Chemistry
Chemistry
Topic Page
MATTER 2
METHODS of SEPARATING MIXTURES 3
FUNDAMENTAL CHEMICAL LAWS 4
THE SUBATOMIC PARTICLE 4
PERIODIC TABLE TRENDS 5
ATOMIC NUMBER, MASS 6
NUCLEAR FAMILIES 6
ELECTRONIC CONFIGURATION 7
QUANTUM NUMBERS 8
MOLECULES AND ION 9
KINDS OF FORMULAS 10
TYPES OF CHEMICAL BONDS 10
MOLE CONCEPT 10
CONCENTRATION OF SOLUTION 11
ACID AND BASES 11
PH AND POH 11
ACID-BASE THEORIES 12
Dalton's Law of Partial Pressure 12
GRAHAM'S LAW OF DIFFUSION 12
RADIOACTIVITY 13
NUCLEAR REACTION 13
Review Problem 14
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MATTER
substance that forms physical objects, has mass and occupies space.
STATES of MATTER
• Solid composed of particles that are tightly
packed and have a regular arrangement. It has
definite shape and volume.
• Liquid - composed of particles whose
arrangement and packing are somewhere
between those in solid and gas. It has definite
volume but no specific shape
• Gas - composed of particles with no regular
arrangement and no appreciable packing. It has
no definite shape or volume (it takes on the
shape and volume of its container).
• Plasma - an ionized gas consisting of positive ions and free
electrons in proportions
• BEC (Bose-Einstein Condensate) formed - when a gas of bosons
at low densities is cooled to temperatures very close to absolute
zero (-273.15 °C)
2
METHODS of SEPARATING MIXTURES
• Filtration
separating an insoluble solid from a liquid through the use of a
porous material.
• Evaporation
separating components of a solution by heating until the solvent
evaporates, leaving the solid residue.
• Simple Distillation - similar to evaporation, but vapor is collected
by condensation.
• Fractional Distillation - separating miscible liquids
miscible - (of liquids) forming a homogenous mixture when
combined
• Chromatography separates complex mixtures; stationary phase
and mobile phase.
3
FUNDAMENTAL CHEMICAL LAWS
• Law of Conservation of Mass - Mass is neither created nor
destroyed in a chemical reaction.
4
• Ernest Rutherford Nucleus and Gold Foil – Experiment
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ATOMIC NUMBER, MASS
𝐴=𝑁+𝑍
𝑛𝑜. 𝑜𝑓 𝑒 + = 𝑛𝑜. 𝑜𝑓 𝑝+
• Atomic Number (Z) - the number of protons in the nucleus of
each atom of an element
• Mass Number (A) total number of nucleons (mass-contributing
subparticles) present in the nucleus of an atom;
NUCLEAR FAMILIES
• Isotopes - equal number of protons
𝐸𝑥. 𝐼1 𝐻1 , 𝐼 2 𝐻1 , 𝐼 3 𝐻1
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ELECTRONIC CONFIGURATION
Electron Configuration describes how electrons are distributed
among the various orbitals.
Ex: 𝐻𝑒1𝑠²
Where;
𝐻𝑒 = The thing we are finding the electron
configuration for
2 = # of electrons in the orbital
1 = Level
s = orbital
QUANTUM NUMBERS
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• Angular Momentum Quantum Number (l)
indicates number of subshells and shape of orbital
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• Aufbau Principle - building-up principle; electrons fill the orbitals
starting at the lowest available energy levels before filling higher
levels.
MOLE CONCEPT
• STOICHIOMETRY - A branch of chemistry dealing with the
quantitative relationship between constituents in a chemical
substance.
• Mole (n) the amount of substance that - contains as many
elementary entities (atoms, molecules, ions, etc.) as there are
exactly 12 grams of the
Where;
carbon-12 isotope.
𝑚 = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑒𝑙𝑒𝑚𝑒𝑛𝑡/𝑠𝑢𝑏𝑡𝑎𝑛𝑐𝑒
𝑀𝑀 = 𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 (𝑔/𝑚𝑜𝑙)
𝑚
𝑛=
𝑀𝑀 Note;
1 𝑎𝑚𝑢 = 1 𝑔/𝑚𝑜𝑙
1 𝑚𝑜𝑙𝑒 = 𝑁𝑎 = [𝐶𝑂𝑁𝑆𝑇 24]
1 𝑎𝑚𝑢 = 𝑢 = [𝐶𝑂𝑁𝑆𝑇 17]
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CONCENTRATION OF SOLUTION
• Percent by Mass
𝑚𝑥
%𝑚𝑥 = × 100%
𝑚𝑥 + 𝑚𝑦
• Mole Fraction
𝑛𝑥
𝑍𝑥 =
𝑛𝑥 + 𝑛𝑦
• Molarity
𝑛𝑥
𝑀= Where;
𝐿𝐴 𝑥 = 𝑠𝑜𝑙𝑢𝑡𝑒
• Molality 𝑦 = 𝑠𝑜𝑙𝑣𝑒𝑛𝑡
𝑛𝑥 𝐴 = 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑚=
𝑘𝑔𝑦
PH AND POH
• pH (power of Hydrogen) Equation: 𝑝𝐻 = −𝑙𝑜𝑔[𝐻 + ]
• POH (power of Hydroxide) Equation: 𝑝𝑂𝐻 = −𝑙𝑜𝑔[𝑂𝐻 − ]
• pH and pOH relationship: 𝑝𝐻 + 𝑝𝑂𝐻 = 14
• Neutralization: 𝐻 + + 𝑂𝐻 − → 𝐻2𝑂
Note: A neutral solution has pH of 7
Where 𝐻 + and 𝑂𝐻 − are ionic concentration in Molars (M)
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ACID-BASE THEORIES
Theory Acid Base
Arrhenius Produce H+ in Produce OH- in
water water
Bronsted Lowry Proton (hydrogen Proton (hydrogen
ion) donor ion) acceptor
Lewis Electron pair Electron pair donor
acceptor (nucleophile)
(electrophile)
3𝑅𝑇
𝑣𝑟𝑚𝑠 = √ (𝑆𝐼)
𝑀𝑀
𝑟2 𝑀1 𝜌1
=√ =√
𝑟1 𝑀2 𝜌2
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RADIOACTIVITY
spontaneous emission of particles and/or radiation; discovered by
Henri Becquerel, termed by Marie Curie.
1. Alpha particle two protons and neutrons bound together into a
particle identical to a helium nucleus; can be blocked by a thin
sheet of paper
2. Beta particle - high-energy, high-speed electron beam due to
decay of free neutrons; can be blocked by metal foils (e.g.
Aluminum)
3. Gamma radiation - EM radiation of extremely high frequency;
biologically hazardous.
NUCLEAR REACTION
Transmutation chemical isotope to another - nuclear conversion of
one
1. Nuclear Fusion - coalescence of light nuclei.
Ex. energy from the sun
2. Nuclear Fission - fragmenting of a heavy nuclei
Ex. energy source in nuclear power plants
Chain reaction modern application of the fission process.
(U-235)
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Review Problems
1. Who is regarded as the Father of Modern Chemistry?
A. John Dalton
B. Antoine Lavoisier
C. Democritus
D. Dmitri Mendeleev
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C. Crystallization
D. Distillation
11. Which of the following nuclear families has the same number of
nucleons but different atomic numbers?
A. Isobars C. Isomers
B. Isotones D. Isotopes
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12. Which nuclear family best characterizes the relationship
between hydrogen to deuterium? (OCT 2017)
A. Isobars
B. Isotones
C. Isomers
D. Isotopes
14. This states that no two electrons can have the same set of four
quantum numbers.
A. Aufbau Principle
B. Hund’s Rule
C. Uncertainty Principle
D. Pauli’s Exclusion Principle
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17. It is the amount of substance that contains as many elementary
entities (atoms, molecules, ions, etc.) as there are exactly 12
grams of the carbon-12 isotope. (OCT 2016)
A. Avogadro’s Number
B. Molar Mass
C. Atomic mass unit
D. Mole
19. The formula for calcium nitrate is Ca(NO_3 )_2 What is its
approximate formula weight?
A. 64 amu Solution:
B. 164 amu 𝐶𝑎 = 2(20) = 40 𝑔/𝑚𝑜𝑙
C. 240 amu 𝑁 = 2(7) = 14 𝑔/𝑚𝑜𝑙
D. 310 amu 𝑂 = 2(8) = 16 𝑔/𝑚𝑜𝑙
𝐹𝑊 = 𝑀𝑀𝐶𝑎 + 𝑀𝑀𝑁 + 𝑀𝑀𝑂
𝐹𝑊 = 40(1) + 14(2) + 16(6)
𝐹𝑊 = 164 𝑔/𝑚𝑜𝑙 = 164 𝑎. 𝑚. 𝑢.
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21. A silicon chip used in an integrated circuit of a microcomputer
has a mass of 5.68 mg. How many silicon (Si) atoms are present
in the chip?
Solution:
A. 1.22x10^23 atoms 𝑚
B. 1.22x10^20 atoms 𝑚𝑆𝑖 × → 𝑛𝑆𝑖 × 𝑛𝐴 → 𝑎𝑡𝑜𝑚𝑆𝑖
𝑀𝑀
C. 6.73x10^20 atoms 5.68𝑚𝑔 (𝐶𝑂𝑁𝑆𝑇 24)𝑎𝑡𝑜𝑚𝑆𝑖
D. 6.73x10^23 atoms =( )( )
28 𝑔/𝑚𝑜𝑙 1 𝑚𝑜𝑙
𝑆𝑖
= 1.22 × 1020 𝑎𝑡𝑜𝑚𝑠
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24. How much oxygen is in 15g of carbon dioxide? (APR 2018)
A. 2.7g B. 12.3g C. 4.1g D. 10.9g
Solution:
1st Solution:
𝑚
(𝑚𝑋 ) ( ) → (𝑛𝑋 )(𝑚𝑜𝑙 𝑟𝑎𝑡𝑖𝑜) → (𝑛𝑂 )(𝑀𝑀) → 𝑚𝑂
𝑀𝑀
𝐶 = 12 𝑔/𝑚𝑜𝑙; 𝑂 = 16𝑔/𝑚𝑜𝑙
𝑀𝑀 = 1(12) + 2(16) = 44 𝑔/𝑚𝑜𝑙
15 𝑔𝐶𝑂2 2 𝑚𝑜𝑙𝑂 𝑔
=( 𝑔 ) ( ) (16 ) = 10.90 𝑔
44 1 𝑚𝑜𝑙𝐶𝑂2 𝑚𝑜𝑙
𝑚𝑜𝑙
2nd Solution:
𝑥 𝑔𝑂 16(2)𝑔𝑂
=
15 𝑔𝐶𝑂2 12(1) + 16(2)𝑔𝐶𝑂 2
Shift solve 𝑥 = 10.90 𝑔
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Board Problem!!!
If the atomic mass of nitrogen, hydrogen,
phosphorus and oxygen are 14.0067amu, 1.00 amu, 30.974 amu
and 16amu, respectively. What percent by mass of (NH_4)_3
PO_4 is nitrogen?
A. 8.11 % B. 20.78% C. 28.18% D. 42.93%
Board Problem!!!
In a biochemical assay, a chemist needs to add 3.81 g of glucose
(C6H12O6) to a reaction mixture. Calculate the volume in
milliliters of a 2.53 M glucose solution she should use for the
addition. C=12.01 g/mol; H=1.008 g/mol; O=16.00 g/mol
A. 8.36 mL
B. 7.36 mL
C. 5.63 mL
D. 4.63 mL
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28. A bottle of certain ceramic tile cleanser, which
essentially a solution of hydrogen chloride, contains 130g of HCl
and 750g of water. What is the percent by mass of HCl in this
cleanser?
Solution:
A. 15.7% 130 𝑔𝐻𝐶𝑙
B. 16.3% %𝑚𝐻𝐶𝑙 = × 100
130 𝑔𝐻𝐶𝐿 + 750 𝑔𝐻2 𝑂
C. 14.8%
%𝑚𝐻𝐶𝑙 = 14.8 %
D. 13.8%
30. These are chemical species that accepts an electron pair to make
a new covalent bond. (SEPT 2014 AND OCT 2015)
A. Electrophiles
B. Nucleophiles
C. Lewis acid
D. Lewis base
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32. A mixture of gases contains 4.46 moles of Ne, 0.74 mole of Ar and
2.15 moles of Xe. Calculate the partial pressure due to Xe if the
total pressure is 2.00atm at a certain temperature.
A. 0.585atm Solution:
B. 1.98atm 𝑃𝑋𝑒 = 𝑋𝑋𝑒 𝑃𝑇
C. 1.21atm 𝑛𝑋𝑒
D. 0.786atm 𝑋𝑋𝑒 =
𝑛𝑁𝑒 + 𝑛𝐴𝑟 + 𝑛𝑋𝑒
𝑛𝑋𝑒
𝑃𝑋𝑒 = ( )𝑃
𝑛𝑁𝑒 + 𝑛𝐴𝑟 + 𝑛𝑋𝑒 𝑇
2.15𝑋𝑒
𝑃𝑋𝑒 = ( ) 2 𝑎𝑡𝑚
4.46𝑁𝑒 + 0.74𝐴𝑟 + 2.15𝑋𝑒
𝑃𝑋𝑒 = 0.585 𝑎𝑡𝑚
33. How fast are the molecules of oxygen running into the sides of
your body at a room temperature of 30°C?
A. 728 m/s Solution:
B. 486 m/s
C. 515 m/s 3(𝐶𝑂𝑁𝑆𝑇 27)(30 + 273)
𝑉𝑟𝑚𝑠 = √
D. 576 m/s 2(16)
𝑉𝑟𝑚𝑠 = 486 m/s
34. Calculate the ratio of the rate of diffusion of hydrogen to the rate
of diffusion of oxygen. How fast does hydrogen diffuse than
oxygen? Given: Density of hydrogen is 0.0899 g/L and the density
of oxygen is 1.43 g/L.
Solution:
A. One
B. Two 𝑟𝐻 𝜌𝑂 1.43
= √ = √ =4
C. Three 𝑟𝑂 𝜌𝐻 0.0899
D. Four
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36. Which particle does not affect the atomic number of an atom?
(OCT 2015)
A. Alpha particle
B. Beta particle
C. Neutron
D. Proton
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