Chem Pp1 Quick Revision Series Exams
Chem Pp1 Quick Revision Series Exams
SIGNATURE………………………………..DATE…………………………
CHEMISTRY 233/1
PAPER 1(THEORY)
TIME:2 HOURS
a) Write your name and index number in the spaces provided above.
b) Sign and write the data of examination in the spaces provided above.
c) Answer All the questions in the spaces provided in the question paper.
d) Non-programmable silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
f) This paper consists of 14 printed pages.
g) Candidates should check the question paper to ascertain that all the pages are
printed as indicated and that no questions are missing
h) Candidates should answer the questions in English.
21 22 23 24 25 26 27 GRAND TOTAL
2. The table below gives the number of electrons, protons and neutrons in
substance X, Y and Z. study it and answer the questions that follow.
Page 2 of 14
3. Study the flow chart below and answer the questions that follow.
Copper metal
Ammonia
Drying agent Heated black solid Y
Gas
Nitrogen
c. Name Y. (1mk)
b. Draw the dot (.) and cross (x) diagram for the compound formed by Y
and Z.
(1mk)
Page 3 of 14
5. 20.0cm3 of a solution containing 4g per litre of sodium hydroxide was
neutralized by 8.0cm3 of dilute sulphuric (VI) acid. Calculate the
concentration of sulphuric (VI) acid in moles per litre. (Na=23, O=16, H=1,
S=32) (3mks)
6. Describe how you can extract oil from ground nuts? (3marks)
Page 4 of 14
8. The scheme below represents some reactions starting with a white solid A.
2MH2SO4 Colourless
Yellow solid B
solution P
Page 5 of 14
b) Write a chemical equation for the reaction between metal Q and water
1mk
10. The diagram below shows the laboratory preparation of hydrochloric acid.
Page 6 of 14
11. Use the reaction scheme below to answer the questions that follow.
Process y Ni /180OC
Alkanol X Propene Compound Z
H2
12. Study the reaction below and answer the questions that follow
13. Define;
a) Solubility 1mk
Page 7 of 14
14. In an attempt to prepare a gas, Njeri added concentrated hydrochloric
acid to Potassium manganate. The products were then passed through two
wash bottles containing water and concentrated sulphuric acid
16. Study the table below and answer the questions that follow
C-C 346
C=C 610
C-H 413
C-Br 280
Br-Br 193
Page 8 of 14
b) Name the type of reaction that took place in (a) above 1 mark
17. Study the diagram below and answer the questions that follow:
NH4+(g) + Cl-(g)
∆H2
∆H1
NH4+(aq) + Cl-(aq)
Energy
∆H3
NH4Cl(s)
Reaction Co-ordinate
Reaction Co-ordinate
∆H1 1mk
∆H2 1mk
Page 9 of 14
18. Nitrogen and hydrogen react reversibly according to the equation:-
19. Study the information in the table below and answer the questions that
follow:
W 0.114 0.195
X 0.072 0.136
Y 0.133 0.216
Z 0.099 0.181
(b) Suggest an element in the table above likely to be the most reactive.
Explain 1 ½ mks
Page 10 of 14
20. Give the IUPAC names of the following compounds: 3mks
(i) CH3COOCH2CH3
ii) CH3CH2COOH
Br
R – S – O-Na+
b) State one advantage and one disadvantage of using the above cleansing agent.
2mks
22. The grid below represents part of the periodic table. Study it and answer the
questions that follow:
S R E X
Q Z M T V
(a) (i) Identify the element that gains electrons most readily 1mk
Page 11 of 14
(ii) Which of the metal is most reactive? Explain 1mk
(iii) What name is given to the family of elements to which elements X and
T belong? 1mk
23. 3.52g of Carbon (IV) Oxide and 1.40g of water are produced when a mass of a
hydrocarbon is completely burnt in oxygen. Determine the empirical formula
of the hydrocarbon;(H = 1 , C= 12, O = 16) 3mks
24. (a) Hydrogen can reduce coppers Oxide but not alluminium oxide.
Explain 1mk
(b) When water reacts with potassium metal the hydrogen produced ignites
explosively on the surface of water.
Page 12 of 14
25. The diagram below shows the extraction of sulphur by Frasch process.
A
B
Ground level
Sulphur beds
26. The set-up below was used to prepare dry sample of hydrogen sulphide
gas
(a) (i) Complete the diagram to show how the gas was collected 2mks
Page 13 of 14
(ii) Identify the following:-
I. Solid H ½ mk
II. Solid I ½ mk
b) Ductility. 1mk
Page 14 of 14
SMARTFOCUS KCSE QUICK REVISION SERIES EXAMS
SERIES 2
Kenya Certificate of Secondary Education
233/ 1 Paper 1
Chemistry
CONTACT US ON: 0724351706/0726960003
For marking schemes and more Post Mock papers for all subjects
Instructions To Candidates
a) Write your name and index number in the spaces provided
b) Sign and write the date of examination in the spaces provided
c) Answer ALL questions in the spaces provided
d) Mathematical table and electronic calculators may be used.
e) ALL working MUST be shown clearly where necessary
f) Candidates should check the question paper to ensure that all pages are printed as indicated
and no questions are missing
For Examiner’s Use Only
QUESTION MAXIMUM SCORE CANDIDATE’S SCORES
1 – 31 80
1
1. a) Name and provide the function of the following pieces of apparatus.
Name: ( ½ Mark)
Function ½ mark
b) Name: ( ½ Mark)
Function ½ mark
3. Proteins are obtained from amino acid monomers. Complete the equation below to show how the
polymer is formed. (1 mark)
H2N CH2 COOH + H2N CH2CH2COOH
2
4. The energy level diagram below is for the reversible reaction.
X2(g) + 3 Y2(g) 2 XY3 (g
Energy (kJ)
2 XY3 (g)
Reaction path
a)Explain how the decrease in temperature will affect the above reaction (2 marks)
b) Sketch on the same axes the energy level diagram for a catalyzed reaction assuming that the above
energy level diagram is for uncatalysed reaction. (1 mark)
5. The set-up below shows how nitrogen gas is prepared in the laboratory.
Nitrogen
Mixture of gas
ammonium chloride
and sodium nitrite
Water
Heat Substance L
3
a) Describe how nitrogen gas is formed in the flask. (2 marks)
b) Nitrogen gas is inert. State one use of the gas based on this property. (1 mark)
6. Unstable nuclide had the equation below occurring. Study the equation and answer the question that
follows:
1 1
𝑂𝑛 1𝑃 +𝑌
a) Name particle Y (1 mark)
7. Starting with copper turnings describe how a sample of copper (II) carbonate can be prepared.
(3 marks)
8. When dilute hydrochloric acid was added to iron (II) sulphide, a colourless gas W with a characteristic
smell of rotten eggs was produced.
a) Name gas W. ( ½ mark)
4
c) Give the test for gas W. (1 mark)
9. a) Name the chief ore from which lead is extracted and give its chemical formula. (1 mark)
b) Describe the froth floatation process in the extraction of lead metal. (2 marks)
10. a) Determine the oxidation number of sulphur in S2O82- hence write the electron arrangement of
sulphur. (2 marks)
b) The standard electrode potentials of a metal G and iron are given below.
Fe2+(aq) + 2e-- Fe(s) - 0.44V
G2+aq + 2e- G(s) - 0.91V
A piece of iron is coated with metal G. If the coating is scratched, would the iron be protected from
rusting. Explain. (2 marks)
Process Q
Al2 Cl6 (g) 2AlCl3 (s)
A Process P B
a) Name process Q. (1 mark)
5
c) List two other substances which show this process. (1 mark)
12. R – OO- Na+ and R – CH2 OSO3- Na + represent two types of cleansing agents. (1 mark)
a) Name the class of cleansing agent to which each belongs.
R – COO- – Na+ ( ½ mark)
R – CH2 OSO3- Na+ ( ½ mark)
b) Which of the above cleansing agent is likely to pollute the environment? Explain. (2 marks)
b) Write the formula of the complex formed when ammonia is added to copper (II) sulphate solution
until in excess. (1 mark)
14. The graph below represents the solubility curve of a gas in water.
6
Solubility(g/100g
water
Temperature (oC)
(a) State and explain the conclusion that can be drawn from this curve about the solubility of the gas.
(1mark)
b) Study the information in the table below on solubility and answer the questions that follow.
Calculate the mass of copper (II) sulphate that will crystalize if 40g of a saturated solution is cooled from
60 oC to 40 oC. ( 2 marks )
15. Carbon is known to occur in different forms is solid form. Study the diagram below and answer the
question that follow.
14
6𝑐 Diamond
P Q
Carbon
7
12 Graphite
6𝐶
ii) Q (1 mark)
C
B
b)Study the flow chart below and answer the questions that follow.
Iron
Sulphur
8
a) Name gas X. (1 mark)
b) State the observation made when gas X is bubbled through a tube containing Iron (III) chloride
(1 mark)
17. Study the flow chart below and answer the questions that follow.
Water
Carbon Acid A
(IV)oxide Burning magnesium
ribbon
White solid B+ Black specs
+ water
Alkaline solution C
19. Below is a sketch required to investigate the reaction between chlorine and heated iron. Use it to
answer the question that follow.
Drying agent
Chlorine
Iron A B
Heat
a) Name a suitable drying agent shown above. (1 mark)
9
b) The iron powder is heated before chlorine is passed over it. What would be observed when chlorine
comes in contact with hot iron. (1 mark)
19. In Turkana, gnawing chalk was used to fight excess stomach acid. A patient suffering from intestinal
ulcer released 30 cm3 of 1M hydrochloric acid in his stomach. He chewed 5g of impure chalk to
neutralize the acid released. (Ca = 40, C = 12, O = 16)
a) Write a balanced equation for the reaction that took place. (1 mark)
20. The table below show elements represented by letters P, Q, R, S, T, U and V and their atomic
numbers.
Elements P Q R S T U V
Atomic 11 12 13 14 15 16 17
number
10
c) Which of these ions P+ and Q+ is more stable? Explain. (1 ½ marks)
21. The diagram below represents the industrial manufacture of hydrochloric acid, study it and answer
the questions that follow.
Water
Glass beads
Hydrochloric
acid
Point Z
Hydrogen
Chlorine
Chlorine (1 mark)
b) The reaction between chlorine and hydrogen can be explosive. How can this be avoided.
(1 mark)
11
d) Explain why copper reacts with concentrated nitric (v) acid but doesn’t react with concentration
hydrochloric acid. (1 mark)
22. Draw a well labelled diagram of an electrolytic cell that can be used to purify impure copper metal.
(2 marks)
23. A mixture of phenolphthalein and methyl orange was separated as shown in the diagram.
24. Calcium reacts with cold water. Explain two observations during the above reaction. (2 marks)
12
25. a) M grams of a radioactive isotope decayed to 5 grams in 100 days. The half life of the isotope is 25
day.
a) Define the term half life. (1 mark)
26 a) A student set up experiments as illustrated by the diagrams below. Before introducing each metal
into the solution it was cleaned.
A B C
Copper (II) sulphate Dilute sulphuric (VI) acid Dilute sulphuric (VI) acid
i)Why is it necessary to clean the metal pieces before introducing them into their respective beakers
( 1 mark)
ii) What observation were made immediately the metal pieces were introduced into the beakers A, B
and C? (3 marks)
13
SMARTFOCUS KCSE QUICK REVISION SERIES EXAMS
SERIES 3
Kenya Certificate of Secondary Education
233/ 1 Paper 1
Chemistry
CONTACT US ON: 0724351706/0726960003
For marking schemes and more Post Mock papers for all subjects
Instructions To Candidates
a) Write your name and index number in the spaces provided
b) Sign and write the date of examination in the spaces provided
c) Answer ALL questions in the spaces provided
d) Mathematical table and electronic calculators may be used.
e) ALL working MUST be shown clearly where necessary
f) Candidates should check the question paper to ensure that all pages are printed as indicated
and no questions are missing
For Examiner’s Use Only
QUESTION MAXIMUM SCORE CANDIDATE’S SCORES
1 – 31 80
1
1. The diagram below shows a set-up of apparatus used to separate immiscible liquids.
Mixture
Heat
a) Name the parts labelled A and B. (1 mark)
A
2. Element K (not actual symbol of the element) has isotopes with relative abundance as shown below.
Isotope abundance %
10
𝐾 18.69%
5
11
𝐾 81.28%
5
Calculate the relative atomic mass of K. (2 marks)
3. The table below gives the ionization energies of the alkali metals.
Element 1st ionization energy kJ mol
A 494
B 418
C 519
2
Which of the three metals is the least reactive. Give a reason. (1mark)
4. A jar full of moist chlorine was inverted over a jar of hydrogen sulphide as shown below.
Moist chlorine
Hydrogen sulphide
(b) Write the equation for the reaction and show using oxidation numbers that the reaction
above is redox. (2 marks)
5. A piece of burning Magnesium was introduced into a gas jar of nitrogen, water was then added to
the products. The resultant solution was tested with litmus paper.
3
(i) Explain the observation. (1mark)
(ii) Write an equation for the formation of the final solution. (1mark)
6. State one reagent that can be used to distinguish between the pairs of ions.
7. 20cm3 of sodium carbonate solution was reacted completely with 25cm3 of a 0.8M hydrochloric
acid according to the equations.
Na2CO3 + 2HCl 2 NaCl + CO2 + H2O
Calculate the concentration of sodium carbonate in grams per litre. (3 marks)
4
S 2:8:8
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Solution M L N P Z
(a) Identify the solution with the lowest concentration of hydrogen ion. Give reason for your
answer (1mk)
…………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………….
(b) Which solution would be used as an anti-acid for treating stomach upset. Give for your answer
(1mk)
……………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………….
b) Name the type of bond and explain whether the compound would conduct
electricity. (2 marks)
12. A given volume of a gas G diffuses through a membrane in 10 seconds. Under same condition an
equal volume of oxygen diffuses for 12.5sec. Determine the molecular mass of G. (2 marks)
13. (a) Using an equation explain the observation made when sodium hydroxide is added to aluminum
oxide dropwise until in excess. (2 marks)
14. (a) Cynogen is a gaseous compound of carbon and Nitrogen only. 250cm3 Cynogen. On
complete combustion in oxygen. 750cm3 of nitrogen (iv) Oxide and 1000cm3 of the rest of product.
Determine the formula of cynogen. (3 marks)
6
………………………
7
Key
+ + + + + + + charged nucleus
+ + + + + +
electron
+ + + + + +
b) In which group of the periodic table does element K belong. Give a reason (2mks)
…………………………………………………………………………………………………………
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17. Propene and propane both decolourises bromine liquid at different conditions.
a) Explain with an equation how the hydrocarbons decolourises bromine. (4 marks)
…………………………………………………………………………………………………………...
8
Using an energy level diagram represent the reaction when vanadium (V) oxide is used.
(2 marks)
(ii)
Chlorine gas was bubbled through Solution turn from green to yellow
an aqueous of P
a) Identify P
R 1mark)
9
c) Name one reagent that can be used to confirm cation in P. (1mark)
a) Iron
……………………………………………………………………………………………………….
b) Copper
……………………………………………………………………………………………………….
c) Sodium
……………………………………………………………………………………………………….
d) Aluminium
……………………………………………………………………………………………………...
21. Calculate the oxidation number of P given the following P2O5 (1mark)
22. State and explain observation made when chlorine gas bubble through a solution of potassium
iodine. (2 marks)
23. Sketch the bond formed between the complex of tetramine copper(II) ions. (1mark)
10
24. Explain why graphite is used as a lubricant in machines. (3 marks)
25. Study the set up below and answer the questions that flows
State all the observations that would be made when the circuit is completed (3mks)
……..…………………………………………………………………….……………………..……
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26. Most natural water occurs as permanent hard water or temporary hard water.
a. Name two compounds that cause;
i. Temporary hardness (1mk)
……..…………………………………………………………………….…………………….
.…………..…………………………………………………………………………………….
……..…………………………………………………………………….…………………….
.…………..…………………………………………………………………………………….
11
b. How is temporary hardness removed from water? (1mk)
……..…………………………………………………………………….……………………..……
……..…………………………………………………………………………………………………
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27. Use the information below to answer the questions that follow.
H2(g) +¹₂O2 H2O(l) ∆H1= -286KJ/Mol
……..…………………………………………………………………….……………………..…………..
………………………………………………………………………………………………………………
……..…………………………………………………………………….……………………..……
……..…………………………………………………………………………………………………
12
SMARTFOCUS KCSE QUICK REVISION SERIES EXAMS
SERIES 4
Kenya Certificate of Secondary Education
2023 Form Four Evaluation Programme
233/1
Chemistry Theory
Paper 1
Time: 2 Hours
CONTACT US ON: 0724351706/0726960003
For marking schemes and more Post Mock papers for all subjects
INSTRUCTIONS
1. Write your name and school and index number in the spaces provided at the top of this page
2. All answers should be written in the spaces provided.
3. Non-programmable silent electronic calculators and KNEC mathematical tables may be used.
4. Students should check the question paper to ascertain that all pages are printed as indicated and that no
questions are missing.
1 – 29 80
This paper consists of 11 printed pages. Candidates should check to ascertain that all pages are printed as
indicated and that no questions are missing.
1
1. In the extraction of zinc, the zinc ore is crushed to a powder, mixed with oil and water and air blown
through the mixture.
(a) What is the name given to this process? (1 mark)
………………………………………………………………………………………………………………………
(b) Explain how this process works. (1 mark)
………………………………………………………………………………………………………………………
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(c) Name the chief ore from which zinc is extracted. (1 mark)
……………………………………………………………………………………………………………….
2. (a) Using the oxidation number, identify and explain oxidizing and reducing agent (2 marks)
2 H2S(g) + SO2(g) → 3S(s) + 2H2O(l)
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………...........
(b) Atomic number of Sulphur is 16. Write the electron configuration of S in SO32- (1 mark)
………………………………………………………………………………………………………………………
2
5. Use the table below to answer the question that follow:
(a) Write an equation for the reaction between element A and water. (1 mark)
………………………………………………………………………………………………………
(b) Explain the trend of atomic radii between elements A and D. (2 marks)
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(b) In terms of structure and bonding, explain why graphite is used as a lubricant. (2 marks)
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(b) A given mass of the gas occupies 20cm3 at 250 C and 670mmHg pressure. Find the volume it will
occupy at 100 C and 335mmHg. (2 marks)
3
8. Concentrated sodium chloride was electrolysed using graphite electrodes. Name the product formed at the
anode and give a reason for your answer. (2 marks)
………………………………………………………………………………………………………………...
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(b) Study the energy level diagram below and answer the question that follows:
∆H
…………………………………………………………………………………………………………….
10. Magnesium chloride dissolves in water to form a neutral solution while aluminium (III) chloride forms an
acidic solution. Explain. (3 marks)
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
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11. When solid B was heated strongly, it gave off water and a solid residue. When water was added to the
solid residue, the original solid B, was formed.
(a) What name is given to the process described? (1 mark)
………………………………………………………………………………………………………………
(b) Give one example of solid B. (1 mark)
4
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12. The scheme below was used to prepare a cleansing agent. Study it and answer the questions that follow.
NaOH (aq); Boil
Fat Solution of cleansing
Step I agent and an alcohol
Step II
(a) What name is given to the type of cleansing agent prepared by the method shown in the scheme? (1 mark)
…………………………………………………………………………………………………………………….
………………………………………………………………………………………………………
(c) What is the purpose of adding the chemical substance named in (ii) above? (1 mark)
……………………………………………………………………………………………………
13. The diagram below represents part of a setup arranged for the collection of hydrogen gas in the laboratory.
Study it and answer the questions that follow.
(a) Complete the diagram to show how a dry sample of hydrogen can be collected. (2 marks)
……………………………………………………….......................................
5
………………………………………………………………………………………………………………
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(b) Explain why the second ionization energy of magnesium is higher than its first ionization energy. (2 marks)
………………………………………………………………………………………………………..………
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15. A state of equilibrium between dichromate (VI) and Chromate ions is established as shown below.
Cr2O72- (aq) +2OH- (aq) CrO42- (aq) + H2O (l)
(Orange) (Yellow)
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………
(b) State and explain observation made when a few pellets of potassium hydroxide are added to the
equilibrium mixture. (2 marks)
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………..
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16. Describe how you would obtain solid sample of each of the following components of solid mixture
containing lead (II) chloride, ammonium chloride and copper (II) oxide (3 marks)
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……………………………………………....………………………………………………………………………
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17. (a) Using dot and cross diagrams, show bonding in hydroxonium ion, H3O+. (2 marks)
6
(b) Identify the type of bonds represented by p and q in the substances below.
H H O
q
O O H H
p
q
H H
p ………………………………………………………………………...…….... (½ mark)
q …………………………………………………………………………………. (½ mark)
18. The diagram below shows a ‘jiko’ when in use. Study it and answer the questions that follow.
Region B
Burning charcoal
Region A
Air
Ash
………………………………………………………………………………………………………
……………………………………………………………………………………………………………………
19. The following table gives the melting point of oxides of the third period elements. Study it and answer the
questions that follow.
(a) Explain the large difference in the melting points of Na2O and SO2. (2 marks)
7
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(b) Write the equation for the reaction between Al2O3 with;
(i) NaOH (1 mark)
………………………………………………………………………………………………………………
(ii) HCl (1 mark)
………………………………………………………………………………………………………………
20. Use the scheme below to answer the question that follow.
…………………..………………………………………………………………………………
H- ………………………………………………………………………………………………
J- ………………………………………………………………………………………………
21. A form one class carried out an experiment to determine the active part of air. The diagram below
shows the set-up of the experiment and also the observation made.
………………………………………………………………………………………………………
8
(b) State two reasons for the suitability of substance M for this experiment (1 mark)
…………………………………………………………………………………………………………………
…….…..…………………..…………………………………………………………………………………
(c) Write the equation for the reaction of substance M and the active part of air (1 mark)
……………………………………………………………………………………………………………..
22. The table below gives three experiments on the reaction of excess hydrochloric acid and 1.5g of zinc done
under different conditions. In each the volume of gas was recorded at different time internals.
I Powder 1.5M
II Granules 1.0 M
On the axis below draw and label three curves that could be obtained from such results. (3 marks)
Time (sec)
23. When solid magnesium carbonate was added to a solution of hydrogen chloride in methylbenzene, there
was no observable change. On addition of some water to the mixture, there was effervescence. Explain the
observation. (2 marks)
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9
24. (a) Define the term solubility. (1 mark)
……………………………………………………………………………………………………………….
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(b) The solubility curve of potassium nitrate is shown in the figure below.
…………………………………………………………………………………………………
(ii) Determine the molar concentration of saturated potassium nitrate at 50oC. (K = 39.0, O =
16.0, N = 14.0 and density of water 1 g/cm3). (2 marks)
25. Use the bond energies given below to calculate the heat of reaction for: (3 marks)
Energy
Bond
(kJ/Mol)
H–H 435
Cl – Cl 243
H – Cl 431
10
26. The following table shows the products formed when nitrates of metals J, Y, and W are heated strongly.
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27. Use the set up below to answer the questions that follow.
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(b) Name another substance that can be used instead of platinum. (1 mark)
11
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28. An experiment was carried out to determine the presence of substances A, B, C and D in mixture E. the
results obtained are shown in the figure below.
(a) Name a suitable solvent used in the method of separation illustrated in the figure. (1 mark)
……………………………………………………………………………………….
(b) Select:
(i) one substance which contains a component not present in E. (½ mark)
……………………………………………………………………………….
(ii) a pure substance which is least soluble in the solvent used. (½ mark)
……………………………………………………………………………….
(c) State one application of chromatography in an athletics competition. (1 mark)
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NAME: ……………………………………..ADM NO.:………CLASS ………
SIGNATURE:…………………...DATE:………………
233/1
CHEMISTRY
PAPER 1
THEORY
FORM 4
TIME: 2 HOURS
SMARTFOCUS KCSE QUICK REVISION SERIES EXAMS
SERIES 5
CONTACT US ON: 0724351706/0726960003
For marking schemes and more Post Mock papers for all subjects
INSTRUCTIONS TO CANDIDATES
• Write your name and index number in the spaces provided above.
• Sign and write the date of examination in the spaces provided above.
• Answer ALL the questions in the spaces provided.
• Mathematical tables and electronic calculators may be used.
• All working MUST be clearly shown where necessary.
1 – 28 80
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1. a) A hydrocarbon consists of 92.3% carbon. Its molecular mass is 26. Calculate it’s
Molecular formula. (2 marks)
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2. a) Explain why melting point of chlorine gas is greater than that of Argon. (l mark)
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b) Using dot(•) and cross (×) to represent electrons draw a diagram to show bonding in
carbon (iv) oxide. (l mark)
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b) Write an equation for the reaction between Lead (ii) oxide and dilute Nitric acid.
(l mark)
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4. State and explain the observation that would be made when zinc powder is heated with
copper (II) oxide. (2 marks)
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5. Why is it dangerous to run a motor car engine in a closed garage? (2 marks)
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6. 2 grams of sodium hydroxide is added to 30 cm3 of IM sulphuric (VI) acid. What volume
of 0. 1M potassium hydroxide solution will be needed to neutralize the excess acid.
(Na23,016,H1) (3 marks)
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7. An aqueous solution of hydrogen chloride gas reacts with manganese (IV) oxide to form
chlorine gas while a solution of hydrogen chloride gas in methylbenzene does not react with
manganese (iv) oxide. Explain (2 marks)
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8. A small piece of potassium Manganate (VII) was placed in a glass of water and was left
standing for 6 hrs without shaking. State and explain the observations made. (2 marks)
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9. Magnessium reacts with both dilute and concentrated sulphuric (VI) acid. Write a
balanced equation for the two reactions. (2 marks)
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10. The table below gives the atomic numbers of elements W, X, Y and Z.
Element W X y Z
Atomic number 14 17 16 19
a) Name the type of bonding that exists in the compound formed when X and Z reacts.
(1 mark)
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b) Select the letter representing the strongest reducing agent. Give a reason for your
answer. (2 marks)
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12. a) Explain the role of common salt in defrosting ice on roads in ice cold countries.
(1 mark)
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b) Explain why the long term effects of use of common salt is costly to motorists.
(1 mark)
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15. Describe how a solid sample of lead(II) chloride can be prepared using the following
reagents : dilute nitric acid, dilute hydrochloric acid and lead carbonate (3 marks)
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(i) State and explain the effect of addition of dilute hydrochloride acid on equilibrium.
(2 marks)
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(ii) Explain the effect of increase in temperature on the yield of ammonia. (2 marks)
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b) Draw energy cycle diagram to show how the standard heat of formation of ethanol
(C2H5OH) can be determined from standard heats of combustion of its elements. (2 marks)
19. 3.78g of a hydrated salt of iron (II) sulphate, FeSO4, in H2O were heated until all the water of
crystallization was driven off. The anhydrous salt left had a mass of 1.52g. Determine the
formula of the hydrated salt. (Fe = 56, S = 32, H = 1, O = 16) (3 marks)
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20. A steady current of 0.2 Amperes was passed through molten silver bromide for 80 minutes.
a) Calculate the quantity of electricity that passed through the set up. (1 mark)
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b) Calculate the mass of product deposited at the cathode. (1F = 96500C; Ag = 108,
Br = 80) (2 marks)
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c) If a sample of cobalt has an activity of 1000 counts per minute, determine the time it would
take for its activity to decrease to 62.50 if the half-life of the element is 30 minutes. (2 marks)
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21. The apparatus set up below was used to prepare an anhydrous solid P
22. Aluminium is obtained from the ore with the formula Al2O3. 2H2O. The ore is first heated and
refined to obtain pure aluminium oxide (Al2O3). The oxide is then electrolysed to get
Aluminium and oxygen gas using carbon anodes and carbon as cathode.
a) Give the common name of the ore from where aluminium is extracted from. (½ mark)
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b) What would be the importance of heating the ore first before refining it? (1 mark)
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c) The refined ore has to be dissolved in cryolite first before electrolysis. Why is this
necessary? (1 mark)
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d) Why are the carbon anodes replaced every now and then in the cell for electrolysing
aluminium oxide? (1 mark)
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23. Use the cell representation below to answer the questions that follow
V(s) / V3+ (aq) //Fe2+ (aq) /Fe(s)
i. Write the equation for the cell reaction (1 mark)
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ii. If the E.M.F of the cell is 0.30 volts and the Eθ value for V3+aq / V (s) is -0.74V, calculate
the Eθ of Fe2+(aq)/ Fe(s) (2 marks)
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24. When 50cm3 1M potassium hydroxide was reacted with 50cm3 of 1M hydrochloric acid, the
temperature rose by 80C. When the same volume of Potassium hydroxide was reacted with
50cm3 of 1M Pentanoic acid, the temperature rose by 30C.
i) Give reasons for the above difference in temperature. (2 marks)
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ii) Write an equation to show dissociation of pentanoic acid? (1 mark)
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a) Draw the structural formula and name the alkanoic acid and alkanol that react to form the
polymer. (2 marks)
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26. A heavy metal P was dissolved in dilute nitric acid to form a solution of compound P(NO3)2.
Portions of the resulting solution were treated as follows:
a) To the first portion a solution of dilute hydrochloric acid is added, where a white
precipitate (S) is formed, which dissolves on warming.
b) The second portion is treated with two drops of 2M Sodium hydroxide solution where a
white precipitate T is formed. The white precipitate dissolved in excess sodium hydroxide
to form a colourless solution.
c) A solution of potassium iodide is added to the third portion where a yellow precipitate (U)
is formed.
d) When the resulting solution is evaporated to dryness and heated strongly a yellow solid
(V) is formed and a brown gas (W) and a colourless gas (X) are formed.
40
Volume of Co2
Curve A
Curve B
30
20
Curve C
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10 20 30 40 50
11
Time
a) Which curves corresponds to the reactions involving powdered calcium carbonate and
large sized marble chips with the dilute acid?
(i) Powdered calcium carbonate (½ mark)
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(ii) Large sized calcium carbonate (½ mark)
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b) All the graphs eventually flatten out at the same level but at different time. Why do the
graphs flatten out at the same level? (1 mark)
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c) Why is curve A very steep at any given point compared to the other curves. (1 mark)
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28. Sodium thiosulphate was reacted with dilute hydrochloric acid in a round bottomed flask as
shown below. The gas evolved was collected by downward delivery in a gas jar.
Dilute hydrochloric acid
Cardboard cover
sodium thiosulphate
a) Write an equation to show the reaction going on in the reaction in vessel. (1 mark)
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b) State the observation noted on the filter paper. Give a reason for your answer.
(1 mark)
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c) Give a reason why the filter paper soaked in the acidified potassium chromium (VI) is
used at the top of the flask (1 mark)
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Name: …………………………………………………………………………….. Index No.:………………………………
Date:…..……………..…………..............
233/1
CHEMISTRY
(THEORY)
PAPER 1
TIME: 2 HOURS
CHEMISTRY
PAPER 1
2 HOURS
1 – 31 80
This paper consists of 11 printed pages. Candidates should check the question paper to ascertain that all
pages are printed as indicated. And that no questions are missing
b) If the two react, what is the formula of the compound they form
(1mk)
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2. a) Draw a dot (•) and a cross (x) diagram to show bonding in Cl2O. (2mks)
b) Explain why the compound Cl2O has a very low melting and boiling point. (1mk)
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3. The empirical formula of a compound is CH2 and it has a molecular mass of 42.
a) What is the molecular formula of this compound?
(1mk)
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b) Write the general formula of the homologous series to which the compound belongs. (1mk)
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c) Draw the structural formula of the third member of this series and give its IUPAC name. (1mk)
4. 3.22g of hydrated sodium sulphate, Na2SO4 X H2O were hearted to a constant mass of 1.42 g.
determine the value of x in the formula ( Na=23.0, s = 32.0, O = 16, H = 1) (3mks)
H Br Br H
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H- C - C - C - C – H
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H Br Br H
ii) State the observations made when acidified potassium chromate (VI) is added to compound
G (1mk)
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8. In terms of structure and bonding explain why diamond has a high melting point while graphite
has a low melting point. (2mks)
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11. The scheme below shows some reaction sequence starting with solid M
H2SO4(aq)
Solid M Solution N + Gas which burns
with a ‘Pop’ sound
Few drops of
NH3(aq)
Colourless Excess NH3(aq)
solution Q White PPt
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(iii)Write ionic equation of reaction between barium nitrate and solution N. (1mk)
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Dilute nitric
acid
Zinc grnaules
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14. A white solid K was heated. It produced a brown gas A and another gas B which relights a glowing
splint. The residue left was yellow even after cooling.
a) Identify gases A and B (2mks)
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15. 100cm3 of 2M Nitric acid reacted with 12.5g of a carbonate MCO3 of metal M, calculate
the relative atomic mass of M ( C = 12, O = 16) (3mks)
17. Write ionic equations for electrolysis of dulite sulphuric acid using platinum electrodes at: (2mks)
(i) Anode
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(ii) Cathode
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18. An atom X contains 90% of X isotope and 10% of 8 X isotope. Calculate the relative
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atomic mass of X. (2mks)
19. A mixture of carbon (IV) Oxide and carbon (II) oxide is passed through potassium hydroxide solution
as shown in the following set up.
Flame of gas X
Mixture of Carbon
(IV) Oxide and Carbon
(II) Oxide
Potassium hydroxide
solution
(iii) Write a well balanced chemical equation for the reaction that takes place in the conical
flask in the first few seconds. (1mk)
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FOR MARKING SCHEMES INBOX 0724351706 Chemistry 233/1 6
20. Explain why aluminium articles are not easily corroded. (1mk)
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21. State the observation made in the set-up below.
Gas Jar
a) Observations. (1mk)
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b) Explain observation in (a) above. (2mks)
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22. When a current of 2.5 amperes was passed through a cell containing N 2+ ions of a metal for
25minutes, the mass of the cathode increased by 0.36g. ( 1 faraday = 96500 coulombs)
Determine the relative atomic mass of element N. (3mks)
23. A solution containing 0.1M sulphuric acid has a pH of 2 while 5M has a pH of more than two.
Explain. (2mks)
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b) The boiling and melting points of alkali metals decreases down the group while the melting
and boiling points of halogens increase down the group. (2mks)
FOR MARKING SCHEMES INBOX 0724351706 Chemistry 233/1 7
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25. Potassium exists as a radioactive Isotope 40 K as well as the non radioactive isotope K
19 19
a) State how the two isotopes differ from each other with respect to their nuclear
composition.(1mk)
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b) Bronze is an alloy of copper and another metal. Identify the other metal. (1mk)
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27. State and explain the function of tartaric acid in baking powder. (2mks)
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Explain how an increase in the following affects the equilibrium position. (3mks)
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(i) Temperature
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(ii) Pressure.
29. The molar heat of formation of carbon (II) oxide is -105kJmol-1, molar heat of combustion of carbon
is -393kJmol-1.
By using an energy cycle diagram, determine the molar heat of combustion of
Carbon(II)oxide. (3mks)
30. Dry chlorine gas was passed through two pieces of coloured cotton cloth as shown.
Dry Dry
chlorine chlorine
a)
Zinc
Copper
Copper (II)
Sulphate
Zinc sulphate
FOR MARKING SCHEMES INBOX 0724351706 Chemistry 233/1 9
i) On the diagram label the salt bridge. (1mk)
ii) Show the direction of flow of electrons. (1mk)
b) Write the overall ionic equation (1mk)
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Solution pH values
P 1.5
Q 6.0
R 14.0
S 8.0
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5) State three observation made when a piece of potassium metal is dropped into cold water giving a
reason for each. (3marks)
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c) Write the equation for the reaction through which the iron ore is reduced to iron in the blast
furnace (1mark)
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a) Mg+ (1mark)
8. When 27.8g of hydrated aluminium oxide ( Al 2 O3 • XH 2 O ) was heated to a constant mass 20.6 g
of aluminium oxide was obtained. Determine the value of X (Al=27, O=16, H=1 (3marks)
9. In the haber process, the industrial manufacture of ammonia is given by the following equation
N 2( g ) + H 2( g ) 2 NH 3( g ) H = −97kJ / mol
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c) What is the effect of increasing temperature on the yield of ammonia? Explain (2marks)
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10. Describe the correct process of heating a liquid in a test-tube using a bunsen burner.
(3marks)
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11. Draw a labelled diagram of a set up that can be used to prepare dry sample of carbon (IV) oxide
using calcium carbonate (3marks)
12.a) Draw structural formulae of two positional isomers with molecular formula C4H8 (2marks)
b) Study the equation below and answer the questions that follow
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b) Given that the lattice energy of NaCl is +781kJ/mol and hydrated energy of Na+ and Cl- are
-390kJ/mol and -384kJ/mol respectively. Calculate the heat of solution of one mole of NaCl(s)
using energy cycle. (3marks)
14. 240cm3 of nitrogen (I) oxide gas takes 16 seconds to diffuse through a certain porous pot. 300cm3
of x takes 12 seconds to diffuse through the same pot calculate the relative molecular mass of gas
x. (N=14, O=16) (3marks)
15. Draw a well labelled diagram that can be used during electrolysis of molten sodium chloride in
the laboratory (3marks)
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17. Use the flow chart below to answer the question below
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b) Name the process that takes place when flower petals are put into solution T (1mark)
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c) Reaction in step I takes place only in presence of moisture. Give a reason for this (1mark)
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i) Anode (1mark)
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b) State the property of carbon powder that make it suitable for use in the cell (1mark)
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c) State one other substance that could be used in place of manganese (IV) oxide (1mark)
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19. The diagram bellow represents part of periodic table. Use it to answer the question that follow
A Q
Z W X
a) Write the electronic arrangement for the stable ion formed by X (1mark)
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20. Write equations to show the effect of heat on each of the following
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21. When excess chlorine gas is bubbled through diluted sodium hydroxide solution; the resulting
solution act as a bleaching agent
a) Write an equation for the reaction between chlorine gas and sodium hydroxide solution
(1mark)
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c) Write an equation to show the bleaching and explain how it occurs (2marks)
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22 Alpha ( )and beta (ß) particles can be distinguished using papers, aluminium foil and an electric
field complete the diagram below to show how this is done (3marks)
24. Starting with sodium metal, describe how a sample of crystal of sodium hydrogen carbonate may
be prepared (3marks)
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25. When 20cm3 of 0.5M sulphuric (VI) acid was mixed with 20cm3 of 1M NaOH, the temperature of
the solution rose from 24.0oC to 32.0oC calculate the molar heat of neutralisation (Specific heat
capacity of the solution is 4.2Jg-1density is 1g/cm3 (3marks)
26. The table below shows the test carried out on a sample of water and results obtained
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DATE : …………………
CANDIDATE’S SIGNATURE……………..
CHEMISTRY
PAPER 1
TIME: 2 HOURS
SMARTFOCUS KCSE QUICK REVISION SERIES
SERIES 8
CONTACT US ON: 0724351706/0726960003
For marking schemes and more Post Mock papers for all subjects
INSTRUCTIONS TO CANDIDATES
▪ Write your Name, Index Number and School in the spaces provided above.
▪ Sign and write the Date of the examination in the spaces above.
▪ Answer all the questions in the spaces provided in the question paper.
▪ Mathematical tables and silent scientific calculators may be used.
▪ ALL the working must be clearly shown where necessary.
1 – 28 80
1
FOR MARKING SCHEMES CALL 0724351706
1. The set-up below represents apparatus that may be used to separate a mixture of two
miscible liquids “C” and “D” whose boiling points are 800C and 1000C respectively.
(a) Describe how you would obtain a sample of gas E from the mixture of gas D and E.
(2mks)
(b) Suggest a possible identity of gas D. Give reasons for your answer. (2mks)
2
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(b) In an experiment, 20cm3 of 2M hydrochloric acid was reacted with excess sodium
carbonate and the volume of carbon (IV) oxide produced recorded with time. In another
experiment, the same volume and concentration of ethanoic acid was also reacted with
excess sodium carbonate and the volume of carbon (IV) oxide produced recorded with
time.
On the grid below, sketch and label the curves if the volumes of carbon (IV) oxide were
plotted against time. (2mks)
Heat Heat
Gas
Write two equations for the reactions which occur in the combustion tube. (2mks)
5. Give the name of the product formed when magnesium reacts with phosphorus. (1mk)
6. The table below gives the energy required to remove the outer most electrons from same
group.
Elements I II III IV
Energy kJ / Mole 494 418 519 376
Arrange the elements in the order of their reactivity starting with the most reactive. (2mks)
3
FOR MARKING SCHEMES CALL 0724351706
7. The electronic structures for elements represented by letters A, B, C and D are:-
A = 2:8:6 B = 2:8:2 C = 2:8:1 D = 2:8:8
(a) Select the element which forms:
(i) Double charged cation. (1mk)
8. State any two differences between luminous flame and non luminous flame. (2mks)
9. The apparatus shown below was used to investigate the effect of carbon (II) oxide on Copper
(II) oxide.
(a) State the observation that was made in the combustion tube at the end of the experiment.
(1mk)
(b) Write an equation for the reaction that took place in the combustion tube. (1mk)
(c) Why is it necessary to burn the gas coming out of tube K? (1mk)
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10. (a) State Graham’s Law of Diffusion. (1mk)
(b) If it takes 30 seconds for 100cm3 of carbon (IV) oxide to diffuse across a porous plate,
how long will it take 150cm3 of nitrogen (IV) oxide to diffuse across the same plate under
similar conditions? (C = 12.0, N = 14.0, O = 16.0) (2mks)
11. (a) Given the IUPAC names of the following compounds:- (2mks)
(i) CH3(CH2)CH2OH
(ii) CH3CH2CH(CH3)COOH
(b) Given the following polymer, draw the structure of the monomer. (1mk)
12. In an experiment, various volumes of 1M sodium iodide solution was added to the same
volume of 1M lead (II) nitrate solution. The height of the precipitate were measured and
plotted against volume of 1M sodium iodide used. The graph below was obtained.
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24
20
16
12
0 24 6 8 10 12 14 16
Volume of sodium iodide (NaI) in cm3
(a) State the observation made when sodium iodide solution is mixed with lead (II) nitrate
solution. (1mk)
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(b) What volume of sodium iodide was required to react completely with lead (II) nitrate?
Explain. (1mk)
13. When excess zinc powder is added to 30cm3 of solution containing copper (II) ions and the
mixture stirred, the temperature is noted to have risen by 150C.
(a) State the observation made after stirring the mixture. (1mk)
(b) Calculate the heat change for the reaction (specific heat capacity of H2O = 4.2KJkg-1k-1)
(2mks)
14. When bismuth (III) chloride is added to water, a reaction occurs and a white precipitate forms
as shown below.
BiCl3(aq) + H2O(l) BiOCl(s) + 2HCl(aq)
What would be the effect on the amount of the precipitate formed if sodium hydroxide
solution is added to the equilibrium mixture? Explain your answer. (2mks)
15. The flow chart below shows some process in extraction of lead metal. Study it and answer
the questions that follow.
Coke CO2
SO2(S)
Raw Unit I
materials Roasting PbO(s) Unit II
Chamber
Pb
(a) Name two raw materials that were fed into Unit I. (1mk)
(b) State one environment hazard associated with the process in Unit I. (1mk)
6
FOR MARKING SCHEMES CALL 0724351706
16. (a) Radioactive Polonium – 216 decays as shown below.
216 208 + M + nβ
84 82
Determine the value of m and n. (2mks)
(b) The table below gives the rate of decay of a radioactive element y.
Number of days Mass in g
0 48
270 1.5
Calculate the half-life of the radioactive element y. (2mks)
17. Water reacts with sodium peroxide forming sodium hydroxide and oxygen gas. Draw a well
labelled diagram showing how a sample of oxygen gas can be prepared and collected in the
laboratory using the above reagents. (3mks)
18. 15g of sodium chloride was dissolved in 120cm3 of distilled water. Calculate the
concentration of the resulting solution in moles per litre. (Na = 23, Cl = 35.5) (3mks)
(b) The volume of a gas at 300C and 780mmHg is 400cm3. What will be its volume at
500Cat 600mmHg. (2mks)
7
FOR MARKING SCHEMES CALL 0724351706
20. Sulphur exhibits allotropy.
(a) What is allotropy? (1mk)
(c) Sulphur powder was placed in a deflagrating spoon and heated on a Bunsen burner.
(i) State the observation made. (1mk)
(ii) The product obtained was dissolved in water. Comment on the PH of the solution
formed. (1mk)
21. (a) A luminous flame has a yellow zone. Explain how the yellow zone is produced. (1mk)
(b) Explain why a non-luminous flame is preferred for heating substances in a laboratory.
(2mks)
22. (a) State two differences between the terms electrolyte and non-electrolyte. (2mks)
23. 0.318g of an oxide of metal M was completely reduced by hydrogen gas to 0.254g of metal.
Calculate empirical formula of the metal oxide. (M = 63.5, O = 16). (3mks)
24. In an experiment to electroplate iron with silver, a current of 0.5A was passed through a
solution of silver nitrate for 60 minutes.
(i) Give two reasons why it is necessary to electroplate iron with silver. (1mk)
(ii) Calculate the mass of silver that was deposited on iron. (Ag = 108, 1 Faraday = 96500C).
(2mks)
8
FOR MARKING SCHEMES CALL 0724351706
25. Given the following reagents: solid sodium carbonate, water, solid lead (II) nitrate. Describe
how a sample of lead (II) carbonate can be prepared in the laboratory. (3mks)
26. The set-up below was used to prepare a sample of an organic compound X.
Gas
Heat
(b) Write the equation for the reaction that produces gas X. (1mk)
27. Draw dot (•) an cross (x) diagram to show bonding in:
(i) Nitrogen molecule (N2) (1mk)
9
FOR MARKING SCHEMES CALL 0724351706
28. Study the diagram below and answer the questions that follow.
Tube M Copper turnings
Tap water
Heat
Tube
Air aspirator K
Solid X
Sodium Hydroxide
(i) What is the purpose of passing tap water through the air aspirator? (1mk)
(ii) State and explain the observation that would be made in tube M after sometime. (1mk)
(iii) The sample of nitrogen collected at point Y had greater density than expected. What
conclusion could be made about the gas? (1mk)
10
FOR MARKING SCHEMES CALL 0724351706
NAME: ……………………………………………………….INDEX NO………………………
SIGNATURE: …………………….
233/1
CHEMISTRY
(Theory)
PAPER 1
1
1. What is the difference between chromatography and chromatology? (1mark)
…………………………………………………………………………………………………………………
…………………………………………………………………………………..
2. When dilute Sulphuric (VI) acid is connected in a circuit to test conduction of electricity, the bulb lights
while when concentrated Sulphuric (VI) acid is used in the same set-up, the bulb does not light. Explain
this observation. (2marks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………
3. Explain why Aluminium Chloride has PH 3 when dissolved in water? (2marks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………
4. Below is a list of substances.
Soap solution, common salt, urine, lemon juice and baking powder.
Select:
(a) A substance that is likely to give a PH of 3.0 when tested? (1mark)
………………………………………………………………………………………………………………
………………………………………………………………………………
(b) A substance (s) which is likely to resemble sodium hydrogen carbonate.(1mark)
………………………………………………………………………………………………………………
………………………………………………………………………………
(c) Two substances when reacted are likely to give the product with same PH as that of common salt.
(1mark)
………………………………………………………………………………………………………………
………………………………………………………………………………
5. Briefly explain the observation made when a small piece of sodium metal is dropped into a bowl of
water. (3marks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………
6. (a) Define Le Chatelier’s principle. (1mark)
…………………………………………………………………………………………………………………
…………………………………………………………………………………
2
(b) A fixed mass of a gas has a volume of 400cm 2 at 20oC, what temperature rise would produce a 10%
increase in volume if the pressure remains constant. (3marks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………..
7. Using Dots (.) and (x) diagram, show the number of electrons used in bonding of H 3O+
(2marks)
CH3(CH2)6COO-Na+
Agent A Agent B
Which one of the cleansing agents would be suitable to be used in water containing magnesium hydrogen
carbonate? Explain. (2marks)
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………
Write two equations for the reactions which occur in the combustion tube. (2marks)
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………
………………………………………………………
4
13. The diagram below represents a set-up that can be used for the electrolysis of dilute Sulphuric acid.
18. The flow chart below shows some process in extraction of lead metal. Study it and answer the
questions that follow;
SO2(S) Coke CO2
Unit I
Raw Roasting PbO(s) Unit II
Material Chamber
s
Pb
(a) Name two raw materials that were fed into Unit I (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(b) State one environment hazard associated with the process in Unit I.
(1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(c) What is the function of Coke in Unit II (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
19.
Sulphur exhibits as an allotropy.
(a) What is allotropy? (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(b) Name the two allotropes of sulphur. (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(c) Sulphur powder was placed in a deflagrating spoon and heated on a Bunsen burner.
6
(i) State the observation made. (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(ii) The product obtained was dissolved in water. Comment on the PH of the solution
formed. (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
20. The set-up below was used to prepare a sample of an organic compound X.
7
21. The apparatus shown below was used to investigate the effect of carbon (II) oxide on Copper (II)
oxide.
(a)
State the observation that was made in the combustion tube at the end of the experiment.
(1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(b)
Write an equation for the reaction that took place in the combustion tube.
(1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
(c) Why is it necessary to burn the gas coming out of tube K? (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
22. The equation below represents changes in the physical state of ions metal:
Fe(s) Fe(I) H= + 15.4Kjmol -1
Calculate the amount of heat energy required to change 10kg of solid iron to gaseous iron. (Fe = 56)
(3marks)
………………………………………………………………………………………………………………………
23. The section below represents part of the periodic table. Study it and answer the questions that
follow; the letters are not the actual symbol of the elements.
8
Q
X B H M T
Y A V
Z S
(a) Explain why the atomic radius of T is smaller than that of M (1mark)
………………………………………………………………………………………………………………………
……………………………………………………………………………................
(b) Compare the electrical conductivity of element X and B. (2marks)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
24. Read the following passage and answer the questions.
A salt X was heated with slaked lime (calcium hydroxide). A colorless gas R with a characteristic smell
that turns red litmus paper blue was evolved. A large quantity of this gas was passed through an inverted
filter funnel into Copper (II) sulphate solution, and a deep blue solution M was obtained.
(a) Identify gas R (1mark)
………………………………………………………………………………………………………………
……………………………………………………………………………..
(b) What is X most likely to be? (1mark)
………………………………………………………………………………………………………………
………………………………………………………………………………
(c) Write an equation for the reaction between X and slaked lime. (1mark)
………………………………………………………………………………………………………………
………………………………………………………………………………
25. Consider the following reaction:
A2(g) + B2(g) 2AB(g), H = +75kj
Sketch an energy level diagram showing the relative activation energies for the catalyzed and
uncatalyzed reactions using the axes below. (2marks)
Energy (kj)
Reaction path
9
26. The diagram below shows the radiations emitted by a radioactive sample.
S ……………………………………………………………………………….
R ………………………………………………………………………………
27.(a) Starting with red roses, describe how a solution containing the red pigments may be prepared?
(2marks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………
(c) How can the solution be used as an indicator? (1mark)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
28.(a) Give one reason why some of the laboratory apparatus are made of ceramics.
(1mark)
…………………………………………………………………………………………………………………
………………………………………………………………………………….
(b) Name the two apparatus that can be used to measure approximately 75cm 3 of dilute sulphuric (VI acid.
(2marks)
………………………………………………………………………………………………………………………
………………………………………………………………………………………
10
29. Dry chlorine was collected using the set-up below.
11
1
School: ……………………………………………………………………………………..
SERIES 11
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
1 – 27 80
………………………………………………………………………………………………………
…………………………………………………………………………………………..…………
……...………………………………………………………………………………………………
2. During distillation in a laboratory the distillate can be collected either by a beaker or a conical
flask.
(a) Define the term distillate. (1 mark)
………………………………………………………………………………………………………
(b) Explain why a conical flask is the most preferred apparatus for the collection of the distillate.
(1 mark)
………………………………………………………………………………………………………
3. Describe how you would test for pH value of plant extract (3 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
3
4. During investigation to identify illegal steroids used by three athletes. Urine samples were
obtained and labeled as A, B and C. Illegal steroid was labeled as X, each urine sample had 2
components each and urine A and C contain the illegal steroid.
a) Give the name of process used to identify illegal steroids in athletes. (1 mark)
………………………………………………………………………………………………………
5. The following set up was used to react steam with Magnesium Powder.
a) Explain why the water-soaked sand was heated before heating the iron powder. (1 mark)
………………………………………………………………………………………………………
………….……………………………………………………………………………………………
b) Write an equation for the reaction that took place between steam and magnesium powder.
(1 mark)
……………………………………………………………………………………………………...
……………………………………………………………………………………………………….
6.(a)Using dots( • ) and crosses(x) ,show bonding in Hydroxonium ion, (H3O+) (H =1.0,O = 16.0)
(1mark)
4
(b) The chloride of Aluminum was added to water and stirred. State and explain the observation
made when two drops of methyl orange were added into the solution. (2 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………….……………………………………………………………………………………………
7. The data below gives the electronic configuration of some selected atoms and ions
A…………………………………………………………………………………………………...
C…………………………………………………………………………………………………..
……………………………………………………………………………………………………..
8. Use the table below to answer the questions that follow:
………………………………………………………………………………………………………
………………………………………………………………………………………………………
9. Starting with Copper metal describe how to prepare pure Copper (II) sulphate crystals. (3 marks)
5
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
……………………………………………………………………………………………………..
………………………………………………………………………………………………………
10. The diagram below was used to electrolyze molten copper (II) chloride using graphite
electrodes.
………………………………………………………………………………………………………
C………………………………………………………………………………………………….
D……………………………………………………………………………………………………..
11. A state of equilibrium between dichromate (VI) and Chromate ions is established as shown
below.
Cr2O72-(aq) +2OH-(aq) CrO42-(aq) + H2O(l
(Orange) (Yellow)
a) What is meant by a dynamic equilibrium? (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
b) State and explain observation made when a few pellets of Potassium hydroxide are added to
the equilibrium mixture. (2 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
6
12. The figure below shows some steps in the industrial preparation of sodium carbonate. Study it
and answer the questions that follow.
B……………………………………………
C……………………………………………
b) Name the method that is used to separate sodium hydrogen carbonate and ammonium chloride.
(1 mark)
………………………………………………………………………………………………………
(c)Name the most suitable substance used in Tower III to produce Carbon (IV) oxide. (1 mark)
………………………………………………………………………………………………………
13.Calculate the relative formula mass of gas A given that the time taken for equal volumes of
oxygen and gas A to diffuse through the same hole is 20 seconds and 24 seconds respectively
(O=16.) (2 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
14. Propane gas was bubbled through bromine liquid in a boiling tube.
(a)State condition required for the reaction to occur. (1 mark)
………………………………………………………………………………………………………
7
(b)Name the type of the reaction above. (1 mark)
………………………………………………………………………………………………………
15.Zinc metal and hydrochloric acid react according to the following equation.
2.0g of zinc were reacted with 100 cm3 of 0.2M Hydrochloric acid,
Determine the reagent that was in excess (3 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
( ½ mark)
0
(iv) Below 96 C
( ½ mark)
8
17. The flow chart below shows the process that can be used to obtain substance C from ammonia
gas when it is heated to about 900oC in air and in the presence of a catalyst.
A
A
M
M 900oC
O Substance C
N Catalyst
I
B A
a) Ammonia is obtained on large scale by Haber process. Name the raw materials A and B.
(1 mark)
………………………………………………………………………………………………………
c) Write an equation to show the product formed when C is cooled in the presence of air. (1 mark)
……………………………………………………………………………………………………….
18. In an experiment, Chlorine gas was passed into moist hydrogen Sulphide gas as shown below
Chlorine gas
Boiling tube
…….…………………………………………………………………………………………………
……………………………………………………………………………………………………….
c) What precaution should be taken in carrying out this experiment? Give a reason. (1mark)
………………………………………………………………………………………………………
……………………………………………………………………………………………………….
9
19. In an experiment to investigate the enthalpy of displacement of copper(II) ions by Zinc,50cm3
of copper(II) sulphate solution was placed in a plastic beaker. Excess zinc powder was then added
into the beaker and allowed to react. After two minutes the highest change in temperature was
noted to be 15 oC
(a) Calculate the amount of heat given out during the reaction (C =4.2kJ/Kg/Density of solution =
1g/cm3) (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(b) Given that the molar heat of displacement of reaction is -63kJ/mol,calculate the concentration
of copper(II)sulphate solution in moles/litre. (2 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
20. The table below gives three experiments on the reaction of excess hydrochloric acid and 1.5g
of zinc done under different conditions. In each the volume of gas was recorded at different time
internals
Experiment Form of Zinc Hydrochloric acid solution
I Powder 1.5M
II Granules 1.0 M
On the axis below draw and label three curves that could be obtained from such results.
(3 marks)
Volume of H2 (cm3)
Time (sec)
10
21. An experiment was carried out where hydrogen chloride gas was bubbled through
methylbenzene and water in separate beakers. The resulting solutions were tested with blue
litmus papers and sodium carbonate
(i) Write the observations made in the following table (2 marks)
Solution of hydrogen Chloride Blue litmus paper Sodium carbonate
gas in:
Water
Methylbenzene
………………………………………………………………………………………………………
………………………………………………………………………………………………………
22. An element R has a relative atomic mass of 88. When a current of 0.5 A were passed through
the fused chloride for 32 minutes and 10 seconds, 0.44g were deposited at the cathode. Determine
the charge on the ion of R. (1 Faraday= 96500 C) (3 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
23. The scheme below was used to prepare a cleansing agent. Study it and answer the questions
that follow.
NaOH(aq); Boil
Fat Solution of cleansing
Step I agent and an alcohol
Step II
i) What name is given to the type of cleansing agent prepared by the method shown in the scheme?
(1 mark)
………………………………………………………………………………………………………
11
ii) Name one chemical substance added in step II (1 mark)
………………………………………………………………………………………………………
iii) What is the purpose of adding the chemical substance named in (ii) above? (1 mark)
………………………………………………………………………………………………………
……………………………………………………………………………………………………….
24. In the extraction of zinc, the zinc ore is crushed to a powder, mixed with oil and water and
air blown through the mixture.
a) What is the name given to this process? (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
25. Radioactive polonium (Po) mass number 212 and atomic number 84 was detected in a sample
of water. The water had an activity of 1000 counts per second.
a). If the water is boiled explain whether the activity would be affected or not. (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
b).Given that polonium resulted from Bismuth (Bi) following emission of a beta (β) particle;
write a nuclear equation for the decay. (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
12
26. (a) State the Hess’s Law (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(b) Calculate the molar enthalpy of formation of ethyne (C2H2) given the following. (2
marks)
C2H2 + 5/2O2(g) → 2CO2(g) + H2O(l) H = -1300kJ/mol
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
27 (a) Using the oxidation number, identify and explain oxidizing and reducing agent (2 marks)
2 H2S(g) + SO2(g) → 3S(s) + 2H2O(l)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
……………………………………………………………………………………………………
(b) Atomic number of Sulphur is 16. Write the electron configuration of S in SO32- (1 mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
School: …………………………………………………………………………………….
SERIES 12
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 29 80
Page 1 of 10
1 a) Bauxite is the chief ore found in the extraction of Aluminium. Name two impurities
found in bauxite (2mks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
b) Name the chief ores of both zinc and copper (1mk)
i. zinc …………………………………………………………………………
ii. copper …………………………………………………………………………
2. a) Identify the products formed when dinitrogen tetra oxide is dissolved in water (2mks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
i. AgBr………………………………………………………………………………………………..
ii. CaSO4.XH2O………………………………………………………………………………………
iii. Tincture of iodine…………………………………………………………………………………..
4. The grid below represents part of the periodic table .Study it and answer the questions that follow
.The letters given do not represent the actual symbols of the elements.
A
B C D E
F G
H
……………………………………………………………………………………………………
Page 2 of 10
ii. Name type of structure would the oxide of C have? (½mk).
……………………………………………………………………………………………………
iii. How does the melting point of A compare with that of E? (½mk).
……………………………………………………………………………………………………
……………………………………………………………………………………………………
iv. 2.6 g of B reacts completely when heated with 2.42 litres of chlorine gas (Cl2) at s.t.p, calculate
1
the relative atomic mass of B.(1 mole of gas occupies 22.4 litres at s.t.p.) (12mk).
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
5. Explain the differences in bleaching properties of chlorine and sulphur (use equations where
necessary) (3mks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
6. Metals K and N were connected to form a cell as shown in the diagram below. Their reduction
potentials are as shown below:
i. P is made by dipping a filter paper in a solution of sodium nitrate, on the salt bridge show the
direction of flow of ions (1mk)
ii. On the diagram, show the flow of electrons (1mk)
Page 3 of 10
iii. Write the equation for the half-cell reaction that occurs at (1mk)
Metal K electrode..........................................................................................................................
Metal N electrode...........................................................................................................................
7. Write equations for the reactions between the following metals and steam. (3mks)
Iron…………………………………………………………………………………………………
Zinc…………………………………………………………………………………………………
Copper………………………………………………………………………………………………
8. Study the diagram below and answer the questions that follow.
Gas W which
Solution of a BaCl2(aq) Solid V HCl(aq) turns K2Cr2O7
sodium salt paper from
orange to green
a. Name (1mk)
i. Solid V ………………………………………………….......
ii. Gas W ………………………………………………………
b. Describe a chemical test for chloride ions (2mks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
……………………………………………………………………………………………
9. Starting with ethanol, describe how a sample of tetrachloroethane can be prepared (3mks)
………………………………………….…………………………………………………………………
……………………………………….……………………………………………………………………
……………………………………….……………………………………………………………………
……………………………………….……………………………………………………………………
…………………………………….………………………………………………………………………
…………………………………………………………………….………………………………………
Page 4 of 10
10. A solution of bromine in water is a chemical reaction in equilibrium. The reaction involved is
represented by the equation below;
Br2(aq) + H2O(l) 2H+(aq) + Br-(aq) + OBr-(aq)
Yellow Colourless
i. State and explain the observation made when dilute sulphuric (VI) acid is added to the mixture
at equilibrium. (2mks)
……………………………………………………………………………………………………………
……………………………………………………………………………………………………………
…………………………………..……………………………………………………..…………………
……………………………………………………………………………………………………………
…………………………………………………………………………………………………
11. Apart from downward delivery name another method that can be used to collect the following
gases (2mks)
ii) Name one gas that can be dried using anhydrous calcium oxide (1mk)
……………………………………………………………………………………………………………
12. Starting with magnesium metal describe how a sample of magnesium carbonate can be prepared.
(3mks)
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Page 5 of 10
13. With aid of well labelled diagrams show how a sample of sodium chloride, iodine and sand can be
separated (3mks)
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15. (a)In an experiment 10.6g of a mixture of a anhydrous Sodium Carbonate and Sodium chloride
were dissolved in water to make 100cm3 of solution .25cm3of this solution required 20cm3 of 1M
Hydrochloric acid solution for complete neutralization.
(i) Calculate the number of moles of Hydrochloric acid used (1mk)
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Page 6 of 10
(ii) Write a balanced equation for the above reaction. (1mk)
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(iii) Calculate the mass of Sodium Carbonate in 25 cm3 of this mixture. (1mk)
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16. Briefly describe how caffeine can be extracted from tea leaves. (3mks)
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17. State the two roles of platinised-platinum in a standard hydrogen electrode (2mks)
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iii Lime water and not potassium hydroxide is used to test for carbon(iv) oxide
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Page 7 of 10
18. Study the information below and use it to answer the questions that follow
∆Hθlattice =MgCl2 - 2477kjmol-1
∆Hθ hydration Cl-1 (aq) -363kjmol-1
∆Hθ hydration Mg+2 (aq) -1891jmol-1
i. Differentiate between hydration energy and lattice energy? (1mks)
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19. Nylon 6,6 is formed from two monomers, hexan-1,6-dioic acid(adipic acid) and hexan-1,6-diamine
(hexamethylene diamine ) through condensation polymerisation as shown in the diagrams below .
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Page 8 of 10
Identify the species that acts as;
i) A base.…………………………………………………………………
Explain …………………………………………………………………………………………..(1mks)
Explain……………………………………………………………………………………………..(1mk)
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b. Apart from protection from rusting state another reason for electroplating (1mk)
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22. The structure of RCOO-Na+ below represents a type of cleansing agent. Describe how the cleansing
agent removes grease from a piece of cloth. (3mks)
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23. The diagram below represents a ‘jiko’ when in use .Study it and answer the questions that follow.
Region A
Region C
Region B
Air in
Page 9 of 10
(i)Write equations for the reactions that occur in region
I: B (1 mk)
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II: C (1 mk)
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(ii) Explain what happens in region A. (1 mks)
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24. A compound contains 82.75% carbon and the rest is Hydrogen. (C=12, H=1)
(a) Determine its empirical formula. (2 Mrks)
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(b) Determine the molecular formula if its molecular mass is 58. (1 Mks)
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25. Determine the oxidation state of manganese in the following; (3mks)
KMnO4
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Mn2O3
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26. Explain why the melting point of magnesium oxide is 3080°C while that of carbon IV oxide is -
79oC. (2mks)
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THIS IS THE LAST PRINTED
Page 10 of 10
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
233/1 - CHEMISTRY- Paper 1
SMARTFOCUS KCSE QUICK REVISION SERIES
SERIES 13
Instructions to students
a) Write your name and index number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above.
c) Answer all the questions in the spaces provided in the question paper.
d) All working must be clearly shown where necessary.
e) Non-programmable silent electronic calculators and KNEC mathematical tables may be used.
f) This paper consists of 8 printed pages.
g) Students should check the question paper to ascertain that all the pages are printed as indicated and
that no questions are missing.
h) Students should answer the questions in English.
1-8 100
4. A student added 50cm 3 of 1.0M aqueous Hydrochloric acid to 50cm 3 of 1.0M potassium
hydroxide and the temperature of the resulting solution rose by 4 oC.
(a) Define the term molar heat of neutralization. (1mk)
2
5. Use the table below to answer the questions that follow:
(a) Write an equation for the reaction between element A and water. (1mk)
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(b) Explain the trend of atomic radii between elements A and D. (2mks)
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6. In terms of structure and bonding, explain why graphite is used as a lubricant. (2mks)
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7. (a) State the Boyle’s law. (1mk)
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3
(b) A given mass of the gas occupies 20cm at 25 oC and 670mmHg pressure. Find the volume it
will occupy at 10oC and 335mmHg. (2mks)
3
8. The diagram below shows an experiment for investigating electrical conduction in lead (II)
flouride. Study it and answer the questions that follow.
(a) Complete the diagram by indicating the condition that is missing and must be present for
electrical conductivity to take place. (1mk)
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(b) State the observation made at the anode. (1mk)
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(c) On the diagram show the direction of movement of electrons. (1mk)
9. The solubility of potassium nitrate is 85g/10g of water at 50oC and 32g/100g of water at 25 oC.
(a) Define the term solubility. (1mk)
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(b) Calculate the mass of the crystals formed if a saturated solution of potassium nitrate in 50g of
water at 50oC is cooled to 25oC. (2mks)
4
10. Draw the structures of the following compounds. (2mks)
(i) Ethylbutanoate
(ii) 3-ethyl-3-methyhexane
5
11. (a) Define the term ‘dynamic equilibrium’ (1mk)
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(b) A reaction at equilibrium can be represented as;
Yellow Orange
6
10 11
13. The relative atomic mass of an element is 10.28, it has two isotopes R. and R
5 5
Calculate the relative percentage abundance of each isotope. (3mks)
7
(b) Why is a non-luminous flame preferred for heating? (2mks)
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16. The curve shown below was obtained when solid naphthalene was heated to boiling.
8
©2023Eagletrial1
18. The chromatogram of two inks and three dyes is drawn below.
9
20. A radio isotope X decays by emitting two apha( ) portions and one beta ( ) particle to form
214
Bi
83
21. Two pieces of cotton wood were separately soaked in concentrated ammonia and hydrochloric
acid respectively. Then were simultaneously placed at the end of an open-ended tube as shown
in figure.
10
22. You are given the following half equations.
I2(s) + 2e - 2I-(aq) E = + 0.54V
11
Solution Phenolphthalein indicator Indicator N
Distilled water Colourless Green
Ammonium hydroxide Blue
Hydrochloric acid Red
26. A farmer intended to plant cabbages in his farm. He first tested the pH of the soil and found it to
be 3.0. If cabbages do well in alkaline soils, explain the advise that would be given to the farmer in
order to realize a high yield. (2mks)
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27. Aluminium is extracted from its ore by electrolysis.
(a) Name the main ore of Aluminium. (1mk)
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(b) The Aluminium ore in (a) above has a very high melting point (2015o C), though it is
electrolyzed at a lower temperature of about 900 o C. Explain how the temperature is achieved.
(1mk)
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(c) In the above process, graphite electrodes are used. What is the disadvantage of using this kind
of electrodes? (1mk)
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28. (a) In an experiment, an equal amount of iron fillings and sulphur powder was heated in a test
tube. The mixture was left to cool then dillute hydrochloric acid added to it.
12
(a) State the obervations that were made;
(i) In the test tube (1mk)
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(ii) Dillute hydrochloric acid was added to the mixture after cooling. (1mk)
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(b) Write an equation for the reaction which occurred in (a) (ii) above. (1mk)
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13
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
School: ……………………………………………………………………………
SERIES 14
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 27 80
1
1. (a) What is radioactivity? (1 mark)
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(b) The half-life of a radioisotope is 2.5 hours. If the initial radioactivity of the
radioisotope is 800 counts per minute, how long will it take for the count to fall to 75
counts per minute? (2 marks)
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6. (a) Explain the difference in boiling points between magnesium oxide and oxygen gas.
(2 marks)
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(b) Give the meaning of the term electron affinity. (1 mark)
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3
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7. (a) Explain why it is not advisable to use potassium sulphate as a salt bridge in an
electrochemical cell formed between the following half cells.
Pb(s) | Pb2+ (aq) Eθ = -0.13 V and Cu (s) | Cu2+ (aq) Eθ = +0.34 V (1 mark)
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(b) Calculate the emf of the cell formed by combining the two half cells in (a) above.
(2 marks)
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8. The figure below shows the blast furnace for the extraction of iron.
(a) Give the name of the two substances coming from point F. (1 mark)
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(b) Write the equation for the reaction taking place at point B. ( 1 mark)
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(c) The iron obtained from the blast furnace is impure. State how the impurities are removed
from the molten iron. (1 mark).
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4
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9. (a) Describe how sodium chloride can be prepared in the laboratory using direct synthesis
method. (2 marks)
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(b) Write an equation for the thermal decomposition of silver nitrate. (1 mark)
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10. When sulphur is heated, it melts into an amber-coloured liquid. On further heating, the
liquid darkens and becomes viscous. Explain these observations. (2 marks)
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11. (a) The diagram below shows three methods of gas collection.
Which method of gas collection is most suitable for collecting dry chlorine gas? Explain.
(1 mark)
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(b) Why was the use of DDT as a pesticide banned? (1 mark)
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5
(c) List two uses of hydrochloric acid. (1 mark)
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12. In a titration, a student added 25.0 cm3 of 0.200 mol / dm3 aqueous sodium hydroxide to a
conical flask. The student then added a few drops of methyl orange to the solution in the
conical flask. Dilute sulphuric (VI) acid is then added from a burette to the conical flask.
The volume of dilute sulphuric (VI) acid needed to neutralise the aqueous sodium
hydroxide was 20.0 cm3.
(a) What is the colour of methyl orange in aqueous sodium hydroxide? (1 mark)
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(b) Calculate the concentration of sulphuric (VI) acid in mol/dm3. (2 marks)
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13. Determine the time it would take 300cm3 of oxygen to diffuse through a small aperture if
it takes 500cm3 of nitrogen (I) oxide 475 seconds to diffuse through the same aperture
under the same conditions of temperature and pressure. (N = 14, O = 16)
(3 marks)
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14. (a) Explain the ‘strike back’ phenomenon that occurs during the lighting of the Bunsen
burner. (2 marks)
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6
(b) What is the use of an aspirator in the laboratory? (1 mark)
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15. (a) What is the meaning of the term melting point? (1 mark)
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(b) Element X undergoes the following physical changes.
7
A piece of zinc foil was added to 50 cm3 of hydrochloric acid, of concentration
2.0 mol/dm3. The acid was in excess. The hydrogen evolved was collected in the gas
syringe and its volume measured every minute.
(a) Sketch a graph of volume against time for the reaction above. Label it graph 1.
(2 marks)
(b) On the same graph, sketch another graph that would be obtained if the experiment
was repeated using the same amounts of reagents and copper (II) sulphate crystals
added into the mixture. Label it graph 2. (1 mark)
18. (a) Suggest the structures and bonds of the following substances. (2 marks)
Substance Bonds Structure
Naphthalene
Copper
(b) Draw the dot (.) and cross (x) diagram to show bonding in tetrachloromethane.
(1 mark)
19. (a) Deduce the molecular formula of the alkanol whose molecular mass is 158. (1 mark)
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8
(b) Explain why the following alcohols are isomers. (1 mark)
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(c) Ethanol is oxidized by acidified potassium manganate (VII). Deduce the name and
write the structural formula of the organic product. (1 mark)
Name…………………………. Structure:
20. The diagram below shows the electrolysis of concentrated zinc (II) chloride solution.
9
(a) Identify gas Q. (1 mark)
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(b) State and explain the observation made in the combustion tube. (1 mark)
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(c) Write the equation for the reaction that takes place in the combustion tube. (1 mark)
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22. Water hardness is caused by dissolved minerals that contain calcium ions and magnesium
ions.
(a) Give another method of removing permanent water hardness apart from distillation.
(1 mark)
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(b) 60 g of a saturated solution of salt W at 20oC was evaporated to dryness over a water
bath and yielded 24g of solid. Calculate the solubility of the salt at 20oC. (2 marks)
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10
23. Use the enthalpy of the following reactions to answer the questions that follow.
H2O (s) → H2O (l) ∆H1 = +6.02 kJ/mol
MgO (s) → MgO (l) ∆H2 = +77.4 kJ/mol
(a) What is the name given to ∆H1? (1 mark)
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(b) Explain the difference between ∆H1 and ∆H2. (2 marks)
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24. The Solvay process is used to manufacture sodium carbonate.
(a) Give two raw materials used in the Solvay process apart from brine. (1 mark)
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(b) Explain why potassium carbonate cannot be manufactured by simply replacing the
brine with potassium chloride in the Solvay process. (1 mark)
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(c) How is carbon (IV) oxide used as a refrigerant? (1 mark)
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11
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(b) Which solution is likely to react with ethanoic acid? (1 mark)
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(c) 1 cm of magnesium ribbon was placed in separate beakers containing 2M solution A and
2M solution B. State and explain the difference in the observations made. (1 mark)
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26. Study the scheme below and answer the questions that follow.
(b) Write the equation for the reaction of 1 mole of B and 1 mole of chlorine gas. (1 mark)
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(c) Draw the structure of substance D. (1 mark)
(d)
27. Describe how a mixture of silver chloride, magnesium chloride and iron (III) chloride can
be separated in the laboratory. (3 marks)
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This is the last printed page.
12
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
School: ……………………………………………………………………………
SERIES 15
Instructions to Candidates
Write your name and Admission number in the spaces provided above.
Sign and write the date of examination in the spaces provided above
Answer ALL the questions in the spaces provided below each question.
1 – 27 80
1
1. Students use these apparatus in volumetric analysis.
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(b)Apparatus C is used as well in collection of distillates. Why is it preferred to a beaker for
this purpose. (1mk)
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2. Substances can be classified as a mixtures, compound or pure elements. Give two reasons
why air is classified as a mixture. (2mks)
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.
3.The table below shows behavior of metals R, X, Y, and Z. Study it and answer the questions
that follow.
Metal Appearance on Reaction in water Reaction with dilute
exposure to air hydrochloric acid
R Slowly tarnishes Slow Vigorous
X Slowly turns white Vigorous Violent
Y No change Does not react Does no react
Z No change No reaction Reacts moderately
(a)Arrange the metals in order of reactivity starting with the least reactive. (2mks)
2
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(b)Name a metal which is likely to be Y. (1mk)
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4. (a)State Graham’s law of diffusion. (1mk)
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(b) 50cm3 of carbon (IV) oxide diffuses through a porous plate in 15 seconds. Calculate the time
taken by 75cm3 of nitrogen (IV) oxide to diffuse through the same plate under similar conditions.
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5. The diagram below represents set – up that can be used to prepare and collect oxygen
gas.
Water
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3
(b)Explain why oxygen is insoluble in water. (½mk)
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(c)Explain why it is important not to collect any gas for the first few seconds of the experiment.
(1mk)
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(d)Write chemical equation for the reaction taking place in the flask. (1mk)
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6. A mass of 3.6g of magnesium reacts in excess chlorine to form a chloride. If the mass of
the chloride is 14.25g, Find the formula of the chloride formed. (2mks)
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7. (a)Describe one chemical test that you would use to distinguish between two compounds
represented by the formulae C2 H6 O and C2 H4 O2 (2mks)
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(b)Use the table below answer the questions that follow.
Substance A B C D E
Symbol R-coo- Na+ CH2OH R-cooCH R-oso3 –
Na+
CHOH CH2 CH2 R-cooCH
n
CH2OH R-cooCH
4
(c)Which substance is
8. (a)What two conditions make it necessary to extract sulphur by frasch process? (1mk)
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(b)Hot air at about 15 atmospheres is forced down through the smallest of three concentric
pipes in the Frasch process. State two roles of hot compressed air. (1mk)
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(c)Excess sulphur (IV) oxide gas was bubbled through a solution of sodium hydroxide
containing phenolphthalein indicator.
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(ii)Write an equation for the reaction between sulphur (vi) oxide and sodium hydroxide
solution. (1mk)
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9. Copper (II) oxide was found to be contaminated with sodium chloride crystals and iron
fillings. Describe how a sample of copper (II) oxide can be obtained from the mixture.
(3mks)
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10. The table below gives the first ionization energies of the alkali metals.
Elements X Υ z
1st ionization
Energy KJmol-1 494 418 519
5
(a)Define the term ionization energy? (1mk)
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(b) Which of the three metals is least reactive? Give a reason. (1mk)
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11. Underground pipes made of iron normally have bags of magnesium scrap attached at the
intervals along pipeline as shown below.
………………………………………………………………………………………………………
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…………………………………………………………………………………………………
…………………………………………………………………………………………………
(b)A radioactive decay series can be represented by
232 ∝ B
B D
90 emission emission
State the mass number and atomic number of element B and D. (2mks)
6
………………………………………………………………………………………………………
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13(a) In an experiment, a student placed a small sample of methanoic acid in a beaker. A small
amount of sodium carbonate was added to the acid. Identify the products formed by writing an
equation for the reaction. (1mk)
…………………………………………………………………………………………………
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(b) State two advantages of synthetic polymers over natural fibres. (2mks)
………………………………………………………………………………………………………
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(c)Name two uses of polychloroethene. (1mk)
……………………………………………………………………………………………
14. Some average bond energies are given below.
Bond Energy KJ/mol
C-C 348
C-H 414
Cl – Cl 243
C – Cl 432
H – Cl 340
………………………………………………………………………………………………………
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15. The solubility of salt Z at 600C is 40g/100g of water and 48g/100g of water at 800C
………………………………………………………………………………………………………
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………………………………………………………………………………………………………
(b) 150g of saturated solution of Z at 800C is cooled to 600C. Calculate the nmass of Z that
crystallize out. (2mks)
7
………………………………………………………………………………………………………
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………………………………………………………………………………………………………
16(a) State the Brownsted – Lowry definition of an acid. (1mk)
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(b)With a reason, identify a base in the equation below. (1mk)
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(c)Distinguish between strong acid and concentrated acid. (1mk)
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17.Study the flow chart below and answer questions that follow.
Colourless
Solution F
8
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(b)Write the formula of the anion in colourless solution F. (1mk)
………………………………………………………………………………………………………
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(c)State the third observation made upon thermal decomposition of solid G in addition to the two
evidenced in the flow chart above. (1mk)
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18. The set up below was used by a student to investigate the products formed when aqueous
copper (ii) chloride was electrolyzed using graphite electrodes.
………………………………………………………………………………………………………
(b)Write the ionic equation for the reaction that explain the observation made in (a) above.
(1mk)
………………………………………………………………………………………………………
……………………………………………………………………………………………………
(c)How would the mass of the anode change if the graphite anode was replaced with copper
metal? Explain (2mks)
………………………………………………………………………………………………………
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19.An element 2311M
(a)To which chemical family does it belong? (1mk)
………………………………………………………………………………………………………
(b)Write electron arrangement of the atom (1mk)
9
………………………………………………………………………………………………………
(c)Draw the structure of its ion (1mk)
………………………………………………………………………………………………………
20. Bismuth chloride undergoes hydrolysis in water resulting in the equilibrium.
………………………………………………………………………………………………………
(ii)Give a reason for the observation in (a) above. (1mk)
………………………………………………………………………………………………………
(b)Explain the effect of increase in temperature on the rate of reaction in terms of the collision
theory. (1mk)
………………………………………………………………………………………………………
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21(a) State Gay Lussac’s law (1mk)
…………………………………………………………………………………………………
Calculate the volume of carbon (iv) oxide measured at S.t.p produced when 8.4g of the carbonate
is decomposed. (Mg=24.0, C=12.0 O= 16.0) (2mks)
………………………………………………………………………………………………………
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22. The table below shows PH values of some common solutions which were investigated by
some students in form 1 class. Study it and answer the questions that follow:
Solution A B C D E
PH value 2.0 6.0 7.0 9.0 13.0
(a)Identify the solutions which correspond to each of the following. (2mks)
10
(i)Methanoic acid (½mk)
………………………………………………………………………………………………………
(ii)Nitric (v) acid (½mk)
………………………………………………………………………………………………………
(iii)Aqueous ammonia (½mk)
………………………………………………………………………………………………………
(iv)Potassium hydroxide solution (½mk)
………………………………………………………………………………………………………
23. The set up below shows how gas P is prepared in the laboratory.
………………………………………………………………………………………………………
………………………………………………………………………………………………………
24.(a) State two allotropes of carbon. (1mk)
…………………………………………………………………………………………………
………………………………………………………………………………………………
(b)Explain the differences in their densities. (1mk)
………………………………………………………………………………………………………
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(c)Write the overall chemical equation for the reaction in the carbonator in the large scale
production of sodium carbonate. (1mk)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
11
25.Use the information below to answer the questions that follow:
………………………………………………………………………………………………………
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(b)Draw an energy level diagram for dissolving of magnesium chloride. (2mks)
26.Chlorine is used to treat water in drinking water plants in process called chlorination. Briefly
explain how chlorine eradicates the micro-organism from water. (2mks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
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27.Starting with lead metal, write a procedure on preparation of lead (II) nitrate crystals. (3mks)
………………………………………………………………………………………………………
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………………………………………………………………………………………
12
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
School: ……………………………………………………………………………
SERIES 16
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 27 80
1
1. State TWO reasons why most apparatus are made of glass (2marks )
…………………………………………………………………………………………………………………………………
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2. A pipette is used to measure exact volume of liquids. Draw a pipette. (1 marks)
………………………………………………………………………………………………………………………………………
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3. An atom exists as an isotope X-30, X-29 and X-33 has relative atomic mass of 30.30,
if X-30 is 10% calculate the percentage abundance of the other two isotopes (2marks)
………………………………………………………………………………………………………………………………………
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5. About 40cm3 of oxygen gas were reacted with 100cm3 of hydrogen gas.
(a) Determine the volume of residual gas at 1050C
(3 marks )
………………………………………………………………………………………………………………………………………
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(b) What volume of oxygen was used during the reaction? (1 mark)
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6. Ethene gas can be prepared as follows
………………………………………………………………………………………………………………………………………
7. (a) Define the term fractional crystallisation (1 mark )
………………………………………………………………………………………………………………………………………
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3
(b) A salt solution has a mass of 65g containing 5g of solute. The solubility of this salt is
25g per 100g water at 20oC. 60g of the salt are added to the solution at 20oC. Calculate the
mass of the solute that remain undissolved (2 marks)
………………………………………………………………………………………………………………………………………
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8. A sample of river water was divided into three portions. The table below shows the test
carried out on the portions and the observations made.
Test Observation Inference
To the first portion, 1 cm3 of soap solution was No lather formed.
added
The second portion was boiled, cooled and 1 No lather formed.
cm3 of soap solution was added.
4
(b) Why is the anode made of graphite? (1 mark)
………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
(c) How are the electrolytic products separated from reacting? (1 mark)
………………………………………………………………………………………………………………………………………
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10. Describe how a mixture of sodium chloride and lead chloride can be separated in the
laboratory. (3marks)
…………………………………………………………………………………………………………………………………
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11. Study the diagram below and answer the following questions.
(i) Write equation that produce the flame in the experiment. (1 mark)
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5
(ii) What is the aim of the experiment? (1 mark)
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12. Form 2 students arranged the set up below to study some properties of heating Lead(II)
nitrate strongly.
6
14. 2.56g of hydrocarbon contains carbon to hydrogen in the ratio of 5.1. If the
molecular mass is 128. Calculate the molecular formula of the hydrocarbon (3 marks)
(C=12, H=1)
………………………………………………………………………………………………………………………………………
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15. Chlorine water is a bleaching agent. Describe the bleaching action of chlorine using
relevant equation. (3marks)
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16. During electrolysis of dilute Magnesium Sulphate, using inert electrode. Explain
(i) The effect on concentration of the electrolyte during electrolysis. (2 marks)
………………………………………………………………………………………………………………………………………
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(ii) The difference in volume of the gasses produced at each electrode. (2 marks)
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17. The diagram below shows a ‘jiko’ when in use. Study it and answer the questions that
follow
7
(a)Identify the gas formed at region B (1mark)
………………………………………………………………………………………………………………………………………
(b)Using an equation, explain what happens at region A (2 marks)
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18. (a) What is half- life? (1mark)
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(b) The half-life of protactinium - 234 is 1.17 minutes. Determine the mass that decays
in 5.85 minutes starting with 100 g of the sample. (2 marks)
………………………………………………………………………………………………………………………………………
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19. Given the following substances: sodium carbonate, orange juice and sodium bromide.
(a) Name one commercial indicator that can be used to show whether sodium
carbonate, orange juice and sodium bromide are acidic, basic or neutral. (1mark)
………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………
(b) Classify the substances in 15 (a) above as acids, bases or neutral. (2 marks)
Acid
Base
Neutral
20. A reaction is described as “having reached equilibrium”. What does this statement
mean regarding the amounts of the reactants and products? (1 mark)
………………………………………………………………………………………………………………………………………
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8
21. Suggest two ways in which the equilibrium concentration of 𝑆𝑂3(𝑔) can be increased in
a closed container, if the only chemical equilibrium is; (2 marks)
1
𝑆𝑂2(𝑔) + 2 𝑂2(𝑔) 𝑆𝑂3(𝑔) ∆𝐻 = −98.3𝑘𝐽
………………………………………………………………………………………………………………………………………
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22. Industrial process of production of 𝑁𝑂(𝑔) is represented by reaction:
𝑁2(𝑔) + 𝑂2(𝑔) 2𝑁𝑂(𝑔)
The reaction is carried out at elevated temperatures to drive the reaction towards
the formation of the product. After sufficient products has formed the reaction
mixture is quickly cooled. Explain. (2 marks)
………………………………………………………………………………………………………………………………………
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23. The Diagram below may be used to react hydrogen sulphide and Sulphur (IV) oxide.
Study it and answer the questions that follow.
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(ii) Explain why the compound above has very high melting point. (1 mark)
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(iii) Explain how the compound above will conduct electricity. (1 mark)
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(iv) The diagram below shows relationship of basic and acidic oxides. In which region will
compound of A and B fall? Explain. (1 mark)
D E F
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25. 100cm3 of gas X takes 30 seconds to diffuse through a porous plug, whereas 300cm3
of oxygen gas takes 120 seconds. Calculate the relative molecular mass of gas X (O=16)
(3 marks)
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10
26. Ammonium nitrate was heated as shown below
11
Draw energy circle diagram linking of formation of butane to its heat of combustion and
heat of combustion and heat of combustion of carbon and hydrogen (2 marks)
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c) Use the energy circle to calculate the heat of formation of butane (2 marks)
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28. a)What is a fuel (1mark)
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THE END
12
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
School: ……………………………………………………………………………
SERIES 17
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 27 80
1
23
1. Draw a labeled diagram showing atomic structure of ( 𝑁𝑎.) 2mks
11
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(b) The atomic number of phosphorus is 15.Draw a dot (•) and cross(x) diagram for the
compound formed when phosphorus reacts with hydrogen atomic number 1
(1mk)
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………………………………………………………………………………………………………
2study the following heat changes and answer questions that follow
NaCl(s) Na+(g)+Cl-(g) ∆ H1 +781kJmol-
H2
b) calculate
the heat of solution of sodium chloride using the above heat changes (2mks)
………………………………………………………………………………………………………
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3. Dry carbon (II) oxide gas reacts with heated lead(II)oxide as shown in the equation below.
2
PbO(s) + CO(g) Pb(s) + CO2(g)
(c) Name another gas that can be used to perform the same function as carbon(II)oxide gas in the
above reaction. (1mk)
………………………………………………………………………………………………………
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State giving reasons how an increase in temperature would affect the amount of sulphur
(VI) oxide gas. (2mks)
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5. The standard electrode potential for elements P, Q, R and S are given below.
Eɵ (volts)
P2+ (aq) + 2e- P(s) -2.40
Q2+ (aq) + 2e- Q(s) -0.80
2R+ (aq) + 2e- R2 (g) 0.00
S2+ (aq) + 2e- S(s) +0.35
½ T2 (aq) + e- T-(aq) +1.40
(a) What is the Eɵ value for the strongest oxidizing agent? (1mk)
(b) Which two of the above elements in an electrochemical cell produce the largest e.m.f . (1mk)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
3
(c) Calculate the electromotive force of the cell in (b) above. (1mk)
c)50g of a radioactive substance was reduced to 6.25g in 36.3years. Calculate the half-life of the
substance. (2mks)
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b) What is the total number of electrons used for bonding in a molecule of the structured
Named in (a) (2mks)
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8. The purple color of a solution containing manganese (vii) ions disappears when iron (ii) ions
are added. The ionic equation for the reaction which occurs is;
MnO-4(aq) + 5Fe2+(aq) + 8H+(aq) Mn2+ (aq) + 5Fe3+ (aq) + 4H2O (l)
With reasons state which substance is acting as a; (2 mks)
i) Reducing agent.
………………………………………………………………………………………………………………
……………………………………………………………………………………
ii) Oxidizing agent.
4
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9) .3.1g of an organic compound containing carbon ,hydrogen and oxygen only produced 4.4g of carbon(iv)
and 2.0 of water on combustion
a) Calculate its empirical formulae (2mk)
………………………………………………………………………………………………………
10. Esters, fats and polyesters all contain the ester linkage. The structural formula of the ester is given
below.
H O H H H
H -C–C–O–C–C–C–H
H H H H
Name two chemicals that could be used to make this ester and draw their structural formulae. Show all
bonds.
(2mks)
………………………………………………………………………………………………………………
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11.An iron sculpture was produced to commemorate the anniversary of founder of a certain village. To
prevent it from rusting, the village elder attached it by a wire to a block of zinc which was stored
underground out of sight.
(i).Explain how the village elder’s action would prevent the rusting of the sculpture. (1mk)
………………………………………………………………………………………………………………
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(ii).What name is given to this method of preventing rusting? (1mk)
………………………………………………………………………………………………………….
(iii).List down two other ways in which rusting of the statue could be prevented. (1mk)
………………………………………………………………………………………………………………
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12) .50cm3 ammonia gas diffuses through a small orifice in 20 seconds. How long will it take a
similar volume of propane (C3H8) to diffuse through the same orifice under the same conditions
of temperature and pressure? (C=12.0, H =1.0, N=14.0) (3mks)
………………………………………………………………………………………………………
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13.(a) what observations would be made if hydrogen sulphide gas was bubbled through a
solution of Copper (II) sulphate. (1mk)
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(b) Write an equation for the reaction that takes place in (a) above. (1mk)
5
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14.The table below gives some properties of three metals: Aluminium, iron and copper. Use it to
answer the questions that follow.
Assuming that steel and stainless steel have similar properties to iron.
(a) Why do some stainless steel sauce pans have a copper base? (1mk)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
(b) Aluminum with a steel core is used for overhead power cables in preference to copper. Why
is a luminium preferred ? (1mk)
……………………………………………………………………………………………………
(c).Apart from over head power cables copper is chosen for almost all other electrical uses.
Suggest two reasons for the choice of copper. (2mks)
…………………………………………………………………………………………………….
……………………………………………………………………………………………………
15. A form four student wanted to determine the solubility of potassium nitrate. He obtained the
following results.
Use the information above to calculate the solubility of potassium nitrate. (3mks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
16. The grid below is part of the periodic table. Use it to answer the questions that follow. ( The
letters do not represent the actual symbols of elements.)
6
R S
N Q T U
P
(a) Indicate in the grid the position of an element represented by letter V, whose atomic number
is 14. (1mk)
………………………………………………………………………………………………….
.
(b) Select a letter which represents a monoatomic gas. (1mk)
………………………………………………………………………………………………….
………………………………………………………………………………………………….
(c) write an equation for the reaction between Q and T (1mk)
………………………………………………………………………………………………………………
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17. The table below shows ammeter readings recorded when two equimolar solutions were tested
separately.
………………………………………………………………………………………………………
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18.A student set up the apparatus for the preparation of carbon (IV) oxide gas as shown below.
Study the set up and answer the questions that follow.
Dilute sulphuric(iv)acid
X
Gas
Calcium
carbonate
Potassium
7 hydrogen
carbonate
(a) Explain using an equation why the reaction in apparatus Y occurs for a very short time then
stops. (1mk)
(b) What is the purpose of passing the gas through potassium hydrogen carbonate? (1mk)
……………………………………………………………………………………………
(c) State and explain why there is no sample of carbon (IV) oxide gas collected. (1mk)
……………………………………………………………………………………………
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19. Describe how a solid of ammonium sulphate can be prepared starting with 100cm3 of 2M
ammonium hydroxide (3mks)
………………………………………………………………………………………………………
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20. Study the scheme below and answer the questions that follow.
Heat NH3(g)
White solid Colorless gas X White fume Y
Conc. H2SO4
Heat with
Pale green/yellow gas V Solution Z
Solid W
……………………………………………………………………………………
b) What is the function of solid W in the reaction? (1 mk)
………………………………………………………………………………………………
c) Identify gas V. (1 mk)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
21. Explain the effect of the following on the rate of reaction in terms of the collisions theory
(3mks)
8
a) Increase in concentration
b) Change in pressure
c) Use of catalyst
……………………………………………………………………………………………………
…………………………………………………………………………………………………….
(bA gas occupies 500cm3.at 27ċ and 100,000pa. What will be its volume at 0ċ
and 101325pa (2mks)
9
25. Study the flow chart below and answer the questions that follow.
Identify (3mks)
Z……………………………………………………………………………………………………
M……………………………………………………………………………………………………
Y…………………………………………………………………………………………………..
26. The diagram below represents pipes used in Frasch pump for the extraction of sulpur
…………………………………………………………………………………………………
……………………………………………………………………………………………
28. In order to prepare hydrogen gas in the laboratory a student set-up the apparatus shown in the
diagram below. Study it and answer the questions that follow.
(a) Suggest why the student did not collect hydrogen gas. (1mk)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
(b) In a separate experiment the student reacted iron and hydrochloric acid to prepare hydrogen
gas.
(i) Write an ionic equation for the reaction. (1mk)
……………………………………………………………………………………………………..
(ii) The hydrogen gas produced was found to have a foul smell. Suggest an explanation for this.
(1mk
………………………………………………………………………………………………………
11
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
School: ……………………………………………………………………………
SERIES 18
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 27 80
5. You are provided with the following: copper turnings, dilute sulphuric (VI) acid and source of heat .
Describe fully how you would prepare copper (II) sulphate crystals (3mks)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
6. The set up below was used to study the reaction between ammonia and air in the absence of a
catalyst
9 . Study the set-up of apparatus below and answer the questions that follow.
13. The schematic diagram for the manufacture of sodium carbonate is shown below.
a) Write an equation for the reaction of formation of ammonium chloride and substance A. (1mk)
…………………………………………………………………………………………………………………
b) State how the following are carried out
(i) Process 1 (1mk)
…………………………………………………………………………………………………………………
(ii) Process 2 (1mk)
…………………………………………………………………………………………………………………
14. The table below shows the solubility of salt X at various temperatures.
Temperature (0c) Solubility(g/ 100g of H2O)
0 36
40 30
80 25
100 22
120 20
15. The figure below shows the apparatus used by students to study the electrolysis of molten lead (ii) iodide.
i).........................................................................
(iii) 3- Methylpentane
17. (a) Hydrogen sulphide gas was bubbed into an aqueous solution of iron (ii) chloride. State and
explain the observations made (2mks)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
b) Write the equation for the reaction that took place (1mk)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
18. Excess magnesium powder was added to 25cm3 of 1M copper (ii) chloride solution. The temperature
of solution increased by 430c.
(Density of solution =1g/cm3, specific heat capacity=4.2 J/g/K)
Determine;
a) The heat of reaction (1mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
b) The molar heat of displacement of copper (2mk)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
P S T W X
M Y
R Z
(a) Draw a dot (·) and cross (x) diagram to show the structure of elements T, (1mk)
b) Write an equation for the reaction that occurs when element R in solid form react with an aqueous
solution containing ions of element P (1mk)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
c) J is an element that belongs to the 4th period of the periodic table and reacts by gaining one electron.
Show the position of J in the grid. (1mk)
…………………………………………………………………………………………………………
20. 15.7 g of an organic acid RCOOH was dissolved in 600cm3 of water and more water added to
make one litre of solution. 25.0cm3 of this solution was found to require 21.5cm3 of 0.207 M
potassium hydroxide solution for complete neutralization. (C=12, O=16, H=1)
(i) Determine the formula mass of the acid (3mks)
21. The set up below shows the apparatus for preparation of nitrogen (i) oxide.
24 . A gold rings contain 3.94g of gold. Calculate the number of gold atoms in the ring. (Avogadro’s
constant = 6.021023, Au = 197) (2mks)
25 . A student accidentally placed a small amount of charcoal in a solution labelled concentrated nitric
(v) acid.
(a) State and explain the observation made (2mk)
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………
b) Write the equation for the reaction (1mk)
…………………………………………………………………………………………………………………
26 (a) Name two reagents that are used to prepare ethyne (1mk)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
b) Propanol and butanol are third and fourth members respectively of the same homologous series.
State and explain how their boiling points compare. (2mks)
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
27 Using a well labelled diagram show how to prepare and collect dry sulphur (iv) oxide starting with
copper turnings. (2mks)
School: ……………………………………………………………………………
SERIES 19
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 27 80
State and explain the effect of addition of Potassium hydroxide pellets on the concentration
of hydrogen sulphide. (3 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
b) Give the structural formula and the name of the organic product formed when equal
volumes of ethane and chlorine react together. (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
5. The diagram below shows the bonding between aluminium chloride and ammonia.
H Cl
H N Al Cl
H Cl
a) Name the types of bonds that exist in the molecule (1 mark)
……………………………………………………………………………………………………………………………………………………
……………………………………………………………………………………………………………………………………………………
b) How many electrons are used for bonding in the molecule? (1mark)
……………………………………………………………………………………………………………………………………………………
c) State one commercial use of dry ice (1 mark)
………................................................................................................................................................
6. a) Give one advantage of universal indicator over other indicators. (1 mark)
………................................................................................................................................................
………................................................................................................................................................
b) Describe how a mixture of barium sulphate and lead (II) chloride be separated in to pure
solids. (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
b) State the physical state of substance Q at room temperature (room temperature =25oC)
(1 mark)
………................................................................................................................................................
8. The set-up below is used to investigate the properties of ammonia.
i) On the diagram, indicate what should be done for the reaction at the combustion tube to occur.
(½ mark)
ii) Name another gas that can be used instead of ammonia gas. (½ mark)
………................................................................................................................................................
iii) State and explain what happens to the red litmus paper. (1 mark)
………................................................................................................................................................
iv) Explain the observation made in the combustion tube. (1 mark)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
b) In an experiment, the quantity of electricity passed to deposit 1.2g of metal Q from its salt,
was 3860 coulombs. (RAM of Q=120, 1 faraday = 96500 coulombs)
i) How many faradays of electricity are required to deposit 1mole of Q? (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
ii) One of the ions present in the solutions of the salt of Q has the formula Qy+. What is the
numerical value of y? (½ marks)
………................................................................................................................................................
………................................................................................................................................................
10. Study the diagram below which shows an energy level diagram.
Na+(g) + Cl-(g)
ΔH2 = - 680kJmol-1
Enthalpy
ΔH1
Na+(aq) + Cl(aq)
ΔH3 = +20kJmol-1
NaCl(s)
Reaction path
………................................................................................................................................................
………................................................................................................................................................
11. Below is a table of 1st ionization energies for elements A, B, C, and D which are metals.
Elements A B C D
Ionization energies kJmol-1 494 418 519 376
………................................................................................................................................................
(ii) State effect of the following changes on the yield of Sulphur (VI) oxide
I. Increasing the pressure (½ mark)
………................................................................................................................................................
II. Using a catalyst (½ mark)
………................................................................................................................................................
(iii) Explain why Sulphur (VI) oxide gas is absorbed in concentrated Sulphur (VI) acid before
dilution (1 mark)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
(b) Determine the molar concentration of saturated potassium nitrate at 50°C. (K = 39.0,
O = 16.0, N = 14.0 and density of water = 1 g/cm3). (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
17. Galvanization is an example of the efficient methods used in preventing rusting.
a) What is meant by galvanisation? (1 mark)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
c) State the use of the mixture of hydrazine with oxygen. (1 mark)
………................................................................................................................................................
18. a) Name 2 gases that are collected during fractional distillation when the temperature of
liquefied air is raised from -200℃ to -185℃of the distillation chamber. (1 mark)
………................................................................................................................................................
………................................................................................................................................................
b) Name 2 gases that are removed at the temperature between 25℃ and -25℃ (1 mark)
………................................................................................................................................................
………................................................................................................................................................
c) Why is it necessary to remove the gases named in (b) above before the cooling dust free
air to -200℃? (1 mark)
………................................................................................................................................................
………................................................................................................................................................
19. The structure of protein is shown below. Study it and answer the questions that follow.
a) Draw the structure of the monomer that undergoes polymerization to form protein.
(1 mark)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
20. Study the flow chart below and answer the question that follows.
Identify: (3 marks)
a) Solution K
………................................................................................................................................................
b) Solid L
………................................................................................................................................................
c) Gas M
………................................................................................................................................................
21. 50cm3 of oxygen gas diffused through a porous plug in 80 seconds. How long will it take
100cm3 of Sulphur (IV) oxide to diffuse through the same plug? (S = 32, O = 16). (3 Marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
23. When excess chloride gas is bubbled through dilute sodium hydroxide solution the resulting
solution acts as a bleaching agent.
a) Write an equation for the reaction between chlorine gas and sodium hydroxide solution.
(1 mark)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
b) Explain how the resulting solution acts as a bleaching agent. (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
24. Calcium oxide can be used to dry ammonia gas.
a) Explain why calcium oxide is not used to dry hydrogen chloride gas. (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
b) Name one drying agent for hydrogen chloride gas. (1 mark)
………................................................................................................................................................
25. a) Explain why it is not advisable to prepare a sample of carbon(IV)oxide using barium
carbonate and dilute Sulphuric(VI) acid. (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
Elements Na Mg Al Si P S Cl
Atomic Numbers 11 12 13 14 15 16 17
(a) Explain the trend in atomic radii from sodium to chlorine. (1 mark)
………................................................................................................................................................
………................................................................................................................................................
(b) Explain how the chloride of aluminium differs from those of other metals in the period.
(2 marks)
………................................................................................................................................................
………................................................................................................................................................
27. When solid magnesium carbonate was added to a solution of hydrogen chloride in
methylbenzene, there was no apparent reaction. On addition of water to the resulting mixture,
there was vigorous effervescence. Explain these observations (2 marks)
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
………................................................................................................................................................
TIME: 2 HOURS
SERIES 20
School: ……………………………………………………………………………
PREDICTION 21
Instructions to Candidates
a) Write your name and Admission number in the spaces provided above.
b) Sign and write the date of examination in the spaces provided above
c) Answer ALL the questions in the spaces provided below each question.
d) Mathematical tables and silent electronic calculators may be used.
e) All working MUST be clearly shown where necessary.
For Examiner’s Use Only
1 – 28 80
Page 1 of 11
1. a) Name another gas, which is used together with oxygen in welding. (1 mark)
……………………………………………………………………………………………………..
(b). Explain the change in mass that occurs when the following substances are separately heated
in open crucibles.
(i) Copper metal. (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
2. Aluminum metal is a good conductor and is used for overhead cables. State any other two
properties that make aluminum suitable for this use. (2marks)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
3. Give two reasons why helium is used in weather balloons. (2marks)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
4. Draw two positional isomers of the third member of alkyne series. (3marks)
5.The apparatus shown below was used to investigate the effect of carbon (ii) oxide on copper
(II) oxide.
Page 2 of 11
a) State the observation that was made in the combustion tube at the end of the experiment.
(1mark)
……………………………………………………………………………………………
……………………………………………………………………………………………
……………………………………………………………………………………………
b) Write an equation for the reaction that took place in the combustion tube (1mark)
……………………………………………………………………………………………
……………………………………………………………………………………………
C) Why is it necessary to burn the gas coming out of tube K? (1mark)
…………………………………………………………………………………………………
6.Give a reason why
(i) Phosphorus is stored under water. (1mark)
………………………………………………………………………………………………..
………………………………………………………………………………………………..
Page 3 of 11
N2 (g) + 3H2 (g) 2NH3 (g); ∆H = -92kJ.
a) How would the yield of ammonia be affected if the temperature was raised to 6000C?
Explain. (2marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………..…
11. The set – up below was used to prepare hydrogen chloride gas and react it with iron
powder. Study it and answer the questions that follow.
At the end of the reaction, the iron powder turned into a light green solid.
a) Identify the light green solid. (1mark)
……………………………………………………………………………………………………
b) At the beginning of the experiment, the pH of the solution in container L was about 14. At
the end, the pH was found to be 2. Explain. (2marks)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
12. Below is part of the Thorium decay series.
(i) Write an overall nuclear equation for the conversion of Th-232 to Ra-224. (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
Page 4 of 11
(ii) Give any two uses of radio isotopes in medicine. (2marks)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
13. The flow chart below shows a series of reactions starting with ethanol , Study it and answer
the questions that follow.
i) Name:
I. Process A……………………………………………………… (1mark)
B...................................................................................................... (½mark)
C…………………………………………………………………… (½mark)
ii) Write the equation for the reaction leading to formation of methane. (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
14. Study the flow chart below and answer the questions that follow.
Page 5 of 11
a) State the condition necessary for the reaction in step 2 to occur (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
b) Name gases D and F: (1mark)
i) Gas D…………………………………………………
Gas F …………………………………………………..
ii) State one use of zinc metal. (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
15. The reaction between a piece of magnesium ribbon with excess 2M hydrochloric acid was
investigated at 25oC by measuring the volume of hydrogen gas produced as the reaction
progressed. The sketch below represents the graph that was obtained.
b) Suggest another parameter that can be used to determine the rate of the above reaction
(1mark)
…………………………………………………………………………………………
…………………………………………………………………………………………
c) On the same diagram, sketch the curve that would be obtained if the experiment is repeated
using powdered magnesium metal. (1mark)
…………………………………………………………………………………………
…………………………………………………………………………………………
16. Zinc oxide reacts with acids and alkalis.
Page 6 of 11
a) Write the equation for the reaction between zinc oxide and:
i) Dilute sulphuric acid (1mark)
…………………………………………………………………………………………
ii) Sodium hydroxide solution (1 mark)
………………………………………………………………………………………………………
..
b) What property of zinc oxide is shown by the reactions in (a) above? (1 mark)
…………………………………………………………………………………………………
17. 0.84 g of aluminum reacted completely with chlorine gas. Calculate the volume of chlorine
gas used (Molar gas volume is 24dm3, al = 27). (3 marks)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
18. Proper use of soaps in washing hands has proven to control the spread of corona novel virus.
a) Write the formula of the grey insoluble substance left in the washing basin when one uses
soap with tap water given that the formula of the soap is C17H35COONa. (1mark)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
b) State two advantages of Soapy detergents over soapless detergents. (2marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
19. a) Use the information given below to draw a labeled diagram of an electrochemical cell
that can be constructed to measure the electromotive force between G and J.
G2+(aq) + 2e → G(s) ; E = - 0.74 V
J2+(aq)+ 2e → J(s); E = -0.14 V (2marks)
b) Calculate the E value for the cell constructed in (a) above. (1mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………
20. a) Sate Le’ Chetelier’s principle. (1mark)
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
b) Study the following equilibrium reaction and answer the questions that follow: -
HL(aq) + H2O(l) H3O+(aq) L-(aq)
Blue
Red +
Given that in an acid solution, H3O (aq) act in place of hydrogen ions, H+, according to the
equation.
Page 7 of 11
H3O+(aq) + OH-(aq) 2H2O(l)
Explain what would be observed when potassium hydroxide solution is added to the above
equilibrium mixture. (2marks)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
……………………………………………………………………………………………………
21. The table below gives information on four elements K, L, M and N. Study it and answer
the questions that follow. The letters do not represent the actual symbols of the elements.
…………………………………………………………………………………………………
…………………………………………………………………………………………………
…………………………………………………………………………………………………
Page 8 of 11
Calculate:
(i)The number of moles of methanol used in this experiment given that the R.F.M is 32.
(1mark)
………………………………………………………………………………………………
………………………………………………………………………………………………
…………………………………………………………………………………………………..
23. Using dots (.) and crosses (x) to represent outermost electrons, draw diagrams to show the
bonding in, CO2 and H3O+. (Atomic numbers; H = 1.0,C= 14.0, O = 8)
i) CO2. (1mark)
24. The diagram below shows a set- up that was used to prepare and collect a sample of nitric
(v) acid
HEAT
a)Give a reason why it is possible to generate nitric (v) acid from sulphuric(vi) acid in the set –
up. (1mark)
……………………………………………………………………………………………………..
b) Name another substance that can be used instead of potassium nitrate. (1mark)
……………………………………………………………………………………………………
c) Give two use of nitric (v) acid. (1mark)
………………………………………………………………………………………………
………………………………………………………………………………………………
Page 9 of 11
………………………………………………………………………………………………
25. When a hydrocarbon was completely burnt in oxygen, 4.2g of carbon (IV) oxide and 1.71 g
of water were formed. Determine the empirical formula of the hydrocarbon
(H= 1.0 ; C=12.0 ; 0 = 16.0). (3marks)
…………………………………………………………………………………………………….
………………………………………………………………………………………………………
………………………………………………………………………………………………………
26 Starting with 50 cm3 of 2.8M sodium hydroxide describe how a sample of pure sodium
sulphate crystals can be prepared. (3 marks)
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
27. The graph below shows the behavior of a fixed mass of a gas at constant temperature.
a) What is the relationship between the volume and the pressure of the gas? (1mark)
……………………………………………………………………………………………………
……………………………………………………………………………………………………
b) Three litres of oxygen gas at one atmosphere pressure were compressed to two
Atmospheres at constant temperature. Calculate the volume occupied by the oxygen gas.
(2marks)
…………………………………………………………………………………………………….
……………………………………………………………………………………………………
………………………………………………………………………………………………….…
Page 10 of 11
28. Explain the following observations
i) Very little amount of hydrogen gas is collected when dilute sulphuric acid react with calcium
metal. (1mark)
…………………………………………………………………………………………………
…………………………………………………………………………………………………..
…………………………………………………………………………………………………..
ii) When hydrogen chloride gas is dissolved in water, the solution turns blue litmus paper to red,
while when hydrogen chloride gas is dissolved in methyl benzene; the resulting solution has no
effect on the blue litmus paper. (2marks)
…………………………………………………………………………………………………..
Page 11 of 11
GOLDLITE ONLINE EDUCATIONAL SERVICES
Kenya Certificate of Secondary Education (KCSE)
SMARTFOCUS KCSE QUICK REVISION SERIES EXAMS
233/1 – CHEMISTRY – Paper 1
2 hours
Name………………………………Adm No………
Class…… …. Date…………………………
SERIES 22
Instructions to candidates
a) Write your name and admission number in the spaces provided above
b) Sign and write the date of examination in the spaces provided above
c) Answer all the questions in the spaces provided on the question paper
d) Non-programmable silent calculators and KNEC mathematical tables may be used
e) All working must be clearly shown where necessary
f) This paper consists of 18 printed pages
g) Candidates should check the question paper to ascertain that all the pages are printed as
indicated and that no questions are missing.
h) Candidates should answer the questions in English
For examiner’s use only
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
17 18 19 20 21 22 23 24 25 26 27 28 29 30
Grand Total
1
1. Give the use of the following apparatus (2mks)
a) Crucible…………………………………………………………………………………
…………………………………………………………………………………………
…………………………………………………………………………………………
b) Separating funnel
………………………………………………………………………………………
………………………………………………………………………………………
2. Describe how you can separate a mixture of sodium chloride and sand (3mks)
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
3. The relative atomic mass of magnesium is 24.3 .Given that the mass number of the three
isotopes of magnesium are 24, 25 and 26 . What is the mass number of the most abundant
isotope of magnesium? Explain. (1mk)
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
a) Write two equations for the reactions which occur in the combustion tube. (2 mks)
Equation
1..........................................................................................................................................................
............................................................................................................................................................
Equation
2..............................................................................................................................................
................................................................................................................................................
5. Vulcanisation a form two student was given solutions P,Q and R in three different beakers .
She put in red and blue litmus papers and recorded the results shown
Solution P Q R
Effect on Changes to Remains Remains
blue litmus red blue blue
paper
Effect on Remains red Remains red Changes to
red litmus blue
paper
………………………………………………………………………………………………………
………………………………………………………………………………………………………
6. Describe how pure copper (II) carbonate can be prepared using the following reagents
(3marks)
-distilled water
-sodium carbonate crystals
-dilute sulphuric (VI) acid
-copper metal
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
(i) Identify the element that gains electrons most readily. (1mk)
……………………………………………………………………………………………
(ii) Which of the metals is most reactive? Explain (1mk)
………………………………………………………………………………………………………
(iii) Explain why the atomic radius of Q is larger than that of M (1mk)
……………………………………………………………………………………………………
8. Give the name of each of the processes described below which takes place when salts are
exposed to air for sometime:- (2mks)
i) Magnesium chloride forms an aqueous solution
…………………………………………………………………………………………
………………………………………………………………………………………….
ii) Fresh crystals of sodium carbonate, Na 2CO3.10H2O become covered with white
powder of formula Na2CO3.H2O
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9. A gas occupies a volume of 40 litres at s.t.p. At what pressure will its volume be doubled
if the temperature rises to 105 0C? (2mks)
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5
10. The diagram below shows the apparatus used for the electrolysis of molten sodium
bromide.
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6
(a) What metal could rod M be made of? (1mk)
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(b) State and explain two observations made inside the conical flask (2mks)
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12. Study the flow charts below and use them to answer the questions that follow:
NH3(aq) in excess
Solution B White precipitate B
H2SO4(aq)
No White precipitate
(i) Solution A
………………………………………………………………………………………………
(ii) Solution B
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7
(b) State and explain the observation made when a sample of dry white precipitate B is
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13. When Magnesium is reacted with steam, it reacts rapidly forming a white solid and
Hydrogen gas.
a).When copper turnings were used instead of magnesium ribbon. Hydrogen gas was not
produced. Explain (1mk)
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b) What property of Hydrogen gas makes it be collected as shown above (1mk)
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c).How would you show that the gas collected is hydrogen gas. (1mk)
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8
14. Hydrogen chloride gas was passed into water as shown below:
Inverted funnel
Water
(a) When a blue litmus paper was dropped into the resulting solution, it turned red. Give a reason
for this observation (1mk)
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(b) What is the function of the funnel? (1mk)
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a) Melting point
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e) Isomer
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9
16. A form four student wanted to determine the solubility of potassium nitrate. She obtained the
following results at 25oC.
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17. An element K forms an ion K3+ This ion has 10 electrons . State the group and period to
whick K belongs. (2mks)
i) Group
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ii) Period
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iii) Using dots and crosses draw the structure of the compound formed when K reacts
with oxygen (1mk)
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18a) Explain why aluminium is a better conductor of electricity than magnesium (1mk)
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10
b)Give one use of magnesium metal(1mk)
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19. Give the change in mass that occur when the following substances are separately heated
in air (2mks)
i) Magnesium
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ii) Anhydrous Sodium carbonate
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20) Excess carbon (II) oxide was passed over a heated sample of an oxide of iron. The
following data was collected .
Determine the :-
11
iii) The empirical formula of the oxide of iron (Fe=56, O=16) (2mks)
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21) Calculate the volume of 0.05M sodium hydroxide which completely neutralizes 25cm 3 of
0.1M sulphuric (VI) acid (2mks)
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22a) State one difference between nuclear reaction and a chemical reaction (1mk)
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55 55
Cr Mn + ____________
24 25
24 25
(c) 100g of a radioactive substance was reduced to 12.5g within 15.6 years. Determine
the half-life of the substance (1mk)
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12
23.The diagram below shows Down’s cell used to extract sodium metal.
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b)In a reaction to prepare ammonia gas. 15 litres of hydrogen gas were reacted with 10 litres of
nitrogen gas . Determine the volume of gas not completely used in the reaction (2mks)
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25) Use the following bond energies to determine whether the reaction below is exothermic or
endothermic (2mks)
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26)The following are formulae of organic compounds .use the formulae to answer the questions
that follow.
CH3CH2CH2CH2OH
CH3CH2COOH
CH3CH2CH3
CH3CCCH3
a) Select :
i) Two compounds which when reacted together produce a sweet smelling compound (1mk
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ii) An unsaturated hydrocarbon (1/2mk)
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27. One of the allotropes of Sulphur is rhombic Sulphur.
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c) Write an equation for the reaction between concentrated sulphuric (VI) acid and sulphur
(1mk)
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b) Explain why is not advisable to allow the solid to accumulate in the environment (1mks)
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29. The set-up below was used by a form one student to determine the percentage of active air.
Study it and answer the questions that follow.
White
Wire phosphorous
Measuring
cylinder
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b) Calculate the percentage volume of air used up in the above experiment (1mk)
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d)Why was the volume above the expected normal volume of active air (1/2mk)
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30. In an experiment 50cm 3 of 0.1M sodium hydroxide solution was placed in a suitable
apparatus and 5.0cm3 portions of hydrochloric acid were added. The resulting mixture was
stirred with a thermometer and the temperature taken after each addition. Both solutions were
initially at 20oC.
16
Volume of 0 5 10 15 20 25 30 35 40 45
3
HCl (cm )
Temperature 20.0 21.5 22.5 24.0 25.5 26.0 27.0 27.5 27.5 27.0
(oC)
a)(i) Plot a graph of temperature against volume of the acid added (3mks)
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(ii) Use the graph to determine the concentration in moles per litre of hydrochloric acid
(2mks)
………………………………………………………………………………………………
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b) Calculate the enthalpy of neutralisation of the alkali with hydrochloric acid .(Specific heat
capacity of mixture = 4.2kJkg -1k-1 and density of solution is 1.0g/cm3 (2mks)
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Energy content
kJ
Reaction progress
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