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    Salt Analysis-3 16/07/2021: Aim: To Analyze and Identify The Given Salt

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    Aryan Pandey
    The document analyzes an unknown salt through a series of tests. Preliminary examination showed the salt is colorless, soluble in water and dilute HCl. Tests for anions found the presence of sulfate but no other common anions. Further tests on a sodium carbonate extract confirmed the presence of sulfate. Cation analysis found aluminum and iron in the third group. Additional tests identified the third group cation as aluminum. The salt was therefore identified as aluminum sulfate.

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    Salt Analysis-3 16/07/2021: Aim: To Analyze and Identify The Given Salt

    Uploaded by

    Aryan Pandey
    24 views2 pages
    The document analyzes an unknown salt through a series of tests. Preliminary examination showed the salt is colorless, soluble in water and dilute HCl. Tests for anions found the presence of sulfate but no other common anions. Further tests on a sodium carbonate extract confirmed the presence of sulfate. Cation analysis found aluminum and iron in the third group. Additional tests identified the third group cation as aluminum. The salt was therefore identified as aluminum sulfate.

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    The document analyzes an unknown salt through a series of tests. Preliminary examination showed the salt is colorless, soluble in water and dilute HCl. Tests for anions found the presence of sulfate but no other common anions. Further tests on a sodium carbonate extract confirmed the presence of sulfate. Cation analysis found aluminum and iron in the third group. Additional tests identified the third group cation as aluminum. The salt was therefore identified as aluminum sulfate.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    24 views2 pages

    Salt Analysis-3 16/07/2021: Aim: To Analyze and Identify The Given Salt

    Uploaded by

    Aryan Pandey
    The document analyzes an unknown salt through a series of tests. Preliminary examination showed the salt is colorless, soluble in water and dilute HCl. Tests for anions found the presence of sulfate but no other common anions. Further tests on a sodium carbonate extract confirmed the presence of sulfate. Cation analysis found aluminum and iron in the third group. Additional tests identified the third group cation as aluminum. The salt was therefore identified as aluminum sulfate.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 2

    Salt analysis-3 16/07/2021

    Aim: To analyze and identify the given salt.


    1.Preliminary Examination
    S.N Experiment Observation Inference
    1. Colour and appearance of the Colourless Absence of salt of
    mixture is noted. Cu, Fe, Co, Ni and
    Mn...
    2. Solubility- A very small amount
    of mixture is warmed with
    following solvents in
    succession.

    a) In water Soluble completely or Absence of NH4+


    partly and the soluble
    portion gives ppt. with
    Na2Co3.

    b) In dil. HCL soluble Absence of 1st


    group cations.

    Preliminary of anions
    S.N Experiment Observation Inference
    1. Action with dil.H2SO4 No characteristic observation Absence of CO32- , S2-
    About 10 mg of [SO32-], NO2-] and
    substance is taken in . acetate
    the test tube and
    dilute H2SO4 is added
    and warm if no
    reaction is seen.
    2. Action of Conc.H2SO4 No characteristic observation Absence of chloride ,
    About 10mg of the bromide , iodide,
    substance is warmed nitrate, acetate and
    with about 0.5 ml of oxalate
    conc.H2SO4

    .
    Preparation of Na2CO3 – Extract
    About 5 mg of the substance and 15 mg of Na2CO3are taken in a china dish, distilled water is added in
    excess and boiled for 15 minutes on heating block, adding distilled water at intervals to take up for the loss
    of evaporation. The ppt. is removed by centrifugation and clear centrifuge known Sodium carbonate extract
    contains the anions as the sodium salt together with the excess of Na2CO3 . As a result of the reaction, the
    cations are eliminated as insoluble carbonates, basic carbonate hydroxide and oxide

    Systematic test for anions


    S.N Experiment Observation Inference
    1. Few drops of Na2CO3 extract White ppt. insoluble in Presence of sulphate is
    prepared is acidified with conc. mineral acid. confirmed. (SO42-)
    HCl and boiled to expel CO2,
    centrifuged if needed. To clear
    solution a few drops of BaCl2
    Solution is added.
    2 To about 1 ml of the extract add White ppt. Presence of SO42 is
    acetic acid and lead acetate soln. confirmed.

    Original solution: The salt is soluble in water so a solution of salt in water


    is taken as o.s.
    Intergroup separation of Cations:
    S.N Experiment Inference
    1. About 1 mg of the substance is dissolved in water. To No Residue. Group 1st
    the above solution dilute HCL is added and centrifuged. cation absent.
    2. Centrifugate- (should not give ppt. with dil.HCL) No Residue. Group 2 cation
    warmed and H2S is passed till precipitation is complete absent.
    if any and centrifuged.
    3. Centrifugate- H2S is boiled off. Add a few drops of con. Residue. Group 3rd Fe3+ and
    HNO3 .Heat and cool the mixture. Solid NH4Cl and Al3+, reddish brown, white
    excess of NH4OH Soln are added and centrifuged. gelatinous respectively.

    Analysis of Group 3rd Cations.


    The group 3rdppt is dissolved in 1 ml of dil.HCl and divided into two portions.
    Test for Al3+
    The Group 3rd ppt. is divided into 3 parts.
    S.N Experiment Observation Inference
    1. Take test 1st part is dissolved in Formation of Blue Presence of Al3+ is
    minimum quantity of dil. HCl. To floating ppt. confirmed.
    this add few drops of litmus Soln.
    2. The 3rd part of the ppt. is A white gelatinous ppt. Presence of Al3+ is again
    dissolved in minimum amount soluble in excess of confirmed.
    of dil. HCl and NaOH is added NaOH solution
    drop by drop into excess.

    Result :The given salt contains sulphate as anion and Aluminium as cation so it is
    Aluminium sulphate.

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