All Reagents in Haloalkanes and Haloarenes ?
All Reagents in Haloalkanes and Haloarenes ?
All Reagents in Haloalkanes and Haloarenes ?
6
cHz-CHy-CH=CHy Hel, Naz/acetene
(But-]-ene)
HBY, CHy-cl
|cHyCoo A KNOL AgcN KCN NaOH(a) kOH(a)(o)
H
tH
"3N@GHp-No,
Hel +
t
HI
Gito
ethang)
>Markovnikov'
HBY’ s CH
Finkelstein
Gts-ooc 4ts- ngcnabmyin SHs-
GHs-NC(Et
ONO
(Ethanal)
<zHs-oH -I
butane) cH,
-8Yomo CN (Iodo
-ch-cH- cH, (Eth (pYepane reatin
Yule(CH,Coo methane)
Ch
nitrite)
n1trile)
GH
O
OMgletherdny
CHy-4-ck-ck-chg
CH-cH-cH
(2-BYomopentone) Alc. HBY/
BY (propene) CH
M R-x koH/<4HoNa
cH-CH=cH -CH peroi
hedy ’ =
CHyt
Soytze de
C,tsot CzHsoNa
hot + ’
CHsot koH
m HBY HBY’
tyGTi
) veaget
mgel gnand mgx R
f
ethoot Avi-
vule ’rcHy
cHCh cH-CHy Mkovn
((-BYomo
pYopang
NaNH
(pert--ene)
ch=Hs CHy- - kov's
HX CHa-
CH
BY Yude
BY
Ex:
( Ex: t
2(0BY 2x
tna Ex: 2 2
Reddish =CkyCH RMgx (cl R-x etheydNaon|y
81ccly O*t2R-Naxt CH-cl
t t +Na
byown CaYignand 2
Na 2NO Na
(ov) t dry dny
ccly ct-cl day y
colus ca ethen, etihet, ether
lcly cHy ’ veagent)
(Methane)
ether,dhy ethen,day
y ’
cH,-Cti, R-R
n,
BY O CHEMIST
ASN RY
’R-H
ppeaty bipheng) thang E
R(de-fittig)
CTeluene)cH, Fittig
reaction)
t
veact
ion)
(6 15)
cH-ccR-CEcNa
Nat H-csC RONaR-x RONa
t <H,+clCH, BYcl
CH,0CH,Naal t ’ heat
Na
+ Allglic heat
() cl Coy
c)
Sodium ( (So A cod Uv Ov
bion illiamson
h
lghtuv igt igt
Benaybc
=C-cHÊalkynidg
acetyde)
QimetCtyocH
nhge) Nac) +RORNax t coR)
ut-2-yne)
ethey haloganatian NBS ASN
Synthels CHEMI
STRY
oNaoH, 9 (0 )
cl, cl Rco
or) R-x/Anhyd
cHycl +
Naot +
623k,
cl+
Bvs cHoycl x/
Awhyd
30
Alclg Amhy
Anhyd Avhyd.
Alcl, Alcl,
623k odtm Alcl,Anhyd Alcl
Al(4-chlovo
cl Alcy
p-dichlYo
®bengene acetophennn) chloroTolwen)(P.
(o) Friedel. ’
ONa Ht’ cl
hecly Friedel-
H
Dow's o crafts
Dichloro
bensehe0- 2-chlo
asetpheron -chlovo
Tekueng crafts
(phena) proca Fe
Br acylaton .cocH
olkylatin