Solution - Act-2-Ja101, Ja02, Ja03-13.11.2022
Solution - Act-2-Ja101, Ja02, Ja03-13.11.2022
Solution - Act-2-Ja101, Ja02, Ja03-13.11.2022
ADVANCED PATTERN
CUMULATIVE TEST (ACT):02
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SOL01JAACT2210822-2
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TEXT SOLUTIONS (TS)
( a d) 2
PAPER-1 – (a – d) = 30
a
2 2 2
a + d + 2ad – a + ad = 30 a
PART-I : MATHEMATICS 2
d = 3a (10 – d)
d is an positive integer & divisible by 3
1. D0
& 10 – d > 0 hence d < 10
b – 4a(6) 0
2
d can be 3,6 or 9.
b – 24a 0
2
3
let ekuk y = 3a + b d=3 then a
7
y–b
0 then a 3
2
b – 24 d=6
3
d=9 then a 27
b – 8y + 8b 0
2
only d = 9 & a = 27 is feasible hence terms
b + 8b – 8y 0 , b R
2
will be
8 18 27 36 48
b=– =–4
2 & their sum = 129
Hindi four terms will be
8y 16 – 32 ( a d) 2
8y – 16 y – 2 a – d, a, a + d,
a
2.
2
f(x) = ax + 2bx + 4c - 16 ( a d) 2
– (a – d) = 30
Since pawfd D < 0 a
2 2 2
a + d + 2ad – a + ad = 30 a
2
d = 3a (10 – d)
d ,d /kukRed iw.kkZad gS rFkk 3 ls foHkkftr gSA
& 10 – d > 0 rFkk d < 10
d dk eku 3, 6 ;k 9 gks ldrk gSA
or 3
d=3 rc a
7
d=6 rc a 3
d=9 rc a 27
Since pawfd f(-2) = 4a - 4b + 4c – 16
= 4(a + c - b - 4) > 0
dsoy d = 9 vkSj a = 27 dsoy vr% in gSA
D 0 & f(2) 0 18 27 36 48
mudk ;ksx = 129
f(x) 0 x R
f(0) 0 4c 16 0 c 4
cos3 4cos3 – 3cos
= 4cos – 3
2
3. Let ekukfd am = 2, an = 31 5. =
cos cos
29
(n – m)d = 29 d = , which = 2(1+cos2) – 3 = 2cos2 – 1
nm = 2cos( – )– 1
is rational tks fd ifjes; gS = 2(coscos + sin sin) – 1 ........(1)
Also iqu% ar – am = (r – m) d
ar is rational (ar ifjes; gS½ Now vc a2 + b2 = 2 + 2coscos + 2sin
As each term is rational, sum to any sin
number of terms must be rational. cos3 2 2
so fromvr% (1) ls =a +b –2–1
pw¡fd izR;sd in ifjes; gS vr% fdrus Hkh inksa dk cos
;ksx ifjes; gksxkA
2 2
=a +b –3
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1
Sn 1
7. P x x 2 bx c n 1
P P 1 0; P x x P 1 x P 2
11. From the second equation, we have
Thusvr% P x x P 1 x P 2 3
sin2B sin2A ….. (i)
P 1 P 2 b; P 1 P 2 c
2
3
1 b c 4 2b c b nwljh lehdj.k ls sin2B sin2A ….. (i)
2
2
4b 2c 5 and from the first equality 3sin A
1 b c 4 2b c c
2
rFkk izFke vlfedk ls 3sin A
2
From eq (i) and (ii) one satisfied with = 1 – 2 sin B = cos 2B …..(ii)
lehdj.k (i) vkSj (ii) ls larq"V gksrk gSA Now vc, cos (A + 2B)
= cos A . cos 2B – sin A . sin 2B
1 3
b ; c 2 3
2 2 = 3 cos A . sin A – . sin A . sin 2A
2
2 2
= 3 cos A . sin A – 3 sin A . cos A = 0
8. case fLFkfr (i) x 2 (k 2)x k 2
,oa & 3
x kx (2k 1) are perfect square iw.kZ oxZ
2 2 A 2B or
2 2
gSA
fLFkfr (i) x 2 (k 2)x k 2 ,oa
x2 kx (2k 1)2 iw.kZ oxZ gSA
12.
2
sin 2
x 2 2 1 tan2 x
so vr% D = 0 D=0 1 tan x 2
1 tan x
2
(k 2) 4k 0
2 2
2 cos2 x sin2 x 2 2
k 4(2k 1) 0
2 2
2 2 2
2 sin2 x 1 2
k 2, k , 2
3 5 3 sin2 x
2 1 2
So vr% k 2
3 0 1
case (ii) x 2 (k 2)x k 2 and 1 2
2 1 1 or 1
x kx (2k 1) have both roots are
2 2
common
fLFkfr (ii) x 2 (k 2)x k 2 13.
2
f(x) = ax –(3+2a) x + 6
,oa x2 kx (2k 1)2 nksuksa ds mHk;fu"B ewy
gSA
1 (k 2) k2
1 k (2k 1)2
k 1
9. Sr r Sr Sr2 Sr r
= ax(x–2) – 3 (x – 2)
= (x – 2) (ax – 3) = 0
10. a2 – a1 = 4
a3 – a2 = 6 3
should [–4, –3)
an – an – 1 = 2n a
an – a1 = 4 + 6 + …………. 2n a 1 1 3
, a 1,
an n2 n 2 2 3 3 4 4
an n2 n
– + 11 = 0
2
1 1 1 14.
a n n 1 3 – 3 + 33 = 0 ……..(i)
3 2
0
– + 11 = 0
2
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2 – 2 + 22 = 0 ……..(ii)
3 2
22 77
9 2 2 36
6 8sec.
18
r 2
log3
Tr r 1 21. For block m1 :
18.
log3 r 1 log3 r 2 T – m1g = m1(0)
T = 10 N
log3 r 2 log3 r 1 For block m2 :
Tr
log3 r 1 log3 r 2 20 – 10 = 2a2
2
a2 = 5 m/s downwards
1 1 2
Tr Acceleration of pulley = 2.5 m/s
log3 r 1 log3 r 2 downwards
2
1 1 and acceleration of M is 2.5 m/s towards
T1 right
log3 2 log3 3
For block M :
1 1 20 = M × 2.5
T2
log3 3 log3 4 M = 8 kg.
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SOL01JAACT2210822-5
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gy. m1 nzO;eku ds fy, : | R T | | W | | R W | | T |
T – m1g = m1(0)
T = 10 N R2 + T2 – 2TR cos = W 2 R2 + W 2 = T2
m2 nzO;eku ds fy, : T>R
20 – 10 = 2a2 T > W.
2
a2 = 5 m/s uhps dh vksj
f?kjuh dk Roj.k = 2.5 m/s2 uhps dh vksj 28. Since acceleration is in x direction only,
velocity in y-direction will not change.
rFkk M dk Roj.k nka;h vksj 2.5 m/s2
When speed = 5 m/s
M ds fy, : Roj.k dsoy x fn'kk esa gS vr% y- fn'kk dk osx
20 = M × 2.5
ifjofrr ugh gksxkA
M = 8 kg.
tc pky 5 m/s gSA
22. vy = 2bx vx ay = 2bv 2x 52 = Vx2 + Vy2 = Vx2 + 42
Vx = ± 3m/s
Vx ux
vt vt Vx = ux + axt t =
v 8t ax
24. 2 2 = 9 v = 54 km/hr
10t 10 34
t1 = = 2.5 s
0.4
3 4
d d t2 = = 17.5 s]
25. tA = tB = –0.4
VA cos A VB cos B
VA cosA = VB cosB
u2 sin2 Rg
Since pqfd VA > VB 29. R= or 2 = sin2 < 1
g u
then rks A > B
option (C) there shall be two values of , that is 1
drift of A dk fopyu = (VA sinA)t and 90° – 1 for same range.
drift of B dk fopyu = (VB sinB)t It is obvious 1 and 90° – 1 are
VA > VB & A > B complementary
So drift of A is greater then B. ds nks eku gksaxs vFkkZr leku ijkl ds fy,
blfy, A dk fopyu B ls vf/kd gksxkA 1 vkSj 90° – 1
nks dks.k gksaxs tks fd ,dnwljs ds iwjd dks.k gSA
26. 2u sin 1
T1 = and
g
P
2usin(90 1) 2ucos 1
V ///
///
T2 = =
///
///
/
g g
B 2u2 sin21 2
T1 T2 = 2
= R
g g
A u
d 1 d 2
= 0 30. Let F be the force exerted by mass m on
dt dt mass M.
–vcos + u = 0 ekuk nzO;eku m }kjk nzO;eku M ij vkjksfir cy
P
F gSA
V 1 ///
/// FBD of mass M (nzO;eku M dk eqä oLrq fp=k)
///
///
/
2
B
A u
F = k1x1 = 2 × 3
32. t = 3 sec. 36. Applying the Newton's law for the system
x = 3 × 3 2 + 1 = 28 m fudk; ij U;wVu ds fu;e }kjk
t = 2 sec. x = 3 × 2 2 + 1 = 13 m F = mAaA + mB aB
Displacement foLFkkiu 20 = 2 × (– 5) + 5 × aB
= 28 – 13 = 15 m aB = 6 m/s2.
x 15m
Vavg = = = 15 m/sec.
t 1 sec __________________________________________________
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SOL01JAACT2210822-7
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Sol. feyk;s x;s KOH ds eksy = 3 × 1
4r R (r)
= 3 eksy
2
2 KOH + H2SO4 K2SO4+2HOH
2
izkjfEHkd eksy 3 3 0 0 (B)
vfHkfØ;k ds i'pkr~ eksy 3 – 3 3 – 1.5 1.5 3
= 0 = 1.5 r
(C) For radial nodes
2 1.5 3
[ H+ ] = = M 6 36 – 24
23 5 =
----------------------------------------------------------------- 2
11.44 2r
38. Molarity of Na2CO3xH2O = M =3± 3
106 18x 3a o
93 3
11.44 r= ao
Na2CO3xH2O dh eksyjrk = M 2
106 18x
9–3 3
first R.N. has r =
ao
Moles of Na2CO3.xH2O = Moles of H2SO4 2
Na2CO3.xH2O ds eksYk = H2SO4 ds eksYk nd 93 3
2 R.N. has r = ao
2
11.44 25 10 gy- (A) d{kd 3s gSA
106 18x 1000 = 1000 (0.1)
4r R (r)
x = 10
2
-----------------------------------------------------------------
2
(B)
39. Orbital angular momentum of electron
h h r
= l(l 1). 3.
2 (C) f=kT; uksMks (radial nodes) ds fy,
l=3 6 36 – 24
number of orientation =
2
= 2l + 1 = 2 × 3 + 1 = 7
2r
Sol. bysDVªkWu dk d{kd dks.kh; laosx =3± 3
3a o
h h
= l(l 1). 3.
2 93 3
r= ao
l=3 2
foU;kl dh la[;k 9–3 3
= 2l + 1 = 2 × 3 + 1 = 7 izFke R.N. ds fy, r = ao
2
-----------------------------------------------------------------
nd 93 3
2 R.N. ds fy, r = ao
CH2 2
-----------------------------------------------------------------
40. , ,
H2 /Ni
44. Moles of NaOH consumed when reacted
+
CH3 with H = 3×1 (because 3L of NaOH is
----------------------------------------------------------------- added with 1M conc.)
moles of H2SO4 present in sample = 1.5
(because every H SO has 2H+) 2 4
weight of H2SO4 in sample = 1.5 × 98 =
42. 147g
147
----------------------------------------------------------------- % purity = × 100 = 80
183.75
+
gy- H ds lkFk fØ;k ij [kpZ NaOH ds eksy = 3×1
43. (A) orbital is 3s.
(D;ksafd 1M lkUnzrk ds lkFk 3L, NaOH feyk;k
tkrk gSA)
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uewus esa mifLFkr H2SO4 ds eksy = 1.5 COOH
(D;ksafd izR;sd H2SO4 , 2H+ j[krk gSA)
uewus esa H2SO4 dk Hkkj = 1.5 × 98 = 147g (C)
COOH
147
% 'kq)rk = × 100 = 80 Cyclohexane-1,3-dicarboxylic acid
183.75
----------------------------------------------------------------- COOH
gy% (B*) HOOC COOH
45. 1 mol Cl2 2 mol KOH 1 mole
COOH
1 1
KClO mol KClO3 mol KClO4 esFksu VsVªk dkcksZfDlfyd vEy
3 4
277 COOH
Mole of KClO4 = 2 mol
138.5
Mole of Cl2 = 8 mol (C)
Mass of Cl2 = 568 g COOH
Mole of KOH = 16 mol lkbDyksgsDlsu-1,3-MkbdkcksZfDlfyd vEy
16 -----------------------------------------------------------------
V (KOH) = 10.67 L
1.5
Sol. 1 mol Cl2 2 mol KOH 1 mole 48. Phenol is less acidic than H2CO3 , So does
1 1 not liberate CO2.
KClO mol KClO3 mol KClO4
3 4 Sol. fQukWy] H2CO3 ls de vEyh; gSA vr% ;s CO2
277 xSl dk fu"dklu ugha djsxkA
KClO4 ds eksy = 2 mol -----------------------------------------------------------------
138.5
Cl2 ds eksy = 8 mol
40 1
Cl2 dk nzO;eku = 568 g 49. 1 X 50 X X 600
M X 12
KOH ds eksy = 16 mol
MX 40
16
V (KOH) = 10.67 L 20 1
1.5 2 X 50 X X 600
M y 12
-----------------------------------------------------------------
My 10
m n 40 10 50
-----------------------------------------------------------------
46.
Cl2
50. Energy of emitted photon
= 1.82 + 0.73 = 2.55 eV.
four monochloro structural products.
2 1 1
So, E = 13.6 × 1 2 – 2 for
n1 n2
gy % n1 = 2 & n2 = 4
Sol. mRlftZr QksVkWu dh ÅtkZ
= 1.82 + 0.73 = 2.55 eV.
pkj eksuksDyksjks lajpukRed mRiknA
2 1 1
----------------------------------------------------------------- vr%, E = 13.6 × 1 2 – 2 n1 ds fy,
n1 n2
COOH = 2 rFkk n2 ds fy, = 4
47. (B*) HOOC COOH -----------------------------------------------------------------
COOH
Methane tetra carboxylic acid 51. KClO3 (s) KCl(s) + 3/2 O2(g)
Thus, loss in mass is due to O2 escaped
and so mass of O2 formed is 0.384 g.
0.384
or Moles of O2 =
32
–2
= 1.2 × 10 mole
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SOL01JAACT2210822-9
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Moles of KClO3 =
2
× Moles of O2 PART-I MATHEMATICS
3 1. Let 2k and k be one of the roots of given
1.2 102 equations
Moles of KClO3 =
1.5 ekuk 2k rFkk k nh xbZ lehdj.k
–3 2 2
= 8 × 10 Mole So 4k –2k + 4a = 0, k –k + 3a = 0 solving
and mass of KClO3 decomposed k = 4a
–3
= 8 × 10 × 122.5 blfy, 4k2 –2k + 4a = 0, k2 –k + 3a = 0 gy
= 0.980 g
djus ij k = 4a
0.980
% of decomposition = × 100 Putting in first equation a = 1/16
4.9
= 20%
izFke lehdj.k esa a = 1/16 j[kus ij
Sol. KClO3 (s) KCl(s) + 3/2 O2(g)
vr% nzO;eku es gkfu eqDr gqbZ O2 ds dkj.k gksrh
gSA vr% cuus okyh O2 dk nzO;eku 0.384 g gSA
0.384
;k O2 ds eksYl =
32
–2
= 1.2 × 10 eksy
2
KClO3 ds eksYl = × O2 ds eksYl
3
1.2 102
KClO3 ds eksYl =
1.5
–3
= 8 × 10 eksy
vr% fo?kfVr KClO3 dk nzO;eku
–3
= 8 × 10 × 122.5
= 0.980 g
0.980
fo?kVu dk izfr'kr = × 100
4.9
= 20%
-----------------------------------------------------------------
-----------------------------------------------------------------
53. % of chlorine =
35 . 5 Mass of AgCl
100
143 . 5 Mass of substance
35 . 5 0 . 287
= 100 71 . 71 % .
143 . 5 0.099
-----------------------------------------------------------------
PAPER-2
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SOL01JAACT2210822-10
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3. given seq. is an A.G.P. vr% (a, b) ds 3 Øfer ;qXe laHko gSA
nh xbZ vuqØe lekUrj xq.kksÙkj Js<h gSA
2
3(3 + d)r, (3 + 2d)r
2
(3 + d)r = – 1 (3 + 2d)r = – 1 6. 2m 2n 48 24 3
2
then rc (3 + d) = – (3 + 2d) 2n 2mn 1 24 22 1
1 n=4 m–n=2 m–n=2
d = –2, – 6 r = – 1,
3 n=4 m=6
5
next term is vxyk in (3 + 3d)r3 = 3, –
9
7. for a b c a, b, c R
if ax + bx + c 0 then a > 0
2
4. x, xlog x , ylog y & (xy)log
10 10 10 xy
are in G.P.
and b – 4ac 0
2
log10 x, (log10 x)2 , (log10 y)2 , (log10 xy )2
bx + cx + a 0 then b > 0 and c – 4ab 0
2 2
are in A.P.
Let log10 x a log10 y b cx + ax + b 0 then c > 0 and a – 4bc 0
2 2
2 2 2
a, a , b , (a + b) are in A.P. a2 + b2 + c2 – 4(ab + bc + ca) 0
a (a b) a b2 2 2
a2 b2 c 2
a 2ab 0 4
ab bc ac
1
a = 0 or b Also since [(a – b) + (b – c) + (c – a) ] 0
2 2 2
2
Case – I a = 0 then b = 0 a2 b2 c 2
1, range is [1, 4]
hence x, y = 1 (1, 1) ab bc ca
1 2 1 ds fy, a b c a, b, c R
Case – II b then 2a = a + Hindi
2 4
2
8a – 4a – 1 = 0 ;fn ax2 + bx + c 0 rc a > 0 rFkk
4 32 b – 4ac 0
2
a
16
bx + cx + a 0 rc b > 0 vkSj c – 4ab 0
2 2
a2 + b2 + c2 – 4(ab + bc + ca) 0
Hindi x, x log10 x
, ylog10 y
& (xy) log10 xy
xq.kksÙkj Js.kh esa gSA
a2 b2 c 2
log10 x, (log10 x)2 , (log10 y)2 , (log10 xy )2 4
ab bc ac
lekUrj Js.kh esa gSA
rFkk pwafd [(a – b)2 + (b – c)2 + (c – a)2] 0
ekuk log10 x a log10 y b
a2 b2 c 2
1, ifjlj [1, 4] gS &
2 2 2
a, a , b , (a + b) lekUrj Js.kh esa gSA
ab bc ca
a (a b)2 a2 b2
a 2ab 0
1 8.
a = 0 ;k b
2
fLFkfr-I a = 0 rc b = 0
hence x, y = 1 (1, 1)
1 1 D 0 4b2 4(9b 14) 0
fLFkfr-II b rc 2a2 = a + 2
b - 9b + 14 > 0
2 4
2 (b - 2)(b - 7) > 0
8a – 4a – 1 = 0
4 32
a
16
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SOL01JAACT2210822-11
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b (, 2) (7, ) ------ (1)
b 2b
0 0 b 0 ------ (2)
2a 2
f(0) > 0
9b 14 0
14
b ------ (3)
9
14
(1) (2) (3) b , 2 (7, )
9
450 = 5(m – 1) m = 91
11. Given fn;k x;k gS, < a < p;
2
Let Tn is common to both for some n for
which m is an integer
ekuk Tn fdlh n ds fy, nksuksa mHk;fu"B gS
tcfd m ,d iw.kk±d gSA
171(n – 1)4 = 16 + (m – 1)5
5m = 4n + 2
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SOL01JAACT2210822-12
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Hence vr% n = 2, 7, 12,…..97 20
tan 3
17. Given fn;k 4
tan
3 tan2
4
1 3 tan2 2
R
2 H
2
1
tan2
11 =
T
1
sin2 2
12 u2 sin2
sin3 (2) Putting R j[kus ij =
Now vc, 3 4 sin2 g
sin
u2 sin2
1 8 H=
3 4 2g
12 3
2usin
T=
1 1 g
18. Let ekuk Ax ny nz
vav =
u
1 3cos2 = 4 m/sec
nx 2
A x nynz 21. For free fall mg cos = ma sin
n 2 x eqDr :i ls fxjus ds nkSjku mg cos = ma sin
nA
ny nz a = g cot
n 2 x 3
ny nz a=g×
Ae 4
n 2 y Taking A and B as a system
Be nxnz A rFkk B dks fudk; ysus ij
n 2 z ma sin
nxny
Ce A C Ma
n 3 x n 3 y n 3 z
nx ny nz
mg cos
A.B.C e
e 3 MB g MB
3g
a= =3
_________________________________________________ MB MA 4 MA
PART-II PHYSICS m
22. v cos t î sint ĵ v = 1 , s = v × t = 2m
5
19. For particle 1 d.k 1 ds fy, R
2
H
2
3 m/s 2 1 4 m/s
2
23. = Vav
V1 = 4 î – 10t ĵ T/2
For particle 2 d.k 2 ds fy, 24. tshort–path – tshort–time = 4
V 2 = –3 î – 10t ĵ d d
4
V1 V 2 = –12 + 100t = 0
2 v
v u
2 2
S
20. (1) vav = 0 t
T/2 dv
25.
dt
k v
v0
v 1/ 2 dv k dt
0
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SOL01JAACT2210822-13
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S V g
2 v 0 kt ; VA = = 0 tan = gksxkA vc ost rFkk CykWd dks ,d
t 3 3
vdv ,dy nzO;eku 2M ds cjkcj eku ldrs gSA
k v
ds
0 s
2 v3 / 2
m
v dv k ds s g
3 k =a 1
v0 0
3 a2
2M
26.
Using constraint relation (cfU/kr xfr ls)
a1 sin = a2 cos
a2 = a1 tan = g/3
FBD of wedge + block system (ost + CykWd
v
fudk; dk FBD)
53º
u Nsin
37º 53º
2M
vsin53º = u cos 37º
v=u Nsin = 2Ma1
–v cos53º = usin37º – gt
N 2Mg 4Mg
3 3 N
–u × = u – gt 2 3 3
5 5
6u FBD of rod (NM+ dk FBD)
gt =
5 Ncos
27. N
N
VW mg a2
VP mg – Ncos = ma2
mg –
N 3 mg
VPW 2 3
W E 4mg
N
3 3
4mg 4Mg
m = 3M
3 3 3
S
VP = 2
VPW VW
2
= 100 2 km/hr
500km 5
T= = h 29. w.r.t. to observer (Vx) football/obs.
VP 2 = 11 – 11 = 0
izs{kd ds lkis{k (Vx) = 11 – 11 = 0
28. If there is no relative motion between So Motion of the ball as seen from observer
wedge and block, acceleration of wedge + will be purely vertical with initial velocity 11
g
block system must be g tan = . Wedge 3 m/s upwards.
3
bl izdkj izs{kd ds lkis{k xsan 11 3 m/s osx
and block now can be assumed as single
mass 2M. ls Åij dh vksj xfr djrh gSA
;fn ost rFkk CykWd ds e/; dksbZ lkisf{kr xfr
ugha gSA rc ost + CykWd fudk; dk Roj.k g
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SOL01JAACT2210822-14
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11 3
m/s 22 m/s
11 3
60°
ball 11m/s
Seen by
Observer
11 m/s Observer
11 3 From wedge certain caf/kr xfr ls
m/s 22 m/s
a2 cos = a1sin ...........(iii)
11 3 From (i),(ii) & (iii) ls
60°
ball 11 m/s a2 = g sin2
izs{kd }kjk = 5 m/s2 .
izs{kd
11 m/s ns[ kk x;k
33.
30.
1 2
36. In the first situation s1 u1t at
2 l
1
izFke fLFkfr esa s1 u1t al t 2
2
1
= (8i 6j) + 10( j)t 2 = 8i 1j
2
1 2
In the second situation s2 u2 t a t
mg – N cos = ma2 ...........(i) 2 2
N sin = ma1 ...........(ii) 1
f}fr; fLFkfr esa s2 u2 t a2 t 2
2
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SOL01JAACT2210822-15
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1
= u2 t + (6i 8j) t 2 -----------------------------------------------------------------
2
s1 s2 u2 = 5i 5j
COOH
CH3 OH
__________________________________________________ 42.
NHCHO
C=O O
PART-III CHEMISTRY CH3
-----------------------------------------------------------------
37. 2 NO2 N2O4
43. n5
100 – x x/2 mol
x from graph (xzkQ ls)
2 2 n 1 2
mole fraction of N2O4 = =
x 3 n=5, 5––1 =2, = 2
(100 x)
2 n = 4, 4––1 =2, = 1
3x n = 3, 3––1 =2, = 0
200 – 2x + x = Total angular nodes = 2+1 = 3
2
200 = 1.5 x + x dqy dks.kh; uksM+ = 2+1 = 3
200 -----------------------------------------------------------------
x= = 80 = 8 Ans.
2.5
2Ke 2 Z
----------------------------------------------------------------- 44. V = ×
, so, atomic number (Z)
h n
38. X2O5 + 2CO X2O3
slope of the graph.
+ 2CO2
h 1
nactual = 10 = , slope of the graph
2qVm m
100
nexpected = 10 = 50 Therefore, statement (A) & (D) are correct.
20
2Ke 2 Z
50 2 Sol. V = × , vr%] ijek.kq Øekad (Z)
nCO required = = 100
1 h n
moles. xzkQ dk <+ky
mCO required = 100 × 28 = 2800 g 1
h
= 2.8 kg 3 kg = , xzkQ dk <+ky
gy X2O5 + 2CO X2O3 2qVm m
+ 2CO2 blfy,] dFku (A) rFkk (D) lgh gSA
nokLrfod = 10 -----------------------------------------------------------------
100
nvk'kkfUor = 10 = 50 45. n = 4, = 2 and rFkk m = 0
20 -----------------------------------------------------------------
nCO vko';d
50 2 47. All have same molecular formula but
= = 100 moles. different functional group.
1
mCO vko';d = 100 × 28 = 2800 g lHkh ;kSfxdksa ds v.kqlw=k leku gS ysfdu buds
= 2.8 kg 3 kg fØ;kRed lewg fHkUu gSA
----------------------------------------------------------------- -----------------------------------------------------------------
H H 49. n=4 4s 4p 4d
CH3
C —C C —CHO 4f
O m 0 1, 0, +1 2, 1, 0,
40. O , O , +1, +2 3, 2, 1, 0, +1, +2, +3
CH3 Cl3
C —C Orbitals having m 1 will be 0 in 4s, 2 in
O 4p, 2 in 4d and 2 in 4f
O
-----------------------------------------------------------------
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SOL01JAACT2210822-16
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m 1 j[kus okys d{kd 4s es 0, 4p es 2, 4d (F) In 100 g Ca 16 O 8 ……. or
40 16
es 2 rFkk 4f es 2 gksxsaA
Total orbital = 6 Ca 2 O 1 ………..
dqy d{kd = 6 5 2
2
n1 = 3. 1000 g esa Ca4O5……….
h -----------------------------------------------------------------
Orbital angular momentum = ( 1)
2
h h
= 2 = n2 . 52. Pressure of dry N2 gas at 287 K
2 2
n2 = 2. = 758 – 14 = 744 mmHg
Spin angular momentum V = 30 ml ; T = 287 K ; P = 744 mmHg
h h h
= s(s 1) = 3 = n3 744 30
2 4 2 atm L
n3 = 3. n = PV = 760 1000
RT Latm
n1 × n2 × n3 = 18. 0.821 287K
Kmol
gy- S-ijek.kq esa vfUre bysDVªkWu ds fy, : = 1 ,oa n = 1.25 × 10
–3
mol of N2
1 –3
s = + , n = 3. weight of N2 = 1.25 × 10 × 28
2
–3
n1 h = 35 × 10
d{kk dks.kh; laosx = . n1 = 3.
2 % composition of N2
h
d{kd dks.kh; laosx = ( 1) 35 10 –3
2 = 100 = 19.02 % 19 %
h h 0.1840
= 2 = n2 . n2 = 2.
2 2 -----------------------------------------------------------------
h h
pØ.k dks.kh; laosx = s(s 1) = 3 O
2 4
h 53. Methyl format esfFky QkWesZV H–C–O–CH3
= n3 n3 = 3.
2 -----------------------------------------------------------------
n1 × n2 × n3 = 18.
-----------------------------------------------------------------
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SOL01JAACT2210822-18
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SOL01JAACT2210822-19
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029