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48 views6 pages

f4 Chemistry Series 5

Uploaded by

mohammadavuru49
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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THE UNITED REPUPLIC OF TANZANIA

REGIONAL ADMINISTRATION AND LOCAL GOVERNMENT


JOIN THE REVOLUTION PROGRAM
FORM FOUR SERIES No.05
CHEMISTRY 1
TIME 3HRS

INSTRUCTIONS
 This paper consists of section A, B and C with total number of eleven (11)
questions.
 Answer all questions in the space provided
 All writing must be in black or blue pen except for diagrams which must be
in pencil.
 Write your examination number at the top right corner of every page
 The following atomic masses may be used; H = 1, 0 = 16, S= 32, Cl = 35.5, Na
= 23, C = 12, Ag = 108, N =14
SECTION A (16 marks)

Answer ALL questions in this section


1. For each of the following item (i)-(x) choose the correct answer from among
the given alternatives and write its letter beside item number in the answer
booklet provided.
(i) Steam and methane can react and produce hydrogen gas according to the
following equation.
𝐶𝐻4 (𝑔) + 𝐻2 𝑂 𝑔 → 𝐶𝑂2 𝑔 + 3𝐻2 𝑂 𝑔
The volume of methane needed to produce 150cm 3 of hydrogen at the same
conditions will be.
A. 25 cm 3
B. 50cm3
C. 150cm 3
D. 75cm3
E. 100cm 3

(ii) When methane undergoes substitution reaction with excess chlorine. What is
the final product?
A. Tetrachloromethane (CCl 4)
B. Monochloromethane
C. Dichloromethane
D. Chloromethane
E. Trichloromethane (CHCl 3)

(iii)Mr nobody want to prepare the standard solution of Sulphuric acid (oil of
vitriol), accidentally, the acid spilled on the skin. Which action should be taken
immediately after concentrated sulphuric acid spilled on the skin?
A. It should be neutralised with concentrated NaOH
B. It should be rinsed off with large volume of running water
C. Should be neutralized with social mgco3
D. It should be neutralised with dilute KOH
E. The affected area should be wrapped tightly and shown to a medical
health provider.

(iv) Mbuga added acid into water during dilution process in order to prepare
standard solution of that acid. What will happen as acid being added to the
water.
A. the acid becomes more acidic and it's PH goes down.
B. the acid becomes neutral and its PH becomes 7
C. the acid becomes less acidic and its PH goes down
D. the acid becomes less acidic and its PH geos up
E. the acid becomes more acidic and its PH goes up
(v) An organic compound has an empirical formula CH. The relative molecular
mass of the compound is 28. The molecular formula of the compound is:-
A. C2H2
B. C2H4
C. C2H6
D. C3H6
E. C7H16

(vi) Which of the following is true when a mixture of bromine and methane is left
in darkness?
A. Ethane and hydrogen bromide are formed
B. Hydrogen bromide and bromo methane are formed
C. There is no visible reaction
D. Bromine id decolourized
E. None of the above

(vii) Students from UBN Secondary School prepare chlorine gas in the laboratory.
When Chlorine gas is bubbled through distilled water by one of the student; the
distilled water turn pale yellow. Which of the following equations represents the
reaction?
A. 𝐶𝑙2 𝑔 + 𝐻2 𝑂 𝑙 → 𝐶𝑙2 . 𝐻2 𝑂(𝑎𝑞)
B. 𝐶𝑙2(𝑔) + 𝐻2 𝑂 𝑙 ⇌ 𝐻𝐶𝑙(𝑎𝑞 ) + 𝐻𝑂𝐶𝑙 𝑎𝑞
C. 2𝐶𝑙2(𝑔) + 2𝐻2 𝑂 𝑙 ⇌ 4𝐶𝑙(𝑎𝑞 ) + 2𝐻2 𝑂(𝑎𝑞 )
D. 𝐶𝑙2(𝑔) + 2𝐻2 𝑂 𝑙 ⇌ 2𝐻𝑂𝐶𝑙(𝑎𝑞 ) + 𝐻2(𝑔)
E. 𝐶𝑙2(𝑔) + 𝐻2 𝑂(𝑎𝑞 ) ⇌ 𝐻𝐶𝑙(𝑙) + 𝐻𝑂𝐶𝑙(𝑙)
(viii) Which of the following can be used in liming?
A. Calcium hydroxide and Calcium oxide
B. Magnesium oxide and Sodium hydroxide
C. Calcium oxide and Sodium hydroxide
D. Magnesium hydroxide and Sodium oxide
E. Magnesium carbonate and calcium carbonate.

(ix) One of the following is a major components photo chemical sources:


A. Ozone and nitrogen dioxide
B. Particulate matter and Ozone
C. Carbon monoxide and particulate matter
D. Nitrogen dioxide and carbon dioxide
E. Ozone Vocs and oxide of nitrogen
(x) Which of the following substances occurs where its dissolution in water causes
permanent hardness of water.
A. Na2Co3
B. NaCl
C. MgCo3
D. CaSo4
E. CaCo3
LIST A LIST B
(i) Burns with Golden yellow flame A. Lead
(ii) Bluish green flame B. Calcium
(iii) Melts easily but not show definite C. Zinc
colour D. Iron
(iv) Burns with yellow sparks E. Potassium
(v) Burn with Basic red flame F. Magnesium
(vi) Pale blue flame G. Copper
H. Sodium

SECTION B (54 Marks)


Answer ALL questions in this section
3. About 2.65g anhydrous sodium carbonate were placed in a 250cm3 flask and
the volume made to the mark with distilled water. Msaki pipette 25.00cm 3 of this
solution and titrate with 23.00cm 3 of sulphuric acid to reach equivalent point. Find
the mass of the pure acid present in a litre solution.

4.(a) What mass of FeSO4 . 7H2 O, do you need to Dose Anemic cat with 50mg of
ion?
(b)The density of 𝑂2 at 0°C and 02 and 1atm is 1.429g/v. Calculate the molar
volume of the gars.

5.(a) The diagrams below represent in laboratory of collecting gases in the


laboratory.

A. B. C.
(i) Name the method A, B and C
(ii) State with reason(s) the most suitable method for collecting each of the
following gases: oxygen, chlorine, Sulphur dioxide, hydrogen and carbon
dioxide.

(b) Write an ionic equation for each of the following reactions:


(i) Laboratory preparation of ammonia.
(ii) Oxidation of aqueous Iron (II) chloride by Chlorine.

6. Study the following chart then use it to answer questions that follow:

(a) Name the compound A and B


(b) Name the reagent involved in 2,3 and 4.
(c) Write the chemical equation for the:
(i) Combustion of CH3 CH2 OH
(ii) Conversion of CH2=CH2 to CH3CH2OH

7.(a) When nitrogen dioxide gas is passed over heated copper it oxidizes Copper
to its high oxide and itself, it is reduced to nitrogen gas. How many nitrogen
molecules will be produced if 25.65 of copper were used at s.t.p?
(b)Complete and balance the following equations.
(i) 𝐴𝑔𝑁𝑂3 𝑠 ∆
(ii) 𝑁𝑎2 𝐶𝑂3 + 𝐶𝑎(𝐻𝐶𝑂3 )2(𝑎𝑞 ) ⟶
(iii) 𝐶𝑎(𝑂𝐻)2(𝑎𝑞 ) + 𝐶𝑂2(𝑔) 𝑒𝑥𝑐𝑒𝑠𝑠 + 𝐻2 𝑂(𝑙) →
(iv) 𝑁𝑎𝐶𝑙(𝑔) + 𝐻2 𝑆𝑜4(𝑎𝑞 ) ⟶

8.(a) Chemistry is a career subject. The knowledge obtained from chemistry


lesson can be used to solve various problems in the fields. You as a chemist
mention only one method that can be used to prevent each of the following
from rusting.
(i) Nuts and Screws in an aeroplane
(ii) Iron sheet for roofing
(iii) Body of a car.
(b)How many Coulombs are there required to liberate 8g of calcium?
(c) Calculate the oxidation number (state) of the following elements.
(i) Nitrogen in 𝐶𝑎 𝑁𝑂3 2
(ii) Carbon in 𝐶𝑂32−

SECTION C(30 Marks)


Answer any two question from this section.

9. Form three students of certain secondary School prepared acid solution by


dissolving 10.08g of hydrated ethanedioic (oxalic) acid in distilled water to make
500cm3 of this solution. 25cm 3 of this solution was titrated against 20cm3 solution
containing 4g of sodium hydroxide in 250cm 3 of the solution. Showing your
procedure clearly.
(i) Calculate the value of X in hydrated ethane dive-acid H2 C2 O4 . XH2 O
(ii) Calculate the percentage by mass of water of crystallization in
H2 C2 O4 . XH2 O
(iii) Suggest the suitable indicator for the titration between sodium hydroxide
and oxalic acid.

10. A blast furnace is used in the chemical reduction of iron ore( haematite) into
ion metal, with the aid of chemical reactions equations, Briefly explain all the
important steps involved in the blast furnace (diagram is not required).

11.(a) The volatile liquid mercaptan, 𝐶2 𝐻6 𝑆 of the most odoriferous substance


known. It is sometime added to natural gas to make gas leaks detectable. How
many 𝐶2 𝐻6 𝑆 molecules are contained in a 1.091L sample? The density of liquid
mercaptan is 0.849g/ml
(b) What mass of K 2 or O4 is needed to prepare exactly 0.2500L of a 0.250m
K a CrO4 solution in water.

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