ACT-2-JA-25.12.2024-SOLUTION

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TARGET : JEE (MAIN + ADVANCED) 2026

TEST DATE: 25.11.2024 ACADEMIC SESSION: 2024-25

COURSE COURSE BATCH


VIKAAS (JA) 01JA,IA,JAZA CLASS XI
DETAILS NAME CODE(S)
TEST TEST JEE TEST CUMULATIVE TEST CODE &
ACT 02
DETAILS PATTERN (ADVANCED) TYPE TEST (CT) SEQUENCE

PAPER-1
Q.No. 1 2 3 4 5 6 7 8 9 10
PART-I : Ans. D A D B A AC ABCD AD D
MATHEMATICS Q.No. 11 12 13 14 15 16 17 18
Ans. ABD C 02.00 01.00 02.00 27.00 00.30 24.00
Q.No. 19 20 21 22 23 24 25 26 27 28
PART-II : Ans. B D B C C D CD BC B AC
PHYSICS Q.No. 29 30 31 32 33 34 35 36
Ans. ABD B 02.00 03.00 07.00 02.00 50.00 08.00
Q.No. 37 38 39 40 41 42 43 44 45 46
PART-III : Ans. C A D C D D ABCD AC AC ACD
CHEMISTRY Q.No. 47 48 49 50 51 52 53 54
Ans. CD ABC 07.00 06.00 00.80 07.00 09.00 04.00
PAPER-2
Q.No. 1 2 3 4 5 6 7 8 9 10
PART-I : Ans. 2 0 4 6 3 3 ABC ABD CD ABCD
MATHEMATICS Q.No. 11 12 13 14 15 16 17 18
Ans. AD BCD 01.00 53.30 01.00 08.00 02.00 01.00
Q.No. 19 20 21 22 23 24 25 26 27 28
PART-II : Ans. 3 5 2 4 5 1 AB AC ABCD AC
PHYSICS Q.No. 29 30 31 32 33 34 35 36
Ans. BD BCD 02.00 02.00 80.00 04.00 05.00 05.00
Q.No. 37 38 39 40 41 42 43 44 45 46
PART-III : Ans. 8 3 4 4 5 2 ABCD ABC ABC ABC
CHEMISTRY Q.No. 47 48 49 50 51 52 53 54
Ans. ABC AC 18.00 07.00 08.00 00.00 12.00 03.00

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TEXT SOLUTIONS (TS)
2 2 2 1
also, a + b + c – (ab + bc + ca) =
PAPER-1 2
2 2 2
[(a – b) + (b – c) + (c – a) ]

2 2 2
PART-I: MATHEMATICS a + b + c – (ab + bc + ca) > 0
 < 1 
2 10 1
1. 6 2 1  0   =1
7. sinx  12  31  cosa sinx  b  0
4  1
sinx =1, cos(a + b) = –1
 R(5, 1) 
Let R(5, 1) divides line segment joining x  2n  , (a + b) = (2k + 1) 
2
P(2,10) and Q(6, – 2) in  : 1

 a + b + x = (2k + 1)  + 2n 
2
6  2 3
5= =3 = 2(k  n) 
 1 2
Hence Harmonic congruent divides in 3 : 1  3
=  
externaly 2 2
 18  2 6  10  
Hence required part is  ,  k = n = –1 – – 2 + =
 3 1 3 1  2
= (8, -8)  5
 3   
2 10 1 2 2
gy. 6 2 1  0   =1 k = 2, n = –1
4  1   11 
3  2   5  
2 2 2
 R(5, 1)
ekuk R(5, 1) fcUnqvksa P(2,10) vkSj Q(6, – 2) dks (3n)!
feykus okys js[kk[k.M dks  : 1 esa foHkkftr djrk 8. A ,
(n! )3 3 !
gSA
(3n  1)! 1 (3n)!
B 
2
(n! ) 2! (n  1) ! (ni)3 3 !
6  2 (3n  2)! 1 (n  1)
5= =3 C A
 1 (n! )2 2! (n  2)! (3n  1)
vr% gjkRed la;qXeh] ckg; :i ls 3 : 1 esa (n  1)
foHkkftr djrk gSA AC  A 2 n=3
(3n  1)
 18  2 6  10  2
vr% vHkh"V fcUnq  ,  = (8, -8) 1 A
 3 1 3 1   AC  A 2  
4 2
gSA
9. 18
Cr–2 + 2.18Cr–1 + 18Cr  20C13
2. A B = {23, 38, 53, 68, 83}
or ;k 19Cr–1 + 19Cr  20C13
3. H.P. is 10, 12, 15, 20, 30, 60 or ;k 20Cr  20C13
a = 15, b = 30, c = 60 r = 7,8,9,10,11,12,13
A.P. is 15, 20, 25, ….., 55, 60
sum of all term of A.P. is 10/2 (15 + 60) 10. Graph of y = |x + 2| – |x + 1| + |x – 1|
= 375
lekaUrj Js.kh ds lHkh inksa dk ;ksxQy gS 10/2 y = |x + 2| – |x + 1| + |x – 1| dk vkjs[k
(15 + 60) = 375
2 2
4. a > 0 , b < 4ac, b > 0 , c < 4ab , c > 0,
2
a < 4bc

2 2 2
a + b + c < 4(bc + ca + ab)
1
 <  
4

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for two solutions nks gy ds fy,  Remainder 'ks"kQy = 8
K  (1, 2)  (3, )
16. Using multinomial theorem
11. Find the co-efficient of x11 in the expansion
(x + x2 + x3 + .......+ x6)3 = x3 (1 – x6)3.(1–x)–
3
is
= 10C8 –3 . 4C2 = 45 – 18 = 27
gy- cgqinh; izes; dk iz;ksx djus ij
(x + x2 + x3 + .......+ x6)3 ds izlkj esa x11 dk
xq.kkad
= x3 (1 – x6)3.(1–x)–3 ds izlkj esa x11 dk xq.kkad
= 10C8 –3 . 4C2 = 45 – 18 = 27

17. f1(x) = ||x| – 2|

f1(x) = 2  3 solution gy
f2(x) = |||x| – 2| – 2|
dy x 2  6 x  5
  0  x  1 and 5
dx 2  x  32
Point of Maxima and Minima
y x 1  2 y x 5  6

f2(x) = 2 4 solution gy
15 sin  + 10 cos  = 6 …..(1)
4 4
12. fn(x) = |fn–1(x) – 2| ds have n + 2 solution gy
after dividing equation (1) by cos 
4
f2015(x) = 2 ds have 2017 solutions gy
 15 tan + 10 = 6 sec 
4 4
18. The three terms of the geometric sequence
Let tan  = t with the common ratio r, are x, xr, xr
2

 15t + 10 = 6(1 + t )
4 2 2
  x + xr + xr = 42
2

 9t – 12t + 4 = 0
4 2
5
 (3t – 2) = 0
2 2 After multiplying the middle term by will
4
2 3 2 get an arithmetic sequence.
tan =  cos  = and sin  =
2 2 2
3 5 5 5 2 5
This yields xr – x = xr – xr
So, 27 sec  + 8 cosec 
6 6
4 4
3 3 After cancelling x, we obtain a quadratic
5 5
=27    8     125 + 125 = 250 equation
3 2 2 1
2r –5r + 2 = 0, with roots r = and r = 2.
2
2
On substituting these in x + xr + xr = 42,
We get x = 6 or 24
gy- xq.kks Js.kh esa rhu in ftldk lkoZvuqikr r gSA
14. x = cos + cos – cos ( + ) 2
x, xr, xr gS
  (   )
  x + xr + xr = 42
2
y = 4 sin sin cos
2 2 2
5
x – y = cos  + cos  – cos ( + ) – 4 sin e/; in dks ls xq.kk djus ij lekUrj
4
  
sin cos   vuqØe izkIr gksrh gSA
2 2  2 
5 2 5
= cos  + cos  – cos ( + ) – 2 rc xr – x = xr – xr
4 4
       
cos  2   cos  2   cos  2  ljy djks ij f}?kkr lehdj.k
      
2 1
= cos  + cos  – cos ( + ) + 2 cos
2
2r –5r + 2 = 0, vr% r = rFkk r = 2.
2
   
 2  – 2 cos  2  cos  2  = 1 eku j[kus ij x + xr + xr2 = 42,
     
x = 6 ;k 24
2003 500 500
15. 2 = 8.(16) = 8 (17–1)

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--------------------------------------------------------------

PART-II: PHYSICS
24. Using conservation of energy :
19. Before collision 1 2
mgR (1- cos) = mv
VDdj ls iwoZ 2
Radial force Equation :
mv 2
2m V1 mgcos– N =
R
mv 2
 N = mgcos – = mg (3 cos–2)
R
m V2

After collision
VDdj ds i'pkr~
Normal act radially outward on bead if cos
> 2/3
2m 0.5V1 Normal radially inward on bead if cos  <
2/3
 Normal on ring is opposite to reaction on
bead.
m V4 1
ÅtkZ laj{k.k ls : mgR (1- cos) = mv2
2
By conservation of momentum before and mv 2
f=kT;h; cy lehdj.k : mgcos– N =
after collision R
VDdj ls iwoZ rFkk ckn esa laosx laj{k.k ls mv 2
 N = mgcos – = mg (3 cos–2)
2mv1 + mv2 = 2m (0.5v1) + mv4 R
v4 = v1 + v2

1 2 2
21. K= mv = as
2
2as 2
v =
2
eksrh ij vfHkyEc f=kT; ckgj dh vksj gksxk ;fn
m
2
cos > 2/3
v 2as 2 eksrh ij vfHkyEc f=kT; ckgj dh vksj gksxk ;fn
aC = =
R mR cos  < 2/3
dv 2as  eksrh ij izfrfØ;k oy; ij vfHkyEc ds
at = v =
ds m foijhr gS
2
 2as 2   2as  2
a=      P2 m2 v 2
 mR   m  25. K.E = 
2(M  m) 2(M  m)
1/ 2
2as  s2 
=  1  2  2
m  R  26. an = kt
1/ 2 v2 2
 s2  = kt
Total force dqy cy = ma = 2as  1   R
 R2 
v= kR t
dv
22. The instantaneous acceleration of tip is at = = kR constant fu;rkad
given by dt
2 a 1
 2  1 –3 tan = t  2
ac =  R =    0.1   10
2
an t
 60  900
p = Ft v
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 t 35. Displacement of the point of 'A' of the string
<p>  t. jLlh ds fcUnq 'A' dk foLFkkiu
= (3 3)2  (3)2 – 42  32
=6–5=1m
k = Work done by tension
29. (A) The acceleration of block A is 5/2 m/s2
ruko }kjk fd;k x;k dk;Z
CykWd A dk Roj.k 5/2 m/s gSA 2 = 50 × 1 = 50 Joule.

(B) The acceleration of block B is 5/(22)


m/s2
CykWd B dk Roj.k 5/(22) m/s2 gSA
(D) The tension in the string connecting A is
150/2 N.
A ls tqM+h gqbZ jLlh esa ruko 150/2 N gSA
36. T = Mg

dv
31. at = = 1 m/s2
dt
v2
ac = = t2
r
Friction force ?k"kZ.k cy
= manet = 2  1  t2
2

= 2  2 = 2 N Ans.
T1 = T + Mg = 2Mg
Kx = 2T1
33. (A2 + B2 + 2AB cos )
1 2T1 4Mg
= (A2 + B2 – 2AB cos  )  or x= = .
4 K K
  3A2 + 3B2 + 10 AB cos = 0 --------------------------------------------------------------
or 12B2 + 3B2 + 10(2B) (B) cos = 0
15B2 + 20B2 cos  = 0 PART-III: CHEMISTRY
3 m
cos  = – =  m + n = 7
4 n 37. An ideal gas cannot be liquefied because
the intermolecular forces among gaseous
molecules are zero.
34. ,d vkn'kZ xSl dks nzfor ugha fd;k tk ldrk
gS] D;ksafd xSlh; v.kqvksa ds e/; vUrjvkf.od
cy 'kwU; gksrk gSA

39. (A) At NTP, H2O does not exists in gaseous


state. So, volume of its 0.5 mole will not be
From work energy theorem W = K 11.2 L.
Mg(R – R cos ) = 1/2 mv
2
(B) 9 g of H2O will be produced and 1 g of
v  2gR(1  cos ) Hydrogen will be left unreacted, since H
and O always combine in a fixed ratio (1 :
mv2 8) by mass to form H2O. However, law of
To loose contact  mgcos 
R conservation of mass still remains valid.
2mg(1 – cos ) = mg cos  (C) Two different compounds composed of
2 – 2 cos  = cos  the same elements and same mass
h h percentages of consitutent elements, must
cos  = 2/3 =   h = 2m have the same empirical formula.However,
R 3 moloecular formula may or may not be
same.
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gy. (A) NTP ij, H2O xSlh; voLFkk esa izkIr ugha bySDVªkWu dh dqy la[;k = 6
gksrk gSA blfy,] blds 0.5 eksy dk vk;ru n  4
11.2 L ugha gksxkA ;fn   bySDVªkWuksa dh dqy la[;k = 2,
  0  4s,
(B) 9 g H2O cusxk rFkk 1 g gkbMªkstu
rc bySDVªkWuksa dh dqy la[;k = 6 + 2 = 8
vfØ;k'khy jg tk;sxk] pwafd H o O, H2O cukus 43. Isoelectronic species have same number of
ds fy, ges'kk fuf'pr ¼Hkkj dk½ vuqikr (1 : 8) electrons.
esa la;ksftr gksrs gSaA ;|fi] nzO;eku laj{k.k dk lebysDVªkWfud Lih'kht bysDVªkWuksa dh leku
fu;e vHkh Hkh ekU; gSA la[;k j[krs gSaA
(C) vo;oh rRoksa ds leku nzO;eku izfr'kr rFkk
leku rRoksa ls cus nks fHkUu ;kSfxd] leku 44. The wave function is independant of angle
which implies it belongs to spherically
ewykuqikrh lw=k j[krs gSaA ;|fi v.kqlw=k leku] gks symmetric s orbital. Further, it has only
Hkh ldrk gS vkSj ugha Hkh gks ldrk gSA one radial node at r = Z/2 which indicates
2s orbital.
gy. rjax Qyu dks.k ls Lora=k gS vFkkZr~ ;g xksyh;
r0 n2 :i ls lefer s d{kd ls lEcaf/kr gSaA vkxs ;g
rn Z r0 n4 r = Z/2 ij dsoy ,d f=kT;h; uksM+ j[krk gSA
41. = =
Un Z2 –2E0 Z 3 tks 2s d{kd dks bafxr djrk gSA
–2E0 2
n
r0n2 E Z2 nh 45. Na2SO4 + BaCl2  2NaCl + BaSO4
rn. KEn.n =  02  (Let V mL volume of BaCl2)
Z n 2
millimole 50 0.1×V
r0E0 Znh 50–0.1V 0 0.2 V 0.1 V
=
2 + (50 – 0.1V)2 – 0.2V 1
[Na ] = =
–2E0 Z2 n3 V  100 3
 T0 2
Un  Tn n 2
Z  V = 200 mL
=
n nh Millimoles of BaSO4 = 0.1 V = 0.1 × 200 =
2 20
2+
–2E0 T0 [Ba ] = 0.1 V / 300 = 200 / 300 = 2/3 M
=  2 –
[Cl ] = 0.2 V / 300 = 200×0.2 / 300=0.133 M
h 2–
[SO4 ] = (0.1 V + 50 – 0.1 V) / 300 = 1/6 M
nh Z2
 f0  3
n  fn 2 n 
 
v n2 2  y y
 Z 47. CxHy +  x   O2  xCO2 + H2O ()
 v 0 n   4 2
i a 7a 0
hf0
   y
2 v 02 ƒ 0 7a –  x   a xa
 4
 y
42. (B) Cr3+ : [Ar]3d3 (Three unpaired electron) Given : 7a –  x   a = xa
spin only magnetic moment  4
 8x + y = 28
= 3(3  2) = 15 BM
Only C3H4 hydrocarbon satisfies the above
n  3 relation.
(C) n+ = 4 ,   1  3p,  y y
  gy. CxHy +  x   O2  xCO2 + H2O ()
total number of electrons = 6  4 2
n  4 i a 7a 0
If   0  4s, total number of electrons = 2.  y
  ƒ 0 7a –  x   a xa
 4 
So, total number of electrons = 6 + 2 = 8.
 y
gy. (B) Cr3+ : [Ar]3d3 ( 3 v;qfXer e) fn;k gS : 7a –  x   a = xa
 4
dsoy pØ.k pqEcdh; vk?kw.kZ
 8x + y = 28
3(3  2) = 15 BM dsoy C3H4 gkbMªksdkcZu] mDr lEcU/k dks larq"V
n  3 djrk gSA
(C) n+ = 4 ,   1  3p, 48. (A) temperature (B) volume
 
(C) pressure
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(A) rkieku ij (B) vk;ru ij total final moles
(C) nkc ij a a
= a + b +a
2 2
dqy vfUre eksy
50. At Boyle's temperature and low pressure, a a a
real gas will show ideal behavour. = a + b +a
2 2
(ckW;y rki ,oe~ fuEu nkc ij] ,d okLrfod =a+b
xSl vkn'kZ O;ogkj djrh gSA) So initial moles = final moles
 a  blfy, izkjafHkd eksy = vfUre eksy
 PV = nR  
 bR   We are simply doubling the
1.2 temperature after reaction.
 0.1 × 1440 = n × ge vfHkfØ;k ds i'pkr rkieku dks
0.05
 n=6 nqxquk djrs gSA
 On doubling the temperature at
51. Weight of H2 = 20 g in 100 g mixture ; constant volume and moles,
Weight of O2 = 80 g pressure doubles.
fu;r vk;ru ij rkieku dks nqxquk
20
 Moles of H2 = = 10 ; djus ij eksy o nkc nqxqus gks tkrs gSA
2
So Finally pressure
80 5
 Moles of O2 =  7
32 2 =2 atm = 7 atm
2
5 25
 Total moles = 10 +  7
2 2 blfy, vfUre nkc = 2  atm = 7 atm
2
 PH' 2 = P x mole fraction of H
T 2

10
=1x = 0.8 bar
25 / 2 PAPER-2
gy. H2 dk Hkkj = 20 g (100 g feJ.k esa½
O2 dk Hkkj = 80 g
PART-I: MATHEMATICS
20
 H2 dk eksy = = 10 ;
2
80 5 2. a, b, c are roots of P(x) + 1 = 0
 O2 ds eksy = 
32 2 let P(x) + 1 = (x – a) (x – b) (x – c) q(x)
5 25 .....(i)
 dqy eksy = 10 +  where q(x) is some polynomial with integral
2 2 coefficients. Let m be an integral roots of
'
 PH2 = P x H dk eksy fHkUu p(x). Then (i) become
T 2
1 = (m – a) (m – b) (m – c) q(m)
10
=1x = 0.8 bar As a, b, c are distinct at least one of m – a,
25 / 2 m – b, m – c is different from 1 or – 1. This
is contradiction.
52. On opening the valve. gy- a, b, c lehdj.k P(x) + 1 = 0 ds ewy gSA
okWYo dks [kqyk djus ij ekuk P(x) + 1 = (x – a) (x – b) (x – c) q(x)
Pf × (10 + 30) = 5 × 10 + 3 × 30
.....(i)
140 tgk¡ q(x) iw.kkZad xq.kkadks ds cgqin gSA ekuk m,
=
40 p(x) ds iw.kkZad ewy gS rc (i) ls
7 1 = (m – a) (m – b) (m – c) q(m)
Pf = atm
2 pwfd a, b, c fofHkUu gS m – a, m – b, m – c esa
Consider reaction ls de ls de ,d tks 1 ;k –1 ls vyx gS ;g
vfHkfØ;k dk voyksdu djus ij
fojks/kkHkkl gSA
N2 (g) + O2 (g) 2NO (g)
t=0 a b 0 (moles) ¼eksy½ 3. Sn = cn2 ; Sn–1 = c(n – 1)2 = cn2 + c – 2 cn
a b a a Tn = 2cn – c ; Tn2 = (2cn – c)2 = 4c2 n2 + c2
finally vUrr% a 2  (moles) ¼eksy½
2 2 2 – 4c2n
total initial moles = a + b
dqy izkjafHkd eksy = a + b
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3
4c 2 . n(n  1)(2n  1) but ijUrq sin x = 3/4sinx – 1/4 sin 3x
Sum =  Tn2 = + nc2
6 so by (i) vr% (i) ls
– 2c2n (n + 1) 3 3 1 3 3
sin 10° = sin10° – , sin 50° =
2c 2n(n  1)(2n  1)  3nc 2  6c 2n(n  1) 4 8 4
=
3 1
sin50° –
nc 2 [4n2  6n  2  3  6n  6] 8
=
3 3 3 1
andvkSj sin (–70)° = sin(–70)° –
nc (4n  1)
2 2 4 8
= i.e. a, b, –c are three roots of
3
gy. Sn = cn2 ; Sn–1 = c(n – 1)2 = cn2 + c – 2 cn 3 3 1
f(t) = t – t +
Tn = 2cn – c ; Tn2 = (2cn – c)2 = 4c2 n2 + c2 4 8
– 4c2n 3 3 1
i.e. a, b, –c, f(t) = t – t + ds rhu ewy gSA
4c 2 . n(n  1)(2n  1) 4 8
;ksx =  Tn2 = + nc2 therefore, vr%
6
– 2c2n (n + 1) (i) a + b – c = 0
2c 2n(n  1)(2n  1)  3nc 2  6c 2n(n  1) 1
= (ii) ab(–c) = – & vkSj
3 8
3
nc [4n  6n  2  3  6n  6]
2 2
(iii) ab – bc – ca = –
= 4
3 –1 –1 –1
a +b =c +6
nc (4n  1)
2 2
=
3

4. log1/2 |sinx| = 2 – log1/2 |cosx|


log1/2 |sinx cosx| = 2
1 8. For domain izkUr ds fy, 21 – 4x – x2  0
|sinx cosx| =
4  x2 + 4x – 21  0
1  (x + 7) (x – 3)  0  x  [–7, 3]
sin2x = ± case-I : (fLFkfr ) : –7  x  –1 then rc 1–
2
21  4x  x 2  0
1
2  1  21  4x  x 2

1  2  x2 + 4x – 20  0 (x + 2)2 – 24  0
2
 (x + 2 + 2 6 ) (x + 2 – 2 6 )  0
Number of solution gyksa dh la[;k = 8.  x  [–2 – 2 6 , 2 6 – 2]
 x  [–2 –2 6 , –1)
2
5. n!(1 + n + 1 + (n + 1)(n + 2)) = n!(n + 2) . case-II : (fLFkfr ) : –1 < x  3 then rc
 either 7 divides (n + 2) or 49 divides n!
1  21 – 4x – x2
 ;k rks (n + 2), 7 ls foHkkftr gS ;k n! , 49 ls
 x2 + 4x – 20  0
foHkkftr gSA  x  (–, –2 – 2 6 ]  [2 6 – 2, )
n = 5, 12, 14
 x  2 6  2, 3
 
 5
 sin  0    [0, ]  x   , 
4 4    
x   2 2 6, 1  2 6  2, 3
 
1 5
x   ,    =
1 5
,=
4 4 4 4 10.
70 98 97
coefficient of x is C68 + C67 C66 +-----
+ 96
46
Hence x   , 
1 5 -------+ C16
46 46 46 47 48
4 4 = – C15 + C15 + C16 + C17 + C18 +-----
98
--------- + C68
46 47 47 48
= – C15 + C16 + C17 + C18 +--------------
7. sin30° = sin150° = – sin210° = 1/2 98
+ C68
46 99
we have
0
= – C15 + C68
sin(3 × 10) = sin(3 × 50°) = sin(3 × –70°) = 99
= C68 – C15
46

1/2 ...(i) So p = 68, q = 15

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 p + q = 83 33
x1  x 2  x 3  , x1x 2  x 2 x3  x 2 x1  0 ,
3 3 3 4
11. Let S(x) = x + (x + 1) + (x + 2) + ..... + 1
(x + 7)
3
x1x 2 x 3  
3 2
= 8x + 84x + 420x + 784 2
3 3 2
(2x + 7) = 8x + 84x + 294x + 343 ; x13  x2 3  x3 3  3x1x2 x3
 (x1  x2  x3 )(x12  x2 2  x3 2  0)
3 3 2
(2x + 10) = 8x + 120x + 600x + 1000
For x 0  ( x 1  x 2  x 3 )3
3 3
(2x + 7) < S(x) < (2x + 10)
 2x +7 < n < 2x +10
If n = 2x + 8  x y z 
3 2 13. G.E. =    

S(x) – n = 4(–3x + 9x + 68) ;  loga abc logb abc logc abc 
2
D = 9 –4(–3)(68) = 897
2 2  1 1 1 
29 = 841, 30 =900  
 No integer solution  x log abc  y log abc  z log abc 
 a b c 
If n = 2x + 9
3 2 (loga)2 x loga logb x loga logc y
S(x) – n = –24x – 66x + 55 ; D = 9636 ;    
2
98 = 9604, 99 = 9801
2 (logabc)2 y (logabc)2 z (logabc)2 x
 No integer solution loga logz (logb)2 y logb logc
 For m, n  0 given equation has no 2
 2

(logabc) (logabc) z (logabc)2
integer solution
Also S(x) satisfies S(–x–7) = –S(x) z logc logz z logc logb (logc )2
  
 No integer solution x (logabc)2 y (logabc)2 (logabc)2
for –x–7  0  x  –7. Hence to check
x = –6, –5, –4, –3, –2, –1

1
(logabc)2
(loga) 2
 (logb)2  (logc )2  2 loga logb  2 logb logc  logc loga 
3 3
S (–6) = –440 ; 7 = 343, 8 = 512
S (–5) = –216  m = –5, n = –6 14.
S (–4) = (–4)  m = –4, n = –4
3
2|3|4
2|3|4
S (–3) =4  m = –3, n = 4
3
648
S (–2) =6  m = –2, n = 6
3 
3 6 6 6
S (–1) = 440
2|3|4
2 00 00
12. Word QUEUE 0
E  2, Q , U - 2 0
= 18 6 7

4!
2 0 2 0 1
2!
=3
4 4/6/7
3!
2! 3× 6 × 6 = 108
=1
th
16 rank Total : 648 – 7 – 108 = 533
n = 16  f(x) = 2 (4x – 1) (x – 8x – 2)
2

1
 zeros are 4 – 18 , , 4  18 3 cos 20  4 sin20 cos 20
4 15. We have x =
sin20
2sin60 cos20  2sin40 sin80  sin40  2sin40
(0, 4)    1.
sin20 sin20

 x 
16. log2 xlog2 x  2  1  log2 x.log2  9  4
 64 
t  log2 x  | t + 1| +|t – 3| = 4
– 1  t  3  t + 1 – (t – 3) = 4
1
 x  8  x = 1, 2, 3, 4, 5, 6, 7, 8
2
y = f(x)

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-------------------------------------------------------------- 40m/s  m V m 60m/s
2m

Initial Final
2m 40 = 60 m + mv
V = 20 m/s
PART-II: PHYSICS Now KE = KEf – KEi =
1 2
m × (20) +
1
m
2 2
2 1 2
1 × (60) – 2m × (40)
19. S  a A t 2A …..(1) 2
2
1
1 KE = m (800)
S  aD t D2 …..(2) 2
2 1 1
KEi =
2
From Equation (1) & (2) 2m × (40) = m × 3200
2 2
t 2A aD KE 1
 Fractional change = 
t D2 aA KE i 4
t 2A g sin  g cos 
  25.
t D2 g sin  g cos 
a B (f1+f2)
tA g sin  g cos  A
 
tD g sin  g cos 
Independent acceleration of A and B would
1 1  3 be
 
2 1  3 A rFkk B dk vyx&vyx Roj.k
a1 = g (sin – 1 cos)
 1  3  4  4 3 and rFkk a2 = g (sin – 2 cos)
if 1 > 2, a1 < a2, so blocks will be in
 5 3  3 contact and will have common acceleration
3 ;fn 1 > 2, a1 < a2, bl izdkj nksuksa CykWd
 
5 leku Roj.k ls laidZ esa jgsxsA
(m1  m2 ) gsin   1m1gcos   2m2gcos 
a1  a2 
(m1  m2 )
22. R = 1m,7
 g[sin   (1  2 )cos ]
dv  2
at = = m/s
dt 2
at t = 0 ij, u = 0, 0 = 0 26.
a 
= t =
2
rad/s
R 2

v = u + att = 0 + ×2 =  m/s
2
 v2
=  m/s
2 2 2
at = m/s , ac = fman =0.6 × g + 0.2 × 4g
2 r
= 6 + 8 = 14 N
2
a= a2t  ac2 =  4 & 2T = 2g = 20
4 T = 10 N
 So system will be in equilibrium. Now
1  42 m/s
2
= fricition on 4 kg
2
Hence N = 4 Ans. vr% fudk; lkE;koLFkk esa gksxk vc 4 kg ij
?k"kZ.k
 1 f = 0.2 × 4 × 10
23. v= 2g1   =8N
 2 
friction on 1kg (1kg ij ?k"kZ.k)= T = T–8=2 kg
= g = 10 2.5 = 5

24. 27.

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T cos 60o

dp

60o 29. F = acost î + asint ĵ
dt
60o T / 2 F.P = 0
 3/2 magnitude of momentum :
V
T sin 60o
laosx dk ifjek.k %
= a2 cos2 t  a 2 sin2 t = a
mg 2
30. an = kt
T 3 mv 2
= ........(1) v2 2
2 ( 3 / 2) = kt
R
T
= mg .......(2) v= kR t
2
dv
Hence T = 2 mg , So (B) holds at = = kR constant fu;rkad
vr% T = 2 mg, (B) lgh gSA dt
2 a 1
From (1) & (2) V = 3 g/2 tan = t  2
2
(1) o (2) ls V = 3 g/2 an t
p = Ft v
3 9.8 1.6
V =   t
2
<p>  t.
V = 2.8 3 m/s . So (C) hold
V = 2.8 3 m/s . vr% (C) lgh gSA
8
2 (3g / 2) 31. aA = g [sin 45 – A cos 45] = , aB = g
ac = V /r = 2
( 3 / 2)
7
= 3 × g = 9.8 3 m/s
2 [sin 45 – B cos 45] =
2
 (D) holds 1
(D) lgh gSA aAB = aA – aB = g (B – A) cos 45 = ,
2
2 r 2  3 /2 2
t= = sAB =
v (3 g / 2) 1 2
t = 4/7  (A) holds.
Now vc sAB =
aAB t
2
 (A) lgh gSA 1 1 2
 2 = × t
2 2
t = 2 sec.
28. Acceleration of block is (CykWd dk Roj.k)
2
= 10 m/s
 displacement (foLFkkiu)
1 2 1 4 35.
s = at = × 10 × = 2m
2 2 10
Tension in the string is 40 N
Work done by gravity is
jLlh esa ruko 40 N gSA
xq:Ro }kjk fd;k dk;Z– 20 × 2 = – 40 J

To complete the vertical circle


1
g 1 = 5g 2 ; =5
2

Å/okZ/kj o`Ùk iw.kZ djus ds fy, g 1 = 5g 2


and work done by tension is 1
ruko }kjk fd;k dk;Z ; =5
2
40 × 2 = 80 J
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36. = 24 + 21.6 = 45.6 g
v2 = gy. 4NH3 + 5O2  4NO + 6H2O
F2
NTP ij O2 dk vko';d vk;ru
13.6 5
F1 =   22.4 = 22.4 L
v1= 5 17 4
m v12 ty dk mRikfnr Hkkj
F1 = 13.6 6
 =   18 = 21.6 g
17 4
m v22
F2 = H2O () dk vk;ru = 21.6 mL

( dH2O = 1000 Kg/m3 = 1 g/mL)
F1
 =5 13.6 4
F2 NO ds mRikfnr eksy = = = 0.8
17 5
-------------------------------------------------------------- NO dk mRikfnr Hkkj = 0.8  30 = 24 g
mRiknksa dk dqy Hkkj = mNO + mH2O
= 24 + 21.6 = 45.6 g
PART-III: CHEMISTRY
44. Any 3d-series element

c  1 1  45. (A) At TC, there is no distinction between


38.  = RcZ2  2  
  n (n  1)2  liquid and vapour state hence density of
liquid become equal to density of vapour.
 1  2n  2 (2n) 3   2P 
= RcZ2  2
 n (n  1)2   RcZ . 4  n  P 
  n (B) At TC, both   and  V 2 
 V  T  T
are equal to zero.
39. [(vrms)X] 546°C = [(vmp)Y]273°C
(C) Z = 3/8 for every gas at T C, and gases
3RTx 2RTY are more compressible than ideal gas
Mx MY 3  819 2  546 (A) TC ij] nzo rFkk ok"i voLFkk ds e/; dksbZ
= = M
9 Y foHksn ugha jg tkrk gSA bl izdkj] nzo dk
 MY = 4 amu ?kuRo] ok"i ds ?kuRo ds leku ¼cjkcj½ gks tkrk
gSA
h
40.  O2 =  P    2P 
2  32  KE1 (B) TC ij,   rFkk  2 
 V  T  V T
h
& He = 2  4  KE2
nksuksa 'kwU; ds cjkcj gSA
(C) izR;sd xSl ds fy, Z = 3/8 gksrk gS rFkk
 O2 4 KE 2 4  18 3 xSlsa] vkn'kZ xSl dh rqyuk esa] vf/kd lEihM~;
= 32 KE1 = 32  1 = 2 .
 He gksrh gSaA

42. (2) 47. SF4 St.NO = 5


hybrid = sp3d 
43. 4NH3 + 5O2  4NO + 6H2O distroted trigonal by pyramidal
Volume of oxygen required at NTP SiF4 St.NO = 4
13.6 5
=   22.4 = 22.4 L hybrid = sp3  Tetrehedral
17 4 gy. SF4 f=kfoe la[;k = 5
Mass of water produced
13.6 6
ladj.k = sp3d 
=   18 = 21.6 g fod`r f=kdks.kh; f}fijSfeMh;
17 4
volume of H2O () = 21.6 mL SiF4 f=kfoe la[;k = 4
( dH2O = 1000 Kg/m3 = 1 g/mL) ladj.k = sp3  prq"Qydh;
13.6 4
moles of NO produced = = = 0.8 49. CaCO3 , Na2S2O3, CaC2O4, KSCN,
17 5
Mass of NO produced = 0.8  30 = 24 g Ca3(PO4)2, Na2ZnO2 ends with 'ate'.
Total mass of products = m NO + mH O CaCO3 , Na2S2O3, CaC2O4, KSCN,
2
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Ca3(PO4)2, Na2ZnO2 ds vUr esa ',sV' gSA 53. 10 lines are obtained as a result of
th
electronic transition from 5 level to lower
50. I.E3 of Li2+= 2.3 × 10–18 × 9 J/atom levels and lines corresponding to UV
spectrum are as follows :
= 2.3 × 10–18 × 9 × 6 × 10 23 J/mole
bysDVªkWfud laØe.k ds ifj.kkeLo:i 5th Lrj ls
= 12.42 × 106 J/mole
= 12420 kJ/mole fuEurj Lrjks rd 10 js[kk,¡ izkIr gksrh gS rFkk
Now for the whole process js[kk,¡ fuEu izdkj UV LisDVªe ls lEcfU/kr gksrh
2 x 104 = I.E1 + I.E2 + I.E3 gS%
So I.E2 = 7000 KJ/mole 51,41,31,21
Ans. I.E2 = 7
Li2+ dh I.E3 = 2.3 × 10–18 × 9 J/atom
= 2.3 × 10–18 × 9 × 6 × 10 23 J/mole
= 12.42 × 106 J/mole
= 12420 kJ/mole 54. CO2 (two p-p bonds), H2SO4 (No p-p
vc lEiw.kZ izØe ds fy, bonds), P4O10 (No p-p bonds) and SO3
2 x 104 = I.E1 + I.E2 + I.E3
(One p-p bond).
vr% I.E2 = 7000 KJ/mole Sum = 2 + 1 = 3
mÙkj- I.E2 = 7 CO2 (nks p-p cU/k), H2SO4 (dksbZ p-p cU/k
ugha), P4O10 (dksbZ p-p cU/k ugha) o SO3 (,d
p-p cU/k).
5 3
51. N O3  N H4 ;ksx = 2 + 1 = 3
8e– + 10H+ + NO3–  NH4+ + 3H2O.
---- TEXT SOLUTIONS (TS) END ----
52. PV = nRT.
50 1
2.5 × = nmix × × 300.
3 12
5
So, nmix = .
3
mH2 mHe 5
Now, mH2+mHe= 5 and   .
2 4 3
5 10
On solving, mH2 = g and mHe = g.
3 3
Simplest mass ratio
5 10
= : =1:2=x:y
3 3
So, 2x – y = 2 × 1 – 2 = 0.

gy. PV = nRT.
50 1
2.5 × = nmix × × 300.
3 12
vr%, nmix = 5 .
3
mH2 mHe 5
vc, mH2 + mHe = 5 rFkk   .
2 4 3
5 10
gy djus ij, mH2 = g rFkk mHe = g.
3 3
nzO;eku dk ljyre vuqikr
5 10
= : =1:2=x:y
3 3
vr%, 2x – y = 2 × 1 – 2 = 0.

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