Module1 - ETS - Crystal Defects

BECE201L
Electronic Materials & Devices
Dr Arivarasi
Solidification and Crystallisation
• Hardening of materials from the casting of molten liquid/gels (metals and alloys).
• Size and shape of the structure of the material depend on its cooling rate.
• Solidification process involves the formation of nuclei and the growth of nuclei to form
grain and crystal structures.
https://www.youtube.com/watch?v=1Ou1bIDn1xE
Crystalline Defects
Point Defects
Point Defects
Point Defects in Ionic Crystals
The conduction electrons are actually moving around randomly in the metal but
as a result of the application of the electric field Ex, they all acquire a net velocity
in the x-direction
The average velocity of the electrons in the x-direction at time ‘t’ is called drift velocity
It is denoted by Vdx(t)
It is the instantaneous velocity vx in the x-direction averaged over many electrons (i.e.)
𝟏
Vdx = [Vx1 + Vx2 + Vx3 + ……. VxN]
𝑵
where, Vxi is the x-direction velocity of the ith electron.

N : Number of conduction electrons in the metal
Number of electrons crossing A in ∆𝑡
• Suppose n is the number of electrons per unit volume in the conductor (n=N/V)
• In time ∆𝑡, electrons move a distance ∆𝑥 = Vdx ∆𝑡
• The electrons within distance ∆𝑥 pass through area A
• Thus, n(A ∆𝑥 ) is the total number of electrons crossing A in time ∆𝑡

The current density in the x-direction is :
∆𝒙 𝑒 𝑛 𝐴∆𝑥 It must be appreciated that the average
Jx = = velocity at one time may not be the same
𝑨 ∆𝒕 𝐴 ∆𝑡
as at another time, because the applied
𝑒 𝑛 𝐴Vdx ∆𝑡 field, for example, may be changing:
=
𝐴 ∆𝑡
Ex = Ex(t)
Jx = e n Vdx
This general equation relates Jx to the
Therefore a time-dependent current is
average velocity Vdx of the electrons.
given by
Jx(t) = e n Vdx(t)
• To relate the current density Jx to the electric field E , the
x
effect of the electric field on the motion of the electrons in the

conductor must be examined.
• To do so, let us consider the copper crystal:
• The copper atom has a single valence electron in its 4s

subshell, and this electron is loosely bound
The mobile electrons are
• The solid metal consists of positive ion cores, Cu+, at free to respond to an
regular sites, in the Face-Centered Cubic (FCC) crystal applied field, creating a
structure current density Jx. The
valence electrons in the
• The valence electrons detach themselves from their electron gas are therefore
parents and wander around freely in the solid, forming a conduction electrons.
kind of electron cloud or gas
The attractive forces between the negative
electron cloud (valence electrons) and the Cu+
Metallic ions are responsible for metallic bonding and
bonding the existence of the solid metal.
The electrostatic attraction between the

conduction electrons and the positive metal
ions, results in the conduction electron having
both potential energy PE and kinetic energy
KE.
The mean KE of the conduction electrons in a metal is primarily determined
by the electrostatic interaction of these electrons with the positive metal ions and
also with each other
In Drude’s model, the temperature dependence of the mean KE is

Neglected
Absence of Electric Field
• In general, the copper crystal will not be perfect and the atoms will not
be stationary. There will be crystal defects, vacancies, dislocations,
impurities, etc., which will scatter the conduction electrons
• More importantly, due to their thermal energy, the atoms will vibrate
about their lattice sites (equilibrium positions)
• Over a long time, the electrons therefore show no net displacement in
any one direction.
Presence of Electric Field
• When the conductor is connected to a battery and an electric field is applied to the crystal
• The electron experiences an acceleration in the x direction in addition to its random motion, so
after some time, it will drift a finite distance in the x direction
• The electron accelerates along the x direction under the action of the force e Ex, and then it
suddenly collides with a vibrating atom and loses the gained velocity. Therefore, there is an
average velocity in the x direction, which, if calculated, determines the current as
Calculation of Drift Velocity
• To calculate the drift velocity Vdx of the electrons due to applied field Ex, let us
first consider the velocity Vxi of the ith electron in the x-direction at time ‘t’
• Suppose its last collision was at time ti; therefore, for time (t − ti), it accelerated free of
collisions
• Let uxi be the velocity of electron i in the x-direction just after the collision, called as the initial
velocity
• Since e Ex ∕me is the acceleration of the electron, the velocity vxi in the x-direction at time t will
be
• However, this is only for the ith electron. The average velocity Vdx for all such electrons
along x. The average expression for i = 1 to N electrons is given by:
• Suppose that τ is the mean free time, or the mean time between collisions (also
known as the mean scattering time)
• For some electrons, (t − ti) will be greater than τ, and for others, it will be shorter
Averaging (t − ti) for N electrons will be the same as τ
• Thus, we can substitute τ for (t − ti) in the previous expression to obtain
The drift velocity increases linearly with the applied field. The constant of
proportionality eτ ∕ me has been given a special name and symbol. It is called the drift
mobility μd, which is defined as
Vdx = μd Ex
where,
μd = eτ / me
From the expression for the drift velocity Vdx , the current density Jx follows
immediately by substituting
Vdx = μdEx
into
Jx (t) = e n Vdx (t)
Jx = e n μdEx
Therefore, the current density is proportional to the electric field and the
conductivity σ is the term multiplying Ex, that is,
σ = e n μd
Problem #1
Calculate the drift mobility and the mean scattering time of conduction electrons in copper
at room temperature, given that the conductivity of copper is 5.9 × 105 Ω−1 cm−1. [n = 8.5 × 1022
electrons cm−3. ]
Solution :
The electron drift mobility is

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BECE201L

Electronic Materials & Devices

where, Vxi is the x-direction velocity of the ith electron.

• In time ∆𝑡, electrons move a distance ∆𝑥 = Vdx ∆𝑡

• The electrons within distance ∆𝑥 pass through area A

• Thus, n(A ∆𝑥 ) is the total number of electrons crossing A in time ∆𝑡

effect of the electric field on the motion of the electrons in the

• The copper atom has a single valence electron in its 4s

The electrostatic attraction between the

In Drude’s model, the temperature dependence of the mean KE is

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