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25 views

Question 1329339

Uploaded by

Manish Mishra
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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BRIJ CHEMISTRY CLASSES

C.C ROAD KAILASHPURI LANE NO.2 DEORIA

DPP-2
Class 12 - Chemistry

1. Explain boiling point elevation constant for a solvent. [1]


2. Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis. [1]
3. When 20 g of a non-volatile solid is added to 250 ml of water, the freezing point of water becomes − 0.9 0
C . [2]
Calculate molecular mass of the solid if kf of water is 1.86 0
C kg/mol .
4. 45 g of ethylene glycol (C2H6O2) is mixed with 600 g of water. Calculate [2]

R
i. the freezing point depression and
ii. the freezing point of the solution.
5.
SI
Predict the state of the solute in the solution in the following situations:
i. When i is found to be more than one.
[3]

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ii. When i is found to be less than one.
6. How is osmotic pressure dependent upon number of moles of solute? [3]
AS

7.
77
A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.86 0
C , whereas pure ether boils at [3]
35.60
0
C . Determine the molecular mass of the solute. [For ether, K = 2.02K kgmol
b
−1
]
8. The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and [5]
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trifluoroacetic acid increases in the order given above. Explain briefly.


9. Boiling point of water at 750 mm Hg is 99.63oC. How much sucrose is to be added to 500 g of water such that it [5]
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AV

boils at 100oC.
10. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 [5]
98

atm at 27oC.
11. a. Which aqueous solution has higher concentration -1 molar or 1 molal solution of the same solute? Give [5]
reason.
b. 0.5 g KCl was dissolved in 100 g water and the solution originally at 20°C, froze at 0.24°C. Calculate the
percentage ionization of salt. Kf per 1000 g of water = 1.86 K.

12. 2 g of benzoic acid (C6H5COOH) dissolved in 25 g of benzene shows a depression in freezing point equal to [5]

1.62 K. Molal depression constant for benzene is 4.9 K kg mol–1. What is the percentage association of acid if it
forms a dimer in solution?
13. 0.3 g of acetic acid (M = 60 g mol-1) dissolved in 30 g of benzene shows a depression in freezing point equal to [2]

0.45o C. Calculate the percentage association of acid if it forms a dimer in the solution.

(Given: Kf for benzene = 5.12 K kg mol-1)


14. What possible value of 'i' will have if solute molecules undergo association in solution? [2]
15. a. Find the van't Hoff factor for aqueous KCl, assuming complete dissociation. [2]

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AVINASH SIR 9889797755
b. A solution of an organic compound is prepared by dissolving 68.4 g in 1000 g of water. Calculate the molar

mass of the compound when elevation in boiling point is 0.104 K and Kb for water is 0.52 K kg mol-1.

16. The molecular mass of a solute is 120 g/mol and van't Hoff factor is 4. What is its abnormal molecular mass? [2]
17. Calculate the freezing point depression expected for 0.0711 m aqueous solution of Na2SO4. If this solution [2]

actually freezes at -0.320'C, what would be the value of Van't Hoff factor? (Kf for water = 1.86oC mol −1
)

18. 19.5 g of CH2FCOOH is dissolved in 500 g of water. The depression in the freezing point of water observed is [3]

1.0°C. Calculate the Van't Hoff factor and dissociation constant of fluoroacetic acid.
19. A 0.01 m aqueous solution of AlCl3 freezes at – 0.068 oC. Calculate the percentage of dissociation. [Given: Kf [3]

for Water = 1.86 K kg mol-1]


20. The freezing point of a solution containing 0.2 g acetic acid in 20.0 g of benzene is lowered by 0.45 0
C . [5]
Calculate:
i. the molar mass of acetic acid from this data

R
ii. van't Hoff factor. [For benzene, K = 5.12 K
f kg mol
−1
] What conclusion can you draw from the value of

SI
van't Hoff factor obtained?

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AS
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89
AV
98

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AVINASH SIR 9889797755

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