Correlations For The Reservoir Fluid Properties of Alaskan Crudes
Correlations For The Reservoir Fluid Properties of Alaskan Crudes
Correlations For The Reservoir Fluid Properties of Alaskan Crudes
SPE 11703
This paper was presented at the 1983 California Regional Meeting held in Ventura, California, March 23-25, 1983. The material is subject to correction
by the author. Permission to copy is restricted to an abstract of not more than 300 words. Write SPE, 6200 North Central Expressway, Drawer 64706,
Dallas, TX 75206.
357
z RESERVOIR PROPERTIES OF ALASKAN CRUDES 1170·
compositional effects into account should be high sulfur crude.
undertaken with caution. If a crude has a
particularly unusual composition, neither of Crudes for the three producing pools at
the above correlating approaches is likely to Prudhoe Bay have high nitrogen and carbon
be very accurate. It is common practice to, dioxide contents. The high nitrogen content
in effect, create new correlations for a causes the bubble point to be considerably
particular region, by applying Standing's higher than that predicted by Standing's
correlation method to the data form that correlation. Glaso's correlation is the only
egion, and shifting the parameters to obtain one currently available which implements non-
a "best-fit" line. The same aP14roach can be hydrocarbon corrections and should be used
aken with Vasquez and Beggs since the for Prudhoe crudes. Due to the lack of
orrelations are of similar form. availability of PVT reports for a large
number of reservoirs on the ANS, the
The properties of crudes which most remainder of this paper deals with crudes
nfluence PVT behavior but which are not from the Cook Inlet Basin.
aken into account in most correlations are
paraffinicity and non-hydro§arbon content Production in the CIB has primarily been
(N Z ' CO 2 , and H2S). Glaso has included from Tertiary formations at depths of around
orrection factors with his correlation to 10,000 feet. It is unusual to find
account for ..fhese factors. An earlier work productive Tertiary formations at this
by Jacobson, reported a correction to depth. CIB crudes are characterized as high
Standing'sl correlation to account for gravity crudes (35 0 API) with a low sulfur
nitrogen content. These corrections are content. 7 CIB crudes typically have high
simply multipliers to be applied to the nitrogen content (.15% wt) and produce
calculated bubble point. Hence either surface gases with as high as 15% mole
correction can be used with any bubble point nitrogen. Most crudes having high nitrogen
correlation. These corrections are content also have high sulfur content. CIB
substantial. Negelecting to use them can crudes are highly unusual in that the
esult in errors of 30% or more in the nitrogen content exceeds the sulfur
~stimation of the bubble point. content.
Bubble Point Pressure the measured gas gravity. The equations for
the Vasquez and Beggs correlation are listed
In this section, the four most in Appendix A. The Vasqu~z and Beggs
frequently used correlations for the bubble correlation has been adopted for use in the
point pressure are described briefly. In Hp 4I-C Petroleum Fluids Pac.
order to clearly contrast the differences in In 1980, Glas0 3 published a correlation
the various correlations, the sources of the based on laboratory data from North Sea
data for the correlations and the parameters crudes. The Glaso correlation is of the
needed to use each correlating equations are form:
indicated. The complete form of the
correlating equations for each of the four
correlations is presented in Appendix A.
359
4 RESERVOIR PROPERTIES OF ALASKAN CRUDES 1170'
correction is superior for the Cook Inlet viscosity below the bubble point:
crudes The correlations of Standing 1 and
Lasater• 2 coupled with the Jacobson 5
correction factor are of approximately equal flob = 10.715(R
sb
+ 100)-0.515 flOd B (7)
accuracy.
- 1.1870
R = .0178 Y (p/C )
s g N2 = oil formation volume factor,
resbbl/STB
ex p (23. ~~_~~APJ (13 )
= oil formation volume factor at the
(T+460) ]
bubble point pressure, resbbl/STB
With both of the above formulations, the
correction for non-hydrocarbon content is
C = bubble point pressure correction
factor for non-hydrocarbon gases
accomplished by using a corrected press~re in
the correlating equations. The Glaso and
Lasater 2 correlations are not explicit in Rs'
p = reservoir pressure, psia
but could be solved by an iterative method.
In each case p/C N should be used as the
= bubble point pressure, psia
corrected pressure. 2
= separator pressure, psia
CONCLUSIONS
= solution gas/oil ratio, SCF/STB
PVT reports were used to analyze the Y API = stock tank oil gravity, °API
accuracy of existing correlations for bubble
point pressure, oil formation volume factor Y!PI = residual oil gravity, °API
at the bubble point, dead oil viscosity, and
live oil viscosity. The following Yst = specific gravity of stock tank
oil, (water = 1)
conclusions were reached:
361
6 RESERVOIR PROPERTIES OF ALASKAN CRUDES 11703
REFERENCES (T+459.6)
= Pf - (A3)
Yg
1• Standing, M.B.: Volumetric and Phase where:
Behavior of Oil Field Hydrocarbon
Systems, Millet the Printer, Inc.,
Dallas (1977), 70-95. = 2.303 + 2.5877 U + 0.62102 U2
2. Lasater, J .A.: "Bubble Point Pressure 3
+ 0.07037 U (A4)
Correlation", Trans., AIME (1958) 213,
379-81.
with U = In y
g
•
3. Glaso, 0.: "Generalized Pressure-
Volume-Tempe ra ture Correlations", ~ yg' the mole fraction of separator fluid in
Pet. Tech. (May 1980) 785-795. tne vapor phase is calculated as:
4. Vasquez, M. and Beggs, H. D.:
"Correlations for Fluid Physical y = (AS)
Property Prediction", J. Pet. Tech. g R /379.3 + P
(June 1980) 968-970. sst
P is the effective molar density of the
5. Jacobson, H.A.: "The Effect of Nitrogen st~~k tank oil in lbmole/STB given by:
as Reservoir Fluid Saturation Pressure",
J. Can. Pet. Tech. (July-Sept. 1967) 30.93 Y;t
_ _ _._._ ___ .:::....::c_ _ _ __
101-105. (A6 )
Pst =
Y~t - 1.289 Yst - 0.4198
6. Magoon, L.B. and Claypool, G.E.: "Two
Oil Types on North Slope of Alaska -
Implications for Explorations", AAPG Equation (A6) is based on Lasater's
Bulletin, V. 65, No.4. (April 1981) correlation for the effective molecular
644-652. weight of the stock tank oil with respect to
stock tank oil gravity.
7. Blasko, D.P., Wenger, W.J. and Dorris,
J.C.: "Oilfields and Crude Oil 3. The correlation of Vasquez and Beggs 4
Characteristics - Cook Inlet Basin, uses separate correlating equations for crude
Alaska", U.S. Bu. Mines, RI 7688 (1972). oils with specific gravity above and below
30 0 API.
8. Standing, M.B.: "A Pressure-Volume-
Temperature Correlation for Mixtures, For YAPI < 0
30 API:
California Oil and Gases", Drill. and
Prod. Prac., API (1947) 275-286.
R )0.9143 -23.5202
9. Beggs, H.D. and Robinson, J.R.: p = 20.788 ___s_ exp
"Estimating the Viscosity of Crude Oil b ( Y gs [ T+460
Systems", J. Pet. Tech. (Sept. 1975)
1140-41. (A7)
APPENDIX A
(0.00091T-0.0125y )
API
A = 10 (A2)
(A9)
2. Lasater's2 correlation, or~ginally
published in graphical form, can be
represented by the following equations:
362
11703 OSTERMANN, EHLIG~ECONOMIDES AND OWOLABI 7
4. The Glas0 3 correlation is given by the
following equations:
where:
1.0 - 693.8 T- 1 • 553 (A16)
YCO 2
p*
b (~)
-
Yg
0.816 (TO.172
0.989
YAP1,corr
) (All )
For hydrogen sulfide:
The Glas0 3 correlation was based on North Sea CH2S = 1.0 - (0.9035 + 0.0015YAPI) YH 2 S
crudes with a UOP paraffinicity factor of
KUOp = 11.9. To allow the correlation to be 2
used with crudes of different paraffinicity, + 0.019(45 - YAPI)(YH S) (Al7)
a correction factor based on the viscosity 2
and API gravity of the residual oil from a
differential liberation, must be applied to 2. Jacobson 5 reported the following
the measured stock tank oil gra vi ty. The correction for nitrogen content to be used
corrected gravity is calculated by: with Standing's correlation:
YAPI, cor~ ~
(YhI corr
YAPI
1 YAPI (A12) 15.85 + 286YN
2
- 0.107T (A18)
where:
APPENDIX B
(A13)
Y!PI, corr
Correlating Equations for the
Oil Formation Volume Factor
with:
- ) 0.5 1 2
Y!PI and ~od are the gravity and the 0.9759 + 12.10-5 R ( ~ + 1.25T •
v1scosity, respectively, of the residual oil s YAPI
from a differential flash at reservoir (B1)
temperature.
log (Bob-I) *
= -6.58511 + 2.91329(10g Bob)
1. Glas0 3 reported the following equations
for corrections in the bubble point pressure
when carbon dioxide, nitrogen, or hydrogen -0.27683(10g B* )2 (B2)
ob
sulfide are present.
where:
For nitrogen:
:y ,,)0.526+
C = 1.0 + r2.65 10-4 YAPI R ~ 0.968T (B3)
N2 s ( YAPI
+ 5.5.10- 3 T
363
8 RESERVOIR PROPERTIES OF ALASKAN CRUDES 11703
(B4)
o
For YAPI > 30 API,
(BS)
364
TABLE 1
~
""'" hlcARTHURRIVEFI
MIDOLEGFIOUND UNN ... MED PfWDHOEBAY UNNAMED UNNAMED
"'.
OllFIE;lDS BEAVEFlCFlEEK GFIANITEPOINT KATALLA FlEDOUBTSHOAl TFIAOINOBAV
TRADING BAYUHIT (POINT THOMSON PRUDtlOE !lAY!JN1T UMIA"!" (A.N.S.) FlAXMAN ISLAND KUPAFlUKRlVEFlS.S.
(C.I.B.) (C.I.B.) (GUlF OF AlASlO.j SHOAL (C.I.B.) (.... N.S.) (CI.B.) (KENAIPENIN.) (C.I.B.)
FlESERVOII'I (C.I.B~ UNIT (A N.S.) AFlEA(AN.S.) "UGNU·' RtVEFI"'I'IEA (A.N.S)
I'ftODUCtNGFOFlMATIOH
OIL ZONE
FlEFEFIENCEOATUM
FEET BELOW SEA lEVEL
•.no 9,350 8,850
'." 10,300 4,1XXI ~,628 12,500
SATUFIATIONPFIESSURE
p.,a
'."
1,181 1,921
TE~PEFIATURE
OILGI'IAVITY
"..
"'"
OFlIGINALGASK»LRATIO
1,110
-31>.2
SCF1STa
OAS/OlLRATIOI2i3118O
SCFISTB
FVFATSATURATION
PFlESSURERBlSTB
OtlVISCOSlTYAT
ORlGtNALPFIESSUREcp
OIL VISCOSITY AT
SAfURATIONPRESSUREcp
~
u'"
O... SFIELD ALBERTKALO ... EASTUMI ... T FALLS CREEK IVANRIVEI'I KAVIK KEMIK KEN ...I
BEAVERCREEK BEI.U(l ... RtVER BIRCH HILL LEWlSRIVER
RESERVOIR (CI.B) (C.I.B.) (C.1.8.) (C.I.B.) (A.N.Sl (CU.) (C.I.8) (A.N.S) (AN.S.) (Col 8.) (C.I.B.)
DATA
I"'·"I;;::~
REFERENCEO ... TUM
FEET 8ELOWSEA lEVEL
JAN. 4. 1968 DEC. 111,1962
1.635 2,215
'.000 1,929
JUNE 25,1961
7,0-45
OCT.B,I'i56
4,130
'."
,,,.,
NOV. 5, 19&9
'." ....,
1,350 1,645
~
u"" MC ... RTHURRIVER
GAS FIELD MOOUAWKIE NORTH MIDDLE
TI'IADtNGBAVUNIT NICOLAI CREEK NORTH COOK NORTHFORK SOUTH BARROW STERLING SWANSON RIVER TRAOINGBAV WEST FOReLAND WEST FORK
RESERVOIR (C.18) (CU.) INLET (C.I.B) (C.I.B.) GROI.INOSHOAL (A.N.S.)
(C.I.B.I (CU.) (C.l8., (C.I.B.) (CIB.) (CU.) (C.I.B.)
"'''
PROOUCING FORMATION
GAS POOL
DEC. 2. 1966 ... AY 1, 19611 SEPT. 1,1962 DEC.20,11III!i AUG. 24, 1957 OCT.5,19N SEPT.26,1$60
REFERENCEOATUM
FEET Bf:LOWSEA LEVEL
'." 5,100 ,,., ,...
2,870-
PRESSURE 12130180
2,305
' .... '.000 ....
1,335-
2,037
". ,.000
TABLE 2
TABLE 3
PVT PROPERTIES OF COOK INLET BASIN CRUDE OILS
BUBBLE POINTS PREDICTED FROM PVT CORRELATIONS
-not corrected for nitrogen content-
.
'APr
YN
(separator)
2
R, Pb
Bob
(res.BBL) ]Job "cd Experimental
Predicted Bubble Point
4 i 2
Sample (oAPI) (%) (SCF/STB) (psia) ~(cp) (cp) Bubble Point
Vasquez-Beggs Standing Lasater
(psia) Pb %error Pb %error Pb %error Pb %error
60 165 .9107 35,0 32.9 14.8 288
60 165 .9548 35.3 32.9 ,., 152
152 224
1637
1159
1.185
1.160
1.05
1.13
2.48
2.48
1637 1180
908
-27.9
-21.7
1060 -35.2 1177 -28.1 1059 -35.3
1159 815 -29.7 8W -25.8 783 -32.4
60 165 1.0943 34.9 32.9 4.7 152 140 515 1.129 1.32 2,48
515 552 7.2 488 - 5.2 450 -12.6 436 -15.3
60 165 .8530 35.2 32.7 13.4 180 306 1782 1.199 0.90 2.10
1782 1372 -23,0 1246 -30.1 1401 -21.4 1247 -30.0
60 165 ,8880 34.9 32.7 10.4 180 236 1263 1.179 1.00 2.10
1263 1067 -14.8 947 -22.9 1054 -16.5 937 -25.8
60 165 1.0197 32.7 32.7 4.8 180 140 565 1.144 1.33 2,10
565 629 11.3 562 - 0.5 534 - 5.5 497 -12.0
60 56 .8899 37.1 46.6 2.5 122 435 1447 1.236 0.44* 0.83*
60 104 .8780
t 25,4 33.1 30,
1447 1571 8,6 1352 - 6,6 1247 -13.8 1440 - 0.5
15.1 180 1802 1.205 0.96 2.05
1802 1370 -24,0 1218 -32.4 1357 -24.7 1217 -32.5
-10.5 -20,3 -18.6 -23.0
* probably in error
standard deviation 16.6 14.0 7.8 12.4
t stock tank gas gravity calculated from
separator liquid flash
* paraffinicity correction included
TABLE 4 TABLE 5
CORRECTION FACTORS FOR NITROGEN CONTENT PREDICTED BUBBLE POINTS - CORRECTED FOR NITROGEN CONTENT
TABLE 6 TABLE 7
EXPERIMENTAL AND PREDICTED OIL FORMATION VOLUME FACTOR EXPERIHENTAL AND PREDICTED OIL VISCOSITY
"
standard deviation 0.690 1. 290 0.960 standard deviation 12.00 10.50
0-
(j.)