Thermodynamics - Answer Key

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Book Crunch Thermodynamics

Thermodynamics

Answer Key
1. (a) U = 0

(b) temperature remains constant

2. (a) U = 37.5 kJ mol

H = 40.6 kJ mol
3. Heat produced = 5.375 kJ
final temperature = 1177.27 K
final pressure 14.39 atm
4. (Athlete should go for 303 lifting.)

5. (ST = 7522.50 J)

6. (KP)300 = 8.94 × 104


(KP)1200 = 0.77
At 300 K, reaction will proceed in forward direction and at 1200 K in backward direction
7. (8) 8. (2)
9. (a) 10. (a)
11. (a) 12. (a)
13. (b, d) 14. (a, b, c, d)
15. (a, c) 16. 93.44 g
17. (Case I : 34 days)
Case II : 24 days
18. (Amount of glucose burnt = 29.25 g)
Heat produced = 458.66 kJ
19. (Molar heat capacity of liquid = 39.04 J/mol)
20. (Eq. of NaOH used for neutralisationof HA = 0.685)
21. (13.4 Kcal)
22. (a)
23. (d)
24. (Heat of transformation = 2.0645 kJ/mole)
25. (56 kJ, 2 × 1010) 26. (671 K)
27. (Backward direction) 28. (–0.16 kJ/mol.k)

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Thermodynamics Book Crunch

29. (Efficiency of engine = 25%)

30. ( H  64.655 kJ

G  – 56 kJ

S  295 / mol k )


31. (–1586 k (theoreticaly))
32. (–61.0 Kcal)
33. (–1479.61 kJ) 34. (–88 kJ)
35. (d) 36. (d)
37. (a) 38. (c)
39. (b) 40. (a)
41. (a) 42. (a)
43. (d) 44. (c)
45. (c) 46. (d)
47. (a) 48. (a)
49. (c, d) 50. (a, c, d)
51. a  (q), b  (p), c  (r), d  (s) 52. (6)

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