CHEM X ICSE Sulphuric Acid

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FALGUNI MISS

CHEMISTRY SUMMARY

10. SULPHURIC ACID 2022 – 2023.

 Scope:
 Large scale preparation
 Dilute acid properties.
 Concentrated acid properties: As an oxidizing agent, oxidation of
carbon & sulphur; as a dehydrating agent: dehydration of sugar &
copper [II] sulphate crystals and non‐volatile nature.

 Sulphuric acid: Oil of vitriol.

 Occurrence: Present in minute traces in hot springs, near sulphide beds, in


metallic sulphate salts.

 Preparation of sulphuric acid:



 S + 6HNO3 → 6NO2 + 2H2O + H2SO4
 Cl2 + SO2 + 2H2O → 2HCl + H2SO4
 SO3 + H2O → H2SO4
 SO2Cl2 + 2H2O → H2SO4 + 2HCl

 Concentrated Acid properties:


 Pure or concentrated H2SO4 is poorly ionized.
 Thermal decomposition H2SO4 yields nascent oxygen [O] which helps
in oxidation.
 Conc. Sulphuric acid behaves like a strong oxidizing agent, strong
dehydrating agent and non‐volatile acid.
1. H2SO4 is a Strong Oxidation Agent:
Reacts with metals, non‐metals, inorganic substances:
Non‐Metals: C + 2H2SO4 (conc.) → CO2 + 2H2O + 2SO2
S + 2H2SO4 (conc.) → 3SO2 + 2H2O

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2P + 5H2SO4 (conc.) → 2H3PO4 + 2H2O + 5SO2
Metals: Cu + 2H2SO4 (conc.) → CuSO4 + 2H2O + SO2
Zn + 2H2SO4 (conc.) → ZnSO4 + 2H2O + SO2
Inorganic 2HI + H2SO4 (conc.) → I2 + 2H2O + SO2
compounds: H2S + H2SO4 (conc.) → S + 2H2O + SO2
2. H2SO4 is a non‐ Due to its high boiling point and non‐volatile nature, it can displace
volatile acid. volatile acid from its salts.

NaCl + H2SO4 ⎯⎯⎯ NaHSO4 + HCl

KCl + H2SO4 ⎯⎯⎯ KHSO4 + HCl

NaNO3 + H2SO4 ⎯⎯⎯ NaHSO4 + HNO3

KNO3 + H2SO4 ⎯⎯⎯ KHSO4 + HNO3
3. H2SO4 is a strong H2SO4 is hygroscopic, hence behaves as a drying agent.
dehydrating agent. It has a strong affinity for water, hence removes elements of water
from a compound as well as water of crystallization from hydrated
salts, hence behaves as a dehydrating agent.
Carbohydrates:
, .
C6H12O6 ⎯⎯⎯⎯⎯⎯⎯⎯ 6C + 6H2O
, .
C12H22O11 ⎯⎯⎯⎯⎯⎯⎯⎯ 12C (sugar charcoal) + 11H2O
, .
[C6H10O5]n ⎯⎯⎯⎯⎯⎯⎯⎯ 6[C]n + 5[H2O]n
Organic compounds:
, .
H.COOH ⎯⎯⎯⎯⎯⎯⎯⎯ CO + H2O
, .
COOH–COOH (C2H2O4) ⎯⎯⎯⎯⎯⎯⎯⎯ CO + CO2 + H2O
, .
C2H5OH ⎯⎯⎯⎯⎯⎯⎯⎯ C2H4 + H2O
Hydrated salts:
, .
CuSO4.5H2O ⎯⎯⎯⎯⎯⎯⎯⎯ CuSO4 + 5H2O

 Differentiate:
 Dilute Sulphuric acid and dil. Nitric acid:
Dilute sulphuric acid. Dilute nitric acid.
Add Barium chloride solution to dil. Adding Barium chloride solution to
H2SO4, it gives a white ppt. of dil. HNO3, it gives a soluble solution
Barium sulphate. of Ba(NO3)2; and no ppt. is formed.

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FALGUNI MISS

 Dilute hydrochloric acid and Dilute sulphuric acid using lead nitrate
solution:
Dilute hydrochloric acid Dilute sulphuric acid
Add dil. HCl to colourless solution Add dil. H2SO4 to colourless solution
of lead Nitrate, it forms a white of lead Nitrate, it forms a white ppt.
ppt. of lead chloride which is of lead sulphate which is insoluble in
soluble in hot water, insoluble in hot or cold water.
cold water.

 Formic acid and oxalic acid:


Formic acid Oxalic acid
Add conc. sulphuric acid, it gives Add conc. sulphuric acid, it gives out
out a colorless gas carbon a colorless gas carbon dioxide, which
monoxide, which burns in air with turns lime water milky.
a blue flame to form carbon
dioxide.
NH4Cl + NaOH → NaCl + H2O + NH3 KCl + NaOH →NaCl + KOH

 Dil. sulphuric acid from dilute HCl and dilute HNO3:


Dil. sulphuric acid Dil. HCl Dil. nitric acid
Add ammonia gas Add ammonia gas and Add ammonia gas and
and heat the residue. heat the residue. heat the residue.
It forms ammonium It forms ammonium It forms ammonium
sulphate, which does chloride, which nitrate, which
not decompose on sublimes on heating. decomposes to form
heating. Thus can be condensed nitrous oxide (laughing
and recovered. gas) and water vapor on
heating. Thus disappears.

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FALGUNI MISS CLASSES

ACADEMIC RESULTS 2021 – 2022 – 8 ALL INDIA RANKERS

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ACADEMIC RESULTS 2021 – 2022


FIRST TERM MARKS (OUT OF 40)
FALGUNI MISS CLASSES – PTS FALGUNI MISS CLASSES - PTS FALGUNI MISS CLASSES - PTS FALGUNI MISS CLASSES - PTS

FIRST TERM ICSE STD X 2021‐22 RESULTS FIRST TERM ICSE STD X 2021‐22 RESULTS FIRST TERM ICSE STD X 2021‐22 RESULTS FIRST TERM ICSE STD X 2021‐22 RESULTS

CHEMISTRY BIOLOGY MATHEMATICS PHYSICS


81% students above 35/40
81% students above 35/40 78% students above 35/40 75% students above 30/40
40 ‐ Aarush Gupta (CNMS) 40 ‐ Omkar Vanjani (Podar)
40 ‐ Aarush Gupta (CNMS) 39 ‐ Aarush Gupta (CNMS)
40‐ Eshan Petkar (Podar) 40 ‐ Ojayit Telang (Podar)
40 ‐ Omkar Vanjani (Podar) 39 ‐ Aaryan Vaidya (Lakshdham)
40 ‐ Ojayit Telang (Podar) 40 ‐ Saakshi Bakliwal(Podar)
40 ‐ Shaina Pradhan (JNS) 39 ‐ Parth Desai (CNMS)
40 ‐ Soniya Deshpande (JNS) 40 ‐ Shaina Pradhan (JNS) 40 ‐ Shaina Pradhan (JNS)
40 ‐ Akshaya Parbhakar (Podar) 38 ‐ Ojayit Telang (Podar)
40 ‐ Atharva Deo (Thakur Int.) 40 ‐ Soniya Deshpande (JNS) 38 ‐ Omkar Vanjani (Podar)
40 ‐ Amogh (Sishya Chennai) 40 ‐ Naman Jalan (Sanskriti, Gauhati) 40 ‐ Naman Jalan ‐ (Sanskriti, Gauhati)
40 ‐ Siddhi Iyer (Ambassador, Dubai) 38 ‐ Atharva Deo (Thakur Int.)
40 ‐ Ahem Shaikh (Podar) 40 ‐ R Janavi (Gokuldham)
40 ‐ Tarush Dhamne (Podar) 38 ‐ Tarush Dhamne (Podar)
40 ‐ Ankit Basu (Cambridge School) 40 ‐ Durva Bhatt (P.G. Garodia)
40 ‐ Dia Jaiswal (AVM) 38 ‐ Atharva Surve (Ryan Int)
40 ‐ Tarush Dhamne (Podar) 40 ‐ Kannika Shetty (A.V.M)
40 ‐ Parth Desai (CNMS) 38 ‐ Nidhi Pusalkar (Prime Academy)
40 ‐ Parth Desai (CNMS) 40 ‐ Tarush Dhamne (Podar)
39 ‐ Akshata Kalyanikar (Thakur Int.) 37 ‐ Yashica (Visanji Academy)
40 ‐ Durva Bhatt (P.G. Garodia) 40 ‐ Twisha Furia (St.Gregorios)
39 ‐ Twisha Furiya (St. Gregorios) 37 ‐ Naman Jalan (Sanskriti Gauhati)
40 ‐ Nidhi Pusalkar (Prime Academy) 40 ‐ Akshata Kalyanikar (Thakur Int.)
39 ‐ Soniya (JNS) 36 ‐ Siddhi Iyer (Ambassador ‐ Dubai)
40 ‐ Yashica Kapahi (Vissanji Academy) 40 ‐ Eshna Sobti (Universal Dahisar)
40 ‐ Iqra Kazi (Podar) 39 ‐ Amogh (Sishya Chennai) 36 ‐ Aaryan Mehta (CNMS)
40 ‐ Akshata Kalyanikar (Thakur Int.)
40 ‐ Nidhi Pusalkar (Prime Academy) 39 ‐ Bhuvana Santosh (Vapii Public school) 35 ‐ Sehej Khanna (JNS)
40 ‐ Archit Desai (P.G. Garodia)
40 ‐ Yashica Kapahi (Visanji Academy) 39 ‐ Harshvardhan Agarwal (Gokuldham) 35 ‐ Durva Bhatt (P.G.garodia)
39 ‐ Keshav Agarwalla (Sanskriti Gauhati) 35‐ R Janavi (Gokuldham)
And a long list from 39 to 30 .... And a long list of 39 to 30.... 39 ‐ Ahem Shaikh (Podar) 35 ‐ Amogh (Sishya Chennai)

FALGUNI THAKKER MISS And a long list from 38 to 30...... And a long list of 34 to 30.....
FALGUNI THAKKER MISS FALGUNI THAKKER MISS FALGUNI THAKKER MISS

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ACADEMIC RESULTS 2020 – 2021 ACADEMIC RESULTS 2019 – 2020

ACADEMIC RESULTS 2003 – 2019

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