29-06-2025

1803CJA101001250011 JA

PART-1 : PHYSICS

SECTION-I(i)

1)

The final position of the particle if the particle starts from x = –15 m is :

(A) 10 m
(B) 5 m
(C) –5 m
(D) –15 m

2)

The position vector of a particle is given as

where a = 1 m/s, b = 1 m, c = m/s2, and d = 1m. The average velocity

during the interval t = 2s to t = 4s is :
(A) 2.5 m/s
(B) 5 m/s
(C) 0.75 m/s
(D) 1.25 m/s

3)

Two balls are thrown from the top of building of height H. Find ratio of horizonal
displacements at any time t.
(A) 1:1
(B) 1:2
(C) 2:1
(D) 1:3

4)

A ball is projected from point A with velocity 10m/sec. perpendicular to the inclined plane as in
figure. Range of the ball on the incline is

(A) 40√3m
(B) 20/13 m
(C) 13/20 m
(D) 40/3m

SECTION-I(ii)

1) At an instant particle-A is at origin and moving with constant velocity m/s and particle-B is
at (4, 4)m and moving with constant velocity m/s. Then at this instant:

(A) relative velocity of A and B is

(B) approach velocity of A and B is
(C) relative velocity of B w.r.t. A remains constant
(D) approach velocity of A and B remains constant

2) Two inclined planes (I) and (II) have inclination α and β respectively with horizontal, (where, α +
β = 90°) intersect each other at point O as shown in figure. A particle is projected from point A with
velocity u along a direction perpendicular to plane (I). If the particle strikes (II) perpendicularly at B,
then :

(A) time of flight = u/g sin β

(B) time of flight = u/g sin α
(C) distance OB = u2/2g sin β
(D) distance OB = u2/2g sin α

3) A projectile of mass 1 kg is projected with a velocity of m/s such that it strikes on the same
level as the point of projection at a distance of Which of the following options are correct?

(A) The maximum height reached by the projectile can be 0.25 m

The minimum velocity during its motion can be
(B)

(C)
The time taken for the flight can be
(D) Maximum angle of projection can be 60°.

4) Two persons A & B are situated at coordinates (300, 0)m & (0, 300)m respectively. At t = 0 they
start to move with speed 30 m/sec and 40 m/s in perpendicular directions as shown in figure. Then

choose correct statement(s) :

(A) Minimum distance between A & B is 60 m.

(B) Minimum distance between A & B is 100m.

(C)
Time taken for closest approach is sec.
(D) Time taken for closest approach is 10 sec.

5) Two boats A and B having same speed in still water are moving in a river ; A moves normal to
river current as observed from ground. B moves normal to river current as observed from the river
frame. Then :-

(A) For a ground observer, B is moving faster then A

(B) For a ground observer A and B are moving with same speed
(C) For an observer in river frame, B is moving faster than A
(D) For an observer in river frame A and B are moving with same speed
6) A stationary person observes that rain is falling vertically down at 30 km/h. A cyclist is moving up
on an inclined plane making an angle 30° with horizontal at 10 km/h. In which direction should the
cyclist hold his umbrella to protect himself from the rain?

(A)
At an angle with the inclined plane

(B)
At angle with the horizontal

(C)
At an angle with the inclined plane

(D)
At an angle with the vertical

7) Two swimmers A and B start swimming from different positions on the same bank as shown in
figure. The swimmer A swims at angle 90° with respect to the river to reach point P. He takes 120
seconds to cross the river of width 10 m. The swimmer B also takes the same time to reach the point

P. Then

(A)
Velocity of A with respect to river is

(B)
River flow velocity is

(C)
Velocity of B along y-axis with respect to earth is

(D)
Velocity of B along x-axis with respect to earth is

8) Four particles A, B, C and D are kept at the vertices of a square of side a . Now all of them
simultaneously start moving with same uniform speed ' v ' such that 'A' is moving towards 'B', B is
moving towards 'C' and so on.

the time particles will take to meet each other is

(A)

the time after the area of square formed by the particles becomes half is
(B)
(C)
the time particles will take to meet each other is
the time after the area of square formed by the particles becomes half is
(D)

SECTION-II

1) A particle moves along a straight line such that its displacement at any time t is given by : s = (t3
– 3t2 + 2)m The displacement when the acceleration becomes zero is (in meter) :-

2) A particle starting from rest moves in a straight line with acceleration as shown in the a-t graph.
Find the distance (in m) travelled by the particle in the first four seconds from start of its motion.

3) The figure shows a velocity-time graph of a particle moving along a straight line

Find distance covered by the particle (in m).

4) A man is moving downward on an inclined plane (θ = 37°) with velocity v0 and rain drops appear
to him moving in horizontal direction with velocity 2v0 towards him. If man increases his velocity to

0
2v then velocity of rain drops as observed by man is Find

5) A boat which has a speed of 5 km/hr in still water crosses a river of width 1 km along the shortest
possible path in 15 minutes. The velocity of the river water in km/hr is :
6) A man can reach directly across a stream of width 20 m in 4 minutes when there is no current and
in 5 minutes when there is a current. Find the velocity of the current in m/min.

PART-2 : CHEMISTRY

SECTION-I(i)

1)

Which of the following statement is CORRECT?

(A) In C3H4 (allene) all hydrogen atoms are in same plane

(B) In XeO2F2 both π bonds are pπ-dπ type
(C) Electronegativity of "C" in CH4 is more than C2H2
(D) In orbital, electron density in 'XY' plane is zero

2) Which of the following order in incorrect ?

(A) dC–Cℓ : CH3Cℓ > CF3Cℓ

(B) dO – O : H2O2 > O2F2
(C) dN – N : N2H4 < N2F4
(D) dC – C : C2H6 > C2F6

3) Which of the following is the correct order of ionisation enthalpy ?

(1) Be+ > Be (2) Be > Be+ (3) C > Be (4) B > Be

(A) 2, 3
(B) 3, 4
(C) 1, 3
(D) 1, 4

4) In a molecule of pyrophosphoric acid, the number of P — OH, P = O and P — O — P

bonds/moiety(ies) respectively are :

(A) 3, 3 and 3
(B) 2, 4 and 1
(C) 4, 2 and 0
(D) 4, 2 and 1

SECTION-I(ii)

1) Which of the following compound(s) is an exception of lewis octet rule?

(A) BF3
(B) PCl5
(C) NO2
(D) XeF2

2) Which of the following 'd' orbital(s) participate in the hybridistaion for Xe in the cationic part of
XeF6(s) :-

(A) dxy
(B)
(C)
(D)

3) Which one of the following compounds indicate correct direction of dipole moment?

(A)

(B)

(C)

(D)

4) Which of the following orders of atomic / Ionic radius is/are correct ?

(A) B < Ga < Aℓ

(B) Sc > Cu < Zn
(C) C < O < N
(D) Al+3 < Al+2 < Al+1

5) Which of the following statement(s) is/are correct?

(A) SO3 is more acidic than SO2

(B) Cs2O is more basic than Li2O
(C) P4O10 is more acidic than P4O6
(D) MgO< Al2O3 < SiO2< N2O5 (correct order of acidic strength)

6) If n + =5, then

(A) Number of possible orbitals are 4

Maximum number of electrons that can be filled with ms = +1/2 is 6 in an atom with above
(B)
condition
(C) for iron (Z = 26) atom, number of electron with above condition must be 1 only
(D) For Germanium (Z = 32), number of electron with above condition can be 5

7) Select the correct statement(s) :

(A) Bond angle order :

(B)
Bond length order :
(C) Bond order of S – O :

(D) Bond angle order : NH3 < PH3 < SbH3 < BiH3

8)

Which of the following statements is correct regarding phosphoric acid ?

(A) pπ–dπ back bonding exist between O and P.

(B) The anion is resonance stablized.
(C) It is a dibasic acid.
(D) Its pyro form has basicity equal to 3.

SECTION-II

1) Find maximum number of electrons in Al for which . (Atomic number of Al = 13).

2) B2H6, Si2H6, Al2Cl6, Be2H4, I2Cl6, BH3.NH3, ⋅CF3, ⋅CH3

Condition (1) : Species in which electron geometry at underlined atom is tetrahedral
Condition (2) : Species in which 3c-2e– bond are present
Condition (3) : Atleast four atoms are present in a plane then find multiplication of x and y
Here, x = number of species which is/are satisfying condition (1) and (3) both
y = number of species which is/are satisfying either condition (2) or (3)

3) Find the number molecules in which bond angle is changed due to back bonding w.r.t B/O/N.
H3BO3, B(OMe)3 , BF3, N(SiH3)3 , O(SiH3)2

4) What is the maximum number of atoms in one plane in XeO3F2 ?

5) In aqueous solution, how many following species have higher hydration energy than Li+.
Na+, K+, Rb+1, Be2+.

6) Successive ionisation energies data (in eV / atom) of an element of 2nd period is

IE1 IE2 IE3 IE4

120 133 167 719

Find the group number of element according to long form periodic table (1 – 18 convention). If your
answer is x, then find the value of 18x + 6

PART-3 : MATHEMATICS

SECTION-I(i)

1) Sum of all possible values of ‘x’ which satisfy the equation log3(x – 3) = log9(x – 1) is :

(A) 2
(B) 5
(C) 7
(D) 10

2)

The complete solution set of 2|log3x| + log3x ≥ 3 is :

(A)

(B)

(C)

(D)

3) If the cubic equation x3 – 5x2 + 7x – 3 = 0 has roots α, β, γ then

(A) α+ β + γ = –5
(B) αβ + βγ + γα = –7
(C) αβγ = –3
(D) α2 + β2 + γ2 = 11

4) Which of the following reduces to an integer?

(A)

(B)

(C)

(D) log48

SECTION-I(ii)

1) If x = log126, y = log2454, then which of the following is true ?

(A)

(B)

(C)

(D) xy + (5x – 2y) = 2

2) If , then which of the following are true (taking base 10)

(A) xyz = 1
(B) xaybzc = 1
(C) xb+cyc+aza+b = 1
(D) xyz = xaybzc

3) Which of the following is/are correct ?

(A)

(B)
If log1227 = x, then log616 = 4
(C)
(D) log35 > log1925

4) Let . Then N is :

(A) a natural number

(B) a prime number
(C) a rational number
(D) an integer
5) If , (α > 0, β > 0, α ≠ 1, β ≠ 1) then value of can be
-

(A) 7
(B) –9
(C) 9
(D) –7

6) If and , then the value of is

(A) 1
(B)
(C)
(D)

7) The equation has :

(A) one irrational solution

(B) no prime solution
(C) two real solutions
(D) one integral solution

8)

The equation (log10x + 2)3 + (log10x – 1)3 = (2log10x + 1)3 has

(A) One natural solution

(B) Two rational solutions
(C) No prime solution
(D) One irrational solution

SECTION-II

1) If roots of the equation x2 – 2x + 4 = 0 are α and β and roots of the equation x2 + bx + c = 0 are α6

– 6α5 + 12α4 – 8α3 + 2α + αβ + 2β + 58 and β4 – 4β3 + 8β2 – 6β + 2α –2 , then is equal to

2) If log2(x2 – 3) < 0 has the solution as then 100a is equal to

3) Sum of all solutions of 1 + log2 (x – 1) = log(x – 1)4 is

4) If the roots of the equation x2 – 2ax + a2 + a – 3 = 0 are real and less than 3, then find largest
integer value of 'a'.
5) If 2x2 + 7xy + 3y2 + 8x + 14y + λ have two linear factor, then find the value of λ.

6) The smallest integral value of ‘c’ for which (c – 3)x2 – 2cx + 3c > 6 is satisfied for all real values of
x is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C D B D

SECTION-I(ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C A,C A,B,C,D A,C A,D A,D A,B,C,D A,B

SECTION-II

Q. 13 14 15 16 17 18
A. 0.00 4.64 180.00 46 3.00 3.00

PART-2 : CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22
A. B C C D

SECTION-I(ii)

Q. 23 24 25 26 27 28 29 30
A. A,B,C,D B,C A,B,C A,B,D A,B,C,D A,D A,B A,B

SECTION-II

Q. 31 32 33 34 35 36
A. 9.00 28.00 4.00 4.00 1.00 240.00

PART-3 : MATHEMATICS

SECTION-I(i)

Q. 37 38 39 40
A. B C D C

SECTION-I(ii)

Q. 41 42 43 44 45 46 47 48
A. A,B,C,D A,B,C,D B,C,D A,B,C,D B,C C,D A,B,C,D A,B,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 1.00 200 4.25 1.00 8.00 7
 SOLUTIONS

PART-1 : PHYSICS

1)

xf = – 15 + Area

= – 15 + 2 +
= –15 + 10 = – 5m

2)

Since position vector

∴ x = at + b and y = ct2 + d

x = t and y =
Now average velocity.

Its magnitude is

= 5/4 m/s

3)

4)

5)

VAB = VA – VB
6)
X Y
ux = u uy = 0
ax = –g cos α ay = –g sin α
vx = 0
vx = ux + axt

7)
umin. = u cosθ

θ = 30°

8) In ground frame

In the grame of B

BC is the minimum distnace between A and B.

= 100 sin 37 =

x = 500 = AD
CD = 80
AC = 420
Time from A to D
9) (A)

(B)

10)

11)

12)

13)
t = 1s

=1–3+2=0

14)

v = 0 at t = 2 sec

= – 9.3 + 6
= – 3.3
0.67 + 0.67 + 3.30 = 4.64

15)
+3 × 20

16)
17)

Shortest possible path comes when velocity of boatman wrt ground comes perpendicular to
river current as shown in figure.

18)

Velocity is distance divided by time:

vman = 5 m/min
Effective velocity is distance divided by time:

The man's velocity, current's velocity, and effective velocity form a right triangle :

Rearrange to solve for

 Substitute the value :

PART-2 : CHEMISTRY

19)

The correct answer is option (B).

20) Fact

21)

(1) Be possesses a fully filled stable v configuration, or 2s2, whereas Be+ positive charge makes
the removal of an electron far more energy-intensive. Therefore, Be+ ionisation energy is
higher than Be.
(3) As atomic size falls and nuclear size rises during the course of the period, the nucleus
tightly holds the electron(s) from the valence shell. Ionisation energy is therefore larger
than Be.

22)

23)

BF3 Incomplete octet

PCl5- expanded octet.
No2 - octet e- molecule
XeF2 - expanded octet (compound of noble gas)

24) in solid state XeF6 exist as and F⊝

sp3d2 hybridization,
and orbitals are involved in sp3d2 hybridization.

25)

26) C > N > O

27)

The tendency of any compound to accept electrons is called acidity of the compound.
As we know that electronegativity is the property of the element to attract electron pairs.
Hence, the acidic character of the oxides “decreases down the group” because the
electronegativity decreases down the group. Similarly, when the metal is more
electropositive, it has more basic oxide in nature.
Metals form basic oxides and Non-metals form acidic oxides. As we move from left to right
across a period, the metallic character decreases and the non-metallic character increases.
Hence, oxides become more acidic as we move from left to right across a period.
Oxides in the higher oxidation state of an element are more acidic than that of the lower
oxidation state.

28)

If n + =5,
m = +1 or -1

n=4 l=1 4p

n = 3 l = 2 3d
no. of posible orbitals = 4

29) Correct statements :

(A) Incorrect → because bond angle of are equal
(B) Correct →

→ bond order = 1.5 Bond order ∝

 → bond order = 1.33(C) correct → B.O. of SO32⊝ → 1.33 → B.O. of
SO42⊝ → 1.5
(D) Incorrect → because bond angle of NH3 > PH3

30)
The P = O contain one pπ-dπ bond. The ion show resonance.

31)

Maximum Number of electrons in Al for which are 9.

32) x = B2H6, Si2H6, Al2Cl6, BH3.NH3 (4)

y = B2H6, Be2H4, Si2H6, Al2Cl6, I2Cl6, BH3.NH3, .CH3 (7)
x × y = 4 × 7 = 28

33) In H3BO3, bond angle changes due to back bonding. Similarly in B(OMe)3
bond angle changes due to back bonding. In N(SiH3)3 and O(SiH3)2 bond angle w.r.t.
oxygen changes due to back bonding.

34)
4 max atoms in one plane & 4 such planes.

35)

Ans is 1
 Hyd Energy
∝ charge
H.E. of

36) Group number is 13. So answer is 13 x 18 + 6=240

PART-3 : MATHEMATICS

37) (x – 3)2 = (x – 1)
⇒ x2 – 7x + 10 = 0
x = 2, 5
x = 2 is not possible

38)

If log x ≥ 0
x≥1
3log3 x ≥ 3
x≥3
If log x < 0
x<1
then – log3x ≥ 3

x≤

∴ Ans.

39) x3 – 5x2 + 7x – 3 = 0
α+β+γ=5
αβ + βγ + γα = 7
αβγ = 3
∵ (α+β+γ)2 = α2+ β2+ γ2+ 2 (αβ + βγ + γα)
α2 + β2 + γ2 = (α + β + γ)2 – 2(αβ + βγ + γα)
=25 – 2(7)
α2+ β2 + γ2 = 11 Ans Option (D)

40) Check option wise :

(A) (not integer)

(B)
(C)

(D)

41) x = log126, y = log2454

y = \(\frac{{\log (2.3)}}{{\log ({2^2}.3)}} = \frac{{\log 2 + \log 3}}{{2\log 2 + \log 3}}\)
(x – 1)log3 = log2(1 – 2x)
\(\frac{{\log 3}}{{\log 2}} = \frac{{1 - 2x}}{{x - 1}} = {\log _2}3\) ......(1)
\(y = {\log _{24}}54 = \frac{{\log ({{2.3}^3})}}{{\log ({{3.2}^2})}} = \frac{{\log 2 +
3\log 3}}{{\log 3 + 3\log 2}}\)
(y – 3)log3 = log2(1 – 3y)
\(\frac{{\log 3}}{{\log 2}} = \frac{{1 - 3y}}{{y - 3}} = {\log _2}3\) .......(2)
\(\frac{{1 - 2x}}{{x - 1}} = \frac{{1 - 3y}}{{y - 3}}\)
⇒ y – 3 – 2xy + 6x = x – 3xy – 1 + 3y
5x + xy – 2y = 2

Þ y – 3 – 2xy + 6x = x – 3xy – 1 + 3y
5x + xy – 2y = 2

42) Let logx = λ(b – c),

logy = λ(c – a)
logz = λ(a – b)
logx + logy + logz = 0 ⇒ log xyz = 0
⇒ xyz = 1
alogx + blogy + clogz = 0
⇒ xaybzc = 1
also (b+ c)logx + (c + a) logy + (a + b)logz = 0
⇒ xb+cyc+aza+b = 1

43) (B)

(D) log35 > log1925

log35 > 2log195

44)

L.H.S. = log224.log296 – log2192 log212

= log2(23.3).log2(25.3) – log2(26.3)log2(22.3)
= (log223 + log23) (log225 + log23) – (log226 + log23) (log222 + log23)
= (3 + log23) (5 + log23) – (6 + log23) (2 + log23)
= 15 + 8 log23 + (log23)2 – 12 – 8log23 – (log23)2
= 3 = R.H.S.

45)

46)

⇒
⇒ …(i)
⇒

⇒
⇒ …(ii)
Multiplying (i) and (ii)

⇒
⇒

47)

⇒
but log2x = t

∴
⇒ 3t2 – 5t – 2 = 0
⇒ (3t + 1) (t – 2) =

⇒
⇒ x = 2–1/3

⇒=
t=2
log2x = 2
x=4

48)

a3 + b3 = (a + b)3 ⇒ a = 0 or b = 0 or a + b =0
log10x + 2 = 0 log10x – 1 = 0
–2
x = 10 x = 10
2log10x + 1 = 0
x = 10–1/2

49) α6 – 6α5 + 12α4 – 8α3 + αβ + 2(α + β) + 58

= α6 – 6α5 + 12α4 – 8α3 + 66

then x2 + bx + c = 0
⇒ x2 – 4x + 4 = 0

50)

log2(x2 – 3) < 0 ⇒ x2 – 3 < 1 ⇒ x ∈ (–2, 2)

x2 – 3 > 0 ⇒

51) Domain : x – 1 > 0, x – 1 ≠ 1 i.e. x > 1, x ≠ 2

log(x –1) 4 = =
Substituting log2(x –1) = y , the equation becomes

1+y= i.e. y2 + y – 2 = 0 i.e. y = –2, 1

when y = –2 i.e. log2(x –1) = –2, then x =

when y = 1 i.e. log2(x –1) = 1, then x = 3

52)

(I) (ii) af (3) > 0 (iii)

53) The given equation ax2 + 2hxy + by2 + 2gx + 2fy + c = 0 represents a pair of lines,
if abc + 2fgh – af2 – bg2 – ch2 = 0, i.e., if

6λ + 2(7) (4) – 2(7)2 – 3(4)2 – λ =0

⇒ 6λ + 196 – 98 – 48 –

⇒ – 6λ = 196 – 146 = 50

⇒ = 50

⇒λ= =8

54) c > 3 …(i)

2
4c – 4(c – 3) (3c – 6) < 0
c2 – (c – 3) (3c – 6) < 0
c2 – [3c2 – 15c + 18] < 0
–2c2 + 15c – 18 < 0
⇒ 2c2 – 15c + 18 > 0
⇒ 2c2 – 12c – 3c + 18 > 0
⇒ (2c – 3) (c – 6) > 0

⇒ …(ii)
(i) ∩ (ii) ⇒
=7