide solution is added. A Black ppt is formed
metal ions(Cu2+)

Analysis of copper ion

Test forcopper:
i). To one portion of the solution added No ppt is obtained, but the
1 Presence of Copper
ammonium hydroxide solutio nis blue

ii) To the blue coloured solution added

about 1ml each of acetic acid and
Presence of Copper
2 potassium ferro cyanide A red brown ppt is obtained
Confirmed

Result:
The Anion Present: Chloride
The cation Present :COPPER
TheGivensimplesalt :COPPER CHLORIDE