Chemistry Hons 20 21

COURSES OF STUDIES
FOR
THREE YEAR DEGREE COURSE
IN
SCIENCE HONOURS
CHEMISTRY HONOURS
Choice Based Credit System(CBCS)
First & Second Semester Examination – 2020-21

Third & Fourth Semester Examination – 2021-22
Fifth & Sixth Semester Examination – 2022-23
GOVERNMENT AUTONOMOUS COLLEGE,

PHULBANI, KANDHAMAL
Courses of Studies, Science (Chemistry Honours)-2020
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SYLLABI FOR CBCS COURSE
Ability Ability
Elective: Elective:
CORE Enhancement Enhancement
Discipline Generic
Sem COURESE Compulsory Elective Course
Specific DSE (GE)
(14) Course (AECC) (AEEC) (2)
(4) (4)
(2) (Skill Based)
CORE-I
I AECC-I GE-1A
CORE-II
CORE-III
II AECC-II GE-1B
CORE -IV
CORE-V
III CORE-VI SEC-II GE-2A
CORE-VII
CORE-VIII
IV CORE-IX SEC-I GE-2B
CORE-X
CORE-XI DSE-I
V
CORE-XII DSE-II
CORE-XIII DSE-III
VI
DSE-IV
CORE-XIV
/ Project
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YEAR & SEMESTER-WISE PAPERS & CREDITS AT A GLANCE

Three-Year (6-Semester) CBCS Programme (B.Sc. Hons) (Chemistry Honours)
Yr. Sl.No. Course Structure Code Credit Points
SEMESTER-I
1 Inorganic Chemistry-I C-1.1 4+2
2 Physical Chemistry-I C-1.2 4+2
FIRST YEAR
3 Physics GE-1.3 4+2

4 EVS AECC-1.4 6
SEMESTER-II
5 Organic Chemistry-I C-2.1 4+2
6 Physical Chemistry-II C-2.2 4+2
7 Mathematics GE-2.3 4+2
8 MIL Communication – Odia / MIL (AE) AECC-2.4 6
SEMESTER-III
9 Inorganic Chemistry-II C-3.1 4+2
10 Organic Chemistry-II C-3.2 4+2
SECOND YEAR
11 Physical Chemistry-III C-3.3 4+2

12 Physics GE-3.4 4+2
13 Quantitative & Logical Thinking SECC-II-3.5 6
SEMESTER-IV
14 Inorganic Chemistry-III C-4.1 4+2
15 Organic Chemistry-III C-4.2 4+2
16 Physical Chemistry-IV C-4.3 4+2
17 Mathematics GE-4.4 6
18 Communicative English SECC-I-4.5 6
SEMESTER-V
19 Organic Chemistry-IV C-5.1 4+2
FINAL YEAR
20 Physical Chemistry-V C-5.2 4+2

21 Polymer Chemistry DSE-5.3 4+2
22 Industrial Chemicals and Environment DSE-5.4 4+2
SEMESTER-VI
23 Inorganic Chemistry-IV C-6.1 4+2
24 Organic Chemistry-V C-6.2 4+2
25 Inorganic Materials of Industrial Importance DSE-6.3 4+2
26 Project Work / Green Chemistry DSE-6.4 6 / 4+2
Notes:
 C- Core Course
 GE- Generic Elective Course
 DSE- Discipline Specific Elective Course
 AECC- Ability Enhancement Compulsory Course
 SECC- Skill Enhancement Compulsory Course
 For a 6 credit course, the total teaching hours are: Minimum- 50 Hours, Maximum-65 Hours
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SEMESTER-I
C-1.1 : INORGANIC CHEMISTRY-I
Full Marks – 100
Mid Sem – 15/1hr
End Sem Theory – 60/3 hrs
End Sem Practical – 25/3 hrs
THEORY
UNIT-I : Atomic structure
Bohr’s theory, its limitations and atomic spectrum of hydrogen atom, Sommerfeld’s modification. Wave mechanics:
de Broglie equation, Heisenberg’s Uncertainty Principle, Schrodinger’s wave equation (time independent) and its
significance, Derivation of Schrodinger’s wave equation (for hydrogen atom) in Cartesian coordinate, significance
of ψ and ψ2. Normalized and orthogonal wave functions. Sign of wave functions; Setting of Schrodinger’s equation
in polar coordinates (derivation not required), radial and angular wave functions for hydrogen atom. Radial and
angular distribution curves; Shapes of s, p, d and f orbitals; Quantum numbers and their significance. Pauli’s
Exclusion principle, Hund’s rule of maximum multiplicity, Aufbau’s principle and its limitations.
UNIT-II : Periodicity of elements
Periodicity of Elements: s, p, d, f block elements, the long form of periodic table. Detailed discussion of the
following properties of the elements, with reference to s & p-blocks. (a) Effective nuclear charge, shielding or
screening effect, Slater rules, variation of effective nuclear charge in periodic table. (b) Atomic radii (van der
Waals) (c) Ionic and crystal radii. (d) Covalent radii (octahedral and tetrahedral) (e) Ionization enthalpy, Successive
ionization enthalpies and factors affecting ionization energy. Applications of ionization enthalpy. (f) Electron gain
enthalpy, trends of electron gain enthalpy. (g) Electronegativity, Pauling’s/ Mulliken’s electronegativity scales.
Variation of electronegativity with bond order, partial charge, hybridization. Sanderson’s electron density ratio.
UNIT-III : Chemical bonding-I
(i) Ionic bond: General characteristics, types of ions, size effects, radius ratio rule and its limitations. Packing of
ions in crystals. Born-Lande equation with derivation. Madelung constant, Born-Haber cycle and its application,
Solvation energy. (ii) Covalent bond: Valence Bond theory (Heitler-London approach). Hybridization with suitable
examples of linear, trigonal planar, square planar, tetrahedral, trigonal bipyramidal and octahedral arrangements,
equivalent and non-equivalent hybrid orbitals, Resonance and resonance energy.
Molecular orbital theory. Molecular orbital diagrams of diatomic and simple polyatomic molecules N2, O2, C2, B2,
F2, CO, NO, and their ions (CO+, NO+, NO-).
UNIT-IV : Chemical bonding-II
VSEPR theory, shapes of simple molecules and ions containing lone and bond pairs of electrons, multiple bonding
(σ and π bond approach) and bond lengths. Covalent character in ionic compounds, polarizing power and
polarizability. Fajan’s rules and consequences of polarization. Ionic character in covalent compounds: Bond
moment and dipole moment. Percentage ionic character from dipole moment and electronegativity difference.
(i) Metallic Bond: Qualitative idea of valence bond and band theories. Semiconductors and insulators. (ii) Weak
Chemical Forces: van der Waals forces, ion-dipole forces, dipole-dipole interactions, induced dipole interactions,
Instantaneous dipole-induced dipole interactions. Repulsive forces, Hydrogen bonding (theories of hydrogen
bonding, valence bond treatment) Effects of chemical force, melting and boiling points, solubility energetics of
dissolution process.
Oxidation-reduction: Redox equations, standard electrode potential and its applications to inorganic reactions.
Principles involved in some volumetric analyses (iron and copper).
Recommended Text Books :

1. Lee J. D., Concise Inorganic Chemistry Wiley India, 5th Edn., 2008.
2. Huheey J. E., Keiter E. A. and Keiter R. L., Inorganic Chemistry – Principles of structure and reactivity, ,
Pearson Education, 4th Ed. 2002.
3. Puri, Sharma, Kalia, Principles of Inorganic Chemistry, Vishal Pub. Co., 33rd ed., 2017
4. Malik, Tuli, Madan Selected Topic in Inorganic Chemistry, S. Chand, New Delhi, 17th Ed., 2010.
Reference books :
 Das Asim K., Fundamentals of Inorganic Chemistry, Vol. I, CBS Publications, 2nd Ed. 2010.
 Pradeep’s Inorganic Chemistry, Vol. I & II, Universal Book seller, 14th Ed. 2017.
PRACTICAL
Students are required to learn the followings:
i. Calibration and use of apparatus
ii. Preparation of solutions of different Molarity/Normality of titrants.
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List of experiments
(A) Acid-Base Titrations
i. Estimation of carbonate and hydroxide present together in mixture.
ii. Estimation of carbonate and bicarbonate present together in a mixture.
iii. Estimation of free alkali present in different soaps/detergents
(B) Oxidation-Reduction Titrimetry
i. Standardization of KMnO4 with standard sodium oxalate and estimation of Fe (II) using standardized KMnO4
solution.
ii. Estimation of percentage of oxalic acid and sodium oxalate in a given mixture.
iii. Estimation of Fe (II) and Fe (III) in a mixture by standard K2Cr2O7 solution.
Reference text Books:

 J. Mendham, A. I. Vogel’s Quantitative Chemical Analysis 6th Ed., Pearson, 2009.
 Gulati Shikha , Sharma Gulati JL and Manocha, Shagun, Practical Inorganic Chemistry, 1st Edn., CBS
Publishers & Distributors Pvt Ltd., (2017).
C-1.2 : PHYSICAL CHEMISTRY- I

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Gaseous state-I
Kinetic molecular model of a gas: postulates and derivation of the kinetic gas equation; collision frequency;
collision diameter; mean free path and viscosity of gases, including their temperature and pressure dependence,
relation between mean free path and coefficient of viscosity, calculation of σ from η; variation of viscosity with
temperature and pressure.
Maxwell distribution and its use in evaluating molecular velocities (average, root mean square and most probable)
and average kinetic energy, law of equipartition of energy, degrees of freedom and molecular basis of heat
capacities.
Behaviour of real gases: Deviations from ideal gas behaviour, compressibility factor, Z, and its variation with
pressure for different gases. Causes of deviation from ideal behaviour. van der Waal’s equation of state, its
derivation and application in explaining real gas behaviour. Isotherms of real gases and their comparison with van
der Waals isotherms, continuity of states, critical state, relation between critical constants and van der Waals
constants, law of corresponding states.
UNIT-II : Liquid state
Qualitative treatment of the structure of the liquid state; physical properties of liquids; vapour pressure, surface
tension and coefficient of viscosity, and their determination. Effect of addition of various solutes on surface tension
and viscosity. Explanation of cleansing action of detergents. Temperature variation of viscosity of liquids and
comparison with that of gases. Qualitative discussion of structure of water.
Ionic equilibria- I
Strong, moderate and weak electrolytes, degree of ionization, factors affecting degree of ionization, ionization
constant and ionic product of water. Ionization of weak acids and bases, pH scale, common ion effect; dissociation
constants of mono- and diprotic acids.
UNIT- III: Solid state
Nature of the solid state, law of constancy of interfacial angles, law of rational indices, Miller indices, elementary
ideas of symmetry, symmetry elements and symmetry operations, seven crystal systems and fourteen Bravais
lattices; X-ray diffraction, Bragg’s law, a simple account of rotating crystal method and powder pattern method.
Analyses of powder diffraction patterns of NaCl, CsCl and KCl. Defects in crystals (stoichiometric and non-
stoichiometric). Glasses and liquid crystals.
UNIT-IV : Ionic equilibria - II
Salt hydrolysis-calculation of hydrolysis constant, degree of hydrolysis and pH for different salts. Buffer solutions;
derivation of Henderson equation and its applications; buffer capacity, buffer range, buffer action and applications
of buffers in analytical chemistry and biochemical processes in the human body. Solubility and solubility product of
sparingly soluble salts –applications of solubility product principle. Qualitative treatment of acid – base titration
curves (calculation of pH at various stages). Theory of acid–base indicators; selection of indicators and their
limitations.
Multistage equilibria in polyelectrolyte systems; hydrolysis and hydrolysis constants.
Recommended Text Books:

1. Atkins P. W. & Paula, J. de, Elements of Physical Chemistry, Oxford University Press, 6th Ed., (2006).
2. Puri, Sharma & Pathania, Principles of Physical Chemistry, Vishal Publishing Co, 47th Edn. 2017.
6|Page
3. Kapoor K. L., Text Book of Physical Chemistry, McGraw Hill, 3rd Edn. 2017
4. Castellan G. W. Physical Chemistry 4th Edn. Narosa (2004).
Reference Books:
 Kheterpal S.C., Pradeep’s Physical Chemistry, Vol. I & II, Pradeep Publications
 Mortimer R. G., Physical Chemistry, Elsevier (Academic Press), 3rd Ed (2008).
 Ball D. W. Physical Chemistry Thomson Press, India (2007).
 Engel T. & Reid P., Physical Chemistry, 3rd Ed. Pearson (2013)
PRACTICAL
Surface tension measurements.
a. Determine the surface tension by (i) drop number (ii) drop weight method.
b. Study the variation of surface tension of detergent solutions with concentration.
Viscosity measurement using Ostwald’s viscometer.
a. Determination of viscosity of aqueous solutions of (i) polymer (ii) ethanol and (iii) sugar at room temperature.
b. Study the variation of viscosity of sucrose solution with the concentration of solute.
pH- metry
a. Study the effect on pH of addition of HCl/NaOH to solutions of acetic acid, sodium acetate and their mixtures.
b. Preparation of buffer solutions of different pH (i) Sodium acetate-acetic acid (ii) Ammonium chloride-
ammonium hydroxide.
c. pH metric titration of (i) strong acid vs. strong base, (ii) weak acid vs. strong base.
d. Determination of dissociation constant of a weak acid.
Ionic equilibria
a. Determination of solubility product of PbI2 by titrimetric method.
Reference Books :
 Khosla, B. D. Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand & Co., New Delhi
(2011).
 Garland, C. W., Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry, 8th Ed.; McGraw-Hill,
New York (2003).
 Viswanathan, B., Raghavan, P.S. Practical Physical Chemistry, Viva Books (2009).
 Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H. Freeman & Co., New York
(2003).
GE-1.3 : MECHANICS AND PROPERTIES OF MATTER, OSCILLATION

AND WAVES, THERMAL PHYSICS, ELECTRICITY
AND MAGNETISM AND ELECTRONICS
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Mechanics and Properties of Matter
Moment of Inertia Parallel axis and perpendicular axis theorem, M.I. of a Solid sphere and Solid cylinder,
Gravitational potential and field due to a thin spherical shell and a solid sphere at external points and internal points,
Relation among elastic constants, depression at free end of a light cantilever, Surface tension, pressure, difference
across a curved membrane, viscous flow, Poiseulles formula.
UNIT-II : Oscillation and Waves
Simple harmonic motion, damped harmonic motion, under damped, over damped and critically damped motion,
Forced vibration, Resonance, Wave equation in a medium, Velocity of Longitudinal waves in an elastic medium
and velocity of transverse wave in a stretched string, Composition of SHM, Lissajous figures for superposition of
two orthogonal simple harmonic vibrations (a) with same frequency, (b) frequency with 2:1.
UNIT-III : Thermal Physics
Entropy, change in entropy in reversible and irreversible process, Carnot engine and its efficiency. Carnot Theorem,
Second law of thermodynamics, Kelvin-Planck, Clausius formula. Thermal conductivity, differential equation for
heat flow in one dimension, Maxwell thermodynamic relation (statement only), Clausius Clapeyron
equation, Black body radiation, Planck radiation formula (No derivation).
UNIT-IV : Electricity and Magnetism
Gauss law of electrostatics, use of Gauss law to compute electrostatic field due to a linear charge distribution,
Magnetic induction B, Lorentz force law, Biot Savarts law, Magnetic induction due to long straight current carrying
conductor, and in the axis of a current carrying circular coil, Amperes Circuital law, its differential form, The law of
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electromagnetic equations, its differential and integral form, Maxwells electro-magnetic equations and their
physical significance, Growth and decay of currents in LR and RC circuits, time constant, alternating currents in
RC, RL and LCR circuits, impedance, power factor, resonance.
P-type and N-type semiconductors, PN-Junction as rectifier, Half wave and Full wave rectifiers (Bridge type),
efficiency, ripple factor, use of RC, LC, and filters, working of PNP and NPN transistors, transistor configurations
in CE and CB circuits and relation between α and β. JFET, its operation and characteristics of V-I curve.
Text Books:
1. Elements of Properties of Matter D.S. Mathur (S. Chand Publication)-2010
2. Heat and Thermodynamics A.B. Gupta and H.B. Ray (New Central Book Agency)-2010
3. A Text Books book of oscillations, waves and acoustics (5thed.) M. Ghosh and D. Bhattacharya (S. Chand
Publication)-2018
4. Electricity and magnetism- R. Murugeshan (S. Chand publishing)-2017
5. Fundamentals of Electronics-Raskhit and Chattopadhyay (New age International Publication)-2018
Reference Books:
 Physics of Degree students Vol.I M. Das, P.K. Jena etal (Sri Krishna Prakashan)-2006
 Physics of Degree students Vol.II M. Das, P.K. Jena etal (Sri Krishna Prakashan)-2006
 Waves and Oscillations (2nd ed) N. Subramaniyam and Brij Lal (Vikas Publications)-1994
 A Text Books book of Sound (2nd ed) - N. Subramaniyam and Brij Lal (S. Chand Publications)-1999
PRACTICAL
(Minimum 6 experiments are to be done)
1. To determine the moment of inertia of a fly wheel.
2. To determine the Young’s modulus Y of a wire by Searl’s method.
3. To determine the modulus of rigidity of a wire by Maxwell’s needle/Torsion Pendulum (Dynamic method).
4. To determine g by bar pendulum.
5. To determine the value of Y of a rubber by using travelling microscope.
6. To determine the Rigidity of modulus by static method.
7. To determine the frequency of a telescope by using Sonometer.
8. Verification of Laws of Vibration of a string by using Sonometer.
9. To compare capacitances using De Sauty bridge.
10. To determine the Law of resistance by using Foster bridge.
11. Compare the specific heat of two liquids by method of Cooling.
Reference Books:
 Advanced Practical Physics for students, B.L. Flintand H.T. Worsnop, 1971, Asia Publishing House
 A Laboratory Manual of Physics for Undergraduate Classes, D.P. Khandelwal (1985), Vani Publication
 A Text Books of Practical Physics, Indu Prakash and Ramakrishna, 11th Edition (2011), Kitab Mahal, New
Delhi
AECC-1.4 : ENVIRONMENTAL STUDIES

Full Marks – 100
Mid Sem – 20/1 hr
End Sem – 80/3 hrs
UNIT – I
The Environment: The Atmosphere, Hydrosphere, Lithosphere, Biosphere, Ecology, Ecosystem,
Biogeochemical Cycle (Carbon Cycle, Nitrogen Cycle), Environment Pollution: Air Pollution, Water Pollution,
Soil Pollution, Radiation Pollution
UNIT – II
Population Ecology: Individuals, Species, Pollution, Community, Control Methods of Population, Urbanization
and its effects on Society, Communicable Diseases and its Transmission, Non-Communicable Diseases
UNIT – III
Environmental Movements in India: Grass root Environmental movements in India, Role of women,
Environmental Movements in Odisha, State Pollution Control Board, Central Pollution Control Board
UNIT – IV
Natural Resources: Conservation of Natural Resources, Management and Conservation of Wildlife, Soil Erosion
and Conservation, Environmental Laws: Water Act, 1974, Air Act, 1981, The Wildlife (Protection) Act, 1972,
Environment Protection, 1986, Natural Disasters and their Management
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Books Recommended:
 Dash MC and Mishra PC, Man and Environment, McMillan, London.
 Mishra PC and Das MC, Environment and Society, McMillan, London.
 Odeem EP, Fundamentals of Ecology, Natraj Publication.
 Mishra DD, Fundamental Concept in Environmental Studies, S. Chand, New Delhi.
 Asthana DK and Asthana Meera, A Text book of Environmental Studies, S. Chand, New Delhi.
 Bharucah Erach, Textbook for Environmental Studies, Universities Press India Pvt. Ltd., Hyderabad.
SEMESTER-II
C-2.1 : ORGANIC CHEMISTRY-I
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I: Basics of organic chemistry
Electronic Displacements: Inductive, electromeric, resonance and mesomeric effects, hyperconjugation and their
applications; Dipole moment; Organic acids and bases; their relative strength. Homolytic and heterolytic fission
with suitable examples. Curly arrow rules; Electrophiles and Nucleophiles; Nucleophilicity and basicity; Types,
shape and relative stability of carbocations, carbanions, free radicals and carbenes. Introduction to types of organic
reactions and their mechanism: Addition, Elimination and Substitution reactions.
Carbon-carbon sigma bonds
Chemistry of alkanes: Formation of alkanes, Wurtz Reaction, Wurtz-Fittig Reactions, Free radical substitutions:
Halogenation -relative reactivity and selectivity.
UNIT- II: Stereochemistry
Fischer Projection, Newmann and Sawhorse Projection formulae; Geometrical isomerism: cis–trans and, syn-anti
isomerism, E/Z notations with C.I.P rules. Optical Isomerism: Optical Activity, Specific Rotation,
Chirality/Asymmetry, Enantiomers, Molecules with one and two chiral-centres, Distereoisomers, meso-structures,
Racemic mixture and resolution, inversion. Relative and absolute configuration: D/L and R/S designations.
UNIT- III: Chemistry of aliphatic hydrocarbons
Carbon-Carbon pi bonds:
Formation of alkenes and alkynes by elimination reactions, Mechanism of E1, E2, E1cb reactions. Saytzeff and
Hofmann eliminations. Reactions of alkenes: Electrophilic additions their mechanisms (Markownikoff/ Anti
Markownikoff addition), mechanism of oxymercuration- demercuration, hydroboration oxidation, ozonolysis,
reduction (catalytic and chemical), syn and anti-hydroxylation (oxidation). 1,2- and 1,4-addition reactions in
conjugated dienes and, Diels-Alder reaction; Reactions of alkynes: Acidity, Electrophilic and Nucleophilic
additions. Hydration to form carbonyl compounds, Alkylation of terminal alkynes.
Cycloalkanes and Conformational Analysis
Types of cycloalkanes and their relative stability, Baeyer strain theory, Conformational analysis of alkanes (ethane
and n-butane): Relative stability with energy diagrams. Energy diagrams of cyclohexane: Chair, Boat and Twist
boat forms.
UNIT- IV: Aromatic hydrocarbons
Aromaticity: Huckel’s rule, aromatic character of arenes, cyclic carbocations/ carbanions and heterocyclic
compounds with suitable examples. Electrophilic aromatic substitution: halogenation, nitration, sulphonation and
Friedel-Craft’s alkylation/acylation with their mechanism. Directing effects of the groups

1. Morrison, R. N. & Boyd, R. N., Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson Education).
2. Bhal and Bhal, Advanced Organic Chemistry, 2nd Edition, S. Chand Publisher, 2012.
3. Kalsi, P. S., Stereochemistry Conformation and Mechanism; 8th Edn, New Age International, 2015.
Reference Books:
 Graham Solomons T. W., Fryhle, Craig B., Snyder Scott A, Organic Chemistry, Wiley Student Ed, 11th Edition
(2013)
 Jonathan Clayden, Nick Greeves, Stuart Warren, Organic Chemistry, 2nd Edition, Oxford Publisher, 2014.
 Dhawan, S.N., Pradeep’s Organic Chemistry, (Vol. I and II), Pradeep Publications
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PRACTICAL
Students are required to learn the followings:
 Checking the calibration of the thermometer
 Determination of melting point, effect of impurities on the melting point – mixed melting point of two unknown
organic compounds
 Determination of boiling point of liquid compounds [boiling point lower than and more than 100°C (up to
160°C) by distillation and capillary method respectively] (e.g., ethanol, cyclohexane, ethyl methyl ketone,
cyclohexanone, acetylacetone, anisole, crotonaldehyde, mesityl oxide etc.).
List of experiments
1. Functional group tests for alcohols, phenols, carbonyl and carboxylic acid groups and identification of unknown
organic compounds of CHO system (without element detection).
2. Separation and purification of any one component of following binary solid mixture based on the solubility in
common laboratory reagents like water (cold, hot), dil. HCl, dil. NaOH, dil. NaHCO3, etc. and determination of
melting point. Benzoic acid/p-Toluidine; p-Nitrobenzoic acid/p-Aminobenzoic acid; p-Nitrotolune/p-Anisidine
etc.
3. Chromatography
a. Separation of a mixture of two amino acids by ascending and horizontal paper chromatography
b. Separation of a mixture of two sugars by ascending paper chromatography
c. Separation of a mixture of o-and p-nitrophenol or o-and p-aminophenol by thin layer chromatography (TLC)
Reference Books:
1. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
2. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry, 5th Ed., Pearson
(2012)
C-2.2 : PHYSICAL CHEMISTRY II

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Chemical thermodynamics
Intensive and extensive variables; state and path functions; isolated, closed and open systems; zeroth law of
thermodynamics. First law: Concept of heat(q), work(w), internal energy(U) and statement of first law;
enthalpy(H), relation between heat capacities, calculations of q, w, U and H for reversible, irreversible and free
expansion of gases (ideal and van der Waals) under isothermal and adiabatic conditions. Thermochemistry: Heats of
reactions: standard states; enthalpy of formation of molecules and ions and enthalpy of combustion and its
applications; calculation of bond energy, bond dissociation energy and resonance energy from thermochemical data,
effect of temperature (Kirchhoff’s equations) and pressure on enthalpy of reactions.
UNIT-II :
Carnot cycle, efficiency of heat engine, Carnot theorem Second Law: Concept of entropy; thermodynamic scale of
temperature, statement of the second law of thermodynamics; molecular and statistical interpretation of entropy.
Calculation of entropy change for reversible and irreversible processes.
Third Law: Statement of third law, concept of residual entropy, calculation of absolute entropy of molecules.
Free Energy Functions: Gibbs and Helmholtz energy; variation of S, G, A with T, V, P; Free energy change and
spontaneity. Relation between Joule-Thomson coefficient and other thermodynamic parameters, inversion
temperature, Gibbs-Helmholtz equation, Maxwell relations, thermodynamic equation of state.
UNIT-III : Systems of variable composition
Partial molar quantities, dependence of thermodynamic parameters on composition; Gibbs Duhem equation,
chemical potential of ideal mixtures, change in thermodynamic functions in mixing of ideal gases.
Chemical equilibrium
Criteria of thermodynamic equilibrium, degree of advancement of reaction, chemical equilibria in ideal gases,
concept of fugacity. Thermodynamic derivation of relation between Gibbs free energy of reaction and reaction
quotient (Vant Hoff’s reaction). Equilibrium constants and their quantitative dependence on temperature, pressure
and concentration. Free energy of mixing and spontaneity; thermodynamic derivation of relations between the
various equilibrium constants Kp, Kc and Kx. Le Chatelier principle (quantitative treatment) and its applications.
UNIT-IV : Solutions and Colligative Properties
Dilute solutions; lowering of vapour pressure, Raoult’s and Henry’s Laws and their applications. Thermodynamic
derivation using chemical potential to derive relations between the four colligative properties: (i) relative lowering
10 | P a g e
of vapour pressure, (ii) elevation of boiling point, (iii) Depression of freezing point, (iv) osmotic pressure and
amount of solute. Applications in calculating molar masses of normal, dissociated and associated solutes in
solution.

2. Puri, Sharma & Pathania, Principles of Physical Chemistry, Vishal Publishing Co, 47th Edn., 2017.
3. K. L. Kapoor, Text Book of Physical Chemistry, Mac Grow Hill, 3rd Edn. 2017
4. Castellan G. W. Physical Chemistry 4th Ed. Narosa (2004).
Reference Books:
 Engel T. & Reid P., Physical Chemistry 3rd Ed. Pearson (2013).
 McQuarrie, D. A. & Simon, J. D. Molecular Thermodynamics Viva Books Pvt. Ltd.: New Delhi (2004).
 Kheterpal S.C., Pradeep’s Physical Chemistry, Vol. I & II, Pradeep Publications.
PRACTICAL
THERMOCHEMISTRY
1. Determination of heat capacity of a calorimeter for different volumes using change of enthalpy data of a known
system (method of back calculation of heat capacity of calorimeter from known enthalpy of solution or enthalpy
of neutralization).
2. Determination of heat capacity of the calorimeter and enthalpy of neutralization of hydrochloric acid with
sodium hydroxide.
3. Calculation of the enthalpy of ionization of ethanoic acid.
4. Determination of heat capacity of the calorimeter and integral enthalpy (endothermic and exothermic) solution
of salts.
5. Determination of basicity/ proticity of a polyprotic acid by the thermochemical method in terms of the changes
of temperatures observed in the graph of temperature versus time for different additions of a base. Also calculate
the enthalpy of neutralization of the first step.
6. Determination of enthalpy of hydration of copper sulphate.
7. Determination of heat of solution (ΔH) of oxalic acid/benzoic acid from solubility measurement.
8. Kinetics of pseudo-unimolecular reaction to determine the pseudo first order hydrolysis rate constant of Methyl
acetate at room temperature in 0.5N H2S4 & 0.5N HCl media.
Reference Books :
 Khosla, B.D.; Garg, V.C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand & Co.: New Delhi
(2011).
 Athawale, V. D. & Mathur, P. Experimental Physical Chemistry, New Age International: New Delhi (2001).
 Viswanathan, B., Raghavan, P.S. Practical Physical Chemistry, Viva Books (2009)
GE-2.3 : CALCULUS AND DIFFERENTIAL EQUATIONS

Full Marks – 100
Mid Sem – 20/1hr
Objective: Calculus invented by Newton and Leibnitz is powerful analytical tool to solve mathematical problems
which arise in all branches of science and engineering. The main emphasis of this course is to equip the student with
necessary analytic and technical skills to handle problems of a mathematical nature as well as practical problems using
calculus and differential equation. The aim should be to expose the students to basic ideas quickly without much
theoretical emphasis with importance on applications.
Excepted Outcomes: After completing the course, students are expected to be able to apply knowledge of calculus and
differential equations in the areas of their own interest.
UNIT-I
Curvature, Asymptotes, Tracing of Curves (Catenary, Cycloid, Folium of Descartes), Rectification, Quadrature,
Elementary ideas about Sphere, Cones, Cylinders and Conicoids.
UNIT-II
Review of limits, continuity and differentiability of functions of one variable and their properties, Rolle’s theorem,
Mean value theorems, Taylor’s theorem with Lagrange’s theorem and Cauchy’s form of remainder, Taylor’s series,
Maclaurin’s series of sinx, cosx, ex, log (1+x ), (1+x )m, L’ Hospital’s Rule, other Intermediate forms.
UNIT-III
Limit and Continuity of functions of several variables, Partial derivatives, Partial derivatives of higher orders,
Homogeneous functions, Change of variables, Mean value theorem, Taylors theorem and Maclaurin’s theorem for
11 | P a g e
functions of two variables (statements & applications), Maxima and Minima of functions of two and three variables,
Implicit functions, Lagrange’s multipliers (Formulae & its applications), Concepts of Multiple integrals & its
applications.
UNIT-IV
Ordinary Differential Equations of order one and degree one (variables separable, homogeneous, exact and linear).
Equations of order one but higher degree. Second order linear equations with constant coefficients, homogeneous
forms, Second order equations with variable coefficients, Variation of parameters.
Books Recommended :
1. Shanti Narayan, P. K. Mittal, Differential Calculus, S. Chand, 2014.
2. Shanti Narayan, P. K. Mittal, Integral Calculus, S. Chand, 2014.
3. S.C. Mallik and S. Arora-Mathematical Analysis, New Age International Publications.
4. J. Sinharoy and S. Padhy: A Course of Ordinary and Partial Differential Equations, Kalyani Publishers.
Reference Books :
 H.Anton,I.Bivens and S.Davis,Calculus,10th Ed.,John Wiley and Sons (Asia) P. Ltd., Singapore, 2002.
 Shanti Narayan and P.K. Mittal-Analytical Solid Geometry, S. Chand & Company Pvt. Ltd., New Delhi.
 Martin Braun-Differential Equations and their Applications-Martin Braun, Springer International.
 B. P.Acharya and D. C.Sahu: Analytical Geometry of Quadratic Surfaces, Kalyani Publishers.
AECC – 2.4 : MIL COMMUNICATIONS – ODIA

(ù~ûMûù~ûM @^êaò]ô, eúZò I cû¤c)
Full Marks – 100
Mid Sem – 20/1hr
1c GKK / dê^òUþ – 1 :
ù~ûMûù~ûMe _eòbûhû, @^êaò]ô, _eòie I _âKûeùb\
2d GKK / dê^òUþ – 2 :
iûlûZKûe, bûhY Kkû
3d GKK / dê^òUþ – 3 :
i´û\e _eòbûhû I i´û\ _âÉêZò
4[ð GKK / dê^òUþ – 4 :
IWÿò@û bûhûe a‰ðcûkû, a‰ðûgê¡òe ^òeûKeY û (a^û^ ZîUò - iû\égýR^òZ @gê¡ò, fòwMZ @gê¡ò,
i§òMZ @gê¡ò, icûiMZ @gê¡ò, aP^ I aòbqòMZ @gê¡ò, aûKý aò]ôR^òZ @gê¡ò, icû[ðùaû]K
g±ûgê¡ò, _âZýd R^òZ @gê¡ò, g± iõù~ûMûcôK I ÊeiwZò R^òZ @gê¡ò)
ijûdK Mâ^ÚiìPú :
1. ù~ûMûù~ûM cìkK cûZébûhû (IWÿò@û) - iûcf aòe*ò ^ûeûdY, iZý^ûeûdY aêK ùÁûe, KUK
2. iõù~ûM @^êaò]ò - iù«ûh Kêcûe Zâò_ûVú, ^ûk¦û, KUK
3. bûhY Kkû I @^ýû^ý _âiw - Ké¾P¦â _â]û^, iZý^ûeûdY aêKþ ùÁûe,KUK
4. _âûùdûMòK IWÿò@û bûhû – IWÿògû eûRý_ûVý _êÉK _âYd^ I _âKûg^ iõiÚû, bêaù^gße
5. i´û\ I iû´û\òKZû – P¦âùgLe cjû_ûZâ, IWÿògû eûRý _ûVý_êÉK _âYd^ I _âKûg^ iõiÚû,
bêaù^gße
6. ^òbðêf ùfLûe cìkiìZâ - ^úkû¦òbìhY jeòP¦^, _ò.iò.@ûe _aäòùKi^, bêaù^gße
7. iaðiûe aýûKeY - ^ûeûdY cjû_ûZâ I gâú]e \ûi, ^òdê ÁêùW<iþ ùÁûe, KUK
12 | P a g e
cìfý aòbûR^ _¡Zò : (iaê[ôeê aòKÌ _Wÿòa)

(K) _Zâe ùcûU ^´e – 100
(L) @«ü_eúlû – 20 I cêLý _eúlû – 80
(M) ^ò¡ûð eòZ _ûVýe iaê GKK(dê^òUþ)eê aòKÌij \êAUò ùfLûGñ ùcûU 8Uò 15^´e aògòÁ \úNð _âgÜ
_Wòa û aò\ýû[ðúuê 4Uò _âgÜe C©e ù\aûKê ùja û (15 x 4 = 60)
(N) ^ò¡ðûeòZ _ûVýe iaê GKKeê 12Uò @Zòiõlò¯ _âgÜ _Wÿòa û ùi[ôeê 10Uò _âgÜe C©e ù\aûKê ùja û
(10 x 2 = 20)
AECC-2.4 : MIL (ALTERNATIVE ENGLISH)

Full Marks – 100
Mid Sem – 20/1hr
Introduction:
The paper is focused upon developing one fundamental skills of Language learning; reading which needs a thorough
rethink and revision. In order to build a strong base for acquisition of the communication skills, suitable reading
content is selected from diverse areas in prose form. This would boost the learner’s competence in expressive and
comprehension skills. The well researched language exercises in the form of usage, vocabulary and grammar is the
other area that should attract the teacher and learner to work out for giving decent shape to the mastery of English
language.
UNIT - I: Short Story

a. Jim Corbett-The Fight between Leopards
b. Dash Benhur- The Bicycle
c. Dinanath Pathy- George V High School
d. Alexander Baron- The Man who knew too much
e. Will F Jenkins- Uneasy Homecoming
UNIT - II: Prose
a. Mahatma Gandhi- The way to Equal Distribution
b. S Radhakrishnan- A Call to Youth
c. C V Raman-Water- The Elixir of Life
d. Harold Nicolson- An Educated Person
e. Claire Needell Hollander- No Learning without Feeling
UNIT - III:
Comprehension of a passage and answering the questions
UNIT - IV:
Language exercises-test of vocabulary, usage and grammar
Text Books:
1. All Stories and Prose pieces
Reference Books:
 The Widening Arc: A Selection of Prose and Stories, Ed. A R Parhi, S Deepika, P Jani, Kitab Bhavan,
Bhubaneswar.
 A Communicative Grammar of English, Geoffrey Leech.
 A University Grammar of English, Randolph Quirk and Sidney Greenbaum
 Developing Reading Skills. F. Grellet. Cambridge: Cambridge University Press, 1981.
13 | P a g e
SEMESTER-III
C-3.1 : INORGANIC CHEMISTRY-II
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : General Principles of Metallurgy
Chief modes of occurrence of metals based on standard electrode potentials. Ellingham diagrams for reduction of
metal oxides using carbon and carbon monoxide as reducing agent. Electrolytic Reduction, Hydrometallurgy.
Methods of purification of metals: Electrolytic process, Parting process, van Arkel-de Boer process and Mond’s
process, Zone refining.
Acids and Bases
Bronsted-Lowry concept of acid-base reactions, solvated proton, relative strength of acids, types of acid-base
reactions, Lewis acid-base concept, Classification of Lewis acids, Hard and Soft Acids and Bases (HSAB)
application of HSAB principle.
UNIT-II : Chemistry of s and p Block Elements - I
Inert pair effect, Relative stability of different oxidation states, diagonal relationship and anomalous behaviour of
first member of each group. Allotropy and catenation. Complex formation tendency of s and p block elements.
Hydrides and their classification ionic, covalent and interstitial. Basic beryllium acetate and nitrate.
UNIT-III : Chemistry of s and p Block Elements - II
Study of the following compounds with emphasis on structure, bonding, preparation, properties and uses. Boric acid
and borates, boron nitrides, borohydrides (diborane) carboranes and graphitic compounds, silanes. Oxides and
oxoacids of nitrogen, Phosphorus and chlorine. Peroxo acids of sulphur, interhalogen compounds, polyhalide ions,
pseudohalogens and basic properties of halogens.
UNIT-IV : Noble Gases
Occurrence and uses, rationalization of inertness of noble gases, clathrates; preparation and properties of XeF2,
XeF4 and XeF6; Nature of bonding in noble gas compounds (Valence bond treatment and MO treatment for XeF2).
Molecular shapes of noble gas compounds (VSEPR theory).
Inorganic Polymers:
Types of inorganic polymers, comparison with organic polymers, synthesis, structural aspects and applications of
silicones and siloxanes. Borazines, silicates and phosphazenes, and polysulphates.

1. Lee J. D., Concise Inorganic Chemistry Wiley India, 5th Edn., 2008.
2. Huheey J. E., Keiter E. A. and Keiter R. L., Inorganic Chemistry – Principles of structure and reactivity, Pearson
Education, 4th Ed. 2002.
3. Puri, Sharma, Kalia, Principles of Inorganic Chemistry, Vishal Pub. Co., 33rd Ed., 2017.
4. Shriver D. E., Atkins P. W., Inorganic Chemistry, Oxford University Press, 5th Edn. (2010).
Reference books
 Das Asim K., Fundamentals of Inorganic Chemistry, Vol. I, CBS Publications, 2nd Ed. 2010.
PRACTICAL
Iodometric / Iodimetric titrations
1. Standardization of sodium thiosulphate solution by standard of K2Cr2O7 solution. (ii) Estimation of Cu(II) using
standard sodium thiosulphate solution (Iodimetrically).
2. Estimation of available chlorine in bleaching powder iodometrically.
Inorganic preparations
1. Cuprous oxide (Cu2O)
2. Cuprous chloride (Cu2Cl2)
3. Manganese (III) phosphate (MnPO4.H2O )
4. Aluminium potassium sulphate (K2SO4. Al2(SO4)2.24H2O - Potash alum).
5. Lead chromate (PbCrO4)
Reference Books:
 Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis, 6th Ed., Pearson, 2009.
 Ahluwalia, V.K., Dhingra, S. and Gulati A, College Practical Chemistry, University Press (2005).
 Gulati Shikha, Sharma Gulati JL and Manocha, Shagun, Practical Inorganic Chemistry, 1st Edn., CBS Publishers
& Distributors Pvt. Ltd., (2017).
14 | P a g e
C-3.2 : ORGANIC CHEMISTRY-II
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Chemistry of Halogenated Hydrocarbons
Alkyl halides: Methods of preparation, nucleophilic substitution reactions – SN1, SN2 and SNi mechanisms with
stereochemical aspects and effect of solvent etc.; nucleophilic substitution vs. elimination.
Aryl halides: Preparation, including preparation from diazonium salts, nucleophilic aromatic substitution; SNAr,
Benzyne mechanism.
Relative reactivity of alkyl, allyl/benzyl, vinyl and aryl halides towards nucleophilic substitution reactions.
Organometallic compounds of Mg and Li – Use in synthesis of organic compounds.
UNIT-II : Alcohols, Phenols, Ethers and Epoxides
Alcohols: preparation, properties and relative reactivity of 1°, 2°, 3° alcohols, Bouvaelt-Blanc Reduction;
Preparation and properties of glycols: Oxidation by periodic acid and lead tetraacetate, Pinacol-Pinacolone
rearrangement;
Phenols: Preparation and properties; Acidity and factors effecting it, Ring substitution reactions, Reimer–Tiemann
and Kolbe’s–Schmidt Reactions, Fries and Claisen rearrangements with mechanism;
Ethers and Epoxides: Preparation and reactions with acids. Reactions of epoxides with alcohols, Ammonia
derivatives and LiAlH4.
UNIT-III : Carbonyl Compounds
Structure, reactivity and preparation:
Nucleophilic additions, Nucleophilic addition-elimination reactions with ammonia derivatives with mechanism;
Mechanisms of Aldol and Benzoin condensation, Knoevenagel condensation, Perkin, Cannizzaro and Wittig
reaction, Beckmann rearrangements, α halo form reaction and Baeyer Villiger oxidation, - substitution reactions,
oxidations and reductions (Clemmensen, Wolff-Kishner, LiAlH4, NaBH4, MPV.; Addition reactions of unsaturated
carbonyl compounds: Michael addition.
Active methylene compounds: Keto-enol tautomerism. Preparation and synthetic applications of diethyl malonate
and ethyl acetoacetate.
UNIT-IV : Carboxylic Acids and their Derivatives
Preparation, physical properties and reactions of monocarboxylic acids: Typical reactions of dicarboxylic acids,
hydroxy acids and unsaturated acids: succinic, lactic, malic, tartaric, citric, maleic and fumaric acids;
Preparation and reactions of acid chlorides, anhydrides, esters and amides; Comparative study of nucleophilic
substitution at acyl group -Mechanism of acidic and alkaline hydrolysis of esters, Claisen condensation, Dieckmann
and Reformatsky reactions, Hofmann-bromamide degradation and Curtius rearrangement.
Sulphur containing compounds: Preparation and reactions of thiols and thioethers.

2. Bhal and Bhal, Advanced Organic Chemistry, 2nd Edition, S. Chand Publisher, 2012.
3. Mendham, J., A. I. Vogel’s Quantitative Chemical Analysis, 6th Ed., Pearson, 2009.
Reference Books:
(2013)
PRACTICAL
Organic preparations:
1. Acetylation of one of the following compounds: amines (aniline, o-, m-, ptoluidines and o-, m-, p-anisidine) and
phenols (β-naphthol, vanillin, salicylic acid) by any one method:
a. Using conventional method.
b. Using green approach
2. Benzolyation of one of the following amines (aniline, o-, m-, p- toluidines and o-, m-, p-anisidine) and one of
the following phenols (β-naphthol, resorcinol, pcresol) by Schotten-Baumann reaction.
3. Bromination of any one of the following:
a. Acetanilide by conventional methods
b. Acetanilide using green approach (Bromate-bromide method)
4. Nitration of any one of the following:
a. Acetanilide/nitrobenzene by conventional method
b. Salicylic acid by green approach (using ceric ammonium nitrate).
15 | P a g e
The above derivatives should be prepared using 0.5-1g of the organic compound.
Calculate percentage yield, based upon isolated yield (crude) and theoretical yield.
Purification of the crude product by recrystallisation from water/alcohol, or sublimation, whichever is applicable and
determination of melting point.
Reference Books
 Vogel, A. I. Elementary Practical Organic Chemistry, Part 1: Small scale Preparations, Pearson (2011)
 Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
 Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry, 5th Ed., Pearson
(2012)
 Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and Quantitative
Analysis, University Press (2000).
 Ahluwalia, V.K. & Dhingra, S. Comprehensive Practical Organic Chemistry: Qualitative Analysis, University
Press (2000).
C-3.3 : PHYSICAL CHEMISTRY-III

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Phase Equilibria-I
Concept of phases, components and degrees of freedom, derivation of Gibbs Phase Rule for nonreactive and
reactive systems, Clausius- Clapeyron equation and its applications to solid-liquid, liquid-vapour and solid-vapour
equilibria, phase diagram for one component systems, with applications (H2O and sulphur system).
Phase diagrams for systems of solid-liquid equilibria involving eutectic (Pb-Ag system, desilverisation of lead),
congruent (ferric chloride-water) and incongruent (sodium sulphatewater) melting points, completely miscible solid
solutions (intermediate, medium, maximum freezing points).
UNIT-II
Phase Equilibria-II
Three component systems, water-chloroform-acetic acid system, triangular plots.
Binary solutions: Gibbs-Duhem-Margules equation, its derivation and applications to fractional distillation of
binary miscible liquids (ideal and non-ideal), azeotropes, partial miscibility of liquids, CST, miscible pairs, steam
distillation.
Nernst distribution law: its derivation and applications.
UNIT-III
Chemical Kinetics
Order and molecularity of a reaction, rate laws in terms of the advancement of a reaction, differential and integrated
form of rate expressions up to second order reactions, experimental methods of the determination of orders.
Kinetics of complex reactions (integrated rate expressions up to first order only): (i) Opposing reactions (ii) parallel
reactions (iii) consecutive reactions and their differential rate equations (steady-state approximation in reaction
mechanisms) (iv) chain reactions.
Temperature dependence of reaction rates; Arrhenius equation; activation energy. Collision theory of reaction rates,
qualitative treatment of the theory of absolute reaction rates.
UNIT-IV
Catalysis
Types of catalyst, specificity and selectivity, mechanisms of catalyzed reactions at solid surfaces; effect of particle
size and efficiency of nanoparticles as catalysts. Enzyme catalysis, Michaelis-Menten mechanism, acid-base
catalysis.
Surface chemistry:
Physical adsorption, chemisorption, adsorption isotherms (Langmuir, Freundlich and Gibb’s isotherms), nature of
adsorbed state.

3. Kapoor K. L., Text Book of Physical Chemistry, McGraw Hill, 3rd Edn. 2017
4. Castellan G. W. Physical Chemistry 4th Edn. Narosa (2004).
16 | P a g e
Reference Books:
 Levine, I. N. Physical Chemistry 6th Ed., Tata McGraw-Hill (2011).
 Ball D. W. Physical Chemistry Thomson Press, India (2007).
 Engel T. & Reid P., Physical Chemistry 3rd Ed. Pearson (2013)
PRACTICAL
1. Determination of distribution coefficients of:
(a) Iodine between water and carbon tetrachloride.
(b) Acetic/ benzoic acid between water and cyclohexane.
2. Study the equilibrium of at least one of the following reactions by the distribution method:
 I2 (aq) + I￣ → I3￣(aq)
 Cu2+ (aq) + nNH3 → Cu(NH3)n
3. Study the kinetics of the following reactions.
(i) Integrated rate method:
a) Acid hydrolysis of methyl acetate with hydrochloric acid.
b) Saponification of ethyl acetate.
(ii) Compare the strengths of HCl and H2SO4 by studying kinetics of hydrolysis of methyl acetate.
4. Verify the Freundlich and Langmuir isotherms for adsorption of acetic acid on activated charcoal.
Reference Books:
 Khosla, B. D.; Garg, V. C. & Gulati, A. Senior Practical Physical Chemistry, R. Chand & Co.: New Delhi
(2011).
 Garland, C. W., Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8th Ed.; McGraw-Hill:
New York (2003).
 Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H. Freeman & Co.: New York
(2003).
GE-3.4 : OPTICS, SPECIAL THEORY OF RELATIVITY, ATOMIC PHYSICS,

QUANTUM MECHANICS AND NUCLEAR PHYSICS
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Optics-I: Elementary ideas of monochromatic aberrations and their minimization, chromatic aberration, achromatic
combination, Theory of formation of primary and secondary rainbow, condition of interference, coherent sources,
Youngs double slit experiment, biprism and measurement of wave length of light of by it, color of thin films and
Newton’s rings, Fresnel and Fraunhoffer diffraction, diffraction by single slit plane transmission grating.
Optics-II : Electromagnetic nature of light, polarized and unpolarized light, polarization by reflection and
refraction, Brewster’s Law, Mauls Law, Double refraction, Ordinary and extraordinary rays.
UNIT-II Atomic Physics
Inadequacy of classical physics, brief outline of Rayleigh Jeans theory and Planck’s quantum theory of radiation,
particle nature of electromagnetic radiation photo electric effect, Compton effect, dual nature of radiation, wave
nature of particles, de-Broglie hypothesis, matter wave, wave-particle duality, Davisson- Germer experiment.
Bohr’s theory of Hydrogen atom, explanation of Hydrogen Spectra, correction for finite mass of the nucleus, Bohrs
correspondence principle, limitations of Bohr’s theory, Discrete energy, exchange by atom Frank Hertz experiment.
UNIT-III
Quantum Mechanics : Heisenberg’s Uncertainty relation, Time dependent Schrodinger’s wave equation in one
dimension and three dimensions, The physical interpretation of the wave function, Probability density and
probability current density, Equation of continuity, Normalization of the Wave function, Expectation value of an
observable, Ehrenfest’s theorem. Time independent Schrodinger’s wave equation in one dimension particle in a
box, energy eigen values and eigen functions.
UNIT-IV
Nuclear Physics : Properties of the nucleus Charge, Size, Spin, Magnetic Moment, Mass, Mass defect, Binding
energy, Packing fraction, Nuclear force and its characteristics features, Radioactive decay laws, average life, half
life, nuclear fission, nuclear fusion, Linear accelerators, and cyclotron.
17 | P a g e
Relativity: Galilean transformation, Newtonian relativity and its limitation, Michelson Morley experiment and it’s
consequence, postulates of special theory of relativity. Lorentz transformation, length contraction, time dilation,
relativistic mass and momentum, mass energy relation.
Text Books:
1. University Physics, H. D. Young, R. A. Freedman (Person)-2017
2. Fundamentals of Physics, Resnick, Halliday, Walker (WIley)-2015
Reference Books:
 A Text Books book of Optics N. Subrahmanyam and Brij Lal (S.Chand Publishing)-2006
 Introduction to Special Relativity-R. Resnick (John Wiley)-2007
 Concepts of Modern Physics Arthur Beiser (McGraw Hill)-2017
 Modern Physics H.S. Mani and G.K.Mehta-2018.
PRACTICAL
(Minimum 6 experiments are to be done):
1. Determination of E.C.E. of a Copper by taking 3readings.
2. Determination of Refractive index of the material of a prism using Sodium light.
3. To determine the wavelength of light using plane diffraction grating.
4. To determine the wavelength of light using Newton’s ring.
5. Determination of refractive index of (a) glass and (b) liquid by using travelling microscope.
6. To plot the I-D curve and to determine the refractive index of a prism
7. Determination of radius of curvature of a convex/concave mirror by using Kohlrausch’s method.
8. T o determine the magnifying power of a given telescope.
9. To Obtain the static characteristics of a P-N-P/N-P-N transistor/Triode Valve.
10. To determine the reduction factor of a tangent Galvanometer.
11. To study the Variation of magnetic field along the axis of a circular coil carrying current.
Reference Books:
 Advanced Practical Physics for students, B.L. Flint and H.T. Worsnop, (1971), Asia Publishing House
 A Laboratory Manual of Physics for Undergraduate Classes, D.P. Khandelwal (1985), Vani Publication
 A Text Books of Practical Physics, Indu Prakash and Ramakrishna, 11th Edition (2011), Kitab Mahal, New
Delhi
SECC-II-3.5 : QUANTITATIVE AND LOGICAL THINKING

Full Marks – 100
Mid Sem – 20/1hr
I. QUANTITATIVE APTITUDE & DATA INTERPRETATION

UNIT – I :
Whole numbers, Integers, Rational and irrational numbers, Fractions, Square roots and Cube roots, Surds and
Indices, Problems on Numbers, Divisibility
Steps of Long Division Method for Finding Square Roots:
UNIT – II :
Basic concepts, Different formulae of Percentage, Profit and Loss, Discount, Simple interest, Ratio and Proportion,
Mixture
UNIT – III :
Time and Work, Pipes and Cisterns, Basic concepts of Time, Distance and Speed; relationship among them
UNIT – IV :
Concept of Angles, Different Polygons like triangles, rectangle, square, right angled triangle, Pythagorean
Theorem, Perimeter and Area of Triangles, Rectangles, Circles
UNIT – V :
Raw and Grouped Data, Bar Graphs, Pie charts, Mean, Median and Mode, Events and Sample Space, Probability
II. LOGICAL REASONING

UNIT – I :
Analogy basing on kinds of relationships, Simple Analogy; Pattern and Series of Numbers, Letters, Figures.
Coding-Decoding of Numbers, Letters, Symbols (Figures), Blood relations
UNIT – II :
Logical Statements– Two premise argument, More than two premise argument using connectives
18 | P a g e
UNIT – III :
Venn Diagrams, Mirror Images, Problems on Cubes and Dices
Books Prescribed :
1. Quantitative And Logical Thinking – Odisha State Higher Education Council, Bhubaneswar
SEMESTER-IV
C-4.1 : INORGANIC CHEMISTRY-III
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Coordination Chemistry
Werner’s theory, valence bond theory (inner and outer orbital complexes), electroneutrality principle and back
bonding. IUPAC nomenclature of coordination compounds, isomerism in coordination compounds.
Stereochemistry of complexes with 4 and 6 coordination numbers. Chelate effect, Labile and inert complexes.
Crystal field theory, measurement of CFSE weak and strong fields, pairing energies, factors affecting the magnitude
of 10 Dq in octahedral vs. tetrahedral coordination, tetragonal distortions from octahedral geometry, Jahn-Teller
theorem, square planar geometry. Qualitative aspect of ligand field and MO Theory.
UNIT-II : Transition Elements-I
General group trends with special reference to electronic configuration, colour, variable valency, magnetic and
catalytic properties, and ability to form complexes. Stability of various oxidation states and e.m.f. (Latimer &
Ebsworth diagrams). Difference between the first, second and third transition series.
UNIT-III : Transition Elements-II
Chemistry of Ti, V, Cr, Mn, Fe and Co in various oxidation states (excluding their metallurgy).
Lanthanoids and Actinoids
Electronic configuration, oxidation states, colour, spectral and magnetic properties, lanthanide contraction,
separation of lanthanides (ion-exchange method only). General features of actinoids, separation of Np, Pm, Am
from U.
UNIT-IV ; Bioinorganic Chemistry
Metal ions present in biological systems, classification of elements according to their action in biological system.
Na/K-pump, carbonic anhydrase and carboxypeptidase. Excess and deficiency of some trace metals. Toxicity of
metal ions (Hg, Pb, Cd and As), reasons for toxicity, Use of chelating agents in medicine. Iron and its application
in bio-systems, Haemoglobin and myoglobin.

1. Lee J. D., Concise Inorganic Chemistry, Wiley India, 5th Edn., 2008.
2. Huheey J. E., Keiter E. A. and Keiter R. L., Inorganic Chemistry – Principles of structure and reactivity, Pearson
Education, 4th Ed. 2002.
3. Puri, Sharma, Kalia, Principles of Inorganic Chemistry, Vishal Pub. Co., 33rd ed., 2017.
4. Shriver D. E. Atkins P. W., Inorganic Chemistry, Oxford University Press, 5th Edn..
Reference books :
 Das Asim K., Fundamentals of Inorganic Chemistry, Vol. II, CBS Publications, 2nd Ed. 2010.
 Bioinorganic Chemistry, Asim Kumar Das, Books & Allied (P) Ltd. 1st Ed. 2015.
 Selected Topic in Inorganic Chemistry, Mallick, Madan and Tuli, S. Chand Publisher. 17th Ed. 2010.
PRACTICAL
Inorganic preparations
Preparation of complexes:
i. Hexamine nickel(II), [Ni(NH3)6]Cl2
ii. Potassium trioxalatoferrate (III) trihydrate
iii. Tetraamminecopper (II) sulphate, [Cu(NH3)4]SO4.H2O
iv. Tetraamminecarbonatocobalt (III) nitrate
19 | P a g e
Complexometric titration
i. Estimation of Ca by EDTA
ii. Estimation of Mg by EDTA
Gravimetric Analysis:
i. Estimation of nickel (II) using dimethylglyoxime (DMG).
ii. Estimation of copper as CuSCN
iii. Estimation of iron as Fe2O3 by precipitating iron as Fe(OH)3.
iv. Estimation of Al(III) by precipitating with oxine and weighing as Al(oxine)3 (Aluminium Oxinate).
Chromatography of metal ions
Principles involved in chromatographic separations. Paper chromatographic separation of following metal ions:
i. Ni(II) and Co(II)
ii. Fe(III) and Al(III)
Reference Books:
 Vogel, A.I. A Textbook of Quantitative Inorganic Analysis, ELBS (1978).
 Ahluwalia, V.K., Dhingra, S. and Gulati A, College Practical Chemistry, University Press (2005).
& Distributors Pvt Ltd., (2017).
C-4.2 : ORGANIC CHEMISTRY-III

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Nitrogen Containing Functional Groups
Preparation and important reactions of nitro and compounds, nitriles. Amines: Effect of substituent and solvent on
basicity; Preparation and properties: Gabriel phthalimide synthesis, Carbylamine reaction, Mannich reaction,
Hoffmann’s exhaustive methylation, Hofmann-elimination reaction; Distinction between 1°, 2° and 3° amines with
Hinsberg reagent and nitrous acid.
UNIT-II : Diazonium Salts
Preparation and their synthetic applications.
Polynuclear Hydrocarbons
Reactions of naphthalene and anthracene Structure, Preparation and structure elucidation and important derivatives
of naphthalene and anthracene. Polynuclear hydrocarbons.
UNIT-III : Heterocyclic Compounds
Classification and nomenclature, Structure, aromaticity in 5-numbered and 6-membered rings containing one
heteroatom; Synthesis, reactions and mechanism of substitution reactions of: Furan, Pyrrole (Paal-Knorr synthesis,
Knorr pyrrole synthesis, Hantzsch synthesis), Thiophene, Pyridine (Hantzsch synthesis), Pyrimidine. Fischer indole
synthesis and Madelung synthesis, Derivatives of furan: Furfural and furoic acid (preparation only).
UNIT-IV : Alkaloids
Natural occurrence, General structural features, Isolation and their physiological action. Hoffmann’s exhaustive
methylation, Emde’s modification, Structure elucidation and synthesis of Hygrine and Nicotine. Medicinal
importance of Nicotine, Hygrine, Quinine, Morphine, Cocaine, and Reserpine.
Terpenes
Occurrence, classification, isoprene rule; Elucidation of structure and synthesis of Citral, Neral and α- terpineol.

2. Advanced Organic Chemistry, 2nd Edition, Arun Bahl & B S Bahl, S. Chand Publisher, 2012.
Reference Books:
(2013)
PRACTICAL
Qualitative organic analysis of organic compounds
1. Detection of extra elements (N, X, S) in organic compounds by Lassaigne’s test.
20 | P a g e
2. Qualitative analysis of unknown organic compounds containing simple functional groups under CHN system
(amine, nitro, amide and imide), determination of melting/ boiling point, and preparation of their derivative.
Reference Books :
 Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009).
(2012)
Press (2000).
 Ghoshal, A., Mahapatra, B., Nad, A. K. An Advanced Course in Practical Chemistry, New Central Book
Agency (2007).
C-4.3 : PHYSICAL CHEMISTRY-IV

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Conductance-I
Arrhenius theory of electrolytic dissociation. Conductivity, equivalent and molar conductivity and their variation
with dilution for weak and strong electrolytes. Molar conductivity at infinite dilution. Kohlrausch law of
independent migration of ions. Debye-Huckel-Onsager equation, Wien effect, Debye-Falkenhagen effect, Walden’s
rules.
UNIT-II : Conductance-II
Ionic velocities, mobilities and their determinations, transference numbers and their relation to ionic mobilities,
determination of transference numbers using Hittorf and Moving Boundary methods. Applications of conductance
measurement: (i) degree of dissociation of weak electrolytes, (ii) ionic product of water (iii) solubility and solubility
product of sparingly soluble salts, (iv) conductometric titrations, and (v) hydrolysis constants of salts.
UNIT-III : Electrochemistry-I
Quantitative aspects of Faraday’s laws of electrolysis, rules of oxidation/reduction of ions based on half-cell
potentials, applications of electrolysis in metallurgy and industry. Chemical cells, reversible and irreversible cells
with examples. Electromotive force of a cell and its measurement, Nernst equation; Standard electrode (reduction)
potential and its application to different kinds of half-cells. Application of EMF measurements in determining free
energy, enthalpy and entropy of a cell reaction, (ii) equilibrium constants, and (iii) pH values, using hydrogen,
quinone-hydroquinone, glass electrodes.
UNIT-IV : Electrochemistry-II
Concentration cells with and without transference, liquid junction potential; determination of activity coefficients
and transference numbers. Qualitative discussion of potentiometric titrations (acid-base, redox, precipitation).
Electrical properties of atoms and molecules
Basic ideas of electrostatics, Electrostatics of dielectric media. Clausius-Mosotti equation and Lorenz-Laurentz
equation (no derivation), Dipole moment and molecular polarizabilities and their measurements.

3. Kapoor, K. L., Text Book of Physical Chemistry, Mac Grow Hill, 3rd Edn., 2017
4. Castellan G. W. Physical Chemistry 4th Ed. Narosa (2004).
Reference Books:
 Engel T. & Reid P., Physical Chemistry 3rd Ed. Pearson (2013).
 Levine, I. N. Physical Chemistry 6th Ed., Tata McGraw-Hill (2011).
 McQuarrie, D. A. & Simon, J. D. Molecular Thermodynamics Viva Books Pvt. Ltd.: New Delhi (2004).
PRACTICAL
Conductometry
1. Determination of cell constant.
2. Determination of equivalent conductance, degree of dissociation and dissociation constant of a weak acid.
21 | P a g e
3. Perform the following conductometric titrations:
i. Strong acid vs. strong base
ii. Weak acid vs. strong base
iii. Strong acid vs. weak base
Potentiometry
1. Perform the following potentiometric titrations:
i. Strong acid vs. strong base
ii. Weak acid vs. strong base
iii. Dibasic acid vs. strong base
2. Determination of distribution coefficient of I2 between H2O & CCl4.
Reference Books:
 Khosla, B. D., Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand & Co., New Delhi
(2011).
 Garland, C. W. Nibler, J. W. & Shoemaker, D. P., Experiments in Physical Chemistry 8th Ed.; McGraw-Hill:
New York (2003).
 Halpern, A. M. & McBane, G. C., Experimental Physical Chemistry 3rd Ed.; W.H. Freeman & Co., New York
(2003).
 Viswanathan, B., Raghavan, P.S., Practical Physical Chemistry, Viva Books (2009).
GE-4.4 : ALGEBRA
Full Marks – 100
Mid Sem – 20/1hr
Objective: This is a preliminary course for the basic courses in mathematics like, abstract algebra and linear algebra.
The objective is to acquaint students with the properties of natural numbers i.e. Euclidean algorithm, congruence
relation, fundamental theorem of arithmetic, etc. The basics of linear algebra i.e. vector spaces, matrices are introduced
here.
Expected Outcomes: The acquired knowledge will help students to study further courses in mathematics like, group
theory, ring theory and field theory and linear algebra. It has applications not only in higher mathematics but also in
other science subjects like computer science, statistics, physics, chemistry etc.
UNIT-I
Sets, relations, Equivalence relations, partial ordering, well ordering, Functions, Composition of functions, Invertible
functions, One to one correspondence and cardinality of a set, statements, compound statements, proofs in
Mathematics, Truth tables, Algebra of propositions, logical arguments
UNIT-II
Well-ordering property of positive integers, Division algorithm, Divisibility and Euclidean algorithm, Congruence
relation between integers, Principles of Mathematical Induction, statement of Fundamental Theorem of Arithmetic.
UNIT-III
Matrices, algebra of matrices, determinants, fundamental properties, minors and cofactors, product of determinant,
adjoint and inverse of a matrix, Rank and nullity of a matrix, Systems of linear equations, row reduction and echelon
forms, solution sets of linear systems, applications of linear systems.
UNIT-IV
Vector spaces and subspaces, examples, linear independence, linear dependence, basis, dimension, examples,
Introduction to linear transformations, matrix representation of a linear transformation, Eigen values, Eigen vectors of a
matrix.
Books Recommended :
1. Edgar G. Goodaire and Michael M. Parmenter, Discrete Mathematics with Graph Theory, 3rd Ed., Pearson
Education (Singapore) P. Ltd., Indian Reprint, 2005.
2. V Krishna Murthy, V P Mainra, J L Arora, An Introduction to Linear Algebra, Affiliated East-West Press Pvt.
Ltd.
Reference Books :
 David C. Lay, Linear Algebra and its Applications, 3rd Ed., Pearson Education Asia, Indian Reprint, 2007.
 B S Vatsa and Suchi Vatsa Theory of Matrices New age International third edition 2010.
 Ward Cheney, David kincaid. Linear algebra theory and applications, Jones and Bartlett, 2010.
22 | P a g e
SECC-I-4.5 : COMMUNICATIVE ENGLISH

(Enriching Linguistic Knowledge & Communication Proficiency)
Full Marks – 100
Mid Sem – 20/1hr
UNIT-I : BUSINESS COMMUNICATION AND GRAMMAR

Why English Communication is Essential and How to Improve the Skill?
Introduction to Voice and Accent, Why do we have such different accents?, Accent Training-Consequences, Voice
and accent in the Enterprise Industry, Globally Comprehensible Accent, Introduction to Phonetics, International
Phonetic Alphabet
Consonant Sounds
Vowels
Diphthongs
A Few Phonic Rules
Word Stress: Syllables
Intonation : Intonation and Stress
Pacing and Chunking : Common Patterns of Pacing, Importance of Chunking
Fluency
Indianisms : Errors relating to Grammar, Vocabulary
UNIT-II : GRAMMAR
English: Spoken Versus Written Communication
Nouns : Kinds of Nouns, Activity 3: Noun Ping-pong, Nouns-Number, Noun-Gender, Countable and Uncountable
Nouns
Pronouns : Reflexive Pronouns, Relative Pronouns, Demonstrative Pronouns, Interrogative Pronouns, Indefinite
pronouns, Activity 4: Sentence Auction
Adjectives : Activity 5 : Picture perfect, Positioning of adjectives, Comparative Degrees of Adjectives, Order of
Adjectives
Adverbs : Kinds of Adverb, Degree of Comparison, Word Order with Adverbs, Activity 6: Relay Race
Prepositions : Activity 7: Treasure Hunt, Activity 8: Route Map, Prepositions with Adjectives, Nouns and Verbs
Conjunctions : Coordinating conjunctions, Subordinating Conjunctions, Correlative Conjunctions, Connecting
Adverbs, Activity 9: The Socks Story
Verbs : Verb Classification, List of irregular verbs, Activity 10: Word Search
Subject and verb agreement, Activity 11: Tossed Word Salad, Activity 12: The Sentence Pageant Determiners and
Modifiers : Kinds of determiners, The Definite and the Indefinite Article, Definite Article: The, Activity 13: Proof
Reading
Tenses : Reference Table, Present Tense, Activity 14: Instruction Manual, Activity 15: Commentary, Past Tense,
Activity 16: The Chain List, Activity 17: Transcription, Future Tense, Activity 18: This Week for You, Activity 19:
Verb Grand Prix
Punctuation : Forms of Punctuation
UNIT-III : READING COMPREHENSION
Reading – A 7 Step Process, Techniques to enhance students’ reading skills, Types of reading skills, Skimming,
Scanning, Extensive reading, Intensive reading, Three levels of Reading, Improving your reading speed, Reading
Comprehension Practice Exercises
Text Books:
1. Communicative English – Odisha State Higher Education Council, Bhubaneswar
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SEMESTER-V
C-5.1 : ORGANIC CHEMISTRY-IV
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Organic Spectroscopy-I
UV Spectroscopy: Types of electronic transitions, λmax, Lambert-Beer’s law and its limitations, Chromophores and
Auxochromes, Bathochromic and Hypsochromic shifts, Intensity of absorption; Application of Woodward rules for
calculation of λmax for the following systems: α, β the unsaturated aldehydes: ketones, carboxylic acids and esters;
Conjugated dienes: alicyclic, homoannular and heteroannular; Extended conjugated systems (aldehydes, ketones
and dienes); distinction between cis and trans isomers.
UNIT-II : Organic Spectroscopy-II
IR Spectroscopy: Fundamental and non-fundamental molecular vibrations; IR absorption positions of O and N
containing functional groups; Effect of H-bonding, conjugation, resonance and ring size on IR absorptions;
Fingerprint region and its significance; application in simple functional group analysis.
UNIT-III
Organic Spectroscopy-III
NMR Spectroscopy: Basic principles of Proton Magnetic Resonance, chemical shift and factors influencing it; Spin-
spin coupling and coupling constant; Anisotropic effects in alkene, alkyne, aldehydes and aromatics; Interpretation
of NMR spectra of simple compounds.
Mass Spectroscopy- Basic principle, Fragmentation pattern, instrumentation, determination of m/e ratio.
Application of mass spectroscopy on CH4, C2H6, n-butane and neo-pentane. Applications of IR, UV & NMR for
identification of simple organic molecules.
UNIT-IV : Carbohydrates
Occurrence, classification and their biological importance.
Monosaccharides: Constitution and absolute configuration of glucose and fructose, epimers and anomers,
mutarotation, determination of ring size of glucose and fructose, Haworth projections and conformational
structures; Interconversions of aldoses and ketoses; Killiani-Fischer synthesis and Ruff degradation;
Disaccharides – Structure elucidation of maltose; Polysaccharides – Elementary treatment of starch, cellulose.

1. Kemp William, Organic Spectroscopy, 3rd Edition, Palgrave Publisher, 1991.
2. Davis, B. G., Fairbanks, A. J., Carbohydrate Chemistry, Oxford Chemistry Primer, Oxford University Press.
3. J Kalsi P. S., Spectroscopy of Organic Compounds, 5th Edition, New Age International Publishers, 2016.
4. Advanced Organic Chemistry, 2nd Edition, Arun Bahl & B S Bahl, S. Chand Publisher, 2012.
Reference Books:
 Y R Sharma, Elementary Organic Spectroscopy, 5th Edition, S. Chand & Company, 2013.
 Jag Mohan, Organic Spectroscopy and Applications, Narosa Publishers, 2012.
(2013).
PRACTICAL
1. Qualitative analysis of carbohydrate: aldoses and ketoses, reducing and non-reducing sugars.
2. Qualitative analysis of unknown organic compounds containing simple bifunctional groups, for e.g. salicylic
acid, cinnamic acid, nitrophenols etc.
3. Quantitative estimation of sugars:
(a) Estimation glucose by titration with Fehling’s solution.
(b) Estimation of sucrose by titration with Fehling’s solution.
(c) Estimation glucose and sucrose in a given mixture.
4. Identification of labelled peaks in the 1H NMR spectra of the known organic compounds explaining the relative
δ-values and splitting pattern.
5. Identification of labelled peaks in the IR spectrum of the same compound explaining the relative frequencies of
the absorptions (CORE PAPERH, O-H, N-H, CORE PAPERO, CORE PAPERN, CORE PAPERX, C=C, C=O,
N=O, C≡C, C≡N stretching frequencies; characteristic bending vibrations are included).
24 | P a g e
Reference Books:
 Vogel, A.I. Quantitative Organic Analysis, Part 3, Pearson (2012).
 Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
(2012)
 Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and Quantitative
Analysis, University Press (2000).
Press (2000).
C-5.2 : PHYSICAL CHEMISTRY-V

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Quantum Chemistry-I
Quantum mechanical operators, Postulates of quantum mechanics, Schrodinger equation and its application to
particle in one-dimensional box (complete solution) - quantization of energy levels, zero-point energy,
normalization of wave functions, probability distribution functions, nodal properties. Extension to three-
dimensional boxes, separation of variables, degeneracy.
Qualitative treatment of simple harmonic oscillator model of vibrational motion: Setting up of Schrodinger
equation and discussion of solution and wave functions. Vibrational energy of diatomic molecules and zero-point
energy.
Angular momentum: Commutation rules, quantization of square of total angular momentum and z-component.
Rigid rotator model of rotation of diatomic molecule: Schrodinger equation, transformation to spherical polar
coordinates. Separation of variables (Preliminary treatment).
UNIT-II : Chemical Bonding
Chemical bonding: Covalent bonding, valence bond and molecular orbital approaches, LCAOMO treatment of H2+.
Bonding and antibonding orbitals. Qualitative extension to H2. Comparison of LCAO-MO and VB treatments of H2
(only wave functions, detailed solution not required) and their limitations. Localized and non-localized molecular
orbitals treatment of triatomic (BeH2, H2O) molecules. Qualitative MO theory and its application to AH2 type
molecules.
UNIT-III : Molecular Spectroscopy-I
Interaction of electromagnetic radiation with molecules and various types of spectra; Born-Oppenheimer
approximation.
Rotation spectroscopy: Selection rules, intensities of spectral lines, determination of bond lengths of diatomic and
linear triatomic molecules, isotopic substitution.
Vibrational spectroscopy: Classical equation of vibration, computation of force constant, amplitude of diatomic
molecular vibrations, anharmonicity, Morse potential, dissociation energies, fundamental frequencies, overtones,
hot bands, degrees of freedom for polyatomic molecules, modes of vibration. Vibration-rotation spectroscopy:
diatomic vibrating rotator, P, Q, R branches.
UNIT-IV : Molecular Spectroscopy-II
Raman spectroscopy: Qualitative treatment of Rotational Raman effect; Effect of nuclear spin, Vibrational Raman
spectra, Stokes and anti-Stokes lines; their intensity difference, rule of mutual exclusion.
Electronic spectroscopy: Franck-Condon principle, electronic transitions, singlet and triplet states, fluorescence and
phosphorescence, dissociation and predissociation.
Photochemistry
Characteristics of electromagnetic radiation, physical significance of absorption coefficients. Laws of
photochemistry, quantum yield, actinometry, examples of low and high quantum yields, photochemical equilibrium
and the differential rate of photochemical reactions, photosensitised reactions, quenching, chemiluminescence.

1. McQuarie D., Quantum Chemistry, University Science Publishers, 2007
2. Chandra, A. K. Introductory Quantum Chemistry Tata McGraw-Hill (2001).
3. Banwell, C. N. & McCash, E. M. Fundamentals of Molecular Spectroscopy 4th Ed. Tata McGraw-Hill: New
Delhi (2010).
4. Prasad R K., Quantum Chemistry, New Age International Publishers, 4th Edn, 2010.
5. Rohatagi Mukherjee K K., Fundamentals of Photochemistry, Wiley Eastern Ltd., 1992.
25 | P a g e
Reference Books:
 Puri, Sharma & Pathania, Principles of Physical Chemistry, Vishal Publishing Co, 47th Edn., 2017.
 Kapoor, K. L., Text Book of Physical Chemistry, McGraw Hill, Vol. II, IV.
 Levine, I. N. Quantum Chemistry, PHI.
PRACTICAL
Spectroscopy/Colorimetry
1. Study of absorption spectra (visible range) of KMnO4 and determine the λmax value. Calculate the energies of the
transitions in kJ mol-1, cm-1, and eV.
2. Verify Lambert-Beer’s law and determine the concentration of CuSO4/ KMnO4/K2Cr2O7 in a solution of
unknown concentration.
3. Determine the dissociation constant of an indicator (phenolphthalein).
Spectrophotometric titration
1. Determine the concentration of HCl against 0.1 N NaOH spectrophotometrically.
2. To find the strength of given ferric ammonium sulfate solution of (0.05 M) by using EDTA
spectrophotometrically.
3. To find out the strength of CuSO4 solution by titrating with EDTA spectrophotometrically.
4. To determine the concentration of Cu(II) and Fe(III) solution photometrically by titrating with EDTA.
5. Estimation of Ca & Mg in a mixture by EDTA titration method.
Reference Books :
 Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand & Co.: New Delhi
(2011).
 Garland, C. W., Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8th Ed.; McGraw-Hill:
New York (2003).
 Halpern, A.M. & McBane, G.C. Experimental Physical Chemistry 3rd Ed.; W.H. Freeman & Co.: New York
(2003).
 J. N. Gurtu, R. Kapoor, Experimental Physical Chemistry.
DSE-5.3 : POLYMER CHEMISTRY

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Introduction and history of polymeric materials:
Different schemes of classification of polymers, Polymer nomenclature, Molecular forces and chemical bonding in
polymers, Texture of Polymers.
Functionality and its importance:
Criteria for synthetic polymer formation, classification of polymerization processes, Relationships between
functionality, extent of reaction and degree of polymerization. Bifunctional systems, Poly-functional systems.
UNIT-II
Mechanism & Kinetics of Polymerization:
Polymerization reactions – addition and condensation, mechanism and kinetics of step growth, radical chain
growth, ionic chain (both cationic and anionic) and coordination polymerizations, Mechanism and kinetics of
copolymerization, polymerization techniques.
Crystallization and crystallinity:
Determination of crystalline melting point and degree of crystallinity, Morphology of crystalline polymers, Factors
affecting crystalline melting point.
UNIT-III
Molecular weight of polymers and their determination (Mn, Mw, Mv, Mz) by end group analysis, viscometry and
osmotic pressure methods. Molecular weight distribution and its significance. Polydispersity index.
Glass transition temperature (Tg) and it determination: WLF equation, Outlines of factors affecting glass
transition temperature (Tg).
UNIT-IV
Properties of polymers (physical, thermal and mechanical properties)
Preparation, structure, properties and applications of the following polymers: polyolefins (polyethylene,
polypropylene), polystyrene, polyvinyl chloride, polyvinyl acetate, polyacrylamide, fluoro polymers (Teflon),
26 | P a g e
polyamides (nylon-6 and nylon 6, 6). Thermosetting polymers - phenol formaldehyde resins (Bakelite, Novalac),
polyurethanes, conducting polymers (polyacetylene, polyaniline). Brief outline of biodegradable polymers.

1. V. R. Gowarikar, Jayadev Sreedhar, N. V. Viswanathan, Polymer Science 1st Edition, New Age International
Publishers, 1986.
2. Premamoy Ghosh, Polymer Science and Technology: Plastics, Rubber, Blends and Composites, 3rd Edition,
McGraw Hill Education, 2010.
3. P. Bahadur & N.V.Sastry, Principles of polymer science, Narosa Publishing house, New Delhi 2002.
4. Fred W. Billmeyer, Textbook of Polymer Science, 3rd ed. Wiley- Interscience (1984)
Reference books :
 L.H. Sperling, Introduction to Physical Polymer Science, 4th ed. John Wiley & Sons (2005)
 Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed. Oxford University Press (2005)
 Seymour/ Carraher’s Polymer Chemistry, 9th ed. by Charles E. Carraher, Jr. (2013).
 Nayak P.L., Polymer Chemistry, Kalyani Publisher (2017).
PRACTICAL
Polymer synthesis (At least three experiments)
1. Preparation of nylon-6,6 / Polyaniline.
2. Preparations of phenol-formaldehyde resin-novalac/ phenol-formaldehyde resin resold.
3. Preparation of urea-formaldehyde resin.
4. Free radical solution polymerization of styrene (St)/Methyl Methacrylate (MMA)/Methyl Acrylate (MA)/
Acrylic acid (AA).
a. Purification of monomer.
b. Polymerization using benzoyl peroxide (BPO)/2,2’-azo-bis-isobutylonitrile (AIBN).
5. Redox polymerization of acrylamide.
6. Precipitation polymerization of acrylonitrile.
Polymer characterization/analysis (At least two different experiments)
1. Determination of molecular weight by viscometry:
a. Polyacrylamide / Polystyrene
b. Polyvinyl pyrolidine (PVP)
2. Determination of acid value/ saponification value of a resin.
3. Determination of hydroxyl number of a polymer using colorimetric method.
4. Estimation of the amount of HCHO in the given solution by sodium sulphite method
5. Analysis of some IR spectra of polymers – Identification of labelled peaks in IR spectra of known polymer.
Reference Books:
 Hundiwale G.D., Athawale V.D., Kapadi U.R. and Gite V. V., Experiments in Polymer Science, New Age
Publications (2009).
 Malcohm P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed.
 Joel R. Fried, Polymer Science and Technology, 2nd Ed. Prentice-Hall (2003).
 Petr Munk and Tejraj M. Aminabhavi, Introduction to Macromolecular Science, 2nd Ed. John Wiley & Sons
(2002).
 Malcolm P. Stevens, Polymer Chemistry: An Introduction, 3rd ed. Oxford University Press (2005).
DSE-5.4 : INDUSTRIAL CHEMICALS AND ENVIRONMENT

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Industrial Gases and Inorganic Chemicals
Industrial Gases: Large scale production uses storage and hazards in handling of the following gases: oxygen,
nitrogen, argon, hydrogen, acetylene, carbon monoxide, chlorine, sulphur dioxide.
Inorganic Chemicals: Manufacture, application and hazards in handling the following chemicals: hydrochloric acid,
nitric acid, sulphuric acid, caustic soda, common salt, bleaching powder, sodium thiosulphate, hydrogen peroxide,
potash alum, potassium dichromate and potassium permanganate.
27 | P a g e
Industrial Metallurgy
Preparation of metals (ferrous and nonferrous) and ultrapure metals for semiconductor technology.
UNIT-II
Environment and its segments
Ecosystems. Biogeochemical cycles of carbon, nitrogen and sulphur.
Air Pollution: Major regions of atmosphere. Chemical and photochemical reactions in atmosphere. Air pollutants:
types, sources, particle size and chemical nature; Photochemical smog: its constituents and photochemistry.
Environmental effects of ozone. Major sources of air pollution. Pollution by SO2, CO2, CO, NOx, and H2S and
control procedures. Effects of air pollution on living organisms and vegetation. Greenhouse effect and global
warming, Ozone depletion by oxides of nitrogen, chlorofluorocarbons and halogens, removal of sulphur from coal.
UNIT-III
Water Pollution: Hydrological cycle, water resources, aquatic ecosystems, Sources and nature of water pollutants,
Techniques for measuring water pollution, Impacts of water pollution on hydrological and ecosystems. Water
purification methods. Effluent treatment plants (primary, secondary and tertiary treatment). Industrial effluents from
the following industries and their treatment: electroplating, textile, tannery, dairy, petroleum and petrochemicals,
fertilizer. Sludge disposal. Industrial waste management: incineration of waste. Water treatment and purification
(reverse osmosis, ion exchange). Water quality parameters for wastewater, industrial water and domestic water.
UNIT-IV
Energy and Environment
Sources of energy: Coal, petrol and natural gas. Nuclear fusion/fission, solar energy, hydrogen, geothermal, tidal
and hydel. Nuclear Pollution: Disposal of nuclear waste, nuclear disaster and its management.
Biocatalysis
Introduction to biocatalysis: Importance in green chemistry and chemical industry.

1. De, A. K. Environmental Chemistry: New Age International Pvt., Ltd, New Delhi, 2010.
2. Stocchi E., Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
3. Sharma, B.K. & Gaur, H. Industrial Chemistry, Goel Publishing House, Meerut (1996).
Reference Books:
 Felder R.M. and Rousseau R.W., Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi.
 Dara S. S., A Textbook of Engineering Chemistry, S. Chand & Company Ltd. New Delhi.
 Miller G.T., Environmental Science, 11th edition. Brooks/ Cole (2006).
 Mishra, Environmental Studies, Selective and Scientific Books, New Delhi (2005).
PRACTICAL
2. Determination of Dissolved Oxygen (DO) in water.
3. Determination of Chemical Oxygen Demand (COD)
4. Determination of Biological Oxygen Demand (BOD)
5. Percentage of available chlorine in bleaching powder.
6. Measurement of chloride, sulphate and salinity of water samples by simple titration method (AgNO3 and
potassium chromate).
7. Estimation of total alkalinity of water samples (CO32-, HCO3-) using double titration method.
8. Measurement of dissolved CO2.
9. Study of some of the common bio-indicators of pollution.
10. Estimation of SPM in air samples.
11. Preparation of borax/ boric acid.
Reference Books:
 Dara S. S., A Textbook on Experiments and Calculations in Engineering Chemistry S Chand & Company; 9th
revised edition (2015).
 E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
 R.M. Felder, R.W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi.
 A. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi.
 S. M. Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd, New Delhi.
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SEMESTER-VI
C-6.1 : INORGANIC CHEMISTRY-IV
Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I : Organometallic Compounds-I
Definition and classification of organometallic compounds on the basis of bond type. Concept of hapticity of
organic ligands. Metal carbonyls: 18 electron rule, electron count of mononuclear, polynuclear and substituted
metal carbonyls of 3d series. General methods of preparation (direct combination, reductive carbonylation, thermal
and photochemical decomposition) of mono and binuclear carbonyls of 3d series. Structures of mononuclear and
binuclear carbonyls of Cr, Mn, Fe, Co and Ni using VBT. π-acceptor behaviour of CO (MO diagram of CO to be
discussed), synergic effect and use of IR data to explain extent of back bonding.
Zeise’s salt: Preparation and structure, evidences of synergic effect and comparison of synergic effect with that in
carbonyls.
UNIT-II : Organometallic Compounds-II
Metal Alkyls: Important structural features of methyl lithium (tetramer) and trialkyl aluminium (dimer), concept of
multicentre bonding in these compounds. Role of triethyl aluminium in polymerisation of ethene (Ziegler – Natta
Catalyst). Species present in ether solution of Grignard reagent and their structures.
Ferrocene: Preparation and reactions (acetylation, alkylation, metallation, Mannich Condensation), structure and
aromaticity, comparison of aromaticity and reactivity with that of benzene.
UNIT-III : Catalysis by Organometallic Compounds
Study of the following industrial processes and their mechanism:
1. Alkene hydrogenation (Wilkinson’s Catalyst)
2. Hydroformylation (Co salts)
3. Wacker Process
4. Synthetic gasoline (Fischer Tropsch reaction)
Theoretical Principles in Qualitative Analysis (H2S Scheme)
Basic principles involved in analysis of cations and anions and solubility products, common ion effect. Principles
involved in separation of cations into groups and choice of group reagents. Interfering anions (fluoride and
phosphate) and need to remove them after Group II.
UNIT-IV : Thermodynamic & kinetic aspects and reaction mechanism of metal complexes
Thermodynamic and kinetic stability, Stepwise and overall formation constants and their relationship, factors
affecting stability. Introduction to inorganic reaction mechanisms-types of reaction and classification of substitution
reaction. Substitution reaction of square planar complexes, Trans effect and its applications, theories of trans-effect
(electrostatic polarization and Static π-Bonding Theory). Kinetics of octahedral substitution (classification of metal
ions based on water exchange rate), General mechanism of ligand substitution reactions in octahedral complexes
(D, I, Id, Ia).

1. Huheey J. E., Keiter E. A. and Keiter R. L., Inorganic Chemistry – Principles of structure and reactivity, ,
Pearson Education, 4th Ed. 2002.
2. Puri, Sharma, Kalia, Principles of Inorganic Chemistry, Vishal Pub. Co., 33rd Ed., 2017.
3. Shriver D. E. Atkins P. W., Inorganic Chemistry, Oxford University Press, 5th Edn.
4. Svehla, G. Vogel's Qualitative Inorganic Analysis, 7th Edition, Prentice Hall, 1996-0307.
Reference books:
 Das Asim K., Fundamentals of Inorganic Chemistry, Vol. II, CBS Publications, 2nd Ed. 2010.
 Selected Topic in Inorganic Chemistry, Mallick, Madan and Tuli, S. Chand Publisher. 17th Ed. 2010.
 Mehrotra R.C. and Singh, A. Organometallic Chemistry, New Age International Publishers, 2nd Edn, 2000.
 Gupta B. D. and Elias A. J., Basic Organometallic Chemistry, 2nd Edn., University Press (2013).
PRACTICAL
1. Qualitative analysis of mixtures containing 4 radicals (2 anions and 2 cations). Emphasis should be given to the
understanding of the chemistry of different reactions. The following radicals are suggested:
CO32-, NO2-, S2-, SO32-, F-, Cl-, Br-, I-, NO3-, PO43-, NH4+, K+, Pb2+, Cu2+, Cd2+, Bi3+, Sn2+, Sb3+, Fe3+, Al3+, Cr3+,
Zn2+, Mn2+, Co2+, Ni2+, Ba2+, Sr2+, Ca2+, Mg2+.
2. Mixtures may contain one insoluble component (BaSO4, SrSO4, PbSO4, CaF2 or Al2O3) or combination of
interfering anions e.g. CO32- and SO32-, NO2 and NO3-, Cl- and Br-, Cl- and I-, Br- and I-, NO3 and Br-, NO3 and
I-.
3. Spot tests should be done whenever possible.
29 | P a g e
Reference Books:
 Vogel’s Qualitative Inorganic Analysis, 7th Ed, Revised by G. Svehela, 4th Ed., Person (2007).
& Distributors Pvt Ltd., (2017).
C-6.2 : ORGANIC CHEMISTRY-V

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Amino Acids, Peptides and Proteins
Amino acids: Classification; α-Amino acids - Synthesis, ionic properties and reactions. Zwitterions, pKa values,
isoelectric point and electrophoresis.
Peptides: Classification, Determination of their primary structures-end group analysis, methods of peptide
synthesis. Synthesis of peptides using N-protecting, CORE PAPER protecting and CORE PAPER activating groups
- Solid-phase synthesis.
Proteins: Structure of proteins, protein denaturation and renaturation
UNIT-II
Enzymes
Introduction, classification and characteristics of enzymes. Salient features of active site of enzymes. Mechanism of
enzyme action (taking trypsin as example), factors affecting enzyme action, coenzymes and cofactors and their role
in biological reactions, specificity of enzyme action (including stereo specificity), enzyme inhibitors and their
importance, phenomenon of inhibition (competitive, uncompetitive and non-competitive inhibition including
allosteric inhibition).
Nucleic Acids
Components of nucleic acids, Nucleosides and nucleotides; Structure, synthesis and reactions of: Adenine, Guanine,
Cytosine, Uracil and Thymine; Structure of polynucleotides.
UNIT-III
Lipids
Introduction to oils and fats; common fatty acids present in oils and fats, Hydrogenation of fats and oils,
Saponification value, acid value, iodine number. Reversion and rancidity.
Concept of Energy in Biosystems
Cells obtain energy by the oxidation of foodstuff (organic molecules). Introduction to metabolism (catabolism and
anabolism).
Overview of catabolic pathways of fat and protein. Interrelationship in the metabolic pathways of protein, fat and
carbohydrate. Caloric value of food, standard caloric content of food types.
UNIT-IV
Pharmaceutical Compounds: Structure and Importance
Classification, structure and therapeutic uses of antipyretics: Paracetamol (with synthesis), Analgesics: Ibuprofen
(with synthesis), Antimalarials: Chloroquine (with synthesis). An elementary treatment of Antibiotics and detailed
study of chloramphenicol, Medicinal values of curcumin (haldi), azadirachtin (neem), vitamin C and antacid
(ranitidine).
Dyes
Classification, colour and constitution; Mordant and Vat dyes; Chemistry of dyeing. Synthesis and applications of:
Azo dyes – Methyl orange and Congo red (mechanism of Diazo Coupling); Triphenylmethane dyes - Malachite
Green, and crystal violet; Phthalein dyes –Phenolphthalein and Fluorescein.
Recommended Text books :

1. Nelson, D.L., Cox, M.M. and Lehninger, A.L. Principles of Biochemistry. 6th Edn. W.H. Freeman and Co.
(2013).
2. Kar Ashutosh, Medicinal chemistry, New Age International (P) Ltd., (2007)
3. Debojyoti Das, Biochemistry, (Part-I) Academic Publishers (1979)
Reference Books:
 Talwar, G.P. & Srivastava, M. Textbook of Biochemistry and Human Biology, 3rd Ed. PHI Learning.
 Berg, J.M., Tymoczko, J.L. & Stryer, L. Biochemistry, W.H. Freeman, 2002.
 Murray, R.K., Granner, D.K., Mayes, P.A. and Rodwell, V.W. (2009) Harper’s Illustrated Biochemistry.
XXVIII edition. Lange Medical Books/ McGraw-Hill.
 Berg, J.M., Tymoczko, J.L. and Stryer, L. (2006) Biochemistry, 6th Edition. W.H. Freeman and Co. (2002).
30 | P a g e
 Wilson, K. & Walker, J. Practical Biochemistry. Cambridge University Press (2009).
 The Tools of Biochemistry (1977; Reprint 2011) Cooper, T.G., Wiley India Pvt. Ltd. (New Delhi), ISBN: 978-
81-265-3016-8.
PRACTICAL
1. Preparations of the following compounds
i. Aspirin
ii. Methyl orange
2. Estimation of phenol and aniline by bromination method.
3. Saponification value of an oil/ fat/ ester.
4. Estimation of glycine by Sorenson’s formalin method.
5. Estimation formaldehyde (formalin).
6. Estimation of ascorbic acid in fruit juices/Vitamin C tablet (Iodometric method)
7. Determination of Iodine number of an oil/ fat.
Reference Books:
 Arthur, I. Vogel, Elementary Practical Organic Chemistry, Part-1 Small scale preparations, Indian Edition,
Pearson (2011).
 Manual of Biochemistry Workshop, 2012, Department of Chemistry, University of Delhi.
 Arthur, I. Vogel, Quantitative Organic Analysis, Pearson.
 Wilson, K. & Walker, J. Practical Biochemistry. Cambridge University Press (2009).
DSE-6.3 : INORGANIC MATERIALS OF INDUSTRIAL IMPORTANCE

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Silicate Industries
Glass: Glassy state and its properties, classification (silicate and nonsilicate glasses). Manufacturing and processing of
glass. Composition and properties of the following types of glasses: Soda lime glass, lead glass, armoured glass, safety
glass, borosilicate glass, fluorosilicate, coloured glass, photosensitive glass.
Ceramics: Important clays and feldspar, ceramic, their types and manufacture. High technology ceramics and their
applications, superconducting and semiconducting oxides, fullerenes carbon nanotubes and carbon fibre.
Cements: Classification of cement, ingredients and their role, Manufacture of cement and the setting process, quick
setting cements.
UNIT-II
Fertilizers: Different types of fertilizers. Manufacture of the following fertilizers: Urea, ammonium nitrate, calcium
ammonium nitrate, ammonium phosphates; polyphosphate, superphosphate, compound and mixed fertilizers,
potassium chloride, potassium sulphate.
Batteries: Primary and secondary batteries, battery components and their role, Characteristics of Battery. Working of
following batteries: Pb acid, Li-Battery, Solid state electrolyte battery. Fuel cells, Solar cell and polymer cell.
UNIT-III
Surface Coatings:
Objectives of coatings surfaces, preliminary treatment of surface, classification of surface coatings. Paints and
pigments-formulation, composition and related properties. Oil paint, Vehicle, modified oils, Pigments, toners and lakes
pigments, Fillers, Thinners, Enamels, emulsifying agents. Special paints (Heat retardant, Fire retardant, Eco-friendly
paint, Plastic paint), Dyes, Wax polishing, Water and Oil paints, additives, Metallic coatings, metal spraying and
anodizing.
UNIT-IV
Alloys: Classification of alloys, ferrous and non-ferrous alloys, Specific properties of elements in alloys. Manufacture
of Steel (removal of silicon, decarbonization, demanganization, desulphurization, dephosphorisation) and surface
treatment (argon treatment, heat treatment nitriding, carburizing). Composition and properties of different types of
steels.
Chemical explosives: Origin of explosive properties in organic compounds, preparation and explosive properties of
lead azide, PETN, cyclonite (RDX). Introduction to rocket propellants.
31 | P a g e
1. Stocchi E., Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
2. Sharma, B.K. & Gaur, H. Industrial Chemistry, Goel Publishing House, Meerut (1996).
3. P. C. Jain, M. Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi.
Reference Books:
 Felder R.M. and Rousseau R.W., Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi.
 Dara S. S., A Textbook of Engineering Chemistry, S. Chand & Company Ltd. New Delhi.
 A. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi.
 R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas Publications, New Delhi.
PRACTICAL
List of Practicals
1. Determination of free acidity in ammonium sulphate fertilizer.
2. Estimation of Calcium in Calcium ammonium nitrate fertilizer.
3. Estimation of phosphoric acid in superphosphate fertilizer.
4. Determination of composition of dolomite (by complexometric titration).
5. Analysis of (Cu, Ni); (Cu, Zn) in alloy or synthetic samples.
6. Analysis of Cement.
7. Estimation of Iron from Cement Volumetrically
8. Preparation of pigment (zinc oxide).
Reference Books :
 Dara S. S., A Textbook on Experiments and Calculations in Engineering Chemistry S Chand & Company; 9th
revised edition (2015).
 E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
 R. M. Felder, R. W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New Delhi.
 W. D. Kingery, H. K. Bowen, D. R. Uhlmann: Introduction to Ceramics, Wiley Publishers, New Delhi.
 J. A. Kent: Riegel’s Handbook of Industrial Chemistry, CBS Publishers, New Delhi.
 P. C. Jain, M. Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi.
 R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry, Vikas Publications, New Delhi.
DSE-6.4 : GREEN CHEMISTRY

Full Marks – 100
Mid Sem – 15/1hr
THEORY
UNIT-I
Introduction to Green Chemistry
What is Green Chemistry? Need for Green Chemistry. Goals of Green Chemistry. Limitations/Obstacles in the
pursuit of the goals of Green Chemistry.
Principles of Green Chemistry and Designing a Chemical synthesis- I
Twelve principles of Green Chemistry. Explanations of principle with special emphasis on - Designing green
synthesis processes: Prevention of Waste/ by-products; maximize the incorporation of the materials used in the
process into the final products (Atom Economy) with reference to rearrangement, addition, substitution and
elimination reactions; Prevention/minimization of hazardous/ toxic products; Designing safer chemicals; Use of
safer solvents and auxiliaries (e.g. separating agent) - green solvents (supercritical CO2, water, ionic liquids),
solvent less processes, immobilized solvents.
UNIT-II
Principles of Green Chemistry and Designing a Chemical synthesis-II
Explanation of green chemistry principles with special emphasis on: Energy efficient processes for synthesis - use
of microwaves and ultrasonic energy. Selection of starting materials (use of renewable feedstock); avoidance of
unnecessary derivatization (e.g. blocking group, protection groups, deprotection); Use of catalytic reagents
(wherever possible) in preference to stoichiometric reagents; designing of biodegradable products use of chemically
safer substances for prevention of chemical accidents, inherent safer design greener – alternative to Bhopal Gas
Tragedy (safer route to carcarbaryl) and Flixiborough accident (safer route to cyclohexanol); real-time, in-process
monitoring and control to prevent the formation of hazardous substances; development of green analytical
techniques to prevent and minimize the generation of hazardous substances in chemical processes.
32 | P a g e
UNIT-III
Examples of Green Synthesis/ Reactions and some real world cases-I
Green Synthesis of the following compounds: adipic acid, catechol, methyl methacrylate, urethane, disodium
iminodiacetate (alternative to Strecker synthesis), paracetamol, furfural. Microwave assisted reactions:
Applications to reactions (i) in water: Hofmann Elimination, hydrolysis (of benzyl chloride, methyl benzoate to
benzoic acid), Oxidation (of toluene, alcohols); (ii) reactions in organic solvents: Diels-Alder reaction and
Decarboxylation reaction. Ultrasound assisted reactions: Applications to esterification, saponification, Simmons-
Smith Reaction (Ultrasonic alternative to Iodine).
UNIT-IV
Examples of Green Synthesis/ Reactions and some real world cases- II
Surfactants for carbon dioxide – replacing smog producing and ozone depleting solvents with CO2 for precision
cleaning and dry cleaning of garments; Designing of Environmentally safe marine antifoulant; Right fit pigment:
synthetic azopigments to replace toxic organic and inorganic pigments; Synthesis of a compostable and widely
applicable plastic (poly lactic acid) from corn; Development of Fully Recyclable Carpet: Cradle to Cradle Carpeting
Future Trends in Green Chemistry
Oxidizing and reducing reagents and catalysts; multifunctional reagents; Combinatorial green chemistry;
Proliferation of solvent less reactions; Green chemistry in sustainable development. (Bio-diesel, bio-ethanol and
biogas).

1. Anastas P.T. & Warner J.K.: Green Chemistry- Theory and Practical, Oxford University Press (2000).
2. Ahluwalia V.K. & Kidwai M.: New Trends in Green Chemistry, Anamalaya Publishers, New Delhi (2004).
3. Kumar V., An Introduction to Green Chemistry, Vishal Publishing Co., (2015).
Reference Books:
 Matlack A.S. Introduction to Green Chemistry, Marcel Dekker (2001).
 Das Asim K. and Das Mahua, Environment Chemistry with Green Chemistry, Books and Allied (P) Ltd. (2010)
PRACTICAL
At least five experiments should be done:
1. Acetylation of primary amine (Aniline to N-phenylacetamide) using Zn dust.
2. Nitration of salicylic acid by green method (Using calcium nitrate and acetic acid).
3. Bromination of acetanilide using ceric ammonium nitrate/KBr.
4. Microwave assisted nitration of Phenols using Cu(NO3)2.
5. Detection of elements in organic compounds by green method (Sodium carbonate fusion).
6. Base catalyzed Aldol condensation (Synthesis of dibenzalpropanone).
7. Vitamin C clock reaction using vitamin C tablets, tincture of iodine, hydrogen peroxide and liquid laundry
starch. Effect of concentration on clock reaction.
8. Photoreduction of benzophenone to benzopinacol in the presence of sunlight.
9. Diels Alder reaction in water: Reaction between furan and maleic acid in water and at room temperature rather
than in benzene and reflux.
10. Preparation and characterization of nanoparticles (Cu, Ag) using plant extract.
11. Preparation of propene by following two methods or any other reactions like addition, elimination, substitution
showing atomic economy can be studied
a. Triethylamine ion + OH- → Propene + Trimethylpropene + water
H2SO4/Δ
b. 1-propanol propene + water
Reference Books:
 Monograph on Green Chemistry Laboratory Experiments, edited and published by Green Chemistry Task Force
Committee, DST Govt. of India, p. 1-79.
 Kirchoff, M. & Ryan, M.A. Greener approaches to undergraduate chemistry experiment. American Chemical
Society, Washington DC (2002).
 Sharma, R.K.; Sidhwani, I.T. & Chaudhari, M.K. I.K. Green Chemistry Experiment: A monograph International
Publishing House Pvt Ltd. New Delhi. Bangalore CISBN978-93-81141-55-7 (2013).
OR
33 | P a g e
DSE-6.4 : DISSERTATION / PROJECT WORK
Full Marks – 100
End Sem Project – 100
A project work is to be carried out by the student in consultation with the teachers of the department. The report of
work (dissertation) in a standard format is to be submitted and presented for evaluation.
Distribution of marks
a. Project Report/Dissertation (Proper documentation of literature, data, discussion etc. and logical flow of work
undertaken): 50 Marks
b. Seminar/Presentation: 30 marks
c. Viva voce: 20 marks
Brief Guidelines to Project Work:

1. Students shall undertake the project work (experimental/theoretical) related to any branch of
chemistry/Chemical science under the guidance of teacher(s) from the department or jointly with
teachers/research personnel of other institutes.
2. The following activities have been outlined as guidelines (not exhaustive):
 Physiochemical studies (pH, conductivity, turbidity, etc.) of different wetlands (ponds, lakes, river etc.)
 Analysis of iron in pond / tube well / river water.
 Analysis of Hardness of water samples.
 Adulteration detection activities in food stuff and other edible items.
 Extraction and preliminary characterization of useful chemicals (as far as possible) from plants.
 Solubility, surface tension, and viscosity measurements of some solution of practical relevance, (cough
syrup, soap solution, pesticides, fertilizers, etc.)
 Pollution related activities (Industrial/Agricultural/Municipal etc.)
 Nutrition related activities, (essential metal detection in food, cereals, pulses, fruits etc.).
 Small synthetical work (inorganic/Organic/Polymeric compounds)
3. The UG level project work is a group activity, maximum number of students being limited to three. HOD to
notify the name of teacher(s) for supervising the project work of each group. A teacher can guide more than one
group, if necessary.
4. No two groups in the same institution are permitted to do project work on the same problem.
5. Each student shall prepare and submit the project report separately for evaluation. Two copies of project report
are required to be submitted in bound form (spiral/paperback).
6. The project report shall be divided as:
Chapter I: Introduction (Introduction on the topic, review of literature, objective and scope of the work)
Chapter II: Materials and methods
Chapter II: Results and discussion
Chapter IV: Conclusions and Scope of future studies
Chapter V: References
Reference Books:
 M. A. Malati, An Investigative, Integrated Approach to Practical Project Work; Mid-Kent College of
Higher/Further Education, UK (October 1999); Imprint: Woodhead Publishing; ISBN: 978-1-898563-47-1.
 Dean, J. R., Jones, A. M., Holmes, D., Reed, R., Weyers, J. & Jones, A. (2011) Practical skills in chemistry. 2nd
Ed., Prentice-Hall, Harlow.
* * *
34 | P a g e

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COURSES OF STUDIES

THREE YEAR DEGREE COURSE

Choice Based Credit System(CBCS)

First & Second Semester Examination – 2020-21

GOVERNMENT AUTONOMOUS COLLEGE,

SYLLABI FOR CBCS COURSE

III CORE-VI SEC-II GE-2A

IV CORE-IX SEC-I GE-2B

YEAR & SEMESTER-WISE PAPERS & CREDITS AT A GLANCE

3 Physics GE-1.3 4+2

11 Physical Chemistry-III C-3.3 4+2

20 Physical Chemistry-V C-5.2 4+2

Recommended Text Books :

Reference text Books:

C-1.2 : PHYSICAL CHEMISTRY- I

Recommended Text Books:

GE-1.3 : MECHANICS AND PROPERTIES OF MATTER, OSCILLATION

AECC-1.4 : ENVIRONMENTAL STUDIES

Recommended Text Books:

C-2.2 : PHYSICAL CHEMISTRY II

Recommended Text Books:

GE-2.3 : CALCULUS AND DIFFERENTIAL EQUATIONS

AECC – 2.4 : MIL COMMUNICATIONS – ODIA

cìfý aòbûR^ _¡Zò : (iaê[ôeê aòKÌ _Wÿòa)

AECC-2.4 : MIL (ALTERNATIVE ENGLISH)

UNIT - I: Short Story

Recommended Text Books:

Recommended Text Books:

C-3.3 : PHYSICAL CHEMISTRY-III

Recommended Text Books:

GE-3.4 : OPTICS, SPECIAL THEORY OF RELATIVITY, ATOMIC PHYSICS,

SECC-II-3.5 : QUANTITATIVE AND LOGICAL THINKING

I. QUANTITATIVE APTITUDE & DATA INTERPRETATION

II. LOGICAL REASONING

Recommended Text Books:

C-4.2 : ORGANIC CHEMISTRY-III

Recommended Text Books:

C-4.3 : PHYSICAL CHEMISTRY-IV

Recommended Text Books:

SECC-I-4.5 : COMMUNICATIVE ENGLISH

UNIT-I : BUSINESS COMMUNICATION AND GRAMMAR

Recommended Text Books:

C-5.2 : PHYSICAL CHEMISTRY-V

Recommended Text Books:

DSE-5.3 : POLYMER CHEMISTRY

Recommended Text Books:

DSE-5.4 : INDUSTRIAL CHEMICALS AND ENVIRONMENT

Recommended Text Books:

Recommended Text Books:

C-6.2 : ORGANIC CHEMISTRY-V

Recommended Text books :

DSE-6.3 : INORGANIC MATERIALS OF INDUSTRIAL IMPORTANCE

DSE-6.4 : GREEN CHEMISTRY

Recommended Text Books:

Brief Guidelines to Project Work:

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