Grade IX Atoms and Molecules Super Notes
Grade IX Atoms and Molecules Super Notes
Grade IX Atoms and Molecules Super Notes
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John Dalton, a British school teacher and scientist born in 1766, made a major contribution to chemistry with his atomic
theory, which provided a scientific explanation for the laws of chemical combination. The main postulates of Dalton's
atomic theory are:
Dalton's theory explains that atoms of different elements combine in simple, whole-number ratios, which accounts for the
fixed composition of compounds. Before Dalton's atomic theory, scientists relied on the ideas of divisibility of matter
proposed by philosophers like Democritus and the laws of chemical combination established by Lavoisier and Proust. The
significance of Dalton's atomic theory lies in its provision of a scientific explanation for the laws of conservation of mass
and constant proportions, laying the foundation for modern chemistry.
An atom is the smallest unit of matter that retains the properties of an element. Atoms are extremely small, typically
measuring around 10⁻¹⁰ meters in diameter. To illustrate their size, a million hydrogen atoms stacked side by side would
be as thick as a sheet of paper. Atoms are much smaller than common objects, such as a grain of sand or water droplet.
For instance, a water droplet contains approximately 10^21 atoms. To visualize the arrangement of atoms on surfaces,
scientists use a Scanning Tunneling Microscope (STM).
John Dalton was the first scientist to use symbols to represent atoms of different elements. His symbols were simple,
circular designs to visually distinguish one element from another.
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Dalton's atomic symbols:
Hydrogen: a plain circle
Carbon: a circle with a dot inside
Silicon image representation: The magnified image of silicon (Fig. 3.2) represents the arrangement of silicon atoms
as visualized through advanced techniques such as scanning tunneling microscopy.
Size of a hydrogen atom: The size of a hydrogen atom is approximately 10⁻¹⁰ meters.
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IUPAC Søaµjaäj(aø¾µ
1 Unique one- or two-letter abbreviations
Historically, the names of elements were often derived from the place where they were first discovered. For example, the
element "Gallium" was named after "Gallia," the Latin name for France.
Modern element symbols are based on their Latin or English names. They are typically one or two letters, with the first
letter always capitalized and the second (if present) in lowercase.
Provide examples of elements whose symbols are derived from their Latin names.
Examples include:
The International Union of Pure and Applied Chemistry (IUPAC) recommends a standardized system of symbols where
each element has a unique one- or two-letter abbreviation derived from its name.
Atomic mass is the mass of an atom, primarily determined by the sum of the masses of protons and neutrons in the
nucleus.
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Q36: What did Dalton conclude about the atomic mass of elements?
A: Dalton concluded that atoms of different elements have different masses, which was crucial for understanding
chemical reactions and the formation of compounds.
A: Scientists calculate atomic mass using the relative masses of atoms, comparing them to the mass of a reference atom,
such as Carbon-12.
Q38: What is the atomic mass unit (u), and why is it used?
A: The atomic mass unit (u) is a standardized unit for measuring atomic mass. It simplifies calculations by providing a
common reference, such as 1 u = (1/12)th the mass of a Carbon-12 atom.
A: Atomic masses are often not whole numbers because they represent the weighted average of the isotopes of an
element, taking into account their relative abundances.
Q51: What are molecules of elements? Molecules of elements are made up of atoms of the
same type. For example, oxygen O₂ is made up of two
oxygen atoms, while helium (He) is made up of single
helium atoms.
Q52: What is a diatomic molecule? Provide an example. A diatomic molecule consists of two atoms. For
example, oxygen (O₂) is a diatomic molecule formed by
two oxygen atoms.
Q53: What are triatomic and polyatomic molecules? A triatomic molecule consists of three atoms, such
Provide examples. as ozone ( O₃)).
A polyatomic molecule consists of many atoms,
such as sulfur (S₈)).
Q54: What is atomicity, and how does it vary among Atomicity refers to the number of atoms in a molecule
non-metals? of an element. For example:
A: Molecules of compounds are formed when atoms of different elements combine in fixed proportions. Examples
include:
Water (H₂O)
Ammonia (NH₃)
Carbon dioxide (CO₂)
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Tab«p 3.4: M¾«pc «pì aµj Acøø 3.2: La ¾ C¾µìøaµø I¾µì aµj I¾µc C¾³á¾ µjì
Maìì Raø¾ì Pä¾á¾äø¾µì An ion is a charged particle formed
Table 3.4 lists molecules of some Activity 3.2 aims to show the fixed when an atom or a group of atoms
compounds, their combining ratio of masses in water (H₂O) and gains or loses electrons.
elements, and their ratio by mass. For confirm the Law of Constant
A positively charged ion is called a
example: Proportions. It involves calculating the
cation.
ratio of hydrogen to oxygen in water
Water (H₂O): Hydrogen and A negatively charged ion is called
and comparing it to the theoretical
Oxygen, Ratio by Mass = 1:8 an anion.
ratio of 1:8.
Ammonia (NH₃): Nitrogen and
Ionic compounds are formed when
Hydrogen, Ratio by Mass = 14:3 The ratio of masses of hydrogen and
oppositely charged ions (cations and
oxygen is calculated using the
anions) combine in definite
following steps:
proportions. These compounds are
1. Divide the given mass of each typically formed between metals and
element by its atomic mass. non-metals.
2. Simplify the resulting numbers to
find the smallest whole number
ratio.
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Ionic compound: A chemical compound formed by the combination of oppositely charged ions (cations and anions) in
a fixed ratio. Examples include calcium oxide (CaO) and magnesium chloride (MgCl₂).
Polyatomic ion: A group of atoms that are covalently bonded and have a net charge, such as ammonium (NH₄⁺) or
sulfate (SO₄²⁻).
Table 3.5: Lists examples of ionic compounds, their constituent elements, and the ratio of their masses. For example:
Calcium oxide (CaO): Calcium and Oxygen, Mass Ratio = 5:2
Sodium chloride (NaCl): Sodium and Chlorine, Mass Ratio = 23:35.5
Chemical formula: A symbolic representation of a compound's composition, indicating the elements it contains and
their relative proportions.
Valency: The combining capacity of an element, defined as the number of hydrogen atoms or other monovalent atoms
it can combine with to form a compound.
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Valency is a crucial concept in chemistry that determines how atoms combine. Let's explore this through an example and
an analogy:
For hydrogen chloride (HCl), hydrogen and chlorine each have a valency of 1, meaning they combine in a 1:1 ratio.
The text uses the analogy of human hands to explain valency. Just as people use hands to hold objects, atoms use
their valency to combine with other atoms.
Table 3.6 provides valuable information about ions, including their names, symbols, and valencies. Here's a summary:
2.4
1.6
0.8
0
Monatomic Polyatomic
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The valencies or charges of the ions must balance. Hydrogen chloride: (HCl)
If a compound consists of a metal and a non-metal, the Water: (H2O)
symbol of the metal is written first.
Magnesium chloride: (MgCl2)
For compounds with polyatomic ions, the ion is written
Calcium oxide: (CaO)
in brackets if more than one is present.
Q71: Waø aäp øp ä «pì ¾ä äøµ a cp³ca« ¾ä³ «a?
A: The rules for writing a chemical formula are:
A: It is necessary to simplify the formula of compounds to represent them in the simplest whole-number ratio of atoms,
ensuring the valencies are balanced.
A: The chemical formula of carbon tetrachloride is (CCl₄), where one carbon atom (valency 4) combines with four chlorine
atoms (valency 1).
- Symbol: Al, O
- Valency: 3 (Aluminium), 2 (Oxygen)
- Cross-over valencies: Al₂O₃, where two aluminium atoms combine with three oxygen atoms.
Q79: Explain the use of brackets in chemical formulas with polyatomic ions.
A: Brackets are used in chemical formulas when more than one polyatomic ion is present. For example, in calcium
hydroxide (Ca(OH)₂), the brackets indicate that two hydroxide (OH) ions are combined with one calcium ion.
Oxygen = 16 u
Molecular mass = 1 + 14 + (16 × 3) = 63 u
3. Formula unit mass: The sum of the atomic masses of all atoms in its formula, expressed in atomic mass units (u).
4. Difference between atomic mass and molecular mass:
Atomic mass refers to the mass of a single atom.
Molecular mass is the total mass of all atoms in a molecule.
5. Molecular masses of compounds:
Al₂(SO₄)₃: (2 × 27) + (3 × 32) + (12 × 16) = 342 u
CaCl₂: 40 + (2 × 35.5) = 111 u
K₂SO₄: (2 × 39) + 32 + (4 × 16) = 174 u
HNO₃: 1 + 14 + (3 × 16) = 63 u
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Let's explore some key concepts related to molecular masses and the mole concept:
A: The formula unit mass of CaCl₂ is calculated as: (40) + (2 × 35.5) = 111 u.
A:
Molecular mass is the sum of the atomic masses of all atoms in a molecule (e.g., H₂O, CO₂).
Formula unit mass is used for ionic compounds, representing the sum of the atomic masses of ions in the formula
unit (e.g., NaCl, CaCl₂).
1. Two molecules of hydrogen combine with one molecule of oxygen to form two molecules of water.
2. 4 grams of hydrogen combine with 32 grams of oxygen to form 36 grams of water.
A: The mole concept was introduced to conveniently express the number of atoms, molecules, or ions in a substance, as
their actual number is extremely large and impractical to count directly.
A: One mole of a substance contains 6.022 × 10²³ particles (atoms, molecules, or ions) and is referred to as Avogadro's
number.
A: Avogadro's number is 6.022 × 10²³, which represents the number of particles in one mole of a substance.
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Q97: How is the mass of 1 mole of a substance determined?
A: The mass of 1 mole of a substance is equal to its molecular or formula mass expressed in grams. For example:
A:
1 6.022E23
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Number of moles = Mass of substance ÷ Molar mass 1 mole = 6.022 × 10²³ particles
The molar mass of a substance is the mass of 1 mole of its particles in grams.
A:
A: Fig. 3.8 shows the relationships between the number of moles, mass, Avogadro's number, and molecular mass. For
example:
A: Avogadro's number (6.022 × 10²³) defines the number of particles (atoms, molecules, or ions) in one mole of any
substance, making it a standard quantity for measuring particles in chemistry.
Q102: Why is it more convenient to use moles instead of counting individual particles?
A: Counting individual particles is impractical because they are extremely small and numerous. Using moles provides a
standard unit that simplifies calculations involving large numbers of particles.
A: The mass of 1 mole of hydrogen atoms is 1 gram, as the atomic mass of hydrogen is 1 u.
A: The mass of 1 mole of oxygen molecules (O₂) is 32 grams, as each oxygen atom has a mass of 16 u, and there are two
atoms in an O₂ molecule.
Q105: How is the relative atomic mass of an element related to its molar mass?
A: The relative atomic mass of an element expressed in atomic mass units (u) is numerically equal to its molar mass
expressed in grams. For example:
1 6.022E23 22.4L
Maìì Paäøc«pì V¾« ³p
1 mole equals the molar mass of a 1 mole contains 6.022 × 10²³ 1 mole of a gas occupies 22.4 liters at
substance in grams. particles. standard temperature and pressure
(STP).
Q111: How do you calculate the mass of a substance if the number of moles is given?
A: The formula to calculate mass is: Mass = Number of moles × Molar mass.
A:
Q113: How do you calculate the number of moles from the number of particles?
A: The formula to calculate moles is: Number of moles = Number of particles / Avogadro's number (6.022 × 10²³).
Q114: How many moles are there in 3.011 × 10²³ atoms of carbon?
Q115: How do you calculate the number of particles from the number of moles?
A: The formula to calculate particles is: Number of particles = Number of moles × Avogadro's number.
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Q116: What is the number of N₂ molecules in 1.5 moles of nitrogen gas?
Q117: How do you calculate the number of atoms in a given number of moles of a compound?
Q118: How many hydrogen atoms are present in 0.25 moles of H₂?
A:
Q119: What is the mass of 1.28 × 10²⁴ molecules of nitrogen gas (N₂)?
A:
Q120: If 1 mole of carbon atoms weighs 12 g, what is the mass of 6 moles of carbon?
3. Molar mass: The mass of 1 mole of a substance, expressed in grams per mole (g/mol).
4. Percentage composition: Calculated as (Mass of the element in the compound / Molar mass of the compound) ×
100%.
5. Mole concept significance: Simplifies counting of atoms, molecules, or ions by providing a standard unit to relate the
number of particles to their mass or volume.
6. Example reaction: 3.00 g carbon + 8.00 g oxygen = 11.00 g carbon dioxide. Governed by the Law of Conservation of
Mass.
7. Polyatomic ions: Groups of covalently bonded atoms with a net charge. Examples: Ammonium (NH₄⁺), Sulfate (SO₄²⁻),
Phosphate (PO₄³⁻).
8. Chemical formulas: MgCl₂ (Magnesium chloride), CaO (Calcium oxide), Cu(NO₃)₂ (Copper nitrate), AlCl₃ (Aluminium
chloride), CaCO₃ (Calcium carbonate).
9. Elements in compounds: Quick lime (CaO): Calcium, Oxygen; Hydrogen bromide (HBr): Hydrogen, Bromine; Potassium
sulphate (K₂SO₄): Potassium, Sulfur, Oxygen.
10. Molar mass calculations: Ethylene (C₂H₄): 28 g/mol; Sulphur molecule (S₈): 256 g/mol; Nitric acid (HNO₃): 63 g/mol.
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Let's explore how to calculate the mass of different moles of atoms:
2. 20 g of water (H₂O):
- Mass = 0.5 × 18 = 9 g.
A:
- Number of molecules = Moles × Avogadro's number = 0.0625 × 6.022 × 10²³ = 3.76 × 10²² molecules.
Q140: Calculate the number of aluminium ions (Al³⁺) present in 0.051 g of aluminium oxide (Al₂O₃).
A:
34 98
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g/mol of H2SO4
0.347 2.09E23
M¾«pì H2SO4 M¾«pc «pì
of H2SO4
= 34 g / (2 + 32 + 64) g mol-1
= 34 g / 98 g mol-1
= 0.347 mol