Metals and Non-Metals - Short Notes (Prashant Kirad)
Metals and Non-Metals - Short Notes (Prashant Kirad)
Metals and Non-Metals - Short Notes (Prashant Kirad)
SCIENCE
Metals and Non Metals
PRASHANT KIRAD
PRASHANT KIRAD
Metals
Those elements which form ions by losing electrons are called metals.
DUCTILITY SONOROUS
Properties Description/Defination
Metals can be drawn into thin wires. This property is called ductility.
Ductility Copper and aluminum are common examples, often used for electrical
wiring.
Most metals have high melting and boiling points due to the strong
High Melting and
bonding between their atoms. For example, iron and tungsten have very
Boiling Points
high melting points.
Most metals are solid at room temperature, with the exception of
Solid State
mercury, which is liquid.
Metals typically have high density, meaning they are heavy for their
Density
size.
Metals produce a ringing sound when struck, a
Sonorous property known as sonority. This is why metals like iron and
brass are used in making bells and musical instruments.
PRASHANT KIRAD
Reaction with oxygen: When metals react with oxygen, they form metal oxides.
Most metal oxides are basic in nature, meaning they can react with acids to form
salt and water.
Metals + Oxygen → Metal Oxide VIP (very import ant portion)
Reaction with Water: Metals react with water to form metal hydroxides and
hydrogen gas. The reactivity with water varies among metals:
Highly reactive metals (like sodium and potassium) react vigorously with cold water.
Less reactive metals (like magnesium) react with hot water.
Least reactive metals (like iron) react with steam.
Reaction with Acids: Metals react with dilute acids to produce salt and hydrogen
gas. This reaction is more vigorous with more reactive metals.
Displacement Reaction: A more reactive metal can displace a less reactive metal
from its compound in solution. This is known as a displacement reaction.
Example: CuSO4 + Zn → ZnSO4 + Cu
Reaction with Non-metals: Metals can react with non-metals to form ionic
compounds, where metals lose electrons to form cations and non-metals gain
electrons to form anions.
Example: 2 Na + Cl2 → 2 NaCl2
PRASHANT KIRAD
Explanation:
In this activity, metal samples are placed in cold water to
observe reactions. Reactive metals are arranged by
increasing reactivity. Fire and floating observations are
noted. Non-reactive metals with cold water are tested in
hot water and steam. The final arrangement is based on
decreasing reactivity with water, considering reactions
with hot water and steam.
Non-Metals
Those elements which form negative ions by gaining electrons are called
non-metals.
Occurrence of Metals
Metals are predominantly obtained from the Earth's crust, which serves as a major
reservoir for these elements.
Seawater contains soluble salts like sodium chloride and magnesium chloride.
The naturally occurring elements or compounds found in the Earth's crust are
referred to as minerals.
Minerals that can be profitably processed to extract metals are specifically termed
ores.
Cinnabar (HgS): 2HgS (Cinnabar) + 302 (g) + heat → 2HgO (crude-metal) + 2SO2 (g)
: 2HgO (s) + heat → 2Hg (1) + O2 (g)
Copper Glance (Cu2S): Cu2S (Copper-pyrite) + 302 (g) + heat → 2Cu2O (s) + 2SO2 (g)
: 2Cu2O(s) + Cu2S (s) + heat → 6Cu (crude metal) + SO2 (g)
Galena (PbS): 2PbS (Galena) + 302 (g) + heat → 2PbO (s) + 2SO2 (g)
: PbS (s) + 2PbO (s) → 2Pb (crude metal) + SO2 (g)
Roasting: Roasting involves heating of ore lower than its melting point in the presence
of air or oxygen.
Example of Zinc Sulphide ore: 2ZnS (s) + 3O2 (s) → 2ZnO (s) + 2SO2 (g)
Calcination: Calcination involves thermal decomposition of carbonate ores.
Example of Zinc carbonate ore: ZnCO3 (s)→ ZnO (s) + CO2 (g)
The metal oxides thus obtained are then reduced to the corresponding metals by
reduction process. Depending upon the reactivity of metals, reduction is done in
different ways as:
Smelting (Reduction with Carbon): This process, the roasted or calcined ore is mixed
with suitable quantity of coke or charcoal (which act as reducing agent) and is heated
to a high temperature above its melting point.
Example of Zinc: ZnO (s) + C (s) → Zn (s) + CO (g)
Thermite process: It is the technique, to reduce metal oxide using more reactive metal
powder as fuel. Aluminium, magnesium, titanium are some metals which are used as fuel
in thermite process. In this process, a mixture of concentrated oxide ore
and metal powder (i.e., thermite) is taken in a steel crucible and kept on
sand. A mixture of magnesium powder and barium peroxide (called ignition
mixture) is used to ignite the reaction mixture. A large amount of heat is
evolved during the reaction which melts the metal.
PRASHANT KIRAD
At cathode: Na+ + e− → Na
At anode: 2Cl− → Cl2 + 2e−
Electrolytic Refining (Purification of copper): In this process, a thick block of impure metal
is used as anode and a thin strip of pure metal is used as cathode. A solution of metal salt (to
be refined) is used as an electrolyte. When electric current is passed, metal ions from the
electrolyte are reduced as metal which get deposited on the cathode. An equivalent amount
of pure metal from the anode gets oxidized to metal ion and goes into the electrolyte and
from there it goes to cathode and deposit.
Corrosion
Corrosion refers to the gradual
deterioration of a material, typically a
metal, due to the influence of moisture, air,
or chemicals in the surrounding environment.
An example is the rusting of iron.
PRASHANT KIRAD
# TOP 7
IMPORTANT QUESTIONS
1) Explain why calcium metal after reacting with water starts floating on its surface.
Write the chemical equation for the reaction. Name one more metal that starts
floating after some time when immersed in water.
Solution:
When calcium metal reacts with water, it produces hydrogen gas and calcium
hydroxide. The hydrogen gas bubbles stick to the surface of the calcium, creating
buoyancy, causing calcium to float on the water's surface. The chemical equation for
the reaction is:
Ca (s) + 2H2O (l) → Ca(OH)2 (aq) + H2 (g)
Another metal that starts floating after some time when immersed in water is sodium.
2) (a) (i) Write two properties of gold that make it the most suitable metal for
ornaments.
(ii) Name two metals which are the best conductors of heat.
(iii) Name two metals that melt when you keep them on your palm.
(iv) Explain the formation of the ionic compound CaO with an electron-dot structure.
Atomic numbers of calcium and oxygen are 20 and 8 respectively. [5M, 2020]
Solution:
(i). The property of gold used in making ornaments is ductility and
luster.
(ii). Silver are copper are the best conductors of heat.
(iii). Gallium and cesium are the metals that melt when kept on the palm.
(iv) Atomic no. of Ca - 20, Electronic Configuration 2,8,8,2. Atomic no.
of O - 8 Electronic Configuration - 2,6
3) (a)Carbon cannot be used as a reducing agent to obtain Mg from MgO. Why?
(b) How is sodium obtained from molten sodium chloride? Give an equation of the
reactions.
(c) How is copper obtained from its sulfide ore? Give equations of the reactions.
Solution:
(a) Carbon and MgO:
- Carbon can't reduce MgO; Mg is more reactive.
(b) Sodium from Molten NaCl:
-Na obtained from molten NaCl by electrolysis: 2NaCl (l) 2Na (l)+Cl2(g)
PRASHANT KIRAD
(c) Copper from Sulfide Ore:
- Copper from CuFeS2 by smelting: CuFeS2(s) + O2(g)→Cu (l)+FeO (s)+SO2(g)
4) The way, metals like sodium, magnesium, and iron react with air and water is an
indication of their relative positions in the 'reactivity series'. Is this statement true?
Justify your answer with examples.
Solution:
Yes, the statement is true. The reactivity series ranks metals based on their
tendency to undergo reactions. Metals like sodium, which reacts vigorously with both
air and water, magnesium, which burns in air and reacts with water, and iron, which
reacts with oxygen and steam, demonstrate the correlation between their reactivity
and their positions in the reactivity series.
5) A non-metal X exists in two different forms, Y and Z. Y is the hardest natural
substance, whereas Z is a good conductor of electricity. Identify X, Y, and Z.
Solution:
X is carbon. Diamond and graphite are allotropes of carbon. Diamond is the hardest
natural substance, and hence Y is diamond. Graphite is a good conductor of electricity,
and hence Z is graphite.
6) What are the constituents of solder alloy? Which property of solder makes it
suitable for welding electrical wires?
Solution:
Constituents of Solder Alloy:
- Typically, tin and lead or lead-free alternatives with elements like silver, copper, or
antimony.
Property Suitable for Welding Electrical Wires:
- Low melting point of solder (below 450°F or 232°C), enabling easy melting and secure
bonding without damaging the electrical wires.
7) A metal that exists as a liquid at room temperature is obtained by heating its sulfide
in the presence of air. Identify the metal and its ore and give the reaction involved.
Solution:
Mercury is the only metal that exists as a liquid at room temperature.
It can be obtained by heating cinnabar (HgS), the sulfide ore of mercury. We can get
metals low in activity series by heating or reducing their sulfides or oxides.
2 HgO → 2 Hg + O2