answer for model qp

II – PUC – CHEMISTRY (34) MODEL QUESTION PAPER -1
For reduced syllabus 2020-21

SOLUTIONS
PART- A
I. ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES 1 MARK.
10 × 1 = 10
1. What is the effect of temperature on molality of a solution?
ANS: Independent of temperature
2. How does the size of blood cell changes when placed in an aqueous solution
containing less than 0.9% (m/v) sodium chloride?
Ans: Swells ,because it becomes hypotonic
3. The resistance of a conductivity cell containing 0.001M KCl solution at 298K
is 1500Ω. What is the cell constant if conductivity of 0.001M KCl solution at
298K is 0.146 x 10-3 Scm-1 ?
Ans: 𝑮∗ = 𝒄𝒐𝒅𝒖𝒄𝒕𝒊𝒗𝒊𝒕𝒚 × 𝑹 = 𝟎. 𝟏𝟒𝟔𝑺𝒄𝒎−𝟏 × 𝟏𝟓𝟎𝟎𝒐𝒉𝒎 = 𝟎. 𝟐𝟏𝟗 𝒄𝒎−𝟏
4. Give an example for pseudo first order reaction.
Ans: Inversion of sugar or acid hydrolysis of methyl acetate
5. What is adsorption isotherm?
Ans: An adsorption isotherm is a curve relating the equilibrium concentration
of a solute on the surface of an adsorbent, qe, to the concentration of the
solute in the liquid, Ce, with which it is in contact.
6. Noble gases have large positive values of electron gain enthalpy. Why?
Ans: Because of closed shell configuration
7. Complete the following equation:
Ans: O2F2
8. Give an example for geminal halide.
Ans: 1,1-dichloroethane or ethylidene dichloride
9. Which type of Aldehydes does not undergo Cannizzaro’s reaction?
Ans: Aldehydes with 𝜶 − 𝑯
10. What are nucleotides?
Ans: Phosphates of nucleosides
PART- B
II. ANSWER ANY FIVE OF THE FOLLOWING. EACH QUESTION CARRIES 2
MARKS. 5×2= 10
11. Give any two differences between amorphous and crystalline solids.
Ans:
Difference between Crystalline and Amorphous
CRYSTALLINE SOLIDS AMORPHOUS SOLIDS
Atoms are arranged in regular 3 They do not have regular

dimension arrangement
Sharp melting point No particular melting point
Anisotropic Isotropic
True solid Pseudo solid
Symmetrical Unsymmetrical
More rigid Less rigid
Long range order Short range order
Any to differences
12. Write the overall cell reaction during the working of Daniel cell.
Ans:
Ion Zn/ZnSO4 half cell, oxidation reaction occurs.
Zn → Zn2+ + 2e–
Ion Cu/CuSO4 half cell, reduction reaction occurs.
Cu2+ + 2e– → Cu
The net cell reaction is
Zn + Cu2+ ⇌ Zn2+ + Cu
13. For the reaction R → P, the concentration of reactant changes from 0.03M to 0.02M in 25 min.
Calculate the average rate of reaction in seconds.
Ans:
14. How will you account for the following?

i) Zr and Hf sizes are almost same.
Ans:This is because of poor screening effect by 4f electrons,which lead to the
lanthanoid contraction.Hence,is the reason of Zn and Hf have almost equal
atomic size.
ii) What is the composition of mischmetal.
Ans: It is an alloy of cerium and lanthanum with some rare earth metals
15. Explain Friedel-Crafts acylation with equation by taking chlorobenzene as
example.
Ans:
Chlorobenzene reacts with acid chloride in the presence of anhydrous
aluminium chloride forms ortho and para acyl chlorobenzene.
16. Explain Kolbe’s reaction.
Ans:
When phenol is treated with sodium hydroxide, sodium phenoxide is

produced, which on treating with carbon dioxide, followed by acidification,
undergoes electrophilic substitution to give Salicylic acid as the main product.
17. Give the preparation of phenol from cumene.
Ans:
cumene is first oxidized in the presence of air of cumene hydro-peroxide.

Then, cumene hydroxide is treated with dilute acid to prepare phenol and
acetone as by-products.
18. Explain carbylamine reaction with an example.
Ans: Aliphatic/aromatic primary amines are heated with
chloroform/alcoholic KOH to form foul-smelling alkyl isocyanides or
carbylamines.
PART- C
III. ANSWER ANY FIVE OF THE FOLLOWING. EACH QUESTION CARRIES
3MARKS. 5×3= 15
19. Discuss the principle involved in the manufacture of ammonia by Haber’s
process along with the chemical equation.
Ans: 3
N2+3H2⇌2NH3
The reaction proceeds in the forward direction
The reaction is exothermic.
In accordance with Le Chatelier’s principle, high pressure would favour the
formation of ammonia.
The optimum conditions for the production of ammonia are a
Pressure -200atm,
Temperature -700K
Catalyst such as iron oxide with small amounts of K2O and Al2O3 to increase
the rate of attainment of equilibrium.
20. Give any three reasons for the anomalous behavior of oxygen. 3
Ans:Reasons for the anomalous behavior of oxygen are given below.
1) Oxygen is small in size.
2) Oxygen has high electronegativity.
3) The valence shell of oxygen lacks vacant d orbitals.
21. i) What is aqua regia?

Ans: It is a freshly prepared mixture of concentrated hydrochloric acid and
concentrated nitric acid in the ratio of 3:1
ii) Write the structure of chlorous acid.
Ans:
iii) Complete the equation: Br2 + 5F2(excess) → _______ 1+1+1

Ans: Br2+(Excess)5F2→2BrF5
22. i) Many copper(I) compounds are unstable in aqueous solution and
undergo disproportionation. Explain.
Ans: Cu2+ Is more stable than Cu+ because of much more negative
ΔhydH∘(hydration enthalpy) of Cu2+ than Cu+, which more than
compensates for seconds ionisation enthalpy.
ii) What are interstitial compounds? 2+1
Ans: The compounds in which small atoms like H, C, N, etc.,
occupy interstitial sites in the crystal lattice are called interstitial compounds.
23. a) Write general valence shell electronic configuration of d-block elements.
Ans: (n-1)1-10,ns0-2
b) d-Block elements act as good catalysts. Give any two reasons. 1+2
Ans: (i) The presence of vacant d-orbitals. (ii) The tendency to exhibit variable
oxidation states. (iii) The tendency to form reaction intermediates with
reactants.
24. Give any three postulates of Werner’s theory of coordination compounds 3
Ans: 1.The central metal atom possess two types of valencies: i Primary
valencies and ii Secondary valencies.
2. Primary valencies denote oxidation state of the metal ion in the complex
and are always satisfied by the negative ions.
3. Secondary valencies correspond to the coordination number of the metal
ion in the complex.
4. The geometry of the complex depends upon the arrangements of the
secondary valencies in the space.
25. Based on VBT, explain the formation of [Ni(CN)4] 2- . 3

Ans:
26. i) Write the structure of decacarbonyldimanganese(0), Mn2(CO)10.

Ans:
ii) What are homoleptic complexes? Give an example. 1+2

Ans: The Complexes compounds in which all the ligands are bound
to the metal center which are identical
PART –D
IV. ANSWER ANY THREE OF THE FOLLOWING. EACH QUESTION CARRIES
5MARKS. 3×5=15
27. a) Calculate the packing efficiency in a cubic close packed (ccp) structure.
Ans:
b) An element having atomic mass 60u has fcc lattice, the edge length of the
unit cell 400pm. Calculate the density of the crystal (NA= 6.022 x 1023) 3+2
Ans:
28. a) Addition of 0.643g of a compound to 50mL of a liquid

(density=0.879g/mL) lowers the freezing point from 5.510C to 5.030C.
Calculate the molar mass of the compound. (Kf for benzene = 5.12KKgmol-1 )
Ans:
b) Give any two differences between ideal and non-ideal solutions. 3+2
Ans:
Ideal solution Non Ideal solution

It obeys Raoult's law over the entire
It does not obeys Raoult's law
range of concentration.
Total vapour pressure of solution is Total vapour pressure of solution is not
the sum of vapour pressure of equal to the sum of vapour pressure of
individual components. individual components.
29. a) The standard electrode potential for Daniel cell is 1.1V. Calculate the
standard Gibbs energy change for the reaction; Zn(s) + Cu2+ (aq) → Zn2+ (aq)
+Cu(s)
Ans:
b) Write any two factors affecting ionic conductance. 3+2

Ans: 1) Dilution or concentration: On dilution, the conductivity of electrolytic
solution decreases.
2) Temperature:
30. a) Derive integrated rate equation for a first order reaction.

Ans:
b) Which step of the reaction mechanism decides the order of reaction in
complex reactions? 4+1
Ans: Slowest step
31. a) How does free energy and entropy changes during adsorption? b) What
is coagulating value? The coagulating value of A and B will be 2.4 x 10-
3millimole per litre and 1.2 X 10-2millimole per litre, which one has higher
coagulating power? c) What is Craft temperature (Tk)? 2+2+1

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II – PUC – CHEMISTRY (34) MODEL QUESTION PAPER -1

For reduced syllabus 2020-21

Difference between Crystalline and Amorphous

CRYSTALLINE SOLIDS AMORPHOUS SOLIDS

Atoms are arranged in regular 3 They do not have regular

Sharp melting point No particular melting point

True solid Pseudo solid

More rigid Less rigid

Long range order Short range order

14. How will you account for the following?

When phenol is treated with sodium hydroxide, sodium phenoxide is

cumene is first oxidized in the presence of air of cumene hydro-peroxide.

21. i) What is aqua regia?

iii) Complete the equation: Br2 + 5F2(excess) → _______ 1+1+1

25. Based on VBT, explain the formation of [Ni(CN)4] 2- . 3

26. i) Write the structure of decacarbonyldimanganese(0), Mn2(CO)10.

ii) What are homoleptic complexes? Give an example. 1+2

28. a) Addition of 0.643g of a compound to 50mL of a liquid

Ideal solution Non Ideal solution

b) Write any two factors affecting ionic conductance. 3+2

30. a) Derive integrated rate equation for a first order reaction.

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