Dy034 Procion Dyes

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Kraftkolour Pty Ltd

Factory 2, 99 Heyington Ave


THOMASTOWN Vic 3074
Tel: 1300 720 493
Web: Kraftkolour.net.au

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING


1.1 Product identifiers
PROCION MX DYES: ASSORTED COLOURS
1.2 Other means of identification
Fibre Reactive dyes – COLD type.
1.3 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Textile dye
1.4 Details of the supplier of the safety data sheet

Company : KRAFTKOLOUR Pty. Ltd.


Factory 2, Heyington Ave
THOMASTOWN VIC 3074 AUSTRALIA
Telephone : +61 03 9465 4865 (1300 720 493)
Fax : +61 -
1.5 Emergency telephone number
Emergency Phone :

2. HAZARDS IDENTIFICATION
2.1 GHS Classification
Skin irritation (Category 2) Eye irritation (Category 2) Skin Sensitisation (Category 1)
Specific target organ toxicity - single exposure (Category 3)
2.2 GHS Label elements, including precautionary statements
Pictogram

Signal word Warning


Hazard statement(s)
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.

SDS: PROCION MX DYES KRAFTKOLOUR P/L Page 1 of 6


Precautionary
statement(s)
Prevention
P260 Do not breathe dust/fumes/gas/mist/vapours/spray.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 P271 P272 P280 Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the
workplace. Wear protective gloves/ eye protection/ face protection.

Response P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
P312 rinsing.
Call a POISON CENTER or doctor/ physician if you feel unwell.
P321 Specific treatment (see supplemental first aid instructions on this
P333 + P313 P337 + label).
P313 P362 If skin irritation or rash occurs: Get medical advice/ attention. If eye
irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Storage P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.


Disposal P501 Dispose of contents/ container to an approved waste disposal
plant.

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Synonyms : Fibre Reactive Dyes

An Azo, Oxazine, Formazine, Disazo, Monoazo or Copper Phthalocyanine Reactive Dyestuff preparation with
simple salt diluents and stabilising agents. Reactive Dye type: Dichlorotriazine dyes and mixtures.

Component Classification Concentration


Various Fibre Reactive Dyes of the Skin Irrit. 2; Eye Irrit. 2; various
Dichlorotriazine type and their mixtures. Skin Sens. 1; STOT SE 3;
H315, H317, H319, H335
*List of homogeneous dyes & Cas # below

COLOUR CAS No. COLOUR INDEX No.


YELLOW MX8G 61951-86-8 YELLOW 86
YELLOW MX4G 12226-49-2 YELLOW 22
GOLD YELLOW MXR 12270-91-6 YELLOW 44
YELLOW MX3R 12270-78-9 ORANGE 37
ORANGE MX2R 12225-82-0 ORANGE 4
RED MX5B 12226-03-8 RED 2
RED MX8B 12226-08-3 RED 11
PINK MXB 12270-82-5 RED 74
MAGENTA MXB 12270-87-0 VIOLET 13
VIOLET MXRA 12237-11-5 VIOLET 12
BLUE MXR 13324-20-4 BLUE 4
NAVY MX3R 12225-37-5 BLUE 9

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COLOUR CAS No. COLOUR INDEX No.
DEEP BLUE MX2R 61901-79-9 BLUE 82
TURQUOISE MXG 71872-74-7 BLUE 140
BLUE MXG 72847-56-4 BLUE 163
BLUE MX4GD 72847-57-5 BLUE 168
BLUE MX2G 61951-75-6 BLUE 109
For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES


4.1 Description of first aid measures General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available

5. FIREFIGHTING MEASURES
5.1 Extinguishing media Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Sodium oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available

6. ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.

7. HANDLING AND STORAGE


7.1 Precautions for safe handling

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Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive
fire protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1 Control parameters Occupational Exposure Limits
We are not aware of any national exposure limit.

8.2 Exposure controls


Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
Personal protective equipment Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).

9. PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
a) Appearance Form: Solid, Various Colours – Powder or Granular
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing point no data available

9.2 Other safety information no data available

10. STABILITY AND REACTIVITY


10.1 Reactivity
no data available

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10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects Acute oral toxicity: LD50 > 2000 mg/kg (rat)
11.2 Acute inhalation toxicity : not determined
11.3 Acute dermal toxicity : not determined
11.4 Irritant effect on skin : no data available
11.5 Irritant effect on eyes : no data available
11.6 Sensitization : In the guinea-pig the product has a sensitising effect (OECD 406)
11.7 Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
11.8 Reproductive toxicity no data available
11.9 Specific target organ toxicity - single exposure: Inhalation - May cause respiratory irritation.
11.10 Specific target organ toxicity - repeated exposure no data available
11.11 Aspiration hazard no data available
11.12 Additional Information RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have NOT been thoroughly
investigated.

12. ECOLOGICAL INFORMATION


12.1 Toxicity
Fish Toxicity : LC50 : > 60mg/l (96hr)
Daphnia toxicity : EC0 > 80mg/l (48 h, Daphnia magna)
Algae toxicity : ErC50 > 12mg/l
Bacteria toxicity : EC50 > 1,000 mg/l

The product has not been tested and the figures above are only approximate and may vary depending
on the colour. Figures derived from products containing similar components.
12.2 Persistence and Degradability no data available
12.3 Bioaccumulative potential no data available
12.4 Mobility in soil no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects no data available

13 DISPOSAL CONSIDERATIONS
Waste treatment methods Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed

SDS: PROCION MX DYES KRAFTKOLOUR P/L Page 5 of 6


professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

14 TRANSPORT INFORMATION
14.1 UN number
ADR/RID: - IMDG: - IATA-DGR: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods.
IMDG: Not dangerous goods.
IATA-DGR: Not regulated. Not dangerous goods

15 REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
Standard for the Uniform Scheduling of Medicines and Poisons: no data available
Carcinogen classification under WHS Regulation 2011, Schedule 10: Not listed
AICS: On the inventory, or in compliance with the inventory

16 OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Eye Irrit. Eye irritation
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Skin Irrit. Skin irritation
Skin Sens. Skin sensitisation
Further information

This SDS summarises our best knowledge of the health and safety hazard information of the product and how
to safely handle and use the product in the workplace. Each user should read this SDS and consider the
information in the context of how the product will be handled and used in the workplace, including in conjunction
with other products. Kraftkolour P/L cannot anticipate or control the conditions under which this information may
be used. Each user should review the information in the specific context of the intended application. Kraftkolour
P/L will not be responsible for damages of any nature resulting from the use of or reliance upon this information.
No expressed or implied warranties are given other than those implied by Commonwealth, State or Territory
Legislation.

Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all
individuals and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with
all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission,
recommendation or authorization, given or implied, to practise any patented invention without a valid license.

Kraftkolour Pty Ltd. shall not be responsible for any damage or injury resulting from: abnormal use of the
chemical; any failure to adhere to recommendations; any hazards inherent in the nature of the chemical.
Kraftkolour Pty Ltd expressly disclaims that the SDS is a representation or guarantee of the chemical
specifications for the product.

ISSUE DATE: 4th May 2017 KRAFTKOLOUR P/L (03) 9460 6432

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