ALCOHOLS ,

PHENOLS I ETHERS
Lcohols preparation
Physical E chemical Properties
alcohol
uses of
Phenols preparation
Physical E chemical Properties
Uses of Phenol

\
Ethers preparation
Physical & chemical Properties
Uses Ether
of

1- 2 Q Is
Alcohols

PREPARATION
from hydrolysis of R -

R -

X t
aqkon ROH

Reduction of Carbonyl compounds

r roti R-

( zoaecohoe)

Reduction acid I derivative

Coon
hw
Rchzon

R COOR Ronson
"
-
'
+ R' on

"

R coil
-
Ronson

R - E -

o - IR
' '
'
2RMz on

Co Zno Cruz
2Mz
-

t ↳3 OH
700k , zooatm
 from Rxn with R -

Mgx
melon
-

R -

mgx t
Homo Ronson
on

E Hulon Chick
-

R Mg X cuz oh
+
cuz
-

,
-
-
-

( 30 alcohols )

hydration of Alkene

)
"
" wth

(
RCM markentkor
-_ oh, Rch -
chz
I Addition
On

physical Properties
•
Boiling point decrease with
branching
•
Boiling point higher as
comparing
Ethanol 7 Metheny methane > Propane
Molwt 46 46 44

B.pt 351K 248k 231K

chemical Properties
• Alcohols acidic due to
polar o n
-
bond
• Electron
withdrawing
go y zo > 30
 NH
GH5H
Red p

Iodoform 24 Ch 23 ( yellow)
Reaction noon

cut cnz.NO
Peel
DDC

R -

Calls OH rmgx

na
CM SONA

20,20 , 30 alcohols
distinguished by arson

383k
Cshsnsoy
Lucas reagent .

HU Znelz Msm
chzchz O Chzchg
-

- -

410k

Hrsou
Cha -
Cha
433k

uses -

•
Cnzon :
paints
alcohol
° commercial made unfit by adding
Cusoy I pyridine ( Denaturation Alcohol
of )
PHENOLS

PREPARATION
Nil
on
>
-

503N
s Egon

MSM'
→
hwlut
Egon
 INDUSTRIAL -
SCALE

- m
@3) z £7
hw
on camera

Process
(end
+
.

↳
,

fog 5y on
-

3150C

Fn on Dow 's
573 -

023K Process

chemical Properties
•
Phenols more acidic than alcohols .

•
Electron
donating Gps i decreases
acidity
-

increases
Electron
withdrawing Corps :
acidity
-

NO
NUZ z

NEX Noz
y
-

LY i y
Noz NO z

picnic tide
Acid I
strength
 oh
3. Bru
) B
# Br

H2O
Mr

oh
come .

N0¥- NOL

HN
03 ¥
NO z

cnclz
°"
on Diemer
a- Cho
Tiemann
NaOH Lod
①
can icon
④
Naoh

on Kolbe
Naoh
tycoon electrolysis
coz ,
I
dilute
O

K p -
benzo -

crozclz quinone
0

Oh Oh
,
I
dit a-Nor a

① El
HN
Og Hoz
 ETHERS
PREPARATION .

mum
Chzchz OH 413k
Cshs0W5

R OR + wax
Rona
-

RX +

Williamson 's synthesis

physical PROPERTIES
ethers
Large difference
and
in
boiling point of
alcohols is due to h -

bonding
despite molecular
of same mass .

Chemical PROPERTIES
halide
• Reaction with
halogen
HI 7 HBR 7 Hcl

R -
O -
R t H2 R X
-
t Ron
•
Electrophilic Aromatic substitution

or
group
:
Activating
-

o
p
-

directing
gunz 0M3
Brain 1- A- Br
44 ①
chzcoon Br

9kHz
^
⑦ och
3
01M I
chdz
hanky KIM
A

&
neg
Csz Ay

ooh
00h31
,
I
Hssoy EINE
HN Oz
Nor

•
R O R thx ( → ZRX 1- Hao
enemy
-
-
previous yrs Impe .