ExSorbtion Overview - 202310
ExSorbtion Overview - 202310
ExSorbtion Overview - 202310
Why? How?
Our proprietary Sorbents last 10X longer We use Carbon Dioxide instead of Acid for regeneration
ExSorbtion Technology Advantages
• The sorbents have shown high lithium selectivity, which means that even in brines that have low lithium content
and higher amounts of salts and other materials, the sorbents show high selectivity for lithium. We have
demonstrated cost effective lithium production from brines that have 40ppm lithium.
• The sorbents take only a few minutes of contact with the brine to extract most of the lithium in the brine and a
few minutes of contact with carbon dioxide gas to remove most of the lithium adsorbed by the sorbent. This
reaction time of <2 minutes for adsorption and <5 minutes for regeneration is >10x faster than similar DLE
processes.
• Carbon dioxide gas is used for the desorption/regeneration step, and thus the process acts as carbon sink to
reduce the carbon footprint of the facility (and is therefore much greener). All (or most of) the CO2 emissions
from a geothermal plant can be captured and used in our DLE process for regeneration.
• Since acid is not used the sorbents last much longer, which is a major cost saving since the cost of the sorbents is
one of the major consumables (20-40% of the operating expense) in the DLE process. The Company has tested
the sorbents for more than 500 cycles.
• Additionally, since the process does not use acid in the desorption/regeneration step to remove the lithium form
the sorbents; therefore, there is no acid storage and pumping requirement, and the process does not require
additional steps to clean the acid for reuse or to dispose of it.
• Without the use of hydrochloric acid, the product is lithium carbonate - a mid-range lithium product, versus other
DLE companies whose product is lithium chloride, the lowest valued lithium product.
• Additionally, our process consumes only an estimated 23 tons of water for each ton of lithium carbonate
produced which is >60% lower than competing DLE processes.
DLE Triangle
• There is a reason why we see a lot of DLE lab and pilot scale units but
nothing in large scale production yet. For DLE to be an economically viable
solution, all three ingredients of the DLE triangle need to be present.
• A sorbent that lasts only 30 cycles which needs to be replaced over ~50
times every year, and at a cost of $10M each time (assumed: $20/kg sorbent
and 500 tons of sorbent for 20 tons/year LCE production). So, replacing it 50
times would cost $500M just in sorbent costs, which is fine if we want to sell
Lithium for $70,000/ton, however if we want to drive electrification, lithium
needs to sell at a price that is 5x lower. And for this to happen, the sorbents
need to last a lot longer (>500 cycles in our case), the adsorption and
regeneration time needs to be a lot faster (<5 minutes in our case) and the
sorbents need to have high selectivity and uptake (90% and up to to 6mg/g
in our case).
• Unlike mining and evaporation pond projects which requires $500M-$2B in
Capex, we estimate a $75M capex investment would allow us to produce
20,000 tons/year of LCE. We estimate a fully-loaded cost of ~$4,200/ton
(including depreciation) for producing LCE. At a sales price of only $9,000/ton
(which is >6x lower than current sales price of LCE) – a 20,000 tons/year
production facility could potentially generate $80M/year in free cash
flow/year, thus providing stellar unit economics as well.
A new kind of Sorbent
• ExSorbtion’s technology is based on nanoparticles comprising a porous particle composite and a metal ion imprinted
polymer acting both as a carrier for the metal ion sieve particles and as sites for selective metal ion exchange. The metal
ion sieve provides for lithium-ion selectivity while the imprinted binder provides additional sites for lithium-ion adsorption
within an overall porous structure permitting fluid transport within and throughout the particle.
• The combination of the two systems in the ExSorbtion composition provides for both efficient lithium-ion uptake, i.e. high
lithium uptake and fast kinetics, and effective lithium-ion separation from competing ions. The combination is unique
compared to other sorbent-based DLE technologies which rely on only one active sorbent system, with the carrier, if any,
having only a passive role.
• For example:
– Lilac Solutions uses only a metal oxide sorbent. The sorbent particles are supported by a polymer matrix but the matrix does not have ion exchange
properties (US Patent 10,150,056 B2).
– Standard Lithium employs a hydrous metal oxide sorbent based on titanium oxide as the sorbent for its process. The sorbent particles are unsupported, with
the sorbent used in slurry form and the particles recovered by filtration (US 2019/0276327 A1).
– Eramet employs a solid alumina-based sorbent in its process, with the sorbent extruded as nodules without the use of any binder to provide cohesive strength
to the particles (US 2020/0316557 A1) or to provide supplemental lithium ion extraction or ion separation capacity.
– Similarly, the sorbent developed by Simbol Inc. for lithium extraction from geothermal brines was an aluminum chloride double layered hydroxide composition
held within a polymer matrix (US 2014/0239224 A1). This technology is also believed to be the basis for the DLE technology developed by International Battery
Metals Inc.
– Also, similarly, the recently announced aluminum chloride double layered hydroxide sorbent developed by Oak Ridge National Laboratory appears to act in the
same unsupported manner as a sorbent developed by All American Lithium (US Patent 10,328,424 B2).
High Lithium Uptake
Brine Composition
Test data on sorbent stability indicates the performance of the sorbent remains consistent over a significant
number of cycles
High Lithium Selectivity
Brine Composition
Company Sorbent Type Feed Solution Lithium Li Concentration Separation Factors Sorbent Durability
Type Uptake Factor (Li/M) (% mass retention)
Capacity (Li in brine/Li in Feed) (Liconc/Lifeed)/(Mconc/Mfeed)
(mgLi/g
sorbent) Mg K Ca SO4 Na
77
Mn-based metal Synthetic 71:1 to 323:1 to
ExSorbtion 5– 16.2* 10 X Very high to No data High
ion sieve geothermal brine 136:1 3855:1
211:1
Alumina-based Synthetic
ORNL No data 3.53 X No data. 212 143.6 No data 47.8 Not available
sorbent geothermal brine
Alumina-based
Eramet Synthetic brine 6-7 1.6 – 2.5 X 15:1 1000:1 10:1 500:1 1000:1 80% after 20 cycles
sorbent
Titania-based Groundwater
Standard Lithium No data 10 X 262 No data 145 O data 41 80%
sorbent brine
Believed to be
Data not
E3 Metals alumina-based Produced water 11.66 X No data No data No data No data No data Not available
available
sorbent
* depends on type of brine and process conditions. Sourced from Company data and patent literature.
Hard Rock v/s Evaporation Ponds v/s DLE
Estimates for producing
Hard Rock Evaporation Ponds DLE
20mt/yr of Li2CO3
Salars
Oil & Gas • High brine flow and high
• Partner with oilfield lithium content justify a
water treatment stand-alone selective
companies since single adsorption plant
wells do not produce • Purchase salar asset and
enough brines to self-operate or partner
justify a stand-alone with salar asset owner on
plant, whereas water a value-share basis
treatment facility get
brines from multiple
wells Geothermal and
• Direct Lithium Smackover
Extraction would be an • High brine flow and high
add-on to their existing lithium content justify a
water treatment stand-alone selective
infrastructure adsorption plant
• 50:50 value share • Partner with Geothermal
model company on a value-
share basis
Team
Anupam Ghildyal
Douglas Heller
Srinivas Bhamidi
Don Hains
15+ years with early and
growth stage companies President and CEO of Sun
Specialty Products, a Invented the DLE
20+ startups in materials, Author of the ‘Best Practice
company that produces technology at SRI
energy, manufacturing Guidelines for Reporting of
and consumer sectors millions of pounds of Led the formulation and
polymeric beads for a development of DLE Lithium Brine Resources and
15+ new products variety of applications. Reserves’
sorbents
commercialized Industrial minerals
Partner in the Significant development
10+ Countries sales and Philadelphia-based exploration and economic
experience in materials
operating experience private equity investment geologist with more than 30
and battery technologies
$500+ million in equity & firm of Heller Hickox & years of experience in
3 United States patents, 3
debt financing Company, that invests in development, use and
invention disclosures and
oil and gas companies analysis of industrial
several publications.
minerals properties and
materials
01 Lithium is the default
choice for modern
batteries
We have a fundamentally
03 different DLE technology/
process
We have demonstrated a
04 green, fast & cost-
effective solution for
extracting Lithium