Periodic Classification
Periodic Classification
Learning Objectives
After a thorough perusal of this unit, the students will be able to:
➢ recognize the basis of the modern periodic law and its development.
➢ list the features of groups and periods of the modern periodic table.
➢ explain the trend in periodic properties along the periods and groups.
➢ distinguish between ores and minerals .
➢ list out the types of separation of impurities from the ores.
➢ recall the various places of occurrences of minerals in the state of Tamil Nadu.
➢ put forth the properties of metals.
➢ identify the stages involved in metallurgical processes.
➢ think scientifically on alloys and their types.
➢ develop an idea on amalgam.
➢ understand the reason for corrosion and the methods of its prevention.
INTRODUCTION
The eighteenth and nineteenth centuries witnessed a rapid
development in chemistry in all spheres of scientific activities. By 1860, scientists had
already discovered 60 elements and determined their atomic masses. They noticed that
some elements had similar properties and hence arranged them into groups. During this
period, several new elements were discovered. These elements were found to have
different properties. It was realized that instead of studying the properties of all these
elements individually, it would be more convenient to divide them into groups and periods
in such a way that each group contained a certain number of elements (like an array of
fruits and vegetables showing orderliness) with similar properties and periods showing a
regular gradation.
So, scientists made several attempts to arrange elements in a logical
way. You have studied about all these early attempts of arrangement of elements in
standard IX. In continuation of the knowledge gained in the topic periodic classification of
elements in standard IX with earlier concepts and their subsequent deliberations, you get
set to go ahead with the higher order of thinking to enhance your knowledge on the
properties of elements.
MODERN PERIODIC LAW
With reference to the modern periodic law, the elements were arranged in
the increasing order of their atomic numbers to form the modern periodic table. The
modern periodic table is a tabular arrangement of elements in periods and groups,
highlighting the regular repetition of properties of the elements.Table shows the
modern periodic table of 118 elements discovered so far. As you have studied the
features of the modern periodic table in standard IX, here let us confine to the study of
the features of periods and groups.
Modern Periodic Table
Features of Periods
❖The horizontal rows are called periods. There are seven periods in the
periodic table.
❖First period (Atomic number 1 and 2): This is the shortest period. It contains
only two elements (Hydrogen and Helium).
❖Second period (Atomic number 3 to 10): This is a short period. It contains
eight elements (Lithium to Neon).
❖Third period (Atomic number 11 to 18): This is also a short period. It contains
eight elements (Sodium to Argon).
❖accommodates 32 elements. Recently 4 elements have been included by
IUPAC.
❖Fourth period (Atomic number 19 to 36): This is a long period. It contains
eighteen elements (Potassium to Krypton). This includes 8 representative
elements and 10 transition elements.
❖Fifth period (Atomic number 37 to 54): This is also a long period. It contains 18
elements (Rubidium to Xenon). This includes 8 representative elements and 10
transition elements.
❖Sixth period (Atomic number 55 to 86): This is the longest period. It contains 32
elements (Caesium to Radon). This includes 8 representative elements, 10
transition elements and 14 inner transition elements (Lanthanides).
❖Seventh period (Atomic number 87 to 118): Like the sixth period, this period also
Features of Groups
✓ The vertical columns in the periodic table starting from top to bottom are called
groups. There are 18 groups in the periodic table.
✓ Based on the common characteristics of elements in each group, they can be
grouped as various families.
✓ The Lanthanides and Actinides, which form part of Group 3 are called inner
transition elements.
✓ Except 'group 18', all the elements present in each group have the same number of
electrons in their valence shell and thus have the same valency. For example, all the
elements of group 1 have one electron in their valence shells (1s1). So, the valency of
all the alkali metals is ‘1’.
✓ As the elements present in a group have identical valence shell electronic
configurations, they possess similar chemical properties.
✓ The physical properties of the elements in a group such as melting point, boiling
point and density vary gradually.
✓ The atoms of the 'group 18' elements have stable electronic configuration in their
valence shells and hence they are unreactive.
PERIODIC TRENDS IN PROPERTIES
Note:
As the positive charge increases the size of the cation decreases
As the negative charge increases the size of the anion increases
Ionisation Energy
Terminology in metallurgy
Minerals: A mineral may be a single compound or a complex mixture of various
compounds of metals found in the Earth.
Ore: The mineral from which a metal can be readily and economically extracted on a
large scale is said to be an ore
Types of separation or concentration of an ore
There are four major types of separation of ores based on the nature of the ore. The
different kinds of ores of metals are given in periodic Table
Concentration of the crushed ore is done mainly by the following methods: -
(i) Hydraulic (Gravity Separation) method
Principle: The difference in the densities or specific gravities of the ore and the gangue is
the main principle behind this method. Oxide ores are purified by this method. e.g.,
Haematite Fe2O3 the ore of iron.
Note: When the ore is heavier than the impurity, this method can be used.
Method: The ore is poured over a sloping, vibrating corrugated table with grooves and a jet
of water is allowed to flow over it. The denser ore particles settle down in the grooves and
lighter gangue particles are washed down by water.
(ii) Magnetic separation method
Principle: The magnetic properties of the ores form the basis of separation. When either the
ore or the gangue is magnetic, this method is employed. e.g., Tinstone SnO2, the ore of tin.
The ore is treated with a suitable reagent such that the ore is soluble in it
but the impurities are not. The impurities are removed by filtration. The solution of the
ore, ie., the filtrate is treated with a suitable reagent which precipitates the ore. E.g.
Bauxite Al2O3.2H2O, (the ore of aluminium).
Valence electrons: Atoms of metals usually have 1,2 or 3 electrons in their outermost shell.
Formation of ions: Metals form Positive ions by the loss of electrons and hence they are electro
positive.
Discharge of ions: Metals are discharged at the cathode during the electrolysis of their compounds.
Atomicity: Molecules of metals in their vapour state are usually monoatomic.
Nature of oxides: Oxides of metals are usually basic.
METALLURGY OF ALUMINIUM
Aluminium is the metal found most abundantly in the Earth’s crust. Since
it is a reactive metal, it occurs in the combined state. The important ores of aluminium
are as follows
Bauxite is the chief ore of aluminium. The extraction of aluminium from bauxite involves
two steps
(i) Conversion of bauxite into alumina – Baeyer’s Process
The conversion of Bauxite into Alumina involves the following steps:
Bauxite ore is finely ground and heated under pressure with a solution of concentrated
caustic soda solution at 150° C to obtain sodium meta aluminate.
The precipitate is filtered, washed, dried and ignited at 1000°C to get alumina.
(ii) Electrolytic reduction of alumina – Hall’s Process
Aluminium is produced by the electrolytic reduction of fused alumina (Al2O3) in the
electrolytic cell.
Cathode: Iron tank lined with graphite
Anode: A bunch of graphite rods suspended in molten electrolyte.
Electrolyte: Pure alumina+ molten cryolite + fluorspar (fluorspar lowers the fusion temperature
of electrolyte)
Electrolytic process of manufacturing aluminum
Temperature: 900 - 950 °C
Voltage used: 5-6 V
Overall reaction: 2Al2O3 → 4Al + 3O2↑
Aluminium is deposited at the cathode
and oxygen gas is liberated at the anode.
Oxygen combines with
graphite to form CO2. Hall's Process
Physical Properties of Aluminium
✓ It is a silvery white metal
✓ It has low density (2.7) and it is light
✓ It is malleable and ductile
✓ It is a good conductor of heat and electricity.
✓ Its melting point is 660 °C.
✓ It can be polished to produce a shiny attractive appearance.
Chemical Properties of Aluminium
i. Reaction with air: It is not affected by dry air. On heating at 800 °C, aluminium burns very
brightly forming it’s oxide and nitride.
❖ 4 Al + 3 O2 → 2 Al2O3(Aluminium oxide)
❖ 2 Al + N2 → 2 AlN (Aluminium nitride)
ii. Reaction with water: Water does not react with aluminium due to the layer of oxide on it.
When steam is passed over red hot aluminium, hydrogen is produced.
v. Refining: Blister copper contains 98% of pure copper and 2% of impurities and is purified
by electrolytic refining. This method is used to get metal of a high degree of purity. For
electrolytic refining of copper, we use:
METALLURGY OF IRON
Occurrence:
Iron is the second most abundant metal available next to aluminium. It occurs in nature
as oxides, sulphides and carbonates. The ores of iron are as follows:
Ores of iron Formula
Haematite Fe2O3
Magnetite Fe3O4
Iron pyrite FeS2
Iron is chiefly extracted from haematite ore (Fe2O3)
i. Concentration by Gravity Separation:
The powdered ore is washed with a steam of water. As a result, the
lighter sand particles and other impurities are washed away and the heavier ore
particles settle down.
The molten iron is collected at the bottom of the furnace after removing the slag.
The iron thus formed is called pig iron. It is remelted and cast into different moulds. This
iron is called cast iron.
Physical properties:
i. It is a lustrous metal, greyish white in colour.
ii. It has high tensility, malleability and ductility.
iii. It can be magnetized.
Chemical properties:
i. Reaction with air or oxygen: Only on heating in air, iron forms magnetic oxide.
3 Fe + 2 O2 → Fe3O4 (black)
ii. Reaction with moist air: When iron is exposed to moist air, it forms a layer of brown hydrated
ferric oxide on its surface. This compound is known as rust and the phenomenon of formation of
rust is known as rusting.
4 Fe + 3 O2 + x H2O → 2Fe2O3 . xH2O(rust)
iii. Reaction with steam: When steam is passed over red hot iron, magnetic oxide is formed.
3 Fe + 4H2O (steam) → Fe3O4 + 4 H2 ↑
iv. Reaction with chlorine: Iron combines with chlorine to form ferric chloride.
2Fe + 3Cl2 → 2FeCl3 (ferric chloride)
v. Reaction with acids: With dilute HCl and dilute H2SO4 it liberates H2 gas.
Fe + 2HCl → FeCl2 + H2 ↑
Fe + H2SO4 → FeSO4 + H2 ↑
With dilute HNO3 in cold condition it gives ferrous nitrate and ammonium nitrate.
4 Fe + 10 HNO3 → 4 Fe(NO3)2 + NH4NO3 + 3 H2O
With con. H2SO4 it forms ferric sulphate and liberates SO2.
2 Fe + 6 H2SO4 → Fe2(SO4)3 + 3 SO2 + 6 H2O
When iron is dipped in con. HNO3 it becomes chemically passive or inert due to the
formation of a layer of iron oxide (Fe3O4) on its surface.
Types and uses of iron
Pig iron (Iron with 2.0% - 4.5% of carbon): It is used in making pipes, stoves, radiators,
railings, manhole covers and drain pipes.
Steel (Iron with 0.25% - 2.0% of carbon): It is used in the construction of buildings,
machinery, transmission cables and T.V towers and in making alloys.
Wrought iron (Iron with < 0.25% of carbon): It is used in making springs, anchors and
electromagnets.
ALLOYS
An alloy is a homogeneous mixture of two or more metals or of one or more
metals with certain non-metallic elements.
The properties of alloys are often different from those of its components. Pure
gold is brittle to be used. The addition of small percentage of copper enhances its strength
and utility.
Amalgam
An amalgam is an alloy of mercury with another metal. These alloys are formed
through metallic bonding with the electrostatic force of attraction between the electrons
and the positively charged metal ions. Silver tin amalgam is used for dental filling.
(a) By fusing the metals together. E.g. Brass is made by melting zinc and copper.
(b) By compressing finely divided metals. E.g. Wood metal: an alloy of lead, tin, bismuth and
cadmium powder is a fusible alloy.
Alloys as solid solutions:
Alloys can be considered as solid solutions in which the metal with high concentration is
solvent and other metals are solute.
For example, brass is a solid solution of zinc (solute) in copper (solvent).
Types of Alloys
Types of Corrosion
➢ Galvanization: It is the process of coating zinc on iron sheets by using electric current.
➢ Electroplating: It is a method of coating one metal over another metal by passing electric
current.