Safety data sheet Safety data sheet

acc. to Safe Work Australia - Code of Practice

2-Propanol 70 %, pure

article number: CN09 date of compilation: 2019-04-04

Version: GHS 4.0 en Revision: 2024-01-30
Replaces version of: 2021-09-09
Version: (GHS 3)

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance 2-Propanol 70 %, pure
Article number CN09
CAS number [ 67-63-0 ]
Alternative name(s) Isopropanol
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for private purposes (household).
Food, drink and animal feedingstuffs.
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co. KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city

NSW Poisons Information Centre Hawkesbury Road 2145 West- 131126

Childrens Hospital mead, NSW

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification acc. to GHS
Section Hazard class Cat- Hazard class and Hazard
egory category statement

2.6 Flammable liquid 2 Flam. Liq. 2 H225

3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319

3.8D Specific target organ toxicity - single exposure (narcotic 3 STOT SE 3 H336
effects, drowsiness)

For full text of abbreviations: see SECTION 16

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2-Propanol 70 %, pure

article number: CN09

The most important adverse physicochemical, human health and environmental effects
The product is combustible and can be ignited by potential ignition sources.
2.2 Label elements
Labelling

Signal word Danger

Pictograms

GHS02, GHS07

Hazard statements
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness

Precautionary statements
Precautionary statements - prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Precautionary statements - response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher for extinction
Precautionary statements - storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P403+P235 Store in a well-ventilated place. Keep cool
Precautionary statements - disposal
P501 Dispose of contents/container to industrial combustion plant
Hazardous ingredients for labelling: 2-Propanol
2.3 Other hazards
Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.
Endocrine disrupting properties
Does not contain an endocrine disruptor (ED) in a concentration of ≥ 0,1%.

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SECTION 3: Composition/information on ingredients

3.1 Substances
not relevant (mixture)
3.2 Mixtures
Description of the mixture
Name of sub- Identifier Wt% Classification acc. to Pictograms Notes
stance GHS

2-Propanol CAS No 70 Flam. Liq. 2 / H225

67-63-0 Eye Irrit. 2 / H319
STOT SE 3 / H336

For full text of abbreviations: see SECTION 16

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Take off contaminated clothing.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.
Following eye contact
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of
eye irritation consult an ophthalmologist.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Vomiting, Irritation, Dizziness, Drowsiness, Narcosis
4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

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2-Propanol 70 %, pure

article number: CN09

Suitable extinguishing media
co-ordinate firefighting measures to the fire surroundings!
water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Combustible. In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-
air mixture. Solvent vapours are heavier than air and may spread along floors. Places which are not
ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are par-
ticularly prone to the presence of flammable substances or mixtures.
Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO₂), May produce toxic fumes of carbon monoxide if burn-
ing.
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-
onable distance. Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Wearing of suitable protective equipment (including personal protective equipment referred to un-
der Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal cloth-
ing. Do not breathe vapour/spray. Avoidance of ignition sources.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose
of it.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

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SECTION 7: Handling and storage

7.1 Precautions for safe handling
Provision of sufficient ventilation.
Measures to prevent fire as well as aerosol and dust generation

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharge. Due to danger of explosion, prevent leakage

of vapours into cellars, flues and ditches.

Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice:
Ground/bond container and receiving equipment.
Ventilation requirements
Use local and general ventilation.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Identi- TW TWA STE STEL Ceil Ceil- Nota- Source
ntr fier A [mg/ L [mg/ ing- ing-C tion
y [pp m³] [pp m³] C [mg/
m] m] [pp m³]
m]

AU isopropyl alcohol 67-63-0 WES 400 983 500 1,230 WES

(propan-2-ol)

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur

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Notation
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

Relevant DNELs of components

Name of sub- CAS No End- Threshol Protection Used in Exposure time

stance point d level goal, route of
exposure

2-Propanol 67-63-0 DNEL 500 mg/m³ human, inhalat- worker (industry) chronic - systemic
ory effects

2-Propanol 67-63-0 DNEL 1,000 mg/ human, inhalat- worker (industry) acute - systemic
m³ ory effects

2-Propanol 67-63-0 DNEL 888 mg/kg human, dermal worker (industry) chronic - systemic
bw/day effects

Relevant PNECs of components

Name of sub- CAS No End- Threshol Organism Environmental Exposure time

stance point d level compartment

2-Propanol 67-63-0 PNEC 140.9 mg/l aquatic organ- freshwater short-term (single
isms instance)

2-Propanol 67-63-0 PNEC 140.9 mg/l aquatic organ- marine water short-term (single
isms instance)

2-Propanol 67-63-0 PNEC 2,251 mg/l aquatic organ- sewage treatment short-term (single
isms plant (STP) instance)

2-Propanol 67-63-0 PNEC 552 mg/kg aquatic organ- freshwater sedi- short-term (single
isms ment instance)

2-Propanol 67-63-0 PNEC 552 mg/kg aquatic organ- marine sediment short-term (single
isms instance)

2-Propanol 67-63-0 PNEC 28 mg/kg terrestrial organ- soil short-term (single

isms instance)

8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection.

Skin protection

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2-Propanol 70 %, pure

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• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as
a guide.
• type of material
NBR (Nitrile rubber)
• material thickness
0,4 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Flame-retardant protective clothing.
Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: A (against organic gases and va-
pours with a boiling point of > 65 °C , colour code: Brown).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state liquid
Colour colourless
Odour like: - alcohol
Melting point/freezing point -89 °C
Boiling point or initial boiling point and boiling 82 °C at 1,013 hPa
range
Flammability flammable liquid in accordance with GHS criteria
Lower and upper explosion limit 50 g/m³ (LEL) - 330 g/m³ (UEL) /
2 vol% (LEL) - 13.4 vol% (UEL) (Isopropanol)
Flash point 12 °C
Auto-ignition temperature 425 °C (Isopropanol)
Decomposition temperature not relevant

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pH (value) 7 (20 °C)

Kinematic viscosity 2.826 mm²/s at 20 °C

Dynamic viscosity 2.43 mPa s at 20 °C

Solubility(ies)
Water solubility miscible in any proportion

Partition coefficient
Partition coefficient n-octanol/water (log value): this information is not available

Vapour pressure 43 hPa at 20 °C

Density and/or relative density

Density 0.85 – 0.86 g/cm³ at 20 °C

Relative vapour density Information on this property is not available.

Particle characteristics not relevant (liquid)

Other safety parameters

Oxidising properties none
9.2 Other information
Information with regard to physical hazard There is no additional information.
classes:
Other safety characteristics:
Miscibility completely miscible with water
Refractive index 1.371 – 1.375 (20 °C)

SECTION 10: Stability and reactivity

10.1 Reactivity
The mixture contains reactive substance(s). Risk of ignition. Vapours may form explosive mixtures
with air.
If heated
Risk of ignition.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions

Exothermic reaction with: strong oxidiser, Iron, Nitric acid, Strong acid, Aldehydes, Aluminium,
Amines,
Danger of explosion: Chlorates, Nitro compound, Hydrogen peroxide, Phosgene

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10.4 Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
10.5 Incompatible materials
plastic and rubber
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5. Peroxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity
formula).
Classification acc. to GHS
Acute toxicity
Shall not be classified as acutely toxic.

Acute toxicity of components

Name of substance CAS No Exposure Endpoint Value Species

route

2-Propanol 67-63-0 inhalation: va- LC50 37.5 mg/l/4h rat

pour

2-Propanol 67-63-0 oral LD50 5,045 mg/kg rat

2-Propanol 67-63-0 dermal LD50 12,800 mg/kg rabbit

Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness.
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).

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Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
Data are not available.
• If in eyes
Causes serious eye irritation
• If inhaled
dizziness, fatigue, narcosis
• If on skin
repeated exposure may cause skin dryness or cracking
• Other information
Other adverse effects: Headache, Dyspnoea, Narcosis, Vertigo
11.2 Endocrine disrupting properties
Does not contain an endocrine disruptor (ED) in a concentration of ≥ 0,1%.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
.

Aquatic toxicity (acute) of components

Name of sub- CAS No Endpoint Value Species Exposure

stance time

2-Propanol 67-63-0 LC50 10,000 mg/l fish 96 h

12.2 Persistence and degradability

Process of degradability

Process Degradation rate Time

biotic/abiotic 95 % 21 d

Degradability of components

Name of CAS No Process Degrada- Time Method Source

substance tion rate

2-Propanol 67-63-0 biotic/abiotic 95 % 21 d modifizierter

OECD Screen-
ing Test

2-Propanol 67-63-0 oxygen deple- 53 % 5d ECHA

tion

12.3 Bioaccumulative potential

Data are not available.

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Bioaccumulative potential of components

Name of substance CAS No BCF Log KOW BOD5/COD

2-Propanol 67-63-0 0.05

12.4 Mobility in soil

Data are not available.
12.5 Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.
12.6 Endocrine disrupting properties
Does not contain an endocrine disruptor (ED) in a concentration of ≥ 0,1%.
12.7 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used.
Handle contaminated packages in the same way as the substance itself. Completely emptied pack-
ages can be recycled.
Relevant provisions relating to waste(Basel Convention)
Properties of waste which render it hazardous
H3 Flammable liquids
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions. Non-con-
taminated packages may be recycled.

SECTION 14: Transport information

14.1 UN number
UN RTDG UN
1219
IMDG-Code UN 1219
ICAO-TI UN 1219
14.2 UN proper shipping name
UN RTDG ISOPROPANOL

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IMDG-Code ISOPROPANOL
ICAO-TI Isopropanol
14.3 Transport hazard class(es)
UN RTDG 3
IMDG-Code 3
ICAO-TI 3
14.4 Packing group
UN RTDG II
IMDG-Code II
ICAO-TI II
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.6 Special precautions for user
There is no additional information.
14.7 Transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport informationNational regulationsAdditional information(UN RTDG)
UN number 1219
Class 3
Packing group II
Danger label(s) 3

Special provisions (SP) -

UN RTDG
Excepted quantities (EQ) E2
UN RTDG
Limited quantities (LQ) 1L
UN RTDG
Emergency Action Code 2YE
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name ISOPROPANOL
Particulars in the shipper's declaration UN1219, ISOPROPANOL, 3, II, 12°C c.c.
Marine pollutant -
Danger label(s) 3

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Special provisions (SP) -
Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
EmS F-E, S-D
Stowage category B
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Isopropanol
Particulars in the shipper's declaration UN1219, Isopropanol, 3, II
Danger label(s) 3

Special provisions (SP) A180

Excepted quantities (EQ) E2
Limited quantities (LQ) 1L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
There is no additional information.
National regulations(Australia)
Australian Inventory of Chemical Substances(AICS)
All ingredients are listed or exempt from listing.

Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status

AU AIIC all ingredients are listed

CA DSL all ingredients are listed

CN IECSC all ingredients are listed

EU ECSI all ingredients are listed

EU REACH Reg. all ingredients are listed

JP CSCL-ENCS all ingredients are listed

JP ISHA-ENCS all ingredients are listed

KR KECI all ingredients are listed

MX INSQ all ingredients are listed

NZ NZIoC all ingredients are listed

PH PICCS all ingredients are listed

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Country Inventory Status

TR CICR not all ingredients are listed

TW TCSI all ingredients are listed

US TSCA all ingredients are listed (ACTIVE)

VN NCI all ingredients are listed

Legend
AIIC Australian Inventory of Industrial Chemicals
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
ISHA-ENCS Inventory of Existing and New Chemical Substances (ISHA-ENCS)
KECI Korea Existing Chemicals Inventory
NCI National Chemical Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Indication of changes (revised safety data sheet)
Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant

1.1 CAS number: yes

[ 67-63-0 ]

2.3 Results of PBT and vPvB assessment: Results of PBT and vPvB assessment: yes
This mixture does not contain any substances Does not contain a PBT-/vPvB-substance in a
that are assessed to be a PBT or a vPvB. concentration of ≥ 0,1%.

2.3 Endocrine disrupting properties: yes

Does not contain an endocrine disruptor (ED) in
a concentration of ≥ 0,1%.

14.8 Emergency Action Code: yes

2YE

15.1 National inventories: yes

change in the listing (table)

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

BCF Bioconcentration factor

BOD Biochemical Oxygen Demand

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

COD Chemical oxygen demand

DGR Dangerous Goods Regulations (see IATA/DGR)

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Abbr. Descriptions of used abbreviations

DNEL Derived No-Effect Level

ED Endocrine disruptor

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

Flam. Liq. Flammable liquid

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval

LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval

LEL Lower explosion limit (LEL)

log KOW n-Octanol/water

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

ppm Parts per million

STEL Short-term exposure limit

STOT SE Specific target organ toxicity - single exposure

TWA Time-weighted average

UEL Upper explosion limit (UEL)

UN RTDG UN Recommendations on the Transport of Dangerous Good

vPvB Very Persistent and very Bioaccumulative

WES Safe Work Australia: Workplace exposure standards for airborne contaminants

Key literature references and sources for data

Safe Work Australia’s Code of Practice for Labelling of Workplace Hazardous Chemicals (under WHS
Regulations).
UN Recommendations on the Transport of Dangerous Good. International Maritime Dangerous
Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

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Classification procedure
Physical and chemical properties. The classification is based on tested mixture.
Health hazards. Environmental hazards. The method for classification of the mixture is based on in-
gredients of the mixture (additivity formula).
List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text

H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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